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1.
Mantle-derived carbonatites provide a unique window in the understanding of mantle characteristics and dynamics, as well as insight into the assembly and breakup of supercontinents. As a petrological indicator of extensional tectonic regimes, Archean/Proterozoic carbonatites provide important constraints on the timing of the breakup of ancient supercontinents. The majority of the carbonatites reported worldwide are Phanerozoic, in part because of the difficulty in recognizing Archean/Proterozoic carbonatites, which are characterized by strong foliation and recrystallization, and share broad petrologic similarities with metamorphosed sedimentary lithologies. Here, we report the recognition of a ~1.85 Ga carbonatite in Chaihulanzi area of Chifeng in north China based on systematic geological, petrological, geochemical, and baddeleyite U-Pb geochronological results. The carbonatite occurs as dikes or sills emplaced in Archean metasedimentary rocks and underwent intense deformation. Petrological and SEM/EDS results show that calcite and dolomite are the dominant carbonate minerals along with minor and varied amounts of Mg-rich mafic minerals, including forsterite (with Fo > 98), phlogopite, diopside, and an accessory amount of apatite, baddeleyite, spinel, monazite, and ilmenite. The relatively high silica content together with the non-arc and OIB-like trace element signatures of the carbonatite indicates a hot mantle plume as the likely magma source. The depleted Nd isotopic signatures suggest that plume upwelling might be triggered by the accumulation of recycled crust in the deep mantle. As a part of the global-scale Columbia supercontinent, the Proterozoic tectonic evolution of the North China Craton (NCC) provides important insights into the geodynamics governing amalgamation and fragmentation of the supercontinent. The Paleo-Mesoproterozoic boundary is the key point of tectonic transition from compressional to extensional settings in the NCC. The newly identified ~1.85 Ga carbonatite provides a direct link between the long-lasting supercontinental breakup and plume activity, which might be sourced from the “slab graveyard,” continental crustal slabs subducted into asthenosphere, beneath the supercontinent. The carbonatite provides a precise constraint of the initiation of the continental breakup at ~1.85 Ga. 相似文献
2.
曲家金矿位于胶东焦家成矿带中段,为新城金矿和马塘金矿的深部延深,矿体赋存深度300~1300 m。对区内32个钻孔岩心样品进行了取样,获得了34个元素的分析数据,研究了各元素的浓度分带及成分分带。发现多元素在此深度范围内除沿矿体轴向有迁移成晕外,在垂向上也有迁移和成晕现象,这对于穿透性地球化学和原生晕找矿机理研究有重要意义。同时发现成矿元素在成矿带轴向和垂向上的扩散受多种因素影响,包括矿体部位,成矿热液中元素浓度、热液的温度压力、围岩化学活性和可渗透性等,在空间分布上具有复杂性。原生晕的高浓度带主要沿断裂蚀变带分布。用格里戈良法和重心法确定的轴向成分分带,在深部有头晕元素与尾晕元素的叠加,预示深部仍存在隐伏金矿体,这与西部邻近招贤勘查区深部发现金矿体的勘查结果相符。垂向上从浅到深成分分带性存在差异,垂向上易在浅部浓集的元素为Se、Cd、Mo、Hg、Bi、S、F、Cu、Ag,成矿带附近浓集的元素为Sb、As、Au、W等,As、Sb在垂向上的迁移能力弱,主要沿轴向迁移。当浅部多个元素同时达到K2O≥4.57×10–2,Au≥0.8×10–9,Ag≥0.057×10–6,Cu≥2.5×10–6,Bi≥0.08×10–6,Hg≥17×10–9,S≥0.0583×10–2,Mo≥0.74×10–6,W≥0.55×10–6时,指示深部发现金矿体的可能性较大,Hg·Ag/(As·W)、Bi·Hg/(As·Au)指数可用来判断金矿体的埋深。 相似文献
3.
The Sanshandao gold deposit (reserves of more than 200 t Au and average grade of 3.96 g/t), located at northwestern edge of the Jiaodong Peninsula, eastern North China Craton, is one of the largest gold deposits in the Jiaodong gold province. In this deposit, disseminated- and stockwork-style ores are hosted in Mesozoic granitoids; mineralization and alteration are largely controlled by the regional Sanshandao–Cangshang fault. Host granitic rocks for the deposit display a complex paragenetic sequence of alteration and mineralization. Activities of the Sanshandao–Cangshang fault created structurally controlled permeability allowing for infiltration of hydrothermal fluids, leading to diffusive K-feldspar alteration on the two fault planes. Later, large scale diffusive sericitization symmetrically developed across the main fault, and partially overprinted the earlier K-feldspar alteration. Following the sericitization, relatively small scale silicification occurred, but now it is only retained in the hanging wall of the main fault. Subsequently, the fault gouge formed as a “barrier layer”, which is impermeable for later fluids to move upward. After that, strong pyrite–sericite–quartz alteration occurred only in the footwall of the main fault, and was accompanied by gold precipitation. The last stage carbonation and quartz-carbonate veins marked the waning of gold-related hydrothermal activity. Mass-balance calculations indicate complex behaviors of different types of elements during fluid–rock interaction. Most major elements were affected by intensive mineral replacement reactions. As expected, the fluid-mobile elements, LILE and LREE, generally show moderate to high mobility. It is notable that even the commonly assumed fluid-immobile elements, such as HREE and HFSE, tend to be changed to various degrees. In addition, Y–Ho, Zr–Hf and Nb–Ta fractionations are observed in altered domains. Studies on alteration assemblages and fluid inclusions suggest that the ore-forming fluids were characterized by low salinity (≤ 8.4 wt.% NaCl equiv.), moderate temperature (300–400 °C), weakly acidic (pH: 3–5), and relatively reducing (log fO2: ~–28) characteristics. In this type of fluids, gold was most likely transported as Au(HS)2− complex. With alteration going on, log (aK+/aH+) of fluids generally decreased due to significant formation of secondary K-bearing minerals. In addition, there might be a decrease of fO2 from pre-gold alteration stage to the main gold mineralization stage, and decrease of fO2 was probably one of the factors controlling gold precipitation. The Sr and Nd isotopic compositions of hydrothermal minerals, combined with previous H–O and He–Ar isotopic studies, indicate that the hydrothermal fluids were mainly derived from crustal sources (e.g., degassing of felsic magmas and meteoric water), but with involvement of mantle derived components. The gold mineralization event just coincided with reactivation of the North China Craton, as marked by asthenosphere upwelling, voluminous igneous rocks, and high crustal heat flow, which may have provided sufficient heat energy and fluid input required for the formation of the gold deposits. 相似文献
4.
《Chemie der Erde / Geochemistry》2023,83(2):125955
The buildup of high pressure in the casing-casing annulus (CCA) threatens well integrity and can cause serious incidents in case of left untreated. Either, trapped water in the cement column or a dynamic water inflow represent potential fluid sources for the elevated CCA pressure. This study presents a sequential methodology to determine the provenance of CCA effluent as trigger for high pressure in newly drilled wells. Single fluid types, multicomponent mixing, and secondary fluid alteration processes were identified through inorganic geochemical techniques; in detail by monitoring the hydrochemical (major, minor, and trace elements) and stable isotopic (δ2H, δ18O) relationship between fluid candidates. As a proof-of-concept, geochemical signatures of CCA effluent from three wells were linked with potential source candidates, i.e., utilized drilling fluids (mud filtrate, supply water) from the prospect well site, groundwater from Lower - Upper Cretaceous aquifers, and Upper Jurassic - Upper Triassic formation waters from adjacent wells and fields. The detection of geochemical affinities of CCA water with groundwater from a Lower Cretaceous aquifer postulates one single lithological unit as source for active groundwater inflow. Nonreactive elements (Na+, Cl−) and environmental isotopes (δ2H, δ18O) were found to be most suited tools for primary fluid identification. The 2H/1H and 18O/16O ratios of supply water and mud filtrate are generally close to global meteoric water and Tertiary groundwater composition, while formation water from Mesozoic units (Cretaceous, Jurassic, and Triassic) can individually be distinguished through increasing ratios in δ18O and δ2H. Compositional anomalies in SO42− and K+, and extreme alkaline conditions for CCA water indicate the occurrence of secondary fluid alteration processes, likely caused by the contact of inflowing groundwater with alkaline minerals in the cement column or by fluid mixing with residuals of potassium chloride (KCl) additives from the drilling process. The geochemical techniques from this study facilitate the detection of high CCA pressure and fluid leakages sources. As a practical benefit, workover engineers are enabled to plan for potential remedial actions prior to moving the rig to affected well sites; thereby significantly reducing operational costs. Appropriate remedial solutions can be induced for safe well abandonment, plus to resume operation at the earliest time. 相似文献
5.
The Qiangma gold deposit is hosted in the > 1.9 Ga Taihua Supergroup metamorphic rocks in the Xiaoqinling terrane, Qinling Orogen, on the southern margin of the North China Craton. The mineralization can be divided as follows: quartz-pyrite veins early, quartz-polymetallic sulfide veinlets middle, and carbonate-quartz veinlets late stages, with gold being mainly introduced in the middle stage. Three types of fluid inclusions were identified based on petrography and laser Raman spectroscopy, i.e., pure carbonic, carbonic-aqueous (CO2–H2O) and aqueous inclusions.The early-stage quartz contains pure carbonic and CO2–H2O inclusions with salinities up to 12.7 wt.% NaCl equiv., bulk densities of 0.67 to 0.86 g/cm3, and homogenization temperatures of 280−365 °C. The early-stage is related to H2O–CO2 ± N2 ± CH4 fluids with isotopic signatures consistent with a metamorphic origin (δ18Owater = 3.1 to 5.2‰, δD = − 37 to − 73‰). The middle-stage quartz contains all three types of fluid inclusions, of which the CO2–H2O and aqueous inclusions yield homogenization temperatures of 249−346 °C and 230−345 °C, respectively. The CO2–H2O inclusions have salinities up to 10.9 wt.% NaCl equiv. and bulk densities of 0.70 to 0.98 g/cm3, with vapor bubbles composed of CO2 and N2. The isotopic ratios (δ18Owater = 2.2 to 3.6‰, δD = − 47 to − 79‰) suggest that the middle-stage fluids were mixed by metamorphic and meteoric fluids. In the late-stage quartz only the aqueous inclusions are observed, which have low salinities (0.9−9.9 wt.% NaCl equiv.) and low homogenization temperatures (145−223 °C). The isotopic composition (δ18Owater = − 1.9 to 0.5‰, δD = − 55 to − 66‰) indicates the late-stage fluids were mainly meteoric water.Trapping pressures estimated from CO2–H2O inclusions are 100−285 MPa for the middle stage, suggesting that gold mineralization mainly occurred at depths of 10 km. Fluid boiling and mixing caused rapid precipitation of sulfides and native Au. Through boiling and inflow of meteoric water, the ore-forming fluid system evolved from CO2-rich to CO2-poor in composition, and from metamorphic to meteoric, as indicated by decreasing δ18Owater values from early to late. The carbon, sulfur and lead isotope compositions suggest the hostrocks within the Taihua Supergroup to be a significant source of ore metals. Integrating the data obtained from the studies including regional geology, ore geology, and fluid inclusion and C–H–O–S–Pb isotope geochemistry, we conclude that the Qiangma gold deposit was an orogenic-type system formed in the tectonic transition from compression to extension during the Jurassic−Early Cretaceous continental collision between the North China and Yangtze cratons. 相似文献
6.
Xincheng is a world-class orogenic-gold deposit hosted by the Early Cretaceous Guojialing granitoid in the Jiaodong Peninsula, eastern China. A zircon U–Pb age of 126 ± 1.4 Ma, together with previous data, constrain the emplacement of the Guojialing intrusion to 132–123 Ma. The granitoid underwent subsolidus ductile deformation at >500 °C following its intrusion. The small difference in age between the youngest zircon U–Pb age of unaltered granitoid (~123 Ma) and the ca. 120 Ma 40Ar/39Ar ages of sericite, associated with breccias and gold mineralization within it indicate initial rapid cooling from magmatic temperatures to those prevalent during brittle deformation and associated gold mineralization at ~220–300 °C. Evidence of a direct association between granitic magmatism and gold mineralization, such as at least localized near-magmatic depositional temperatures and metal zoning evident in undoubted intrusion-related gold deposits, is absent. The 40Ar/39Ar age of ~120 Ma coincides with the mineralization age of many other orogenic-gold deposits along the Jiaojia Fault. Sixteen zircon fission-track (ZFT) ages across the ore and alteration zones range from 112.9 ± 3.4 to 99.1 ± 2.7 Ma. The long period of cooling to the ~100 Ma ZFT closure temperatures recorded here suggests that ambient temperatures for hydrothermal alteration systems lasted to ~100 Ma, possibly because of their focus at Xincheng within the young Guojialing granitoid as it cooled more slowly below approximately 300 °C to 220 °C. However, the restricted number of auriferous ore stages, combined with the presence of cross-cutting gold-free quartz-carbonate veins, indicate that gold itself was only deposited over a restricted time interval at ~120 Ma, consistent with studies of orogenic gold deposits elsewhere. This highlights the complex interplay between magmatism, deformation and the longevity of hydrothermal systems that cause genetic controversies. Based on apatite fission-track (AFT) ages, the Xincheng gold deposit was then uplifted and exhumed to near the surface of the crust at 15 Ma, probably due to movement on the crustal-scale Tan-Lu Fault. Recognition of such exhumation histories along gold belts has conceptual exploration significance in terms of the probability of discovery of additional exposed or sub-surface gold ore bodies as discovery is as much a function of preservation as formation of the deposits. 相似文献
7.
《Gondwana Research》2014,25(3-4):1172-1202
The Shandong Province along the southeastern margin of the North China Craton is the largest gold producing region in China. The nature and extent of gold metallogeny between the Western Shandong (Luxi) and Eastern Shandong (Jiaodong) sectors display marked contrast. In this paper, we synthesize the information on mineralization and magmatism, S–Pb–H–O–C–He–Ar isotopic data of the ores and Sr–Nd–Pb–Hf isotopic data of the Mesozoic plutons from the Shandong region. Combined with the salient regional geophysical data, we discuss the geodynamic setting of the gold mineralization in Shandong. The age data converge to indicate that the peak of gold metallogeny in this region occurred at ca. 120 ± 10 Ma. The mineralization in Luxi area shows links with sources in the Tongjing and Yinan complexes. The ore-forming materials in the Jiaodong area were derived from multiple sources and show clear evidence for crust–mantle mixing. The Moho depth on both sides of the Tan–Lu fault is broadly similar with only a minor variation across the Tan–Lu fault. The LAB (lithosphere–asthenosphere boundary) in the Jiaodong region is shallower than that in the Luxi area. The Tan–Lu fault is identified as a major corridor for asthenosphere upwelling. Geochemical features show that the mantle beneath the Luxi area is mainly of EM1 type, whereas the mantle in the eastern part, close to the Tan–Lu fault shows mixed EM1 and EM2 features. In contrast, the mantle beneath the Jiaodong area is mainly of EM2 type, suggesting the existence of more ancient lithospheric mantle beneath the Luxi area, in comparison to the extensively modified lithospheric mantle and asthenosphere beneath the Jiaodong area. The gold metallogeny in Shandong Province occurred in the geodynamic setting of lithospheric thinning. The differences in the character and intensity of gold mineralization between the Western and Eastern Shandong regions might be a reflection of the contrasting tectonic histories. The Western Shandong region preserves imprints of destruction through the Yangtze plate collision which probably marks the prelude for gold metallogeny in Jiaodong area. Subsequent magmatic input and cratonic destruction through Pacific plate subduction provided the settings for the later widespread mineralization in multiple phases. 相似文献
8.
月岭作为月海中一种广泛分布的线性构造,多表现为褶皱逆冲推覆为主的构造样式,且具雁列式展布。因此,月岭对月表区域乃至全月的构造应力分析有着非常重要的指示作用,但其成因机制不清。虹湾是中国嫦娥绕月探测工程研究的重点区域,区域内最明显的线性构造是虹湾东缘呈雁列式展布的月岭构造带,对这一月岭构造带的研究将有助于了解虹湾地区的区域应力特征和构造演化过程。文中通过对虹湾东缘雁列式月岭构造带的高分辨率影像进行解译并与其他区域对比分析,结合虹湾地区已有地质资料和前人提出的相关构造演化模式及目前最新的研究成果,认为虹湾东缘雁列式月岭构造带受虹湾撞击坑坑缘基底和表面玄武岩性影响,虹湾撞击盆地沉降引起的径向挤压应力和表面熔岩流导致的挤压应力由于方向与大小的差异,共同导致该月岭构造带呈类似走滑剪切中右阶左行的形貌特点。在此基础上讨论了此月岭构造带的演化过程,并根据月岭与撞击坑的交切关系,发现虹湾东缘月岭构造带在哥白尼纪仍在继续活动。 相似文献
9.
The Jiaodong peninsula contains the most important concentration of gold deposits in China, which can be divided into Jiaojia-type and Linglong-type deposits based on mineralization style. The former is characterized by disseminated- and stockwork-style mineralization hosted in first-order regional faults, with relatively larger tonnages and lower gold grades. The latter is characterized by massive auriferous quartz veins commonly hosted in subsidiary second- or third-order faults, with smaller tonnage but higher grade orebodies. Despite these differences, both groups of deposits have the same alteration assemblages, mineral paragenesis, element concentrations, and ore-forming ages.The mainly Jiaojia-type Luoshan gold deposit and the mainly Linglong-type Fushan gold deposit are characterized by H-O-S-Pb isotope data that indicate the ore-forming fluids have a dominantly metamorphic source. The fluids were derived during the Yanshanian orogenic event, and were most likely associated with dehydration and decarbonization processes near the top of the subducting paleo-Pacific plate. The Linglong-type ores have relatively lighter calculated δ18O compositions (−3.9 to −2.3‰) than the Jiaojia-type ores (0.3–8.0‰), possibly because of a greater degree of mixing with meteoric water. Petrographic, cathodoluminescence, microthermometric, and laser Raman spectroscopic analyses of fluid-inclusion assemblages in quartz from the two types of ores indicate fluids were similar, in both cases characterized by medium–high homogenization temperatures (211–393 °C), significant CO2 (∼15% mol), minor CH4 (⩽18% in the carbonic phase), and low salinity (⩽11.2 wt% NaCl eq.). The Linglong-type ores, however, have a wider range of CO2 and CH4 concentration and salinity than the Jiaojia-type ores. Fluid immiscibility, occurred in main ore stage of both ore types, with the trapping conditions of 77–185 MPa and 284–328 °C, although the unmixing is more intense and widespread in the Linglong-type ores. Both fluid-wallrock interaction and fluid immiscibility are important gold-deposition processes in the two types, but immiscibility is more important in the Linglong-type ores and that has led to the typical higher gold grade.In general, there is little geochemical differences between the ore-forming fluids for Jiaojia- and Linglong-type gold deposits. Both Jiaojia- and Linglong-type ores can exist in a single deposit and form in the same metallogenic event. The Linglong-type ores developed as more massive veins, because of their location in zones of more extensive extension and they lack significant post-ore cataclastic deformation. 相似文献
10.
虹湾幅月球数字地质图是中国首次编制的关于月球地质演化的地质图,应用的主要数据资料来源于"中国首次月球探测工程"嫦娥一号CCD影像数据、DEM数据,结合Clementine750nm影像数据,主要月坑的高分辨率图片,同时结合前人的研究成果,如主要矿物元素含量分布图、多波段反射率特征分布图等编制完成。所有的数据处理应用的是ArcMap平台,同时结合使用了MapGIS软件和Photoshop软件,数据模型采用Geodatabase地理数据模型。详细介绍了基于ArcGIS平台编制月球数字地质图的工作流程,编制方法及依据、编制规则及数据库的建立等,为今后开展月球数字地质图的编制积累了经验。 相似文献