Soft X-ray spectroscopic studies of the reaction of fractured pyrite surfaces with Cr(VI)-containing aqueous solutions     

Colin S. Doyle  Tom Kendelewicz  Gordon E. Brown Jr 《Geochimica et cosmochimica acta》2004,68(21):4287-4299

We have used synchrotron-based soft X-ray core-level photoemission and adsorption spectroscopies to study the reaction of aqueous sodium chromate solutions with freshly fractured pyrite surfaces. Pyrite surfaces were reacted with 50 μM sodium chromate solution at pH 7 for reaction times between 1 min and 37 hr. Additional experiments were performed at pH 2 and pH 4 with 50 μM sodium chromate solutions and at pH 7 with 5 mM solutions. At chromate concentrations of 50 μM, all chromium present on the pyrite surface was in the form of Cr(III), while at 5 mM, both Cr(III) and Cr(VI) were present at the pyrite surface. Minor quantities of oxidized sulfur species (sulfate, sulfite, and zero-valent sulfur) were identified as reaction products on the pyrite surface. The amount of oxidized sulfur species observed on the surface was greater when pyrite was reacted with 5 mM Cr(VI) solutions because the rate of chromium deposition exceeded the rate of dissolution of pyrite oxidation products, effectively trapping Cr(VI) and oxidized sulfur species in an overlayer of iron(III)-containing Cr(III)-hydroxide. This work shows that pyrite, an extremely cheap and readily available waste material, may be suitable for the removal of hexavalent chromium from acidic to circumneutral waste streams. The reduced chromium ultimately forms a coating on the pyrite surface, which passivates the pyrite surface towards further oxidation.  相似文献   

Long term atmospheric deposition as the source of nitrate and other salts in the Atacama Desert, Chile: New evidence from mass-independent oxygen isotopic compositions   总被引：1，自引：0，他引：1  

Greg Michalski  J.K. Böhlke 《Geochimica et cosmochimica acta》2004,68(20):4023-4038

Isotopic analysis of nitrate and sulfate minerals from the nitrate ore fields of the Atacama Desert in northern Chile has shown anomalous ¹⁷O enrichments in both minerals. Δ¹⁷O values of 14-21 ‰ in nitrate and 0.4 to 4 ‰ in sulfate are the most positive found in terrestrial minerals to date. Modeling of atmospheric processes indicates that the Δ¹⁷O signatures are the result of photochemical reactions in the troposphere and stratosphere. We conclude that the bulk of the nitrate, sulfate and other soluble salts in some parts of the Atacama Desert must be the result of atmospheric deposition of particles produced by gas to particle conversion, with minor but varying amounts from sea spray and local terrestrial sources. Flux calculations indicate that the major salt deposits could have accumulated from atmospheric deposition in a period of 200,000 to 2.0 M years during hyper-arid conditions similar to those currently found in the Atacama Desert. Correlations between Δ¹⁷O and δ¹⁸O in nitrate salts from the Atacama Desert and Mojave Desert, California, indicate varying fractions of microbial and photochemical end-member sources. The photochemical nitrate isotope signature is well preserved in the driest surficial environments that are almost lifeless, whereas the microbial nitrate isotope signature becomes dominant rapidly with increasing moisture, biologic activity, and nitrogen cycling. These isotopic signatures have important implications for paleoclimate, astrobiology, and N cycling studies.  相似文献   

Palaeozoic deformation and magmatism in the northern area of the Anatolide block (Konya), witness of the Palaeotethys active margin   总被引：1，自引：0，他引：1  

Ya ar Eren  Hüseyin Kurt  François Rosselet  Gérard M. Stampfli 《Eclogae Geologicae Helvetiae》2004,97(2):293-306

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Simulations of a coupled hydro-chemo-mechanical system in rocks     

Jishan Liu  Barry H. Brady 《Geotechnical and Geological Engineering》2004,22(1):121-133

A coupled hydro-chemo-mechanical numerical model is developed for these coupled phenomena in many engineering fields. The model has been applied to predicting the response of a stressed rockmass column to an injected reactive fluid (reagent) flow. The response includes evolutions of porosity, permeability, reagent and mineral concentrations during dissolution. In the model, the progress of dissolution is defined by the change in porosity ratio and the porosity increases with dissolution assuming there is no precipitation. The numerical evolutions of porosity, permeability, reagent and mineral concentrations during dissolution are validated against steady state solutions. The model results show that these evolutions are regulated to a certain extent by the applied external loadings: an applied extensional stress enhances the progress of the dissolution process while an applied compression stress slows the progress of the dissolution process. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Coastline configuration and geomorphologic development mode of arc-shaped coast in South China   总被引：1，自引：0，他引：1  

Dai Zhijun  Li Chunchu 《地理学报(英文版)》2004,14(4):473-480

1IntroductionArc-shaped bays are quite common on exposed sediment coast in South China, where the crenulate-bay beaches occur with the presence of two consecutive headlands and a predominant wave approach oblique to the alignment of the upcoast and downcoast headlands (Yasso, 1965). Oblique persistent swell striking a shoreline transports sediment alongshore and sculptures a coast into arc-shaped beaches. The shoreline of beach appearance mainly consists of straight segment and shadow segment…  相似文献   

Inviscid behaviour of fines-rich pyroclastic flows inferred from experiments on gas-particle mixtures     

O. Roche  M.A. Gilbertson  R.S.J. Sparks 《Earth and Planetary Science Letters》2005,240(2):401-414

Experiments were carried out on granular flows generated by instantaneous release of gas-fluidised, bidisperse mixtures and propagating into a horizontal channel. The mixture consists of fine (< 100 μm) and coarse (> 100 μm) particles of same density, with corresponding grain size ratios of ∼ 2 to 9. Initial fluidisation of the mixture destroys the interparticle frictional contacts, and the flow behaviour then depends on the initial bed packing and on the timescale required to re-establish strong frictional contacts. At a fines mass fraction (α) below that of optimal packing (∼ 40%), the initial mixtures consist of a continuous network of coarse particles with fines in interstitial voids. Strong frictional contacts between the coarse particles are probably rapidly re-established and the flows steadily decelerate. Some internal friction reduction appears to occur as α and the grain size ratio increases, possibly due to particle rolling and the lower roughness of internal shear surfaces. Segregation only occurs at large grain size ratio due to dynamical sieving with fines concentrated at the flow base. In contrast, at α above that for optimal packing, the initial mixtures consist of coarse particles embedded in a matrix of fines. Flow velocities and run-outs are similar to that of the monodisperse fine end-member, thus showing that the coarse particles are transported passively within the matrix whatever their amount and grain size are. These flows propagate at constant height and velocity as inviscid fluid gravity currents, thus suggesting negligible interparticle friction. We have determined a Froude number of 2.61 ± 0.08 consistent with the dam-break model for fluid flows, and with no significant variation as a function of α, the grain size ratio, and the initial bed expansion. Very little segregation occurs, which suggests low intensity particle interactions during flow propagation and that active fluidisation is not taking place. Strong frictional contacts are only re-established in the final stages of emplacement and stop the flow motion. We infer that fines-rich (i.e. matrix-supported) pyroclastic flows propagate as inviscid fluid gravity currents for most of their emplacement, and this is consistent with some field data.  相似文献   

大功率激电测深法寻找焦家式深部金矿床的试验应用研究     

牛如宝  陈长峰  宋海平  王友芳  王轮吉 《应用地球物理》2005,2(1):51-55

利用大功率的激电测深法可以寻找焦家式深部金 矿。首先,由物理和数学推导建立多层极化体的数 理模型,其数理模型产生的极化场可由多层若干 个极化单元场相叠加而成。由多次去除极化单元 场的原理而导出大功率激电测深资料进行消除浅 部强激电干扰异常的数据处理公式,从而突出了 深部矿床的激电异常。并利用处理后的激电测深 曲线,定量求取了深部金矿蚀变矿化带的顶界面 埋深。  相似文献   

Source time-function as discriminant using empirical Green’s function     

HE Yongfeng  & CHEN Xiaofei . Department of Geophysics  School of Earth & Space Sciences  Peking University  Beijing  China  . North-West Institute of Nuclear Technology  Xi’an  China 《中国科学D辑(英文版)》2005,48(12):2118-2122

Since the sign up of CTBT (Comprehensive Test Ban Treaty), the nuclear monitoring and distinguishing has gained great attention by the treaty countries. Seismology is one of the primary technical means available for monitoring compliance to a CTBT. However, there does not exist a single criterion, so far, that can effectively distinguish explorations from earthquakes. It has been known that source time function (abbreviated to STF) of an underground nuclear explosion contains important p…  相似文献   

Editorial     

John Stix 《Bulletin of Volcanology》2005,68(1):1-2

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On the variability of the flow along the Meso-American Barrier Reef system: a numerical model study of the influence of the Caribbean current and eddies     

Tal Ezer  Deeptha V. Thattai  Björn Kjerfve  William D. Heyman 《Ocean Dynamics》2005,55(5-6):458-475

A high resolution (3–8 km grid), 3D numerical ocean model of the West Caribbean Sea (WCS) is used to investigate the variability and the forcing of flows near the Meso-American Barrier Reef System (MBRS) which runs along the coasts of Mexico, Belize, Guatemala and Honduras. Mesoscale variations in velocity and temperature along the reef were found in seasonal model simulations and in observations; these variations are associated with meandering of the Caribbean current (CC) and the propagation of Caribbean eddies. Diagnostic calculations and a simple assimilation technique are combined to infer the dynamically adjusted flow associated with particular eddies. The results demonstrate that when a cyclonic eddy (negative sea surface height anomaly (SSHA)) is found near the MBRS the CC shifts offshore, the cyclonic circulation in the Gulf of Honduras (GOH) intensifies, and a strong southward flow results along the reef. However, when an anticyclonic eddy (positive SSHA) is found near the reef, the CC moves onshore and the flow is predominantly westward across the reef. The model results help to explain how drifters are able to propagate in a direction opposite to the mean circulation when eddies cause a reversal of the coastal circulation. The effect of including the Meso-American Lagoon west of the Belize Reef in the model topography was also investigated, to show the importance of having accurate coastal topography in determining the variations of transports across the MBRS. The variations found in transports across the MBRS (on seasonal and mesoscale time scales) may have important consequences for biological activities along the reef such as spawning aggregations; better understanding the nature of these variations will help ongoing efforts in coral reef conservation and maintaining the health of the ecosystem in the region.  相似文献