Geochemical patterns of arsenic-enriched ground water in fractured,crystalline bedrock,Northport, Maine,USA     

《Applied Geochemistry》2006,21(3):528-545

High mean As concentrations of up to 26.6 μmol/L (1990 μg/L) occur in ground water collected from a fractured-bedrock system composed of sulfidic schist with granitic to dioritic intrusions. Sulfides in the bedrock are the primary source of the As in the ground water, but the presence of arsenopyrite in rock core retrieved from a borehole with As concentrations in the ground water barely above the detection limit of 2.0 μmol/L, shows that there are complicating factors. Chemical analyses of water from 35 bedrock wells throughout a small watershed reveal spatial clustering of wells with high As concentrations. Stiff diagrams and box plots distinguish three distinct types; calcium-bicarbonate-dominated water with low As concentrations (CaHCO₃ type), sodium-bicarbonate-dominated water with moderately high As concentrations (NaHCO₃ type), and calcium-bicarbonate-dominated water with very high As concentrations (High-As type). It is proposed that differences in recharge area and ground-water evolution, and possible bedrock composition difference are responsible for the chemical distinctions within the watershed. Lack of correlation of As concentrations with pH indicates that desorption of As is an insignificant control on As concentration. Correlations of As concentrations with Fe and redox parameters indicates that reductive dissolution of Fe(III) oxyhydroxides may play a role in the occurrence of high As concentrations in the NaHCO₃ and High-As type water. The oxidation of sulfide minerals occurs within the ground-water system and is ultimately responsible for the existence of As in the ground water, but there is no correlation between As and SO₄ concentrations, probably due to precipitation of Fe(III) oxyhydroxides and adsorption of As under oxidizing conditions.  相似文献   

Combined investigations of fluid inclusions in opaque ore minerals by NIR/SWIR microscopy and microthermometry and synchrotron radiation X-ray fluorescence     

《Applied Geochemistry》2006,21(5):813-819

An alternative IR microscopy system in the NIR (near infrared, up to 10 μm) and SWIR (short wavelength infrared, up to 1.4 μm) ranges has been developed for the study of opaque ore minerals. The system uses either IR LED or IR light bulb sources depending on the degree of opacity of the investigated minerals. This paper presents the methodology and the promising results obtained in studies of opaque ore minerals such as Ag minerals (pyrargyrite) from epithermal deposits and Nb-tantalates (columbite) from pegmatites. It also presents results on the internal features of hematites from Fe ore banded formations and tungstates from granite–greenstone belt deposits. The data obtained on fluid inclusions from pyrargyrite and hematite crystals have been integrated by complementary information from X-ray fluorescence analysis using synchrotron radiation (μ-SXRF) under conditions specifically designed for the study of opaque ore minerals.  相似文献   

1990～2003年洪湖水体环境质量演变分析   总被引：16，自引：0，他引：16  

胡学玉  陈德林  艾天成 《湿地科学》2006,4(2):115-120

以详细的水质监测资料为基础,采用标准指数法并结合实地调查,分析了1990~2003年洪湖水质的变化状况。结果表明,14 a间,洪湖水质类别以Ⅲ类和Ⅳ类为主。水质恶化的驱动因子是氮、磷及其它有机污染物。1991年到1994年期间,水体中氨氮(NH4 -N)占溶解无机氮(D IN)的比例逐年增高;1995~2003年,以氨氮和硝酸盐(NO3--N)同时作为水体中溶解无机氮的主要存在形式,与1990~1994年的水质状况相比,亚硝酸盐(NO2--N)所占的比例呈增加之势。氨氮、硝酸盐和亚硝酸盐的年际变化表明,洪湖水体自净能力在逐渐降低。以总磷(TP)、总氮(TN)和溶解无机氮(D IN)作为评价指标,洪湖水体已属中富营养型湖泊。洪湖水质演变与该区域人类活动(围湖造田、围网养殖等)以及江湖连通的变化对水环境的作用相耦合。  相似文献   

华南地区晚二叠和晚三叠世煤中稀土元素特征研究   总被引：2，自引：0，他引：2  

杜美霞  庄新国 《中国煤田地质》2006,18(2):22-26

在华南地区贵州六盘水、江西乐平、露庆和湖北黄石矿区晚二叠和晚三叠世煤层的稀土元素ICP—MS分析数据的基础上，系统研究了研究区煤中稀土元素的含萤分布特征、赋存特征、配分模式以及地质控制因素。含量分布表明晚二叠世稀土元素含量总体高于晚三叠世；煤中稀土元素与灰分成正相关关系，部分煤样品由于有富稀土元素的重矿物组合的存在而出现稀土元素的异常高值；同一矿区、同一时代煤中稀土元素的配分模式具有一定的相似性，而不同地区同一时代和同一地区不同时代煤中稀土元素的配分模式具有较大差异；煤的沉积环境，煤中无机矿物组成以及海水的影响是控制煤中稀土元素含量和配分模式的主要地质因素。  相似文献   

Fission track evidence for the Mesozoic Cenozoic tectonic uplift of Mt. Bogda, Xinjiang, Northwest China     

沈传波  梅廉夫彭蕾 张士万刘麟  汤济广 《中国地球化学学报》2006,25(2):143-151

1 IntroductionThe Mesozoic-Cenozoic tectonic evolution and ki-netics mechanism of the intracontinental orogen are thekey subjects of continental dynamics (Ma Zongjin andGao Xianglin, 2004) and the key to understanding theregional geological tectonics (Qia…  相似文献   

A study on the geochemical characteristics of Upper Permian continental marginal arc volcanic rocks in the northern segment of South Lancangjiang Belt     

沈上越冯庆来  魏启荣张志斌 张虎 《中国地球化学学报》2006,25(3):216-222

1IntroductionThe northern segment of the South LancangjiangBelt refers to the terrain about200km east of theYunxian-Lingcang granite in the South LancangjiangBelt(Fig.1).During the seventh Five-Year Plan peri-od,Mo Xuanxue et al.(1993)undertook the resear…  相似文献   

基于ASP．NET技术的全国地质资料目录服务系统     

周春磊 《国土资源信息化》2005,(1):24-26

本文阐述了基于ASP.NET技术的地质资料目录服务系统的总体设计,并对其功能和关 键技术进行详细描述。  相似文献   

基于GIS的城镇土地定级信息系统建模方法探讨   总被引：2，自引：0，他引：2  

刘艳中  汪新庆 《国土资源信息化》2005,19(3):37-40

基于GIS的城镇土地定级信息系统在建设过程中,定级方法确定、定级单元大小确定和定级因素/子权重值的生成是关键,且三者都具有不同的确定方法,因此选择什么样的方法决定了系统建立的优劣。本文着重归纳、总结了城镇土地定级信息系统定级方法,通过对比分析,探讨了最优定级方法、最优网格单元大小划分方法和最优因素/子权重值计算方法。  相似文献   

不等电极距情况下高密度电阻率法的反演结果分析     

吴云超  王传雷  陈超 《物探与化探》2005,29(1):19-21

通过高密度电阻率法的模型实验,得出不等电极距情况对直立高阻薄板和低阻球体反演结果的影响:缺失电极对它正下方的ρ_s影响最大,而异常形态主要在水平方向有明显的变化,异常体随电极缺失的位置有趋势变化,电极缺失的数目越多,异常形态变化越大,但是从整体来看反演剖面图基本相似。  相似文献   

量子磁力仪研究和开发近况   总被引：11，自引：1，他引：11  

张昌达 《物探与化探》2005,29(4):283-287

介绍了核子旋进磁力仪、欧弗豪泽磁力仪、光泵磁力仪、超导磁力仪和原子磁力仪研究和开发近况, 提出了开展研究工作的建议。  相似文献