Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

Self-regulated black hole accretion, the M–σ relation and the growth of bulges in galaxies     

Mitchell C. Begelman †  Biman B. Nath ‡ 《Monthly notices of the Royal Astronomical Society》2005,361(4):1387-1392

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A measurement of the 362 GHz absorption line of Mars atmospheric H₂O₂     

R.T Clancy  B.J Sandor 《Icarus》2004,168(1):116-121

The 362.156 GHz absorption spectrum of H₂O₂ in the Mars atmosphere was observed on September 4 of 2003, employing the James Clerk Maxwell Telescope (JCMT) sub-millimeter facility on Mauna Kea, Hawaii. Radiative transfer analysis of this line absorption yields an average volume mixing ratio of 18±0.4 ppbv within the lower (0-30 km) Mars atmosphere, in general accordance with standard photochemical models (e.g., Nair et al., 1994, Icarus 111, 124-150). Our derived H₂O₂ abundance is roughly three times greater than the upper limit retrieved by Encrenaz et al. (2002, Astron. Astrophys. 396, 1037-1044) from infrared spectroscopy, although part of this discrepancy may result from the different solar longitudes (L_s) of observation. Aphelion-to-perihelion thermal forcing of the global Mars hygropause generates substantial (>200%) increases in HO_x abundances above ∼10 km altitudes between the L_s=112° period of the Encrenaz et al. upper limit measurement and the current L_s=250° period of detection (Clancy and Nair, 1996, J. Geophys. Res. 101, 12785-12590). The observed H₂O₂ line absorption weakens arguments for non-standard homogeneous (Encrenaz et al., 2002, Astron. Astrophys. 396, 1037-1044) or heterogeneous (Krasnopolsky, 2003a, J. Geophys. Res. 108; 2003b, Icarus 165, 315-325) chemistry, which have been advocated partly on the basis of infrared (8 μm) non-detections for Mars H₂O₂. Observation of Mars H₂O₂ also represents the first measurement of a key catalytic specie in a planetary atmosphere other than our own.  相似文献   

Constraints on a planetary origin for the gap in the protoplanetary disc of GM Aurigae   总被引：1，自引：0，他引：1  

W. K. M. Rice  Kenneth Wood  P. J. Armitage  B. A. Whitney  J. E. Bjorkman 《Monthly notices of the Royal Astronomical Society》2003,342(1):79-85

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Astrometric signatures of self-gravitating protoplanetary discs     

W. K. M. Rice  P. J. Armitage  M. R. Bate  I. A. Bonnell 《Monthly notices of the Royal Astronomical Society》2003,338(1):227-232

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The nature of Europa's dark non-ice surface material: Spatially-resolved high spectral resolution spectroscopy from the Keck telescope     

John R. Spencer  William M. Grundy  Robert W. Carlson  Gary B. Hansen 《Icarus》2006,182(1):202-210

We present new 1.45-1.75 μm spectra of Europa's dark non-ice material with a spectral resolution (λ/δλ) of 1200, obtained by using adaptive optics on the Keck telescope to spatially separate the spectrum of the non-ice material from that of the surrounding ice-rich regions. Despite the great increase in spectral resolution over the previous best spectra of the non-ice material, taken with Galileo's near-infrared mapping spectrometer (NIMS) with λ/δλ=66, no new fine-scale spectral structure is revealed. The smoothness of the spectra is inconsistent with available laboratory spectra of crystalline hydrated salts at Europa temperatures, but is more consistent with various combinations of non-crystalline hydrated salts and/or hydrated sulfuric acid, as have been matched to the lower-resolution NIMS spectra.  相似文献   

Photoevaporation of protoplanetary discs – I. Hydrodynamic models     

R. D. Alexander  C. J. Clarke  J. E. Pringle 《Monthly notices of the Royal Astronomical Society》2006,369(1):216-228

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The D-CIXS X-ray mapping spectrometer on SMART-1     

M Grande  R BrowningN Waltham  D ParkerS.K Dunkin  B KentB Kellett  C.H PerryB Swinyard  A PerryJ Feraday  C HoweG McBride  K PhillipsJ Huovelin  P MuhliP.J Hakala  O VilhuJ Laukkanen  N ThomasD Hughes  H AlleyneM Grady  R LundinS Barabash  D BakerP.E Clark  C.D MurrayJ Guest  I CasanovaL.C d'Uston  S MauriceB Foing  D.J Heather  V FernandesK Muinonen  S.S RussellA Christou  C OwenP Charles  H KoskinenM Kato  K SipilaS Nenonen  M HolmstromN Bhandari  R ElphicD Lawrence 《Planetary and Space Science》2003,51(6):427-433

The D-CIXS Compact X-ray Spectrometer will provide high quality spectroscopic mapping of the Moon, the primary science target of the ESA SMART-1 mission. D-CIXS consists of a high throughput spectrometer, which will perform spatially localised X-ray fluorescence spectroscopy. It will also carry a solar monitor, to provide the direct calibration needed to produce a global map of absolute lunar elemental abundances, the first time this has been done. Thus it will achieve ground breaking science within a resource envelope far smaller than previously thought possible for this type of instrument, by exploiting two new technologies, swept charge devices and micro-structure collimators. The new technology does not require cold running, with its associated overheads to the spacecraft. At the same time it will demonstrate a radically novel approach to building a type of instrument essential for the BepiColombo mission and potential future planetary science targets.  相似文献   

Mesoscale linear streaks on Mars: environments of dust entrainment     

P.C Thomas  P Gierasch  D.S Miller  B Cantor 《Icarus》2003,162(2):242-258

Variable surface albedo features on Mars are likely caused by the entrainment and deposition of dust by the wind. Most discrete markings are associated with topographic forms or with regional slopes that serve to alter the effective wind shear stress on the surface. Some of the largest variable features, here termed mesoscale linear streaks, are up to 400 km in length and repeatedly occur in one of the smoothest regions of Mars: Amazonis Planitia. Their orientations and apparent season of variability as observed by Viking and Mars Orbiter cameras indicate linear streak formation by enhanced surface wind stresses during regional or local dust storms and during the initial stages of global dust storms. They provide an example of the ability of large-scale winds, without significant local enhancement, to initiate dust motion on Mars. The sizes and spacing of the linear streaks may be controlled by boundary layer rolls. The repetitive formation of these streaks, over a span of more than 11 Mars years, gives one measure of the stability of Mars’ eolian processes.  相似文献   

Doublet craters on Venus     

Cheryl M Cook  William F Bottke Jr. 《Icarus》2003,165(1):90-100

Of the impact craters on Earth larger than 20 km in diameter, 10-15% (3 out of 28) are doublets, having been formed by the simultaneous impact of two well-separated projectiles. The most likely scenario for their formation is the impact of well-separated binary asteroids. If a population of binary asteroids is capable of striking the Earth, it should also be able to hit the other terrestrial planets as well. Venus is a promising planet to search for doublet craters because its surface is young, erosion is nearly nonexistent, and its crater population is significantly larger than the Earth's. After a detailed investigation of single craters separated by less than 150 km and “multiple” craters having diameters greater than 10 km, we found that the proportion of doublet craters on Venus is at most 2.2%, significantly smaller than Earth's, although several nearly incontrovertible doublets were recognized. We believe this apparent deficit relative to the Earth's doublet population is a consequence of atmospheric screening of small projectiles on Venus rather than a real difference in the population of impacting bodies. We also examined “splotches,” circular radar reflectance features in the Magellan data. Projectiles that are too small to form craters probably formed these features. After a careful study of these patterns, we believe that the proportion of doublet splotches on Venus (14%) is comparable to the proportion of doublet craters found on Earth (10-15%). Thus, given the uncertainties of interpretation and the statistics of small numbers, it appears that the doublet crater population on Venus is consistent with that of the Earth.  相似文献