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Magmatism,metamorphism and metasomatism in the Palaeoproterozoic‐Mesoproterozoic Mt Painter Inlier and overlying Neoproterozoic Adelaidean rocks in the northern Flinders Ranges (South Australia) have previously been interpreted as resulting from the ca 500 Ma Delamerian Orogeny. New Rb–Sr, Sm–Nd and U–Pb data, as well as structural analysis,indicate that the area also experienced a second thermal event in the Late Ordovician (ca 440 Ma). The Delamerian Orogeny resulted in large‐scale folding, prograde metamorphism and minor magmatic activity in the form of a small volume of pegmatites and leucogranites. The Late Ordovician event produced larger volumes of granite (the British Empire Granite in the core of the inlier) and these show Nd isotopic evidence for a mantle component. The high‐temperature stage of this magmatic‐hydrothermal event also gave rise to unusual diopside‐titanite veins and the primary uranium mineralisation in the basement, of which the remobilisation was younger than 3.5 Ma. It is possible that parts of the Mt Gee quartz‐hematite epithermal system developed during the waning stages of the Late Ordovician event. We suggest that the Ordovician hydrothermal system was also the cause of the commonly observed retrogression of Delamerian metamorphic minerals (cordierite, andalusite) and the widespread development of actinolite, scapolite, tremolite and magnetite in the cover sequences. Deformation during the Late Ordovician was brittle. The recognition of the Late Ordovician magmatic‐hydrothermal event in the Mt Painter Province might help to link the tectonic evolution of central Australia and the southeast Australian Lachlan Fold Belt.  相似文献   
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The Taihe intrusion is one of the layered intrusions situated in the central zone of the Emeishan Large Igneous Province (ELIP), SW China. The cyclic units in the Middle Zone of the intrusion are composed of apatite-magnetite clinopyroxenite at the base and gabbro at the top. The apatite-rich oxide ores contain 6–12 modal% apatite and 20–50 modal% Fe-Ti oxides evidently distinguished from the coeval intrusions in which apatite-rich rocks are poor in Fe-Ti oxides. Most of apatites of the Taihe Middle and Upper Zones are fluorapatite, although four samples show slightly high Cl content in apatite suggesting that they crystallize from a hydrous parental magma. Compared to the apatite from the gabbro of the Panzhihua intrusion, situated 100 km to the south of the Taihe intrusion, the apatite of the Taihe rocks is richer in Sr and depleted in HREE relative to LREE. The calculated magma in equilibrium with apatite of the Taihe Middle and Upper Zones also shows weakly negative Sr anomalies in primitive mantle normalized trace element diagrams. These features indicate that the apatite of the Taihe Middle and Upper Zones crystallizes after clinopyroxene and before plagioclase. The apatite of the Taihe Middle and Upper Zones shows weakly negative Eu anomalies suggesting a high oxygen fugacity condition. The high iron and titanium contents in the oxidizing magma result in crystallization of Fe-Ti oxides. Crystallization of abundant Fe-Ti oxides and clinopyroxenes lowers the solubility of phosphorus and elevates SiO2 concentration in the magma triggering the saturation of apatite. The positive correlations of Sr, V, total REE contents and Ce/Yb ratio in apatite with cumulus clinopyroxene demonstrate approximately compositional equilibrium between these phases suggesting they crystallized from the same ferrobasaltic magma. Early crystallization and accumulation of Fe-Ti oxide together with apatite produced the apatite-rich oxide ores at the base of the cyclic units of the Taihe Middle Zone.  相似文献   
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《Gondwana Research》2016,29(4):1543-1565
Early Cambrian small skeletal fossils (SSFs) are studied and revised from the Zhenba–Fangxian Block of the transitional zone between the Yangtze Block and the South Qinling Terrane. The study reveals a diverse fauna with 47 species of various biological affinities, including the new species Gapparodus gapparites sp. nov. The SSFs are assigned to the newly defined Cambroclavus fangxianensisRhombocorniculum cancellatum Assemblage Zone. Based on the investigated SSF fauna from Zhenba County, Southeast Shaanxi of China and published data, a palaeobiogeographic study is carried out for the Cambrian Stage 3 (equivalent to the Atdabanian–Botoman of Siberia). A hierarchical Pearson similarity cluster analysis of 295 species from 32 regions of the world indicates a distinct palaeobiogeographic pattern with seven faunal provinces. The result is mostly consistent with existing palaeogeographic reconstructions for the early Cambrian. However, it is also shown that the SSF assemblages of the Zhenba–Fangxian Block have low similarity with those of the Yangtze Block. Instead, they share high similarity with those from Armorica, Tarim and the Karatau–Naryn terranes (South Kazakhstan/North Kyrgyzstan). The Yangtze Block has a unique SSF assemblage dissimilar to most of other regions. The Terreneuvian–Cambrian Stage 3 sedimentary sequence of the Zhenba–Fangxian Block is more consistent with that of the South Qinling Terrane. Besides, sedimentary Ediacaran manganese ore deposits and Cambrian barite/witherite deposits have unique distribution pattern on the Zhenba–Fangxian Block. Derived from the profound dissimilarities in faunal composition, sedimentary sequence and distribution of sedimentary ore deposits, we hypothesize that during the Neoproterozoic–Cambrian transition, the Zhenba–Fangxian Block might have been an independent terrane and more distant from the Yangtze Block. The palaeobiogeographic analysis of SSFs also indicates a closer alliance between Avalonia and Siberia. It corroborates the palaeogeographic reconstruction of North China at the margin of Gondwana, in the vicinity of Australia, Antarctica, and Armorica.  相似文献   
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The tectonics, dynamics, and biogeographic landscape of the early Paleozoic were dominated by the opening and expansion of one large ocean—the Rheic—and the diminution to terminal closure of another—Iapetus. An understanding of the evolution of these oceans is thus central to an understanding of the early Paleozoic, but their chronicle also presents a rich temporal profile of the Wilson cycle, illustrating continental-scale rifting, microcontinent formation, ocean basin development, arc accretion, and continent–continent collision. Nevertheless, contemporary paleogeographic models of the Iapetus and Rheic oceans remain mostly schematic or spatiotemporally disjointed, which limits their utility and hinders their testing. Moreover, many of the important kinematic and dynamic aspects of the evolution of these oceans are impossible to unambiguously resolve from a conceptual perspective and the existing models unsurprisingly present a host of contradictory scenarios. With the specific aim to resolve some of the uncertainties in the evolution of this early Paleozoic domain, and a broader aim to instigate the application of quantitative kinematic models to the early Paleozoic, I present a new plate tectonic model for the Iapetus and Rheic oceans. The model has realistic tectonic plates, which include oceanic lithosphere, that are defined by explicit and rigorously managed plate boundaries, the nature and kinematics of which are derived from geological evidence and plate tectonic principles. Accompanying the presentation and discussion of the plate model, an extensive review of the underlying geological and paleogeographic data is also presented.  相似文献   
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The overall effects of trawling on benthic habitats and their assemblages are dependent on the distribution and intensity of trawl effort. The benthic habitats of the Spencer Gulf prawn trawling grounds are subjected to known variable levels of trawling disturbance recorded from fisher's logbooks. These habitats have not been quantitatively investigated. The aim of the study was firstly to characterise the macro-faunal and -floral assemblages and secondly, to comparatively assess trawl impact by testing the null hypothesis of no differences between five sites exposed to different intensity of trawl effort. The distribution and abundance of benthic macro-fauna and -flora were studied at two sampling resolutions by using beam trawl sampling (10,000 m2) and underwater stereophotography (4.5 m2) at five sites with different levels of trawl disturbance (effort). The results showed that the Spencer Gulf prawn trawling grounds are characterised by sandy sediments with a low content of silt and clay, with the exception of one site with very fine gravel. Biomass, abundance and cover of macro-fauna and -flora were generally low throughout, but with large differences among sites. Biomass, abundance and cover were found to be negatively correlated to both trawl hours from 1994–1998 and during the period of study. ANOSIM and SIMPER analyses using biomass, abundance and percentage cover as variables showed significant differences between sites with eight species or taxonomic groups contributing more than 10% to the observed similarity within sites. The two northern sites were dominated by sponges and the bearded mussel, Trichomya hirsutus, and the southern hammer oyster, Malleus meridianus. Other species that contributed to the similarity within sites were the ascidian, Polycarpa viridis, mobile epifauna (the blue swimmer crab, Portunus pelagicus, and the western king prawn, Penaeus (Melicertus) latisulcatus) and demersal fish species (Degens leatherjacket, Thamnaconus degeni, and the Melbourne silver belly, Parequula melbournensis). Simpson's Index of Diversity (1 − λ) and species richness in the beam trawl samples were fairly even across all sites, but a significant effect of site was found in the stereophotographic transect samples. It was concluded that prawn trawling has a strong influence on the structure of the benthic habitats of the Spencer Gulf prawn fishing grounds highlighted by the magnitude of change and the strength of the gradient of effects. Confounding factors linked to the biophysical attributes of the sites are believed to be minor.  相似文献   
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Chloride and hydrosulfide are the principal ligands assumed to govern transport of copper in hydrothermal fluids. Existing solubility experiments suggest that Cu(I)-hydrosulfide complexes are dominant compared to chloride complexes at low salinities in alkaline solutions (H2S(aq)/HS pH buffer), and may be important in transporting Cu in low density magmatic vapors, potentially controlling the liquid-vapor partitioning of Cu. This study provides the first in situ evidence of the solubility of copper sulfides and the nature and structure of the predominant Cu species in sulfur-containing fluids at temperatures up to 592 °C and pressures of 180-600 bar. XANES and EXAFS data show that at elevated T (?200 °C), Cu solubility occurs via a linear Cu complex. At 428 °C in alkaline solutions, Cu is coordinated by two sulfur atoms in a distorted linear coordination (angle ∼150-160°). This geometry is consistent with the species predicted by earlier solubility studies. In addition, in situ measurements of the solubility of chalcocite in 2 m NaHS solutions performed in this study are in remarkably good agreement with the solubilities calculated using available thermodynamic data for Cu(I)-hydrosulfide complexes, also supporting the interpretation of speciation in these studies and validating the extrapolation of low-T thermodynamic properties for to high P-T. Data on phase separation for the 2 m NaHS solution show that while significant amounts of copper can be partitioned into the vapor phase, there is no indication for preferential partitioning of Cu into the vapor. This is consistent with recent partitioning experiments conducted in autoclaves by Pokrovski et al. (2008a) and Simon et al. (2006). XANES data suggest that the species present in the low density phase is very similar to that present in the high density liquid, i.e., , although Cu(HS)(H2S)0 cannot be excluded on the basis of XAS data.  相似文献   
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Phengite is the main potassic dioctahedral mica identified at the Olympic Dam iron oxide–copper–gold (IOCG) deposit, South Australia, where its mineral chemistry is quite variable. These differences can be explained by contrasting degrees of hydrothermal alteration. In the heavily-sericitized, ore-bearing rocks, the phengites display a lower-Si content, a higher-Al content, and a lower Mg-number than the phengites from the weakly-sericitized alteration halo that surrounds the deposit. Variations are also observed in the near- and mid-infrared reflectance spectra collected from phengite-bearing rocks. In the near-infrared, high-Al phengite produces a spectral absorption feature at 2.206 μm, and this feature is displaced to 2.213 μm for low-Al phengite. In the mid-infrared, high-Al phengite produces a strong reflectance peak at 9.59 μm, whereas this peak is observed at 9.57 μm in the spectra from low-Al phengite. Additional peaks were also identified at 10.98, 12.22, and 13.33 μm. These were most intense in the spectra from high-Al phengite. A drill core profile was produced using the results of the spectral analysis that shows the change in phengite mineral chemistry and phengite abundance as a function of depth. In general, near- and mid-infrared reflectance spectroscopy can be used to characterize the aluminum content of potassic dioctahedral micas like phengite, and this information can be used to infer the degree of sericitic alteration that has occurred as a result of hydrothermal fluid flow.  相似文献   
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The Neoproterozoic (815.4 ± 4.3 Ma) Aries kimberlite intrudes the King Leopold Sandstone and the Carson Volcanics in the central Kimberley Basin, northern Western Australia. Aries is comprised of a N–NNE-trending series of three diatremes and associated hypabyssal kimberlite dykes and plugs. The diatremes are volumetrically dominated by massive, clast-supported, accidental lithic-rich kimberlite breccias that were intruded by hypabyssal macrocrystic phlogopite kimberlite dykes and plugs with variably uniform- to globular segregationary-textured groundmasses. Lower-diatreme facies, accidental lithic-rich breccias probably formed through fall-back of debris into the vent with a major contribution from the collapse of the vent walls. These massive breccias are overlain by a sequence of bedded volcaniclastic breccias in the upper part of the north lobe diatreme. Abundant, poorly vesicular to nonvesicular, juvenile kimberlite ash and lapilli, with morphologies that are indicative of phreatomagmatic fragmentation processes, occur in a reversely graded volcaniclastic kimberlite breccia unit at the base of this sequence. This unit and overlying bedded accidental lithic-rich breccias are interpreted to be sediment gravity-flow deposits (including possible debris flows) derived from the collapse of the crater walls and/or tephra ring deposits that surrounded the crater. Diatreme-forming eruptions may have been initiated by magma–water interactions along fracture and joint-controlled aquifers within the King Leopold Sandstone. The current level of exposure of the diatremes probably extends from the lower-diatreme facies up into the base of a bedded upper-diatreme sequence.  相似文献   
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