Physicochemical characteristics and levels of microbial activity in some florida peat swamps     

P.H. Given  W. Spackman  J.R. Imbalzano  D.J. Casagrande  A.J. Lucas  W. Cooper  C. Exarchos 《International Journal of Coal Geology》1983,3(1):77-99

Although microorganisms are certainly present in swamp and marsh peats, their geochemical role has not been demonstrated, in spite of their importance in determining the input to coalification processes. In order to obtain information on the gross level of microbial activity in the natural habitats, a broad-spectrum test for a type of enzyme important in the respiration of all organisms has been applied to cores of peat from a number of different environments in the Florida Everglades. In most cases, the respiratory activity in the upper layer is comparable to that in a fertile mineral soil, and this level of activity is found also at greater depths in several cores. In addition, some properties of the peat that tend to define their character as habitats for microorganisms were determined. pH values close to neutrality were observed at all sites. Chlorinity and total ionic strength naturally were high in the coastal swamps; seasonal variations in profiles in the brackish areas somewhat away from the coast suggested that some bulk flow of water through the peat into the porous limestone bedrock occurs in the rainy season. Eh profiles, regarded as empirical characterizations of environments, did differ considerably between saline and fresh water peats, though on a graphite indicator electrode were more positive than might have been expected in systems in which sulfate reduction was active. However, in these non-equilibrium systems, the potential recorded apparently depends on the nature of the electrode material used.  相似文献   

Regional Energy Demand Responses To Climate Change: Methodology And Application To The Commonwealth Of Massachusetts   总被引：1，自引：2，他引：1  

Anthony D. Amato  Matthias Ruth  Paul Kirshen  James Horwitz 《Climatic change》2005,71(1-2):175-201

Climate is a major determinant of energy demand. Changes in climate may alter energy demand as well as energy demand patterns. This study investigates the implications of climate change for energy demand under the hypothesis that impacts are scale dependent due to region-specific climatic variables, infrastructure, socioeconomic, and energy use profiles. In this analysis we explore regional energy demand responses to climate change by assessing temperature-sensitive energy demand in the Commonwealth of Massachusetts. The study employs a two-step estimation and modeling procedure. The first step evaluates the historic temperature sensitivity of residential and commercial demand for electricity and heating fuels, using a degree-day methodology. We find that when controlling for socioeconomic factors, degree-day variables have significant explanatory power in describing historic changes in residential and commercial energy demands. In the second step, we assess potential future energy demand responses to scenarios of climate change. Model results are based on alternative climate scenarios that were specifically derived for the region on the basis of local climatological data, coupled with regional information from available global climate models. We find notable changes with respect to overall energy consumption by, and energy mix of the residential and commercial sectors in the region. On the basis of our findings, we identify several methodological issues relevant to the development of climate change impact assessments of energy demand.  相似文献   

Forecasting extreme events in the tropical Indian Ocean sector climate     

Roxana C. Wajsowicz   《Dynamics of Atmospheres and Oceans》2005,39(1-2):137

Prospects for forecasting climate variability over the tropical Indian Ocean sector, specifically extreme positive events of the Indian Dipole Mode (IDM), with lead times of a season or more are investigated using the NASA Seasonal-to-Interannual Prediction Project (NSIPP) coupled-model system. The coupled system presents biases in its climatology over the Indian Ocean sector, which include (i) warmest sea-surface temperatures (SSTs) occurring in the central equatorial basin rather than on the eastside with the eastern (western) tropical SSTs up to 1 °C too cool (warm), (ii) a too northwest lying InterTropical Convergence Zonal over the ocean in boreal fall, (iii) a thermocline shallower (deeper) than observed west of Sumatra-Java (north of Madagascar), (iv) a delay of about a month in the onset (cessation) of the southwest (southeast) monsoon in the west (east) in boreal spring (fall). These biases affect the effectiveness of the SST-clouds-shortwave radiation negative feedback, the sensitivity of SST to wind-stress perturbations, and the character of equatorial coupled ocean-atmosphere modes. Despite these biases, ensemble hindcasts of the SST anomalies averaged over the eastern and western poles of the IDM for the decade 1993–2002, which included extreme positive events in 1994 and 1997/1998, are encouragingly good at 3-months lead. The onset of the 1997/1998-event is delayed by about a month, though the peak and decay are correctly timed. At 6-months lead-time, the forecast at the eastern pole deteriorates with either positive or negative false alarms generated each boreal fall. The forecast at the western pole remains good.  相似文献   

Soil erosion along a long slope in the gentle hilly areas of black soil region in Northeast China     

CUI Ming  CAI Qiangguo  ZHU Axing  FAN Haoming 《地理学报》2007,17(3):375-383

Characteristics of soil erosion change along a long slope in the gentle hilly areas in black soil region in Northeast China are discussed. A simplified slope model based on seg-ments was used to analyze the runoff data and soil erosion data observed between 2003 and 2004 over 10 field plots with different slope length in Heshan Farm, Heilongjiang Province. We found that soil erosion rate over long slopes in the black soil region changed alternatively along the slope and creates alternative zones of intensive erosion and week erosion.The exact place of each zone is different for different rainfall conditions. In a year with less and mild precipitation, rill cannot happen within the top 50 m, while in a year with large and inten-sive precipitation, rill can be formed starting even at 15 m from the top of the slope.  相似文献   

Acceleration response modification factors for nonstructural components attached to inelastic moment‐resisting frame structures     

Ragunath Sankaranarayanan  Ricardo A. Medina 《地震工程与结构动力学》2007,36(14):2189-2210

A statistical analysis of the peak acceleration demands for nonstructural components (NSCs) supported on a variety of stiff and flexible inelastic regular moment‐resisting frame structures with periods from 0.3 to 3.0 s exposed to 40 far‐field ground motions is presented. Peak component acceleration (PCA) demands were quantified based on the floor response spectrum (FRS) method without considering dynamic interaction effects. This study evaluated the main factors that influence the amplification or decrease of FRS values caused by inelasticity in the primary structure in three distinct spectral regions namely long‐period, fundamental‐period, and short‐period region. The amplification or decrease of peak elastic acceleration demands depends on the location of the NSC in the supporting structure, periods of the component and building, damping ratio of the component, and level of inelasticity of the supporting structure. While FRS values at the initial modal periods of the supporting structure are reduced due to inelastic action in the primary structure, the region between the modal periods experiences an increase in PCA demands. A parameter denoted as acceleration response modification factor (R_acc) was proposed to quantify this reduction/increase in PCA demands. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Comparison of Agricultural Impacts of Climate Change Calculated from High and Low Resolution Climate Change Scenarios: Part I. The Uncertainty Due to Spatial Scale   总被引：1，自引：1，他引：1  

L. O. Mearns  W. Easterling  C. Hays  D. Marx 《Climatic change》2001,51(2):131-172

We investigated the effect of two different spatial scales of climate change scenarios on crop yields simulated by the EPIC crop model for corn, soybean, and wheat, in the central Great Plains of the United States. The effect of climate change alone was investigated in Part I. In Part II (Easterling et al., 2001) we considered the effects ofCO₂ fertilization effects and adaptation in addition to climate change. The scenarios were formed from five years of control and 2 ×CO₂ runs of a high resolution regional climate model (RegCM) and the same from an Australian coarse resolution general circulation model (GCM), which provided the initial and lateral boundary conditions for the regional model runs. We also investigated the effect of two different spatial resolutions of soil input parameters to the crop models. We found that for corn and soybean in the eastern part of the study area, significantly different mean yield changes were calculated depending on the scenario used. Changes in simulated dryland wheat yields in the western areas were very similar, regardless of the scale of the scenario. The spatial scale of soils had a strong effect on the spatial variance and pattern of yields across the study area, but less effect on the mean aggregated yields. We investigated what aspects of the differences in the scenarios were most important for explaining the different simulated yield responses. For instance, precipitation changes in June were most important for corn and soybean in the eastern CSIRO grid boxes. We establish the spatial scale of climate changescenarios as an important uncertainty for climate change impacts analysis.  相似文献   

Calculation of the UV Absorption Spectra of As(III) Oxo- and Thio- Acids and Anions in Aqueous Solution and of PF3 in the Gas-phase     

J. A. Tossell 《Aquatic Geochemistry》2001,7(4):239-254

Changes in the UV spectra of As(OH)₃ solutions with variations in pH and temperature have recently been used to determine the temperature dependence of the pK_a of the acid. In previous studies I used quantum mechanical techniques to study changes in structure and vibrational spectra as a function of pH for arsenites and thioarsenites. I previously calculated UV spectra for ``molecular' minerals, like realgar As₄S₄. Here I use a number of different quantum mechanical methods, both Hartree-Fock and density functional theory based, to calculate the UV spectra for both a related simple well-characterized gas-phase molecule PF₃ and for As(OH)₃ and As(SH)₃ and their conjugate anions and some neutral and anionic oligomers in aqueous solution. For the monomeric species small numbers of water molecules have been explicitly included, in a supermolecule or microsolvation approach. I find that UV absorption energies accurate to a few tenths of an eV can be obtained both for gas- phase PF₃ and for neutral arsenious acid in aqueous solution, for which the UV absorption maximum is calculated to occur around 6.5 eV, consistent with experiment. Accurate calculation of the UV energies for arsenite anions in aqueous solution is much more difficult, since basis set size and solvation effects are considerably larger than for the neutral molecules, but fairly reliable results can still be obtained. Deprotonation is found to reduce the lowest calculated UV transition energy by about half an eV. Oligomerization also reduces the lowest calculated UV energy by at least half an eV. Replacement of one or all the –OH groups by –SH groups reduces the lowest calculated UV energies by about 2 eV. UV excitation energies have been calculated for oligomeric species as large as As₃E₃(EH)₃ and As₄E₆, where E = O, S, and may be useful for identifying such species in solution.  相似文献   

Accuracy of ozonesonde measurements in the troposphere     

S. J. Reid  G. Vaughan  A. R. W. Marsh  H. G. J. Smit 《Journal of Atmospheric Chemistry》1996,25(2):215-226

Measurements of atmospheric ozone at concentrations typical of the free troposphere have been compared for ECC sondes and a UV-absorption photometer, using a Bendix chemiluminescent analyser as a transfer standard. Comparisons were conducted in the laboratory and in the tropospheric part of the atmosphere. It was found that the measurements agreed to within 4% provided that the background current for the ECC sonde was measured before exposure to ozone in the preparation procedure, and was assumed to be constant throughout the sonde flight. These results confirm those of earlier experiments and mean that the methods currently used to correct for the background current in the troposphere need to be revised.  相似文献   

Oysters and the Chesapeake Bay ecosystem: A case for exotic species introduction to improve environmental quality?     

Sara J. Gottlieb  Mona E. Schweighofer 《Estuaries and Coasts》1996,19(3):639-650

Restoration of the Chesapeake Bay ecosystem has been a priority for residents and governments of the bay watershed for the past decade. One obstacle in the efforts to “save the bay” has been continuing nutrient enrichment from agricultural and sewer runoff. The attainability of a mandated 40% nutrient reduction goal has yet to be seen. Furthermore, disappearance of certain organisms may have had an adverse effect on the resilience of the ecosystem. The Eastern oyster (Crassostrea virginica), once abundant in Chesapeake Bay, was a vital part of the food web, processing excess phytoplankton and depositing materials on the bottom. Over harvesting and disease have decimated the native oyster population. The introduction of an exotic species, the Japanese oyster (Crassostrea gigas), may be a way to reestablish a robust oyster community in the bay. The literature on the role of bivalve molluscs in estuarine ecosystems shows that they are an essential part of healthy estuaries around the world. A comparison ofC. virginica andC. gigas in terms of temperature and salinity tolerance and resistance to disease shows thatC. virginica is ideally adapted to conditions in Chesapeake Bay, but it is unable to stave off the endemic diseases, whereasC. gigas is adapted to conditions in the lower bay only but is much less susceptible to the same diseases. We conclude that the potential introduction ofC. gigas to Chesapeake Bay would be limited by the Japanese species’ physiological requirements but that the revitalization of a bivalve population is imperative to the restoration of ecosystem function.  相似文献   

Post-collapse volcanic history of calderas on a composite volcano: an example from Roccamonfina,southern Italy     

P D Cole  J E Guest  A M Duncan  D K Chester  R Bianchi 《Bulletin of Volcanology》1992,54(4):253-266

Roccamonfina, part of the Roman Potassic Volcanic Province, is an example of a composite volcano with a complex history of caldera development. The main caldera truncates a cone constructed predominantly of this caldera may have been associated with one of the ignimbritic eruptions of the Brown Leucitic Tuff (BLT) around 385 000 yr BP. The Campagnola Tuff, the youngest ignimbrite of the BLT, however, drapes the caldera margin and must postdate at least the initial stages of collapse. During the subsequent history of the caldera there were several major explosive eruptions. The largest of these was that of the Galluccio Tuff at about 300 000 yr BP. It is likely that there was further collapse within the main caldera associated with these eruptions. It is of note that despite these subsequent major explosive eruptions later collapse occurred within the confines of the main caldera. Between eruptions caldera lakes developed producing numerous lacustrine beds within the caldera fill. Extensive phases of phreatomagmatic activity generated thick sequences of pyroclastic surge and fall deposits. Activity within the main caldera ended with the growth of a large complex of basaltic trachyandestite lava domes around 150 000 yr BP. Early in the history of Roccamonfina sector collapse on the northern flank of the volcano formed the northern caldera. One of the youngest major events on Roccamonfina occurred at the head of this northern caldera with explosive activity producing the Conca Ignimbrite and associated caldera. There is no evidence that there was any linkage in the plumbing systems that fed eruptions in the main and northern calderas.  相似文献