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Jean-Jacques Peucat Johildo Salomão Figueiredo Barbosa Ivana Conceição de Araújo Pinho Jean-Louis Paquette Hervé Martin C. Mark Fanning Angela Beatriz de Menezes Leal Simone Cruz 《Journal of South American Earth Sciences》2011,31(4):397-413
This work provides five new U–Pb zircon dating and the corresponding Nd isotope data for felsic granulites from the south Itabuna-Salvador-Curaçá Block (ISCB), in the São Francisco Craton, Brazil. Three major sets of felsic granulites can be recognised. The oldest set is tonalitic in composition and of TTG affinity. It is Archaean in age with magmatic zircon cores dated at 2675 ± 11 Ma by LA-ICPMS and up to ca 2.7–2.9 Ga by SHRIMP on an other sample. It exhibits epsilon Nd values between ?8 and ?11 at 2.1 Ga. This Nd signature is similar to that of granulites found in the western Archaean Jequié Block. Cartographically, this set of Archaean terrains represents at least 50% of the granulites in the studied area. The second set corresponds to a Palaeoproterozoic calc-alkaline tonalitic suite with zircon ages from 2019 ± 19 Ma to 2191 ± 10 Ma and epsilon Nd values between ?3 and ?4 at 2.1 Ga, corresponding partially to a newly formed crust. The third set of granulites is also Palaeoproterozoic. It is shoshonitic to monzonitic in composition and synchronous with the high grade metamorphism dated by metamorphic zircons at 2086 ± 7 Ma (average of five samples). The Nd isotope signature for this alkaline set is similar to that of the Palaeoproterozoic calc-alkaline one. Nd isotopes appear to be a very efficient tool to distinguish Archaean from Palaeoproterozoic felsic protoliths in granulitic suites of the Itabuna-Salvador-Curaçá Block (ISCB). Finally, the southern part of the ISCB is composed of a mixture of Archaean and Palaeoproterozoic protoliths, in similar amounts, suggesting that it was probably an active margin between 2.1 and 2.2 Ga located on the eastern border of the Archaean Jequié Block. A major crustal thickening process occurred at ca 2.09 Ga in the ISCB and seems significantly younger towards the west, in the Jequié granulites, where an average of 2056 ± 9 Ma is determined for the high grade event. 相似文献
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The Zhibula Cu skarn deposit contains 0.32 Mt. Cu metal with an average grade of 1.64% and is located in the Gangdese porphyry copper belt in southern Tibet. The deposit is a typical metasomatic skarn that is related to the interaction of magmatic–hydrothermal fluids and calcareous host rock. Stratiform skarn orebodies occur at the contact between tuff and marble in the Lower Jurassic Yeba Formation. Alteration zones generally grade from a fresh tuff to a garnet-bearing tuff, a garnet pyroxene skarn, and finally to a wollastonite marble. Minor endoskarn alteration zonations are also observed in the causative intrusion, which grade from a fresh granodiorite to a weakly chlorite-altered granodiorite, a green diopside-bearing granodiorite, and to a dark red-brown garnet-bearing granodiorite. Prograde minerals, which were identified by electron probe microanalysis include andradite–grossularite of various colors (e.g., red, green, and yellow) and green diopside. Retrograde metamorphic minerals overprint the prograde skarn, and are mainly composed of epidote, quartz, and chlorite. The ore minerals consist of chalcopyrite and bornite, followed by magnetite, molybdenite, pyrite, pyrrhotite, galena, and sphalerite. Three types of fluid inclusions are recognized in the Zhibula deposit, including liquid-rich two-phase inclusions (type L), vapor-rich two-phase inclusions (type V), and daughter mineral-bearing three-phase inclusions (type S). As the skarn formation evolved from prograde (stage I) to early retrograde (stage II) and later retrograde (stage III), the ore-forming fluids correspondingly evolved from high temperature (405–667 °C), high salinity (up to 44.0 wt.% NaCl equiv.), and high pressure (500–600 bar) to low-moderate temperature (194–420 °C), moderate-high salinity (10.1–18.3 and 30.0–44.2 wt.% NaCl equiv.), and low-moderate pressure (250–350 bar). Isotopic data of δ34S (− 0.1‰ to − 6.8‰, estimated δ34Sfluids = − 0.7‰), δDH2O (− 91‰ to − 159‰), and δ18OH2O (1.5‰ to 9.2‰) suggest that the ore-forming fluid and material came from magmatic–hydrothermal fluids that were associated with Miocene Zhibula intrusions. Fluid immiscibility likely occurred at the stage I and stage II during the formation of the skarn and mineralization. Fluid boiling occurred during the stage III, which is the most important Cu deposition mechanism for the Zhibula deposit. 相似文献
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金川铜镍硫化物矿床是我国最主要的铂族元素(PGE)资源产地,其矿石受热液蚀变作用影响明显,并产出多种铂族矿物(PGM)。岩浆演化和热液蚀变过程中PGE的迁移富集机制和PGM的成因,一直是研究PGE地球化学行为非常关注的问题。本文对金川铜镍硫化物矿床中PGM的研究发现,其主要类型包括含PGE的硫砷化物(硫砷铱矿)和砷化物(砷铂矿),Pd的铋化物、碲化物和硒化物,以及少量其他铂族矿物。其中,硫砷铱矿可包裹于各种贱金属硫化物(镍黄铁矿、磁黄铁矿和黄铜矿)中,表明硫砷铱矿可能结晶于早期的含As硫化物熔体,随后被包裹于硫化物熔体冷凝分异产生的单硫化物固溶体(MSS)和中间硫化物固溶体(ISS)中。硫化物熔体中的As可能主要通过地壳混染作用加入幔源岩浆。大量铋钯矿(PdBi)呈微细乳滴状包裹于黄铜矿中,为晚期ISS冷凝形成黄铜矿过程中出溶的产物。少量铋钯矿(PdBi_2)呈不规则状充填于矿物裂隙,与次生磁铁矿脉紧密共生,并随矿石的蚀变程度增加,铋钯矿的化学成分由PdBi逐渐向PdBi_2转变,表明这部分铋钯矿为后期热液蚀变产物。铋碲钯矿和钯的硒化物则主要产出于镍黄铁矿裂隙且与次生磁铁矿紧密共生,指示明显的热液成因。钯的硒化物的出现表明,岩浆期后酸性、高盐度、高氧逸度的富Cl~-流体对金川铜镍硫化物矿床中Pd的迁移和富集起到了关键控制作用。 相似文献
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广西丹池成矿带芒场矿田岩浆岩源区特征及锆石U-Pb年龄分析 总被引：1，自引：0，他引：1
丹池成矿带是我国重要锡多金属成矿带,过去对丹池成矿带成岩成矿研究主要集中在大厂矿田及五圩矿田,而对丹池成矿带北部的芒场矿田岩浆作用时代、源区特征及其成矿性缺少分析。芒场矿田岩浆活动强烈,发育隐伏斑状花岗岩及有关的花岗斑岩脉和隐伏细粒花岗斑岩及有关的白云母花岗斑岩脉。本文分析花岗斑岩脉U-Pb年龄及花岗斑岩脉和白云母花岗斑岩脉主、微量元素组成,以探讨岩浆活动时代、岩浆源区特征及其成矿潜力。芒场矿田花岗斑岩脉锆石U-Pb年龄为89.1±0.9Ma (MSWD=0.9),和丹池成矿带内大厂矿田岩浆活动时代相近,表明丹池成矿带岩浆活动时代都发生于90Ma左右。白云母花岗斑岩脉具高A/CNK比值(2.69～2.88),含高铝硅酸盐矿物白云母及在Th-Rb图上沿S型花岗岩趋势线分布,和大厂矿田S型黑云母花岗岩的特征基本一致,表明其主要为S型花岗岩。花岗斑岩脉形成时代晚于白云母花岗斑岩脉,但其具有更低的SiO_2含量和更高的MgO、Fe_2O_3~T、CaO和TiO_2含量,且在SiO_2与TiO_2、Fe_2O_3~T、Al_2O_3和P_2O_5关系图中分布于不同区域,没有线性变化关系,显示两者不是同一岩浆结晶分异演化形成的,而为不同沉积变质岩部分熔融形成的。白云母花岗斑岩脉富Al_2O_3、K_2O、Rb、Cs、Sn、W、Nb和Ta,在Rb/Ba-Rb/Sr图上位于富粘土源区,为强风化作用形成的富粘土质富稀有金属源区部分熔融形成的产物。华南西部基底发育经强风化作用形成的富粘土质富稀有金属元素沉积变质源区,为华南西南缘大规模锡矿床的形成提供了物质基础。 相似文献
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《Journal of Asian Earth Sciences》2007,29(1):177-180
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《Russian Geology and Geophysics》2014,55(2):237-251
The authors analyze the geodynamic settings of large fields of spodumene pegmatites hosting Li and complex (Li, Cs, Ta, Be, and Sn) deposits of rare metals within the Central Asian Fold Belt. Most of the studied fields show a considerable time gap (from few tens of Myr to hundreds of Myr) between the spodumene pegmatites and the associated granites, which are usually considered parental. This evidence necessitates recognition of an independent pegmatite stage in the magmatic history of some pegmatite-bearing structures in Central Asia. The Precambrian–Late Mesozoic interval is marked by a close relationship between the large fields of spodumene pegmatites and extension settings of continental lithosphere. They occur either as (1) zones of long-lived deep faults bordering on trough (rift) structures experiencing the tectonic-magmatic activity or as (2) postcollisional zones of shearing and pull-apart dislocations. Thus, large fields of spodumene pegmatites might serve as indicators of continental-lithosphere extension. Important factors favoring the formation of rare-metal pegmatites both in collision zones and continental-rift settings are the presence of thick mature crust dissected by long-lived, deeply penetrating (down to the upper mantle) fault zones. They ease the effect of deep sources of energy and substance on crustal chambers of granite and pegmatite formation. 相似文献
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The initiation timing and mechanism of lithospheric thinning of the North China Craton (NCC) was still controversial. Late Triassic igneous rocks especially mantle derived mafic rocks would provide constrains on Early Mesozoic lithospheric mantle geodynamics and initiation of lithospheric thinning. This paper reports Late Triassic magmatic rocks, including lamprophyre, diorite dykes and biotite monzogranite cropped out in Qingchengzi district of Liaodong peninsula, northeastern NCC. LA–ICPMS zircon U–Pb dating yield ages of 210–227 Ma and 224 Ma for lamprophyres and biotite monzogranite respectively. Lamprophyre is ultrapotassic, strongly enriched in REE and LILEs, depleted in HFSEs, and negative Hf isotopes, which are discriminating signatures of crustal source, but distinguishingly high compatible element contents indicate the primary magma originated from mantle source—a fertile one. Lamprophyre derived from partial melting of an enriched lithospheric mantle, which was modified by slab-derived hydrous fluids/melts associated with deep subduction between the Yangtze Craton and the NCC. The diorite displays distinct features with relatively enriched Nb, Ta, HREE and depleted Th, U, which suggest it derived from a relatively depleted source. The depletion was caused by break-off of the Yangtze slab during deep subduction introducing asthenospheric mantle into the source. The biotite monzogranite shows adakitic affinity, and originated from partial melting of the thickened lower crust with addition of small proportion of mantle material. The recognition of Late Triassic magmatism implies extensional tectonic settings in Liaodong peninsula and suggests initiation of lithospheric thinning of North China Craton in eastern segment might begin early in Late Triassic. 相似文献
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The Yinjiagou Mo–Cu–pyrite deposit of Henan Province is located in the Huaxiong block on the southern margin of the North China craton. It differs from other Mo deposits in the East Qingling area because of its large pyrite resource and complex associated elements. The deposit’s mineralization process can be divided into skarn, sulfide, and supergene episodes with five stages, marking formation of magnetite in the skarn episode, quartz–molybdenite, quartz–calcite–pyrite–chalcopyrite–bornite–sphalerite, and calcite–galena–sphalerite in the sulfide episode, and chalcedony–limonite in the supergene episode. Re–Os and 40Ar–39Ar dating indicates that both the skarn-type and porphyry-type orebodies of the Yinjiagou deposit formed approximately 143 Ma ago during the Early Cretaceous. Four types of fluid inclusions (FIs) have been distinguished in quartz phenocryst, various quartz veins, and calcite vein. Based on petrographic observations and microthermometric criteria the FIs include liquid-rich, gas-rich, H2O–CO2, and daughter mineral-bearing inclusions. The homogenization temperature of FIs in quartz phenocrysts of K-feldspar granite porphyry ranges from 341 °C to >550 °C, and the salinity is 0.4–44.0 wt% NaCl eqv. The homogenization temperature of FIs in quartz–molybdenite veins is 382–416 °C, and the salinity is 3.6–40.8 wt% NaCl eqv. The homogenization temperature of FIs in quartz–calcite–pyrite–chalcopyrite–bornite–sphalerite ranges from 318 °C to 436 °C, and the salinity is 5.6–42.4 wt% NaCl eqv. The homogenization temperature of FIs in quartz–molybdenite stockworks is in a range of 321–411 °C, and the salinity is 6.3–16.4 wt% NaCl eqv. The homogenization temperature of FIs in quartz–sericite–pyrite is in a range of 326–419 °C, and the salinity is 4.7–49.4 wt% NaCl eqv. The ore-forming fluids of the Yinjiagou deposit are mainly high-temperature, high-salinity fluids, generally with affinities to an H2O–NaCl–KCl ± CO2 system. The δ18OH2O values of ore-forming hydrothermal fluids are 4.0–8.6‰, and the δDV-SMOW values are between −64‰ and −52‰, indicating that the ore-forming fluids were primarily magmatic. The δ34SV-CDT values of sulfides range between −0.2‰ and 6.3‰ with a mean of 1.6‰, sharing similar features with deeply sourced sulfur, implying that the sulfur mainly came from the lower crust composed of poorly differentiated igneous materials, but part of the heavy sulfur came from the Guandaokou Group dolostone. The 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb values of sulfides are in the range of 17.331–18.043, 15.444–15.575, and 37.783–38.236, respectively, which is generally consistent with the Pb isotopic signature of the Yinjiagou intrusion, suggesting that the Pb chiefly originated from the felsic–intermediate intrusive rocks in the mine area, with a small amount of lead from strata. The Yinjiagou deposit is a porphyry–skarn deposit formed during the Mesozoic transition of a tectonic regime that is EW-trending to NNE-trending, and the multiepisode boiling of ore-forming fluids was the primary mechanism for mineral deposition. 相似文献
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Two late Mesozoic granitoids in the Luanchuan area of the East Qinling orogen are considered; ore-bearing rocks are granite porphyries and granodiorite, with K2O > Na2O, appearing in the form of stocks. The Laojunshan rocks contains dominantly monzonitic granite, with K2O ≈ Na2O, in the form of a batholith. Both the ore-bearing rocks and the Laojunshan rocks are highly siliceous and shoshonitic, high-K calc-alkaline, similar to some I-type granites. Light rare earth elements (LREEs) are enriched in both rock suites, although the Luanchuan ore-bearing granitoids have higher concentrations, with (La/Yb)N ratios twice that of the barren Laojunshan granite suite. Ore-bearing rocks have, therefore, undergone greater fractionation of heavy rare earth elements. All Laojunshan rocks have negative Eu anomalies, indicating plagioclase fractionation. δEu values are different in both rock suites, the values in the ore-bearing granites, ranging from 0.52 to 1.04, which are much higher than that of Laojunshan batholith, ranging from 0.4 to 0.65. (La/Sm)N values of ore-bearing granites are 5.32–8.28, while that of Laojunshan batholith are 3.75–5.77, confirming the observation that the ore-bearing granites have undergone a higher degree of strong differentiation than that of Lanjunshan batholith.Major and trace element data, and REE data, combined with isotope data from previous work and the close relationships between the tectonic settings of the barren and ore-bearing rocks indicate that both groups of rocks were derived from the lower crust. At ∼157 Ma, with the tectonic regime in transition from a syn-collisional to a post-collisional setting, highly fractionated granites ascended from their storage area via faults; at ∼145 Ma, ore-bearing plutons, which are triggered by slab melts, formed at the junctions of fault planes trending WNW-ESE and NE-SW. At ∼115 Ma, the tectonic regime changed from compression to extension; in this environment, the barren Laojunshan batholith was emplaced, representing the end of the collisional event. 相似文献