富铌玄武岩：板片熔体交代的地幔楔橄榄岩部分熔融产物   总被引：4，自引：0，他引：4  

张海祥  张伯友  牛贺才 《地球科学进展》2005,20(11):1234-1242

富铌玄武岩是一类具有特殊地球化学特征的岛弧玄武岩。与正常岛弧玄武岩相比，它具有硅饱和并富钠的特征；同时具有相对高的Nb（一般>7×10-6）、TiO2（1%～2%）和P含量，以及低的LILE/HFSE和HREE/HFSE比值，并富集高场强元素；它的原始地幔标准化微量元素图显示了弱的Nb、Ta负异常（有时出现弱的正异常），原始地幔标准化La/Nb比值小于2（但很少小于0.7），它是由受埃达克质熔体交代过的地幔橄榄岩部分熔融形成的。由于富铌玄武岩与埃达克岩是大洋板片俯冲作用的直接产物，因此，通过对该岩石组合及与俯冲作用有关的流体和熔体的研究，不仅可以查明洋壳俯冲作用过程中的岩浆活动特征，还可以阐明洋壳俯冲及壳幔相互作用，具十分重要的地质意义。  相似文献   

Microthermometric measurement of fluid inclusions and its constraints on genesis of PGE-polymetallic deposits in Lower Cambrian black rock series, southern China   总被引：2，自引：0，他引：2  

WANG Min 《中国地球化学学报》2005,24(4):297-305

Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series.  相似文献   

Intrusion and its implication for subsidence: A case from the Baiyun Sag, on the northern margin of the South China Sea   总被引：12，自引：0，他引：12  

Xiaobin Shi  Evgenii Burov  Sylvie Leroy  Xuelin Qiu  Bin Xia 《Tectonophysics》2005,407(1-2):117-134

We develop a series of simple numerical models to explain the anomalous subsidence and deposition phenomena on the northern continental margin of the South China Sea, in particular in the Baiyun Sag. The results suggest that a short-period high rate deposition of around 17 Ma is related to a rapid subsidence event, which may be due to episodic emplacement of a dense intrusion. Necking and gravity models indicate that in the basement of the Baiyun Sag, there is a dense zone that is 100–200 kg/m³ more dense than the surrounding country rock. Considering its high magnetic intensity and regional igneous activity, the dense zone is thought to be related to a phase of basalt intrusion that may have taken place around 17 Ma. Thermal and subsidence models indicate that a hot denser intrusion can cause significant subsidence immediately after the intrusion. The subsidence rate then slows down with cooling, thus becoming consistent with the observed subsidence curves at around 17 Ma. The results also indicate that the lithospheric strength under the Baiyun Sag is negligible, and that the high-velocity layer in the lowermost crust may be not an original part of the pre-rift crust. Instead, it is thought to be underplated intrusion emplaced at around 30 Ma when the continental margin broke up.  相似文献   

燕山中段南麓蓟县北部常州沟-杨庄一带地质构造基本特征   总被引：1，自引：0，他引：1  

姬广义汪洋  夏希凡 《城市地质》2005,17(4):1-32,F0003

在燕山中段南麓的蓟县北部山区有着中国国家地质公园，中国北方中-新元古代正层型剖面标志碑就耸立在那里。对这一地区基本地质事实和地质体真实位态的研究，不仅关系着对华北地区晚前寒武纪标准剖面可靠性的评价，也关系着燕山运动命名地的基本地壳结构的合理解析和我国北方中生代以来构造一岩浆活动序列的正确建立。本文展示的基础地质调查成果可揭示：蓟县北部常州沟-杨庄一带的地质结构构造远不是我国大多数地学学者们对此描述的那样简单。调查区约200km。面积可代表燕山中段南麓的大面积中-新元古界分布区的基本地质结构构造特征。已识别出的18条断层和由其限制的21个以上构造岩片的现实位态表明，该地区地壳上部是由多个复杂地块堆叠构成的，主体构造形成于燕山晚期，在形成方式上以大规模多次不同方向运移的薄皮构造岩片叠覆为主要特征。  相似文献   

Element mobility during pyrite weathering: implications for acid and heavy metal pollution at mining-impacted sites   总被引：1，自引：0，他引：1  

Long Lu  Rucheng Wang  Fanrong Chen  Jiyue Xue  Peihua Zhang  Jianjun Lu 《Environmental Geology》2005,49(1):82-89

Based on back scattered electron images and electron micro-probe analysis results, four alteration layers, including a transition layer, a reticulated ferric oxide layer, a nubby ferric oxide layer and a cellular ferric oxide layer, were identified in the naturally weathering products of pyrite. These layers represent a progressive alteration sequence of pyrite under weathering conditions. The cellular ferric oxide layer correlates with the strongest weathering phase and results from the dissolution of nubby ferric oxide by acidic porewater. Leaching coefficient was introduced to better express the response of element mobility to the degree of pyrite weathering. Its variation shows that the mobility of S, Co and Bi is stronger than As, Cu and Zn. Sulfur in pyrite is oxidized to sulfuric acid and sulfate that are basically released into to porewater, and heavy metals Co and Bi are evidently released by acid dissolution. As, Cu and Zn are enriched in ferric oxide by adsorption and by co-precipitation, but they would re-release to the environment via desorption or dissolution when porewater pH becomes low enough. Consequently, Co, Bi, As, Cu and Zn may pose a substantial impact on water quality. Considering that metal mobility and its concentration in mine waste are two important factors influencing heavy metal pollution at mining-impacted sites, Bi and Co are more important pollutants in this case.  相似文献   

Neoproterozoic bimodal magmatism in the Cathaysia Block of South China and its tectonic significance     

《Precambrian Research》2005,136(1):51-66

SHRIMP U–Pb zircon age, geochemical and Sm–Nd isotopic results are reported for the Mamianshan volcanic rocks in the Cathaysia Block of southeastern South China. The Mamianshan volcanic rocks are bimodal in composition and are dominantly transitional to mildly alkaline basalts and subordinate alkaline rhyolite, with an eruption age of 818 ± 9 Ma. The basaltic samples are characterized by LREE-enriched and “humped” trace element patterns, similar to many alkali basalts in continental rifts. Variable ɛNd(T) values between +3.33 and −4.35 indicate that the primary magma of these basalts was derived from an OIB-like mantle source and underwent fractional crystallization plus crustal contamination. The rhyolitic rocks are highly enriched in Th, Ta, Nb, REE, Zr, Hf and Y and depleted in Sr, P, Eu and Ti, sharing affinity to A₁-type granites. Combined with their slightly positive ɛNd(T) values (+0.22 to +0.92), the Mamianshan felsic rocks were most likely generated by partial melting of the regional Paleoproterozoic Mayuan amphibolites. The Mamianshan bimodal volcanic rocks in the Cathaysia Block are coeval with the widespread intraplate magmatism around the Yangtze Block. Our results support the idea that a coherent South China Craton was formed during the ca. 1.0 Ga Sibao orogeny, and it subsequently underwent extensive continental rifting related to mantle plume or superplume activities beneath Rodinia since ca. 825 Ma.  相似文献   

Controls on roxarsone transport in agricultural watersheds     

《Applied Geochemistry》2005,20(1):123-133

The use of the organoarsenical roxarsone, added to poultry feed to increase weight gain, results in elevated As concentrations (10–50 mg/kg) in poultry litter. This litter is used extensively as fertilizer in agricultural regions. The authors investigated the sources and sinks of As within the vadose zone of an agricultural watershed in the Shenandoah Valley of Virginia, USA, an area of intense poultry production. Batch experiments were constructed to examine adsorption and biotransformation characteristics of roxarsone within the Ap and Bt soil horizons of Frederick series soils, common in the Shenandoah Valley. Roxarsone exhibits weak adsorption to the Ap soils; however, it is rapidly biotransformed to As(V) in this soil horizon. Although the Bt horizon demonstrated strong adsorption of roxarsone and thus may act as a sink for As species, soil water data collected from lysimeters at an agricultural field site suggest that As, as As(V), is mobile in the Bt soil water. It is unclear if this mobilization is due to competitive reactions with phosphate or organic acids, also present in litter. These results have implications for As cycling within poultry-dominated watersheds. For watersheds that have experienced years of litter application, As and other litter-associated species will be attenuated in soils through adsorption to mineral surfaces, but a variety of geochemical processes, such as competitive adsorption, may allow for enhanced transport of As through the vadose zone and into aquifer systems.  相似文献   

Geochronology of granulites from the south Itabuna-Salvador-Curaçá Block,São Francisco Craton (Brazil): Nd isotopes and U–Pb zircon ages     

Jean-Jacques Peucat  Johildo Salomão Figueiredo Barbosa  Ivana Conceição de Araújo Pinho  Jean-Louis Paquette  Hervé Martin  C. Mark Fanning  Angela Beatriz de Menezes Leal  Simone Cruz 《Journal of South American Earth Sciences》2011,31(4):397-413

This work provides five new U–Pb zircon dating and the corresponding Nd isotope data for felsic granulites from the south Itabuna-Salvador-Curaçá Block (ISCB), in the São Francisco Craton, Brazil. Three major sets of felsic granulites can be recognised. The oldest set is tonalitic in composition and of TTG affinity. It is Archaean in age with magmatic zircon cores dated at 2675 ± 11 Ma by LA-ICPMS and up to ca 2.7–2.9 Ga by SHRIMP on an other sample. It exhibits epsilon Nd values between ?8 and ?11 at 2.1 Ga. This Nd signature is similar to that of granulites found in the western Archaean Jequié Block. Cartographically, this set of Archaean terrains represents at least 50% of the granulites in the studied area. The second set corresponds to a Palaeoproterozoic calc-alkaline tonalitic suite with zircon ages from 2019 ± 19 Ma to 2191 ± 10 Ma and epsilon Nd values between ?3 and ?4 at 2.1 Ga, corresponding partially to a newly formed crust. The third set of granulites is also Palaeoproterozoic. It is shoshonitic to monzonitic in composition and synchronous with the high grade metamorphism dated by metamorphic zircons at 2086 ± 7 Ma (average of five samples). The Nd isotope signature for this alkaline set is similar to that of the Palaeoproterozoic calc-alkaline one. Nd isotopes appear to be a very efficient tool to distinguish Archaean from Palaeoproterozoic felsic protoliths in granulitic suites of the Itabuna-Salvador-Curaçá Block (ISCB). Finally, the southern part of the ISCB is composed of a mixture of Archaean and Palaeoproterozoic protoliths, in similar amounts, suggesting that it was probably an active margin between 2.1 and 2.2 Ga located on the eastern border of the Archaean Jequié Block. A major crustal thickening process occurred at ca 2.09 Ga in the ISCB and seems significantly younger towards the west, in the Jequié granulites, where an average of 2056 ± 9 Ma is determined for the high grade event.  相似文献   

In situ U–Pb isotopic dating of columbite–tantalite by LA–ICP–MS     

《Ore Geology Reviews》2015

Columbite–tantalite (Coltan) is the most important niobium (Nb)- and tantalum (Ta)-bearing economic mineral, commonly occurring in rare metal granite and pegmatite, alkaline granite, syenite and carbonatite. Its high U but low common Pb contents make it an ideal mineral for U–Pb isotopic dating of Nb–Ta mineralization. In order to establish a feasible coltan dating method by in situ laser-ablation (LA) ICP–MS, we determined the U–Pb ages of five coltan samples from different pegmatites and rare-metal granites in China. In order to evaluate the potential matrix effect between different minerals, a 91500 zircon was used as external standard during analyses. The results show that, compared to the recommended ages, approximately 7–15% younger ages were yielded for the analyzed coltan samples in both single spot and line raster scan analytical methods, indicating a significant matrix effect between coltan and zircon. However, by using a coltan standard from Namibia (Coltan139), the coltan sample from Dahe pegmatite (SNNT) has a weighted mean ²⁰⁶Pb/²³⁸U age of 363 ± 4 Ma (2σ, n = 25) and 357 ± 5 Ma (2σ, n = 20) in single spot and line raster scan analytical methods, respectively; the coltan samples from Altai No.3 pegmatite (713-79), Yichun topaz-lepidolite granite (Yi-1) and Huangshan albite granite (LS-15) have weighted mean ²⁰⁶Pb/²³⁸U ages of 218 ± 2 Ma (2σ, n = 20), 160 ± 1 Ma (2σ, n = 20) and 130 ± 1 Ma (2σ, n = 20), respectively, in single spot mode. These ages agree well with the previously published data, and hence support the reliability of our analytical method. Although the analyzed coltan minerals show a large variation of chemical compositions, no significant matrix effect was observed, which suggests that a coltan material should be used as an external standard for U–Pb dating of coltan by LA–ICP–MS. Using the established analytical protocol, we date the Nanping pegmatite (NP155), a main Nb–Ta deposit in China without known age, and obtain a weighted mean ²⁰⁶Pb/²³⁸U age of 391 ± 4 Ma (2σ, n = 20), which is considered as the best estimation of Nb–Ta mineralization time in the area.  相似文献   

Determination of regional soil geochemical baselines for trace metals with principal component regression: A case study in the Jianghan plain,China     

《Applied Geochemistry》2014

The soil geochemical baseline is an important index in environmental assessment. Detailed baseline studies are necessary in large areas with complex geological settings, landforms and soil types. The Jianghan plain, a major industrial and agricultural region located in central China, has a soil geochemical baseline that has yet to be fully defined. The objective of this paper is to study the baseline of Cd, Pb and Zn in the topsoil of the Jianghan plain in a subarea using principal component regression (PCR). A total of 9030 samples were collected from the surface layer, and 2 soil profiles and 2 sedimentary columns were sampled near the Yangtze and Han rivers. Fifty-two elements and two parameters were analyzed. Data processing and the creation of spatial distribution maps of the elements were performed using MapGIS, R and SPSS software. The results show that the distributions of Cd, Pb and Zn are mainly controlled by parent material, drainage system and soil type. The study area is divided into 3 subareas, with factors reflecting the physico-chemical characteristics of the soil using factor analysis (FA). The geochemical baseline model is established in every subarea to predict the Cd, Pb and Zn values using principal component regression analysis (PCR); the exceptional values (as a result of anthropogenic input or mineralization) are distinguished by residuals (γ); and the natural background values and anthropogenic contributions are clearly distinguished. Therefore, the PCR method in these subareas is objective and reasonable, and the conclusion provides effective evidence of exceptional high values for further environmental assessment.  相似文献