Origin of K-rich diamond-forming immiscible melts and CO2 fluid via partial melting of carbonated pelites at a depth of 180–200 km     

《Gondwana Research》2019

Melt inclusions in kimberlitic and metamorphic diamonds worldwide range in composition from potassic aluminosilicate to alkali-rich carbonatitic and their low-temperature derivative, a saline high-density fluid (HDF). The discovery of CO₂ inclusions in diamonds containing eclogitic minerals are also essential. These melts and HDFs may be responsible for diamond formation and metasomatic alteration of mantle rocks since the late Archean to Phanerozoic. Although a genetic link between these melts and fluids was suggested, their origin is still highly uncertain. Here we present experimental results on melting phase relations in a carbonated pelite at 6 GPa and 900–1500 °C. We found that just below solidus K₂O enters potassium feldspar or K₂TiSi₃O₉ wadeite coexisting with clinopyroxene, garnet, kyanite, coesite, and dolomite. The potassium phases react with dolomite to produce garnet, kyanite, coesite, and potassic dolomitic melt, 40(K_0.90Na_0.10)₂CO₃·60Ca_0.55Mg_0.24Fe_0.21CO₃ + 1.9 mol% SiO₂ + 0.7 mol% TiO₂ + 1.4 mol% Al₂O₃ at the solidus established near 1000 °C. Molecular CO₂ liberates at 1100 °C. Potassic aluminosilicate melt appears in addition to carbonatite melt at 1200 °C. This melt contains (mol/wt%): SiO₂ = 57.0/52.4, TiO₂ = 1.8/2.3, Al₂O₃ = 8.5/13.0, FeO = 1.4/1.6, MgO = 1.9/1.2, CaO = 3.8/3.2, Na₂O = 3.2/3.0, K₂O = 10.5/15.2, CO₂ = 12.0/8.0, while carbonatite melt can be approximated as 24(K_0.81Na_0.19)₂CO₃·76Ca_0.59Mg_0.21Fe_0.20CO₃ + 3.0 mol% SiO₂ + 1.6 mol% TiO₂ + 1.4 mol% Al₂O₃. Both melts remain stable to at least 1500 °C coexisting with CO₂ fluid and residual eclogite assemblage consisting of K-rich omphacite (0.4–1.5 wt% K₂O), almandine-pyrope-grossular garnet, kyanite, and coesite. The obtained immiscible alkali‑carbonatitic and potassic aluminosilicate melts resemble compositions of melt inclusions in diamonds worldwide. Thus, these melts entrapped by diamonds could be derived by partial melting of the carbonated material of the continental crust subducted down to 180–200 km depths. Given the high solubility of chlorides and water in both carbonate and aluminosilicate melts inferred in previous experiments, the saline end-member, brine, could evolve from potassic carbonatitic and/or silicic melts by fractionation of Ca-Mg carbonates/eclogitic minerals and accumulation of alkalis, chlorine and water in the residual low-temperature supercritical fluid. Direct extraction from the hydrated marine sediments under conditions of cold subduction would be another possibility for the brine formation.  相似文献   

Benthic foraminiferal fauna and sediment provenance of Eocene syn-rift sequences in Taiwan: implication for onset of Asian epi-continental marginal seas off China coast     

Huang  Chi-Yue  Shao  Lei  Wang  Ming-Huei  Xue  Wei-Guang  Qiao  Pei-Jun  Cui  Yu-Chi  Hou  Yuan-Li 《Marine Geophysical Researches》2019,40(2):111-127

Marine Geophysical Research - Early Cenozoic rift basins developed commonly on the Mesozoic basement along the SE Asia Continent. However, Eocene–Oligocene sequences were only exposed widely...  相似文献   

Preface to Special Issue ‘Insights on the vertebrate paleontology of the Neuquén Group,Argentina’     

《Cretaceous Research》2018

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南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪   总被引：1，自引：1，他引：0  

张美  陆红锋  管红香  刘丽华  邬黛黛  吴能友 《海洋学报(英文版)》2018,37(7):20-27

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.  相似文献   

Using Models of the Deep Structure of the Earth’s Crust and Upper Mantle Based on GOCE Gravity Data in Metallogenic Analysis     

Volkov  A. V.  Galyamov  A. L.  Savchuk  Yu. S. 《Izvestiya Atmospheric and Oceanic Physics》2020,56(12):1528-1536

Izvestiya, Atmospheric and Oceanic Physics - Gravimetric data obtained by the GOCE spacecraft contributes to the development of global models of the deep structure of the Earth’s crust and...  相似文献   

Two generations of Variscan garnet: Implications from a petrochronological study of a high-grade Avalonia-derived paragneiss from the Drosendorf unit,Bohemian Massif     

《Gondwana Research》2020

Garnets in metapelitic paragneisses from the southern Drosendorf unit in the Austrian part of the Bohemian Massif exhibit two episodes of growth during the Variscan orogeny, which can be distinguished on textural and chemical grounds. The first garnet (grt1) records evidence of high-grade metamorphism in the Late Devonian (Frasnian–Famennian), while the second garnet (grt2) formed by a second high-grade event in the Early Carboniferous (Visean). Both garnet generations contain abundant inclusions, of which monazite, rutile and crystallised melt droplets are particularly useful for reconstructing P–T–t conditions. The Late Devonian age (373 ± 9 Ma) for the first episode of garnet growth was obtained from chemical dating of monazite inclusions in grt1. Metamorphic conditions during the first episode of garnet growth are estimated to have been between 0.7 and 0.8 GPa at 680–700 °C and 0.95–1.10 GPa at 745–785 °C. There followed a phase of cooling and exhumation, after which the second garnet (grt2) were formed beginning under amphibolite facies conditions and continuing prograde to peak conditions of 0.95–1.10 GPa and 745–785 °C, which are similar to those of the first garnet forming event. Subsequently, the rocks experienced near isothermal decompression to 0.5–0.8 GPa. Chemical dating of both monazite inclusions in grt2 and the matrix provide a Visean age (343 ± 3 Ma).A study of detrital zircons in these paragneisses revealed zircon forming events at around 1.2, 1.5 and 1.8 Ga, suggesting an Avalonian provenance. The lack of zircons younger than 1 Ga and the presence of Cadomian metamorphic monazite relics (652 ± 15 Ma) indicates an Early Neoproterozoic deposition age for the sedimentary protolith likely. Our documentation of a Late Devonian high-grade metamorphic event in rocks derived from Avalonian corroborates tectonic models which assume that frontal parts of the Armorican terrane had already docked with Avalonia by this time.  相似文献   

Stratigraphy and palaeoenvironments across the Jurassic-Cretaceous boundary in the reference section (Olenek River) for eastern regions of Laptev Sea area (Arctic Siberia,Russia)     

《世界地质(英文版)》2019,22(4)

The Volgian-Valanginian succession of shallow-water deposits from the Olenek section(Anabar-Lena region, Arctic Siberia) has been studied by sedimentological and palaeontological methods. High-resolution biostratigraphy of studied interval is based on the ammonites, foraminifers, marine and terrestrial palynomorphs. Foraminiferal and palynological zones have important regional implications providing well-constrained biostratigraphy of the Anabar-Lena region. Sedimentological studies together with ecological analysis of the associations of microbenthos, microphytoplankton and terrestrial palynomorphs allow the palaeoenvironmental reconstructions for the marginal area of the Anabar-Lena palaeosea and coastal land areas.  相似文献   

Comprehensive Geological–Geophysical and Botanic Study of the Tectonic Junction Zone between the Katun Ridge and Uimon Depression (Altai Mountains)     

Boyarskikh  I. G.  Agatova  A. R.  Kulikova  A. I.  Bakiyanov  A. I.  Skaptsov  M. V.  Mazeika  J. 《Izvestiya Atmospheric and Oceanic Physics》2018,54(8):805-825

Izvestiya, Atmospheric and Oceanic Physics - Areas with large gradients and anomalous variations in geomagnetic and radiation fields have been revealed and mapped at the northwestern foot of the...  相似文献   

Geophysical Signature of the Shallow Water Flow in the Deepwater Basin of the Northern South China Sea     

Xiaohua Zhang  Yunbao Sun  Shiguo Wu 《中国海洋大学学报(英文版)》2018,17(4):791-798

Shallow water flow (SWF), a disastrous geohazard in the continental margin, has threatened deepwater drilling operations. Under overpressure conditions, continual flow delivering unconsolidated sands upward in the shallow layer below the seafloor may cause large and long-lasting uncontrolled flows; these flows may lead to control problems and cause well damage and foundation failure. Eruptions from over-pressured sands may result in seafloor craters, mounds, and cracks. Detailed studies of 2D/3D seismic data from a slope basin of the South China Sea (SCS) indicated the potential presence of SWF. It is commonly characterized by lower elastic impedance, a higher Vp/Vs ratio, and a higher Poisson’s ratio than that for the surrounding sediments. Analysis of geological data indicated the SWF zone originated from a deepwater channel system with gas bearing over-pressured fluid flow and a high sedimentation rate. We proposed a fluid flow model for SWF that clearly identifies its stress and pressure changes. The rupture of previous SWF zones caused the fluid flow that occurred in the Baiyun Sag of the northern SCS.  相似文献   

珠江口淇澳岛滨海湿地沉积环境演化及其对人类活动的响应   总被引：1，自引：1，他引：0  

叶翔  李靖  王爱军 《海洋学报》2018,40(7):79-89

滨海湿地作为人类活动和全球变化反应最为敏感的区域，其沉积记录可以反映出周边地区环境变化及人类活动信息。珠江口淇澳岛滨海湿地钻孔分析结果表明，在中全新世期间淇澳岛附近海域为河口湾环境，在风化层以上开始出现淤积，但在4 200 a BP前后受极冷气候的影响，沉积物粗化；自2 500 a BP以来，沉积环境相对稳定，在小冰期期间略有变化。沉积速率计算结果显示:淇澳岛附近海域自中全新世高海面以来的平均沉积速率为0.29 cm/a，4 160~2 500 a BP、2 500 a BP-1488年、1488-1893年、1893-1986年、1990-2007年期间的平均沉积速率分别为:0.17 cm/a、0.23 cm/a、0.35 cm/a、1.37 cm/a和5.94 cm/a，沉积速率逐渐增大，反映了珠江三角洲演化过程中沉积相与沉积环境的变化；1986-1990年期间的海堤建造极大地扰动了该钻孔上部的沉积过程，在工程施工期间共沉积了厚度约112 cm的沉积层，而在海堤建成后，沉积速率也显著增大。沉积物总有机碳、总氮和C/N值的垂向分布表明，在4 160~2 500 a BP期间受海洋环境影响较大，沉积物中有机碳以海源为主，2 500 a BP以来沉积物中碳、氮含量明显增大，C/N也相应变大，有机碳主要来源于陆源输入，但在小冰期期间海源有机碳贡献略有所增大；近百年来由于受人类活动影响显著，陆源有机碳的贡献快速增加。  相似文献