Oxidation of pyrite during extraction of carbonate associated sulfate     

Pedro J. Marenco  Frank A. Corsetti  Douglas E. Hammond  Alan J. Kaufman  David J. Bottjer 《Chemical Geology》2008,247(1-2):124-132

The sulfur isotopic composition of carbonate associated sulfate (CAS) has been used to investigate the geochemistry of ancient seawater sulfate. However, few studies have quantified the reliability of δ³⁴S of CAS as a seawater sulfate proxy, especially with respect to later diagenetic overprinting. Pyrite, which typically has depleted δ³⁴S values due to authigenic fractionation associated with bacterial sulfate reduction, is a common constituent of marine sedimentary rocks. The oxidation of pyrite, whether during diagenesis or sample preparation, could thus adversely influence the sulfur isotopic composition of CAS. Here, we report the results of CAS extractions using HCl and acetic acid with samples spiked with varying amounts of pyrite. The results show a very strong linear relationship between the abundance of fine-grained pyrite added to the sample and the resultant abundance and δ³⁴S value of CAS. This data represents the first unequivocal evidence that pyrite is oxidized during the CAS extraction process. Our mixing models indicate that in samples with much less than 1 wt.% pyrite and relatively high δ³⁴S_pyrite values, the isotopic offset imparted by oxidation of pyrite should be much less than ? 4‰. A wealth of literature exists on the oxidation of pyrite by Fe³⁺ and we believe this mechanism drives the oxidation of pyrite during CAS extraction, during which the oxygen used to form sulfate is taken from H₂O, not O₂. Consequently, extracting CAS under anaerobic conditions would only slow, but not halt, the oxidation of pyrite. Future studies of CAS should attempt to quantify pyrite abundance and isotopic composition.  相似文献   

华南前寒武系基底变质杂岩和中-新生代地幔岩的稀有气体同位素组成及其大地构造意义          下载免费PDF全文

谢窦克  邢光福  陆志刚  陈荣  周宇章 《地质科学》2008,43(1):175-204

对华南前寒武系变质岩浆杂岩稀有气体He、Ne、Ar和Xe的系统研究表明:扬子克拉通基底为含高³He的下地壳"原始岩石层",(³He/⁴He)×10^-6比值为2.8～4.6;而华夏板块基底变质岩浆杂岩则是在缺乏³He、低(³He/⁴He)×10^-8比值(3.15～17.7)的构造环境下形成的大陆中-上地壳变质岩浆杂岩层,反映出两者基底性质迥然不同。华南中-新生代爆破岩筒He同位素组成相反,相对稳定的扬子克拉通(³He/⁴He)×10^-8比值仅0.18～4.22,而郯庐-四会-吴川断裂以东,中-新生代活动地块(太平洋构造域)(³He/⁴He)×10^-8比值高达3.7～20.5。He同位素表明郯庐-四会-吴川断裂带为切割深至地幔的边界深大断裂,是扬子克拉通与华夏板块间的边界且控制了燕山期火山-侵入岩浆向西扩展。Ar同位素组成表明华南大陆中-新生代地幔形成接近"均一"的地幔组份。¹³⁶Xe/¹³⁰Xe-¹²⁹Xe/¹³⁰Xe相关组份表明它们具有地幔柱岩石同位素组成特征。  相似文献   

试论雁荡山岩石地貌     

陶奎元  沈加林  姜杨  余明刚 《岩石学报》2008,24(11):2647-2656

雁荡山岩石地貌由叠嶂、方山、石门、柱峰、锐峰、岩洞、天生桥和峡谷、涧溪、瀑、潭、湖等岩石地貌组合而成。其形成的地质学、岩石学基础是白垩破火山岩相与构造。不同类型地貌景观反映了这一破火山构造。断裂切割、重力崩塌与流水侵蚀是形成此类地貌的主要外动力地质作用。雁荡山岩石地貌在形态、成因和审美学意义上均有别于我国砂砾岩岩石地貌、碳酸岩岩石地貌和花岗岩岩石地貌。雁荡山地貌可作为流纹质火山岩地貌的代表。  相似文献   

花岗岩研究的误区——关于花岗岩研究的思考之五   总被引：3，自引：3，他引：0  

张旗  潘国强  李承东  金惟俊  贾秀勤 《岩石学报》2008,24(10):2212-2218

本文在对花岗岩四大基石(混合作用、结晶分离作用、构造环境和源区)问题分析的基础上,指出花岗岩研究存在的三大误区: (1)不恰当地仿效玄武岩的理论和研究方法,忽视了花岗岩的复杂性。(2)不恰当地用板块构造学说解释大陆花岗岩问题。板块构造是地球演化到一定阶段的产物,并成功解释了与板块边界相联系的岩浆活动,但是,它不能解决主要来源于大陆的花岗岩的地质问题。(3)太过重视花岗岩的地球化学研究而忽视了对花岗岩基础地质的研究。作者指出,地球化学方法在花岗岩中的使用应当是有限制的,花岗岩研究陷入误区是我们缺少扎实的基础研究、对板块构造的理解不深和对花岗岩复杂性认识不足等三个方面的原因造成的。文中还批评了学术界存在的人云亦云的奴性思想,指出它严重地阻碍了我们的创新思维,是当前亟待改进和克服的。  相似文献   

21世纪的花岗岩研究, 路在何方？——关于花岗岩研究的思考之六     

张旗  潘国强  李承东  金惟俊  贾秀勤 《岩石学报》2008,24(10):2219-2236

21世纪的花岗岩怎样研究是一个需要探索的问题。作者认为,应当对现有的花岗岩理论、流行的说法以及术语等进行清理和反思,汲取其精华,剔除其糟粕,抛弃那些不科学、不符合实际、不符合逻辑的部分。例如,在花岗岩研究中摈弃结晶分离的理论,缩小花岗岩混合作用的意义,限制花岗岩构造环境理论的应用,取消幔源、壳源和壳幔混合源的术语等。作者指出,今后花岗岩研究应当着重解决两个问题: (1)花岗岩是怎样的？(2)它何以是这样的？文中提出5个方面的任务作为今后研究的重点,即: 开展花岗岩立典式的研究,将花岗岩研究与古老地壳的研究结合起来,将花岗岩物理性质研究与地球化学究结合起来,开展广泛的实验岩石学研究和创建新的“大陆构造学”理论。鉴于花岗岩研究目前存在的严重误区,现有的花岗岩理论几乎全面崩溃,由四大基石支撑的花岗岩大厦行将坍塌,花岗岩研究正面临全球大洗牌。为此,作者建议开展一场关于花岗岩的大辩论,目的是清理思路,认清问题,明确方向,找到出路。作者呼吁,我们应当加强学习,加速引进人才,克服急躁情绪和浮夸的学风,摈弃从众思想和奴性思想,不以SCI论英雄,改进我们的学习,改善我们的制度,以推进花岗岩研究迈上新台阶。  相似文献   

柴达木察尔汗盐湖贝壳堤剖面介形类组合及其环境意义   总被引：3，自引：0，他引：3       下载免费PDF全文

张虎才  王强  彭金兰  陈光杰 《第四纪研究》2008,28(1):103-111

柴达木盆地察尔汗贝壳堤剖面记录了约39.7～17.514CkaB.P.期间古湖泊高湖面扩张、收缩的演化历史。剖面中丰富的介形类,皆为我国东部山间盆地～平原区系与西部高原区系常见种。依据青海地区现代介形类分布调查,可知研究剖面高湖面发育期为淡水湖,其中高分异度介形类组合代表近静水的浅湖环境,单种或近单种土星介大量出现层位指示缓流水环境,大量原生双壳类共生可能指示静水、较深水环境。据地层中介形类分布,自下而上划分为7个组合-沉积环境带,分别为:①少量湖沼种出现（积水洼地形成带）——湖泊前期,②单种缓流水种连续出现（湖泊初始形成带）——高湖面初始形成期,③高分异度组合、介形类富集（浅水大湖带）——高湖面水深加大期,④中分异度组合、介形类少量出现（深湖带）——高湖面最盛期,⑤中分异度组合、介形类少量出现、双壳类连续富集（湖泊变浅带）——高湖面略下降期,⑥缓流水介形类繁盛、双壳类多少不等（湖泊水位下降带）——古湖泊退缩期和⑦介形类稀少带——古湖泊快速消亡期。贝壳堤剖面所见双壳类在现代介形类调查区域没有发现,它们在地层中的出现,进一步指示大体相当MIS3阶段时期柴达木盆地比现代更温暖的气候背景,降水条件好于现代。  相似文献   

中国奥陶纪地理区划纲要          下载免费PDF全文

周志毅  甄勇毅  周志强  袁文伟 《古地理学报》2008,10(2):175-182

根据区域构造、古地理和地层资料,中国奥陶纪的诸多板块、地体和活动带应分属11个地理区。文章重点研究了各地理区的边界。这些相邻的地理区块在奥陶纪曾处于远距离分离状态,除华北区南界和华南区北界明显由同期秦岭活动带限定之外,地理区的界线大多只能沿发生在奥陶纪之后的构造拼贴结合带划定,只有塔里木区北界和北疆区南界,得以通过追索代表曾在奥陶纪时段内发育于塔里木板块/哈萨克斯坦中间板块/西伯利亚板块之间的局限洋盆或深海盆地遗迹（即残留缝合带）来予以确定。中国大陆的最终形成经历了从晚石炭世至新生代的长期地质演化过程,主要包括活动带的消减以及板块和地体的漂移、增生与会聚。  相似文献   

Carbon isotope stratigraphy using carbonate cements in the Triassic Sherwood Sandstone Group: Corrib Field,west of Ireland     

《Chemical Geology》2006,225(1-2):137-155

Carbon stable isotopes from carbonate minerals (mainly dolomite) from six wells from the Lower Triassic Sherwood Sandstones of the Corrib Gas Field, Slyne Basin, west of Ireland, allow stratigraphic correlation. The results also provide information on palaeoenvironmental change during the deposition of these continental redbed sedimentary rocks. The Triassic reservoir rocks have been buried to > 4000 m and heated to > 165 °C and now contain methane-rich gas. Although the oxygen isotopic signal has been at least partially reset during burial and heating, a primary carbon isotopic signal appears to have survived diagenesis. The carbon isotope ratio varies from − 3.2‰ to + 2.1‰. All six wells show similar stratigraphic changes when all the carbon isotope data are plotted relative to a major playa horizon. δ¹³C increases from about − 3‰ at the base of the Sherwood to about + 2‰ 170 m above the base. δ¹³C then decreases to about − 2‰ for the next 70 m and remains steady for the following 50 m. The top 20 m of the Sherwood contains carbonate with a δ¹³C values decreasing to about − 3‰. The occurrence of a stratigraphically-correlatable carbon isotope pattern implies that the primary evolution signal has been preserved. The change in δ¹³C correlates with indicators of aridity and biological stress such that the highest δ¹³C values are in sedimentary rocks deposited in a playa lake (arid times); these rocks contain the greatest quantity of dolomite cement. Conversely, the lowest δ¹³C values correspond to sedimentary rocks deposited from well-developed rivers (relatively humid times) from the lowest quantity of dolomite cement. The same carbon isotope evolution has been found in another well in the Slyne basin and in Belgium, suggesting that the palaeoenvironmental isotope signal in the Triassic sedimentary rocks of the Corrib Field may have a regional significance.  相似文献   

蒙脱石脱水作用与地面沉降关系的研究展望   总被引：7，自引：0，他引：7  

杨献忠杨祝良  陈敬中胡存礼袁平  魏乃颐 《岩石矿物学杂志》2005,24(6):659-665

粘土矿物在地面沉降中的作用、粘土矿物的脱水作用对地面沉降的影响等日益成为评价和防治地质、工程、水文、环境等问题的关键,也一直是相关领域的研究难题而逐渐引起高度重视。本文回顾了蒙脱石层间水性质、层间水化膨胀和脱水收缩的影响因素,提出蒙脱石层间的固溶体特征,在总结蒙脱石脱水作用与地面沉降关系研究成果的基础上,提出了用蒙脱石脱水作用研究地面沉降的思路。最后讨论了用蒙脱石的脱水作用研究地面滞后沉降及沉降趋势预测的可能性。  相似文献   

Geology, Geochemistry and Genesis of the Hongshijing Gold Deposit in Ruoqiang,Xinjiang     

肖惠良  周济元  王鹤年  崔炳芳  陈世忠 《中国地球化学学报》2003,22(3):280-288

1IntroductionTheHongshijinggolddepositislocatedinthenorthofLuobupouLakeofRuoqiang ,about 30 0kmsouthwestofHamiCity ,Xinjiang .ItwasdiscoveredbytheSixthGeologicalTeamofXinjiangduringgeo chemicalexploration .TheHongshijinggolddeposit,whichoccursinthegold bearingformationcomposedofMiddleandLateCarboniferousvolcanicandpyroclasticrocks ,isabrittle ductileshearzonetypegolddepositcontrolledbyariftbelt.TheHongshijinggolddepositislocatedinthesouthwestoftheHongshi jing -Maotoushanmineralizationb…  相似文献