微波等离子体原子发射光谱法测定偏远矿区海泡石中的主微量元素     

周学忠  谢华林 《岩矿测试》2021,(5):680-687

海泡石是具有层状结构的含水富镁硅酸盐黏土矿物,其中无机元素含量是揭示其成矿物质来源、成矿流体性质和矿床成因的重要依据,通常采用电感耦合等离子体发射光谱/质谱法(ICP-OES/MS)进行测定,等离子体(ICP)的高温激发会产生成大量谱线干扰,维持ICP稳定工作需使用高纯氩气,持续供气对于偏远矿区海泡石的检测还将面对气体采购和运输不便的问题。本文基于微波等离子体原子发射光谱(MP-AES)的低温激发技术减少光谱干扰,建立了准确测定偏远矿区海泡石中主量元素Mg、Al、Ca、Fe、K、Na和微量元素Cu、Zn、Mn、Pb含量的分析方法。利用硝酸-盐酸-氢氟酸混合酸对海泡石进行微波消解,避免了样品处理过程中分析元素的损失,加快了样品处理速度,同时提高了样品溶液的稳定性。通过选择各元素光谱线的分析波长,并利用快速线性干扰校正(FLIC)技术校正光谱干扰,以Lu为内标元素校正基体效应,提高了灵敏度和准确度。各元素的检出限为0.19～14.6μg/L。海泡石国家标准物质(GBW07138)各元素测定值与认定值的相对误差在-5.0%～6.7%之间。本方法具有检出限低、线性范围宽、结果准确等优点;MP-AES采用自带的氮气发生器为等离子体提供氮气作为工作气,无需引入复杂气体,提高了分析效率,尤其适用于气体采购和运输不便的偏远矿区。  相似文献   

湖南省近54年冬季降水分区及趋势分析     

胡倩  贺新光  卢希安  章新平 《热带气象学报》2019,35(1):135-144

基于湖南省89个气象站点1960—2013年的冬季降水观测数据,应用旋转经验正交函数（REOF）和层次聚类法（HCA）对湖南省冬季降水进行分区,并在分区的基础上,运用离散小波变换结合Mann-Kendall（MK）和Sequential MK（SQMK）的方法,讨论湖南省各分区冬季降水的变化趋势,并识别影响各自变化趋势的主周期分量。结果表明:（1）REOF的前3个旋转空间模态揭示湖南省冬季降水存在3个主要的异常敏感区:湘南、湘西北及湘中;（2）湖南省冬季降水在空间上可划分为5个一致性子区域:湘西北区（DJF1）、湘西-湘北区（DJF2）、湘西南-湘中区（DJF3）、湘南丘陵区（DJF4）和湘南山地区（DJF5）,且每一子区域从西南向东北呈带状展布;（3）近54年来,5个子区的冬季降水均表现出增加趋势但各区存在差异,其中,湘西南-湘中区、湘南丘陵区和湘南山地区均呈显著的上升趋势;（4）D₁分量是影响湖南省不同区域冬季降水变化趋势的最占优的周期分量,揭示湖南省的冬季降水变化趋势存在准2年的主周期。   相似文献   

中国人皮肤相对湿度的地理分布   总被引：3，自引：0，他引：3  

毛政旦 《气象》1994,20(8):12-16

根据Ｂｅｒｇｌｕｎｄ等人（１９８３）公式：Ｗ＝（ｅｓｋ－ｅａ）／（ｅｓｓｋ－ｅａ），利用大气温度，大气水汽压和皮肤温度的月平均值，计算皮肤相对湿度，并按皮肤相对湿度划分舒适带。结果表明，决定我国皮肤相对湿度地理分布的基本因素是纬度，海陆分布，地形和大气环流，季节不同，则各因素所起作用有差异。作者以皮肤相对湿度２５％－４５％表示舒适带，计算表明，我国气候舒适带有明显的地区差异和季节变化。  相似文献   

湖南省桂东县自然资源特征及其可持续发展研究     

谢玉华  吴甫成  郭建平  熊建安 《热带地理》2007,27(6):548-552

湖南省桂东县处于边远山区,经济发展水平低,为国家级贫困县。但其自然资源丰富,生态环境质量良好,旅游资源独具特色。通过对边远山区县资源环境特点和经济发展现状的分析,提出了促进地区可持续发展的建议:调整产业结构,在发展超级稻和优质稻基础上,发展具有地方特色的药、菜、茶、果、烟,外加楠竹和园艺的种植业,发展以牛、羊等草食性牲畜为主的养殖业;发展小水电和以电力为基础的电化工业及农产品加工业;发展红色旅游和休闲度假相结合的生态旅游业;加强生态环境保护力度,以促进桂东区域经济的可持续发展。  相似文献   

洞庭湖流域水生态系统服务功能经济价值研究   总被引：9，自引：2，他引：9  

李景保  常疆  李杨  周亮  喻小红 《热带地理》2007,27(4):311-316

以洞庭湖流域水生态系统为例,在明确河湖库塘生态系统服务功能内涵的基础上,运用生态学与生态经济学方法对洞庭湖流域各类水生态系统服务功能经济价值进行了评估。结果表明,全流域河湖库塘水生态系统服务功能总价值量为1106.19亿元,约占湖南省2004年GDP(5612.26亿元)的19.7%,其中,城镇和农村生活供水、工农业生产供水、水力发电、内陆航运等直接利用价值为415.698亿元;调洪、输沙、水资源贮存等间接利用价值为690.492亿元。可以认为,流域水生态系统服务功能对湖南省工农业生产的持续发展,维系生态环境健康和人民生命财产安全起到了不可替代的支撑和保障作用。  相似文献   

青藏高原崇测冰芯氯离子、硫酸根离子记录     

刘业祥  刘永建  韩建康 《云南地理环境研究》2007,19(3):11-14

通过对青藏高原崇测冰帽一支18．70m冰芯中Cl^-、SO4^2-离子含量变化的分析表明，20世纪90年来Cl^-、SO4^2-离子含量在波动中呈下降趋势，两种离子的周期性波动变化相似，20世纪晚期比早期和中期的波动幅度小，总体上离子含量逐渐减少与温度在波动中上升相一致，但每一次温度的升高与离子含量的下降并非一一对应。陆源物质和青藏高原上的盐湖是冰芯中Cl^-、SO4^2-离子的主要贡献者。揭示了研究地区大气成分和环境变化与气候变化的关系及亚洲粉尘在全球环境变化中的源区地位。  相似文献   

The δ18O in the Guliya shallow ice core during the prevailing summer monsoons and sea-air interactions     

Zhang Xin-ping Ph.D.  Masayoshi Nakawo  Yao Tan-dong 《地理学报(英文版)》2001,11(4):438-448

The correlations of the δ¹⁸O_max in the shallow ice core from the Guliya ice cap on the Tibetan Plateau with the global sea surface temperatures (SST) and height at the 500 hPa over the Northern Hemisphere were analyzed. The correlated regions on oceans that have a significant influence on the δ¹⁸O_max in the Guliya ice core are all located in ocean currents, or convergent regions of currents. They are the eastern Equatorial Pacific, the Northern Pacific Current, the Hot Pool in the eastern Indian Ocean, the Mozambique Current, the Northern Atlantic Current, the Canary Current and the Atlantic Equatorial Current. The δ¹⁸O_max in the Guliya ice core has negative correlations with the SST located in the lower latitudes, and positive correlations with the SST in the middle latitudes. The correlated areas at the 500 hPa that have a great impact on the δ¹⁸O_max are located in the subtropical highs over the mid-low-latitude oceans and the long-wave trough area over Balkhash Lake, where there are marked negative correlations between the heights in those areas and the δ¹⁸O_max. The influencing mechanism is displayed by the diversity of the vapor origins transported to the Guliya region. The strengths of the European ridge and the ridge over Baikal Lake have notable positive correlations with the δ¹⁸O_max. The two systems indirectly influence the vapor transportation towards the Guliya region by the adjustment of long-wave trough and ridge.  相似文献   

Variation of precipitation in Langtang Valley,Himalayas     

ZHANG Xinping  Masayoshi NAKAWO  Koji Fujita  YAO Tanndong  Han Jiankang 《中国科学D辑(英文版)》2001,44(9)

The variation of the δ 18O in precipitation and the relationship with precipitation amountat Kyangjin Base House and Yala Glacier Camp in Langtang Valley, Nepal Himalayas were ana-lyzed. The variations of the δ 18O with precipitation had great scatter, and the correlations betweenthe δ18O and precipitation changed with time on the synoptic scale. On the seasonal scale, therewas marked amount effect at Kyangjin Base House. However, the δ18O-precipitation gradient wassmaller than that on the synoptic scale. Because of the maintenance of the basic equilibrium be-tween stable isotopic compositions in atmospheric vapor and precipitation, the evaporation en-richment was light during the rainy season. Therefore, the variation of stable isotopic compositionsin precipitation was independent on the sampling intervals. Simulations show that the rainfall inLangtang Valley was not the outcome of the initial condensation of ocean vapor that originatedfrom low latitudes. The stable isotopic compositions in precipitation were greatly depleted due tothe strong rainout of the vapor from oceans as the vapor was raised over the Himalayas  相似文献   

Globally synchronous climate change 2800 years ago: Proxy data from peat in South America     

《Earth and Planetary Science Letters》2007,253(3-4):439-444

Initial findings from high-latitude ice-cores implied a relatively unvarying Holocene climate, in contrast to the major climate swings in the preceding late-Pleistocene. However, several climate archives from low latitudes imply a less than equable Holocene climate, as do recent studies on peat bogs in mainland north-west Europe, which indicate an abrupt climate cooling 2800 years ago, with parallels claimed in a range of climate archives elsewhere. A hypothesis that this claimed climate shift was global, and caused by reduced solar activity, has recently been disputed. Until now, no directly comparable data were available from the southern hemisphere to help resolve the dispute. Building on investigations of the vegetation history of an extensive mire in the Valle de Andorra, Tierra del Fuego, we took a further peat core from the bog to generate a high-resolution climate history through the use of determination of peat humification and quantitative leaf-count plant macrofossil analysis. Here, we present the new proxy-climate data from the bog in South America. The data are directly comparable with those in Europe, as they were produced using identical laboratory methods. They show that there was a major climate perturbation at the same time as in northwest European bogs. Its timing, nature and apparent global synchronicity lend support to the notion of solar forcing of past climate change, amplified by oceanic circulation. This finding of a similar response simultaneously in both hemispheres may help validate and improve global climate models. That reduced solar activity might cause a global climatic change suggests that attention be paid also to consideration of any global climate response to increases in solar activity. This has implications for interpreting the relative contribution of climate drivers of recent ‘global warming’.  相似文献   

湖南农业抗旱能力综合评价   总被引：2，自引：0，他引：2  

刘迎春  肖谦益 《云南地理环境研究》2007,19(4):39-42,57

利用灰色系统理论中的关联分析建立了湖南农业抗旱能力评价的指标体系，运用密切值法对湖南14个地州市的抗旱能力进行了综合排序。其结果表明湖南省各州市的农业抗旱能力差异较大，其中：衡阳（0．03）、常德（0．32）密切值小，抗旱能力强，株洲（3．14）、张家界（3．34）密切值大，抗旱能力弱。并根据湖南的实际为其抗旱减灾、提高抗旱能力提出了合理的建议与对策。  相似文献