Calorimetric study of high pressure polymorphism in FeTiO3: Stability of the perovskite phase     

Apurva Mehta  Kurt Leinenweber  Alexandra Navrotsky  Masaki Akaogi 《Physics and Chemistry of Minerals》1994,21(4):207-212

A calorimetric study of the ilmenite and lithium niobate polymorphs of FeTiO₃ was undertaken to assess the high-pressure stabilities of these phases. Ilmenite is known to be the stable phase at ambient pressure, but the lithium niobate form may be a quench phase from a perovskite form which has been previously observed in situ at high pressure.In this study, the lithium niobate phase of FeTiO₃ was synthesized from an ilmenite starting material at 15– 16 GPa and 1473 K, using a uniaxial split-sphere high-pressure apparatus (USSA 2000). The energetics of the ilmenite to lithium niobate transformation were investigated through transposed-temperature drop calorimetry. The heat of back-transformation of lithium niobate to ilmenite was measured by dropping the sample in argon from ambient conditions to a temperature where the transformation occurs spontaneously. In drops made at 977 K, an intermediate x-ray amorphous phase was encountered. At 1273 K, the transformation went to completion. A value of -13.5±1.2 kJ/mol was obtained for the heat of transformation.  相似文献   

Rare earth element evidence for differentiation of McMurdo volcanics,Ross Island,Antarctica     

Shen -Su Sun  Gilbert N. Hanson 《Contributions to Mineralogy and Petrology》1976,54(2):139-155

Eighteen samples of the McMurdo volcanics on Ross Island, Antarctica consisting of basanitoid, trachybasalt and phonolite have been analyzed for rare earth elements (REE) in order to determine the details of differentiation using quantitative trace element modeling. The basanitoids have REE patterns similar to those for alkali basalts or nephelinites from ocean islands. Since there is no correlation between REE and silica contents among five basanitoids, some of the variability in the REE contents must be related to the extent of partial melting, variation in the residual mineralogies of the mantle during melting, or to inhomogeneities in the REE composition of the mantle.In order to explain the data, more than one differentiation sequence is necessary. In each case a basanitoid melt is the parent which differentiates to trachybasalt upon separation of olivine, clinopyroxene, spinel, ±kaersutite±plagioclase±apatite. If clinopyroxene, kaersutite, anorthoclase, plagioclase and apatite separate from a trachybasalt melt, a mafic phonolite results.If, however, no kaersutite is involved, an anorthoclase phonolite results. A distinct type of mafic phonolite results if kaersutite is one of the minerals that separates from the anorthoclase phonolite. If the anorthoclase phonolite precipitates plagioclase and anorthoclase and if the melt reacts with plagioclase-rich continental rocks, a trachyte results.Formerly spelled: Shine Soon Sun  相似文献   

The duration of volcanism in Mare Serenitatis     

O.A. Schaeffer  L. Husain  G.A. Schaeffer 《Earth and Planetary Science Letters》1976,31(3):358-368

The crystallization ages of a suite of Apollo 17 basalts from four different stations have been measured using the³⁹Ar-⁴⁰Ar stepwise heating technique. The rocks analyzed include all principal petrographic types found at Apollo 17 landing site. A correlation between the ages and the petrographic type exists; plagioclase-poikilitic ilmenite basalts are youngest and olivine porphyritic ilmenite basalts are the oldest. The duration of volcanism in Mare Serenitatis is about 200 m.y., the same as observed for Mare Imbrium, and less than observed for Mare Tranquillitatis, 400 m.y. A relationship between duration of volcanism and gravity anomalies is noted. The cosmic ray exposure ages (in m.y.) for various locations range as: station 4, 58–315; station 5, 85–440; station 6, 110; station 8, 90–160.  相似文献   

A valid Margules formulation for an asymmetric ternary solution: revision of the olivine-ilmenite thermometer,with applications     

David J Andersen  Donald H Lindsley 《Geochimica et cosmochimica acta》1981,45(6):847-853

The olivine-ilmenite thermometer of Andersen and Lindsley (1979) was based on an incorrect formulation for the excess free energy of an asymmetric ternary solution. A valid formulation is derived and used to revise the parameters of the olivine-ilmenite thermometer. For olivine and ilmenite that have equilibrated above 700°C, temperature can be calculated from: $\text{T(°C) = ?273 +¦-12549 + P[0.03X}{}_{\mathrm{fa}}\text{+ 0.01099(X}{}_{\mathrm{gk}}\text{?X}{}_{\mathrm{il}}\text{)?0.062] + 10496 X}{}_{\mathrm{fa}}\text{+ 5767(X}{}_{\mathrm{gk}}\text{?X}{}_{\mathrm{il}}\text{) + X}{}_{\mathrm{hem}}\text{(38602?141550X}{}_{\mathrm{il}}\text{?47183X}{}_{\mathrm{gk}}\text{)|/[5.67?R ln K}{}_{\mathrm{D}}\text{+ 6.52X}{}_{\mathrm{fa}}\text{+ 3.09(X}{}_{\mathrm{gk}}\text{?X}{}_{\mathrm{il}}\text{) + X}{}_{\mathrm{hem}}\text{(16.49?109.46 X}{}_{\mathrm{il}}\text{?36.49X}{}_{\mathrm{gk}}\text{)]}$ with $\text{K}{}_{\mathrm{d}}\text{=}\text{(X}{}_{\mathrm{il}}\text{X}{}_{\mathrm{fo}}\text{)}\text{(X}{}_{\mathrm{gk}}\text{X}{}_{\mathrm{fa}}\text{)}$. The revised model gives W^il·gk_G = 5767?3.09T + 0.011P and ΔG_exch = 7301 ? 8.9T ? 0.047P (T in K, P in bars). Applications include Apollo 17 breccias and kimberlites.  相似文献   

Chemical studies of L-chondrites—I. A study of possible chemical sub-groups     

Charles W. Neal  Robert T. Dodd  Eugene Jarosewich  Michael E. Lipschutz 《Geochimica et cosmochimica acta》1981,45(6):891-898

Radiochemical neutron activation analysis of Ag, As, Au, Bi, Co, Cs, Ga, In, Rb, Sb, Te, Tl and Zn and major element data in 14 L4-6 and 3 LL5 chondrites indicates that the L-group is unusually variable and may represent at least 2 sub-groups differing in formation history. Chemical trends in the S/Fe-rich sub-group support textural evidence indicating late loss of a shock-formed Fe-Ni-S melt; the S/Fe-poor sub-group seemingly reflects nebular fractionation only. Highly mobile In and Zn apparently reflect shock-induced loss from L-chondrites. Data for L5 chondrites suggest higher formation temperatures and/or degrees of shock than for LL5 chondrites.  相似文献   

Lunar volcanic glasses and their constraints on mare petrogenesis     

J.W Delano  K Livi 《Geochimica et cosmochimica acta》1981,45(11):2137-2149

Volcanic glasses from the Apollo 11, 14, 15, and 16 landing sites have been analyzed for major elements and Ni by electron microprobe. The 19 varieties of volcanic glass define two distinct chemical arrays that provide new insights into (a) the petrogenesis of mare basalts and (b) the structure of the deep lunar interior. A simple model is proposed whereby mare basaltic liquids may have been derived from two isolated, cumulate systems occurring at depths of ~300 km and ? 400 km. Each system was itself composed of two lithologic components (low-Ti vs high-Ti) that underwent hybridization, assimilation, or mixing to generate the large compositional range of magmas observed within each array. While the distribution of the two components within each system was locally heterogeneous, data indicate that the components themselves were chemically uniform on at least a regional scale. The surface-correlated volatiles associated with the lunar volcanic glasses seem to have come from some other reservoir within the Moon.The simplicity of the chemical relationships observed among the lunar volcanic glasses allow specific-predictions to be made. We believe that they should readily reveal any strengths or weaknesses of this new model.  相似文献   

Elastic properties from acoustic and volume compression experiments     

Jay D. Bass  Robert C. Liebermann  Donald J. Weidner  Stephen J. Finch 《Physics of the Earth and Planetary Interiors》1981,25(2):140-158

Hydrostatic compression data for a number of high-pressure phases of oxides and silicates, which have been studied independently by acoustic techniques, have been analyzed by least-squares fitting of the Birch-Murnaghan equation of state to determine the zero-pressure bulk modulus K₀ and its pressure derivative K′₀ for each material. The standard deviations of K₀ and K′₀ so determined are generally underestimated unless the experimental errors in the measurements of volume and pressure are explicitly included. When the values of K₀ determined from the acoustic and compression techniques are consistent, test results for quartz and rutile demonstrate that constraining K₀ to be equal to the acoustic value significantly improves both the accuracy and the precision of K′₀ obtained from the compression data. Similar analyses for high-pressure phases (e.g., pyrope garnet and silicate spinels) indicate that by combining the acoustic and P-V data, the standard deviation of K′₀ is typically reduced by a factor of three. Thus, we conclude that this approach does allow precise determinations of K′₀ even when neither technique alone is able to resolve this parameter. For some materials, however, the P-V and acoustic experiments do not define mutually consistent values of K₀, invalidating any combination of these data. The compression data for stishovite clearly exhibit run to run effects, and we infer that systematic errors are present in some of the P-V data which are responsible for many of the interlaboratory inconsistencies. Such systematic biases in the P-V data can at least be partially compensated for by performing several duplicate experimental runs.  相似文献   

An experimental investigation of Iceland and Reykjanes Ridge tholeiites: I. Phase relations     

M. R. Fisk  J. -G. Schilling  H. Sigurdsson 《Contributions to Mineralogy and Petrology》1980,74(4):361-374

Tholeiite basalts from 60° N to 65° N on the Mid-Atlantic Ridge were melted and recrystallized at atmospheric pressure in a CO₂-H₂ gas mixture. Seven basalts are from the Langjokull-Thingvellir volcanic zone and the Reykjanes Peninsula of Iceland and nine are from the Reykjanes Ridge. The crystallization sequence in both Iceland and Reykjanes Ridge basalts with (Total Fe as FeO)/(Total Fe as FeO+ MgO) [F/F + M] less than 0.6 is olivine, plagioclase, clinopyroxene. Chromian spinel crystallizes before plagioclase in one Iceland and one Reykjanes Ridge basalt with F/F+M less than 0.57. Chemical differences of the two groups of basalts (lower SiO₂ and higher alkalis in Iceland basalts) can not simply be a result of low pressure fractional crystallization. Liquidus temperatures of the seven Iceland basalts decreases from 1,230° C to 1,170° C as the F/F+M of the rock increases from 0.52 to 0.70. The liquidus temperatures of the Reykjanes Ridge basalts are about 10° C lower than those of the Iceland basalts for the same F/F+M value. The profile of measured liquidus temperatures from 65° N on Iceland to 60° N on the Reykjanes Ridge has a minimum value at 63.2° N on the Reykjanes Ridge just south of Iceland. Model calculations of the pressure of phenocryst crystallization indicate that olivine and plagioclase in Langjokull basalts could have equilibrated between 2.0 and 6.2 kb (200 to 620 MPa). Phenocryst assemblages in Reykjanes Ridge basalts at 60° N could have crystallized together at greater than 2 kb (200 MPa) and probably less than 8 kb (800 MPa). A minimum in the equilibrium pressure of phenocryst crystallization occurs between 62.9° and 64° N and coincides with the minimum in the experimentally determined liquidus temperatures. The more extensive fractionation at low pressure in this area could be related to the shift of the Mid-Atlantic Ridge axis along the leaky transform fault from the Reykjanes Ridge to the Thingvellir volcanic zone.  相似文献   

Kinetics of silica sorption and clay dissolution reactions at 1 and 670 atm     

Ramesh Dayal 《Geochimica et cosmochimica acta》1977,41(1):135-141

Rates of reactions between clay minerals and silica-spiked seawater and the effect of pressure on the direction, extent and rate of such reactions have been studied. Kinetic behavior of short-term, clay-silica reaction indicates that diffusion is the rate controlling process in both clay dissolution and clay reconstitution reactions. Rate constants of these reactions are of the order of 10^?13 moles/ sec^{$\text{1}\text{2}$}cm². No significant pressure effect on the rate of clay dissolution was observed. Estimates of diffusion coefficient of silicic acid for clay dissolution and silica sorption reactions indicate that the true value lies within the range, 10^?13–10^?17cm²/sec, thus reflecting the semicrystalline or amorphous nature of the reaction product through which diffusion is occurring.  相似文献   

Incipient melting in and shock classification of L-group chondrites     

R.T. Dodd  E. Jarosewich 《Earth and Planetary Science Letters》1979,44(2):335-340

Thirty-three of 52 type L4 to L6 chondrites that we have examined in thin section contain closed bodies of crystal-laden glass or devitrified glass (melt pockets) that testify to in-situ melting. A close correlation between the distribution of melt pockets and shock intensity as inferred from the characteristics of olivine and plagioclase indicates that the pockets reflect shock melting. The appearance of pockets coincides with a sharp decrease of⁴⁰Ar in L-group chondrites, suggesting that shock melting was responsible for loss of argon and raising the possibility that this process redistributed other volatile elements as well. The use of three criteria for shock intensity — olivine and plagioclase characteristics, and the presence or absence of melt pockets — leads to a refined shock classification for equilibrated chondrites that is based entirely on petrographic observations.  相似文献