Carbon isotopic fractionation during the CO₂ exchange process between air and sea water under equilibrium and kinetic conditions     

Hisayuki Inoue  Yukio Sugimura 《Geochimica et cosmochimica acta》1985,49(11):2453-2460

Carbon isotopic fractionation during the air/sea exchange process is not fully understood at present. Information on the equilibrium and kinetic fractionation factors is an essential requirement, together with the value of the CO₂ partial pressure, for understanding the carbon cycle in the atmosphere and marine environments. Using a specially designed countercurrent equilibrator system, the fractionation factors between gaseous CO₂ and dissolved inorganic carbon in sea water were determined under both kinetic and equilibrium conditions. The following results were obtained: kinetic fractionation factor for air to sea (α_as) is 0.998 at 288.2 K; kinetic fractionation factor for sea to air (α_sa) is 0.990; equilibrium fractionation factor (α_eq) is 0.991 at pH = 8.3 and 288.2 K. From these results, the carbon isotopic ratio of CO₂ passed through the air/ sea interface is estimated to be about ?10 %. for air to sea and ?8 %. for sea to air when CO₂ exchange takes place between air (δ¹³C = ?8 %.) and surface sea water (δ¹³C = 2 %.) at 288.2 K.  相似文献   

Oxygen isotope exchange rate between dissolved sulfate and water at hydrothermal temperatures     

Hitoshi Chiba  Hitoshi Sakai 《Geochimica et cosmochimica acta》1985,49(4):993-1000

Oxygen isotope exchange rate between dissolved sulfate and water was experimentally determined at 100, 200 and 300°C. The isotope exchange rate is strongly dependent on temperature and pH of the solution. Combining the temperature and pH dependence of the reaction rate, the exchange reaction was estimated to be first-order with respect to sulfate. The logarithm of apparent rate constant of exchange reaction at a given temperature is a function of the pH calculated at the experimental temperatures. From the pH dependence of the apparent rate constant, it was deduced that the isotope exchange reaction between dissolved sulfate and water proceeds through collision between H₂SO⁰₄ and H₂O at low pH, and between HSO^?₄ and H₂O at intermediate pH. The isotope exchange rate obtained indicates that oxygen isotope geothermometry utilizing the studied isotope exchange is suitable for temperature estimation of geothermal reservoirs. The extrapolated half-life of this reaction to oceanic temperature is about 10⁹ years, implying that exchange between oceanic sulfate and water cannot control the oxygen isotope ratio of oceanic sulfates.  相似文献   

Thermodynamic mixing properties of Mg(Al,Cr)2O4 spinel crystalline solution at high temperatures and pressures     

Yastami Oka  Petra Steinke  Niranjan D. Chatterjee 《Contributions to Mineralogy and Petrology》1984,87(2):196-204

Three Al-Cr exchange isotherms at 1,250°, 1,050°, and 796° between Mg(Al, Cr)₂O₄ spinel and (Al, Cr)₂O₃ corundum crystalline solutions have been studied experimentally at 25 kbar pressure. Starting from gels of suitable bulk compositions, close approach to equilibrium has been demonstrated in each case by time studies. Using the equation of state for (Al, Cr)₂O₃ crystalline solution (Chatterjee et al. 1982a) and assuming that the Mg(Al, Cr)₂O₄ can be treated in terms of the asymmetric Margules relation, the exchange isotherms were solved for Δ G ^*, and . The best constrained data set from the 1,250° C isotherm clearly shows that the latter two quantities do not overlap within three standard deviations, justifying the choice of asymmetric Margules relation for describing the excess mixing properties of Mg(Al, Cr)₂O₄ spinels. Based on these experiments, the following polybaric-polythermal equation of state can be formulated: , P expressed in bars, T in K, G _m ^ex and W _G,i ^Sp in joules/mol. Temperature-dependence of G _m ^ex is best constrained in the range 796–1,250° C; extrapolation beyond that range would have to be done with caution. Such extrapolation to lower temperature shows tentatively that at 1 bar pressure the critical temperature, T _c, of the spinel solvus is 427° C, with dT_c/dP≈1.3 K/kbar. The critical composition, X _c, is 0.42 , and changes barely with pressure. Substantial error in calculated phase diagrams will result if the significant positive deviation from ideality is ignored for Al-Cr mixing in such spinels.  相似文献   

Fractionation of sulfur isotopes and selenium between coexisting sulfide minerals from the Besshi deposit,Central Shikoku,Japan     

M. Yamamoto  K. Kase  M. Tsutsumi 《Mineralium Deposita》1984,19(3):237-242

Fractionation of sulfur isotopes and selenium was measured between coexisting pyrite and chalcopyrite and between coexisting pyrrhotite and chalcopyrite from the Besshi deposit of Kieslager-type, Central Shikoku, Japan. In all the pyrite-chalcopyrite pairs studied, ³⁴S is enriched in pyrite relative to chalcopyrite, while selenium is enriched conversely in chalcopyrite relative to pyrite. The mean ³⁴S_py-cp value is +0.53±0.36 per mil, and the mean value of the distribution coefficient of selenium, D_cp-py, is 2.58±0.64. In all the pyrrhotite-chalcopyrite pairs studied, the two minerals are very close to each other both in sulfur isotope and Se/S ratios. The mean ³⁴S_po-cp value is –0.08±0.16 per mil and the mean D_cp-po value is 0.99±0.05. The results have been discussed in comparison with similar data obtained for the Hitachi deposits of Kieslager-type, Japan (Yamamoto et al. 1983).  相似文献   

Pressure-temperature dependent compositional variation of phlogopitic micas in upper mantle peridotites     

Shoji Arai 《Contributions to Mineralogy and Petrology》1984,87(3):260-264

Compositional variation of phlogopitic micas in upper mantle peridotites is reviewed. Phlogopitic micas in garnet peridotites are systematically lower in Al (or eastonite component) than those in spinel peridotites. The core of phlogopite megacryst and phenocryst of kimberlite is always lower in Al than the rim. It is apparent that Al/(Al + Si) ratio or eastonite component in phlogopitic micas in ultramafic rocks is controlled by the equilibrium pressure and temperature. In the upper mantle peridotites containing garnet or spinel, the Al/(Al + Si) ratio of phlogopitic mica decreases with increasing pressure at constant temperature. Phlogopitic mica is a potential thermo-barometer in both garnet- and spinel-peridotite facies.  相似文献   

Hypocenter distribution and focal mechanism of AE events during two stress stage creep in Yugawara andesite     

Osamu Nishizawa  Kaoru Onai  Kinichro Kusunose 《Pure and Applied Geophysics》1984,122(1):36-52

More than a thousand acoustic-emission (AE) hypocenters were determined in a cylindrical andesite specimen under two-stage uniaxial creep at stresses of 204 and 214 MPa. Strains were monitored for 6 peripheral points at the middle part of the cylindrical specimen's wall. The strain data indicate gradual increase of nonuniform deformation during steady creep and strong intensification of the nonuniformity during acceleration creep and, therefore, biased stress distribution within the specimen. The correlation between dilatant strain and AE hypocenters was investigated for whether or not tensile cracks emit AE. The region with high AE activity shows only a small dilatant strain. This negative correlation between AE and the dilatant region may eliminate tensile cracks as possible AE sources. A composite focal-mechanism solution of local AE events, covering a wide solid angle of the focal hemisphere, indicates that shear fractures emit AE waves. The direction of the compressional axis in this solution shows a significant deviation from that inferred from the applied external force, suggesting that the local stress field is governed by preexisting weak zones that are, presumably, produced by tensile cracks within the specimen. AE hypocenters tended to form clusters during steady creep under the constant compressional stress. During acceleration creep caused by a small step increase of the external stress, the preceding clusters disappeared while a new cluster appeared in an incipient fault plane. This suggests that changes in seismicity pattern such as migrations or quiescences of swarm—important clues for earthquake predictions—may be caused by an instantaneous change in the tectonic-stress levels.  相似文献   

On the chondrite—achondrite transition: mineralogy and chemistry of Yamato 74160 (LL7)     

Hiroshi Takeda  Ted J. Huston  Michael E. Lipschutz 《Earth and Planetary Science Letters》1984,71(2):329-339

We report on the petrology, mineralogic properties and contents of major elements and trace elements Ag, Au, Bi, Cd, Co, Cs, Ga, In, Rb, Se, Te, Tl, U and Zn (determined by radiochemical neutron activation analysis) in Yamato 74160, interpreted as an LL7 chondrite. All properties are consistent with this meteorite having been recrystallized and partially melted locally once at temperatures well above 1090°C under conditions such that some minerals (e.g. plagioclase, euhedral pyroxene, tetrataenite) grew from melt pockets and siderophilic and chalcophilic elements were lost by extraction into eutectic melt that drained away. Inhomogeneous plagioclase compositions and mobile element loss suggest shock as the most likely heat source. Yamato 74160, while inferentially chondritic, is a larval achondrite: even higher temperatures and longer times would have been required to cause the separations necessary to transform it to an identifiable achondrite type.  相似文献   

Excess²²⁸Th in the airborne dust: an indicator of continental dust from the East Asian deserts     

Katsumi Hirose  Yukio Sugimura 《Earth and Planetary Science Letters》1984,70(1):110-114

Thorium isotopes in the airborne dust collected at Tsukuba Science City in Japan from January 1981 to December 1982 show clear seasonal variations. Especially²²⁸Th in the airborne particles have a typical maximum cincentration between February and April, which is about an order of magnitude higher than during the remainder of the year. According to the result of size distribution of thorium isotope-bearing particles in the air, about 53% of²²⁸Th is associated with the particles less than 1.6 μm aerodynamic diameter. These results reveal that²²⁸Th in the airborne particles is present in fine soily matters originating from the East Asian deserts.  相似文献   

Numerical and experimental models on the formation mechanism of collapse basins during the Green Tuff orogenesis of Japan     

H. Komuro  Y. Fujita  K. Kodama 《Bulletin of Volcanology》1984,47(3):649-666

The geological model about volcanism of the Green Tuff geosyncline deduced from the field observations consists of the following processes:

1. Dome-shaped uplift with a mean diameter of 30 km.
2. Collapse of the central part of the domes forming basins with a mean diameter of 10 km.
3. Volcanic activity inside the collapse basins. It is considered that these consecutive processes resulted from the magmatic uplift from a deep part of the crust.

In finite element analyses performed as plane strain problems, earth's crust is assumed to be an elasto-plastic homogeneous layer and to undergo sinusoidal vertical displacement at the base of the layer due to an ascending magma reservoir. These analyses reveal that the diameter of the dome is proportional to the depth of the magma reservoir rather than to its size. The magma reservoir is estimated at 12 ～ 24 km in depth. Scale model experiments using powdered material were performed in order to reproduce a collapse basin. These three-dimensional models are reduced to a scale of 1:200,000 th of the natural size. The results of experiments show that radial and concentric cracks are produced on top of the dome and a central part encircled by concentric cracks collapses to form a basin. The boundary of the collapsed portion forms a steep cliff with a height of about 2 mm. This is equivalent to 400 m in natural size and is nearly similar to field observations.  相似文献   

Application of an infrared carbon dioxide and humidity instrument to studies of turbulent transport   总被引：4，自引：0，他引：4  

Eiji Ohtaki 《Boundary-Layer Meteorology》1984,29(1):85-107

A calibration equation and some results of the field performance of an infrared instrument, which is designed to measure simultaneous fluctuations of atmospheric carbon dioxide and water vapor, are described. Field observations show that the instrument is suitable for simultaneous measurement of turbulent fluxes of carbon dioxide and water vapor in conjunction with a sonic anemometer. Measured values of carbon dioxide and water vapor fluxes show diurnal variations characterized by crop activity with respect to assimilation, respiration and evapotranspiration. Carbon dioxide is transferred downward during the daytime and upward at night, while latent heat and sensible heat are transferred in the opposite sense. The non-dimensional gradient of carbon dioxide is expressed in the following form under weak unstable conditions: _c = (1 – 16 _v )^-1/2. Here, _v is the Monin-Obukhov stability parameter including the humidity effect. This relation was originally proposed for temperature and humidity. Thus, the results indicate that the turbulent mechanisms of carbon dioxide fluctuations are similar to those of other scalar entities. This is strongly supported by the high correlation coefficient found between fluctuations of carbon dioxide and temperature or humidity in the air layer over crop fields.  相似文献