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131.
《Marine pollution bulletin》2012,64(5-12):73-76
We first used semipermeable membrane devices as samplers to evaluate concentrations of organochlorines and PAHs in the Brisbane River in 1998. Here we revisit this work and repeat the study a decade later in the same season (summer), also taking account of results from a similar study involving PAHs in the summer of 2001–2002. The accumulation of organochlorines and most PAHs in the samplers in the recent assessment was substantially less than in the 1998 deployment, suggesting that the ambient concentrations of these chemicals have decreased considerably over the last decade. In all cases there was high reproducibility of the mass of chemicals accumulated in the sampler. We used performance reference compounds in the later deployment, and assuming that the kinetics were similar in both deployment periods, we estimate that the concentration of dieldrin, the organochlorine found at highest concentrations, decreased from approximately 3.9 ng/L to about 1.4 ng/L. The decrease of most other analytes of interest including DDE and DDD was greater, potentially indicating that dieldrin is still entering the Brisbane River through run-off from urban areas where it was used widely for treatment of termites until 1995. DDT use in Australia ceased in the mid 1980s. 相似文献
132.
本文以21世纪初渤海湾大规模的围填海工程为背景,对2000-2015年典型年份的卫星遥感影像资料进行了岸线提取,并分析了其时空演变规律.以此为基础,建立了不同岸线及地形条件下的渤海湾水动力数值模型,计算结果与塘沽、黄骅港和东风港三个潮位观测站的实测数据吻合良好.模拟结果显示:渤海湾大规模围填海工程的建设使得三个主要工程区(曹妃甸工业区、天津港及黄骅港)附近的潮流运动更加剧烈,但对于渤海湾离岸潮流场的影响不大.M2分潮流速及流向变化明显,其最大流速方向与建筑物布置、深水航道航线方向一致.黄骅港挡沙堤的建设使其附近流场出现局部涡旋,导致潮流以旋转流的形式运动. 相似文献
133.
以解决挑流消能工在泄洪期间为提高消能率而加重下游雾化问题为目标,探究不同体型挑坎的下游雾化特性。通过水力学模型试验,对典型的非对称舌型坎、标准舌型坎、扭面贴坎和连续坎的下游水舌风分布、下游溅水雨强和不同液滴体积分布以及挑流水舌水力特性与冲刷特性进行了研究。研究表明:① 各种工况下,非对称舌型坎、标准舌型坎、扭面贴坎的下游水舌风风速均大于连续坎。② 对于非对称舌型坎,其溢洪道轴线左侧溅水强度大于右侧,其雨强左右两侧峰值差值最大为5.625 g/(m2·min);对于扭面贴坎,其溢洪道轴线右侧溅水强度更大,其雨强左右两侧峰值差值最大为45.125 g/(m2·min)。③ 随着距离水舌入水点长度增大,大粒径水滴数量和体积占比均剧烈下降;连续坎和舌型坎的挑宽均随着角度的增加而增加;冲坑深度随着角度的减小而增大。④ 在挑坎合适边墙侧设置扭面贴角能改善下游雾化危害,同时适当增加挑角可以减弱下游冲刷破坏。 相似文献
134.
Identifiability analysis enables the quantification of the number of model parameters that can be assessed by calibration with respect to a data set. Such a methodology is based on the appraisal of sensitivity coefficients of the model parameters by means of Monte Carlo runs. By employing the Fisher Information Matrix, the methodology enables one to gain insights with respect to the number of model parameters that can be reliably assessed. The paper presents a study where identifiability analysis is used as a tool for setting up measuring campaigns for integrated water quality modelling. Particularly, by means of the identifiability analysis, the information about the location and the number of the monitoring stations in the integrated system required for assessing a specific group of model parameters were gained. The analysis has been applied to a real, partially urbanised, catchment containing two sewer systems, two wastewater treatment plants and a river. Several scenarios of measuring campaigns have been considered; each scenario was characterised by different monitoring station locations for the gathering of quantity and quality data. The results enabled us to assess the maximum number of model parameters quantifiable for each scenario i.e. for each data set. The methodology resulted to be a powerful tool for designing measuring campaign for integrated water quality modelling. Indeed, the crucial cross sections throughout the integrated wastewater system were detected optimizing both human and economic efforts in the gathering of field data. Further, a connection between the data set and the number of model parameters effectively assessable has been established leading to much more reliable model results. 相似文献
135.
我国城市污泥产量巨大,如果得不到妥善处理将会严重影响环境综合治理。为了研究一种高效、资源、稳定的城市污泥处理技术,对城市污泥先进行生石灰消化处理,再通过正交试验,以无侧限抗压强度为指标,优选出生石灰、原料土、城市污泥、固化剂等的最佳配比,配制成一种新型城市污泥固化土,并对其力学特性进行试验研究。试验结果表明：研制的新型城市污泥固化剂固化处理城市污泥效果很好,重金属浸出量满足国家规范要求,污泥固化土强度随着养护龄期的增加而增大,且28 d后慢慢趋于相对稳定,碱性对强度有促进作用,建议固化土初始配制含水率最高控制在45%～50%之间。三轴剪切试验得到的应力峰值和结构屈服应力随着围压和养护龄期的增大而增大,环剪试验得到的残余强度与养护龄期及有效法向应力成正比,与剪切位移成反比。 相似文献
136.
《Applied Geochemistry》2005,20(3):627-638
Concentrations of total Hg and methylmercury (MMHg) in riparian soil, mine-waste calcine, sediment, and moss samples collected from abandoned Hg mines in Wanshan district, Guizhou province, China, were measured to show regional dispersion of Hg-contamination. High total Hg and MMHg concentrations obtained in riparian soils from mined areas, ranged from 5.1 to 790 mg kg−1 and 0.13 to 15 ng g−1, respectively. However, total Hg and MMHg concentrations in the soils collected from control sites were significantly lower varying from 0.1 to 1.2 mg kg−1 and 0.10 to 1.6 ng g−1, respectively. Total Hg and MMHg concentrations in sediments varied from 90 to 930 mg kg−1 and 3.0 to 20 ng g−1, respectively. Total Hg concentrations in mine-waste calcines were highly elevated ranging from 5.7 to 4400 mg kg−1, but MMHg concentrations were generally low ranging from 0.17 to 1.1 ng g−1. Similar to the high Hg concentrations in soil and sediments, moss samples collected from rocks ranged from 1.0 to 95 mg kg−1 in total Hg and from 0.21 to 20 ng g−1 in MMHg. Elevated Hg concentrations in mosses suggest that atmospheric deposition might be an important pathway of Hg to the local terrestrial system. Moreover, the spatial distribution patterns of Hg contamination in the local environment suggest derivation from historic Hg mining sites in the Wanshan area. 相似文献
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138.
基于系统学理论,构建区域旅游创新评价指标体系,将区域旅游创新系统分为创新能力系统和创新效率系统,采用离差算法,对广东省2007—2008年、2012—2013年、2017—2018年3个节点数据进行测算,分析各地市旅游子系统的创新协调水平,揭示出区域旅游创新协调能力“时间上波动、空间上差异”的时空特征。将广东省创新变化型城市分为四大类,发现旅游创新系统是自我调整和优化的系统,该系统能力子系统和效率子系统协调共生,系统协调值的时空变化符合“中心-边缘”的空间衰减规律和经济周期变化规律。 相似文献
140.
针对城市光伏屋顶类型多样致使样本不平衡,高空间分辨率卫星影像光伏屋顶提取问题,提出了一种材质和倾角属性筛选的方法。通过选取天津市南开区、红桥区、和平区、河东区卫星影像,利用标注于光伏屋顶的材质和倾角两种属性筛选出样本均衡的数据集,借助TensorFlow框架下集成的U-Net算法并合理设置参数,得到了光伏屋顶提取结果,并与未利用材质和倾角两种属性筛选情况下的光伏屋顶提取结果进行对比。试验结果表明：本文方法提取精度较高,尤其是对于研究区域不常见的光伏屋顶,能够提取出更为完整准确且边界清晰的结果。 相似文献