Preliminary Interlaboratory Trial for ISO/DIS 12010: Determination of Short Chain Polychlorinated Alkanes (SCCP) in Water     

Sabine Geiß  Nicole Lettmann  Aurélien Rey  Herbert Lepper  Birgit Körner  Silvio Mais  Theodor Prey  Bettina Hilger  Moana Engelke  Stephan Lebertz  Claudine Chatellier  George Sawal  Dirk Löffler  Tom Schillings 《洁净——土壤、空气、水》2011,39(6):537-542

A first preliminary interlaboratory trial was planned to prepare ISO/DIS 12010: Water quality – determination of short chain polychlorinated alkanes (SCCP) in water – method using GC/MS and electron capture negative ionisation (ECNI). The task was to determine the sum of short chain polychlorinated n‐alkanes with carbon chain lengths of C₁₀–C₁₃ and a chlorine content between 49 and 67% in water by GC‐ECNI‐MS and quantification by multiple linear regression described in ISO/DIS 12010 as the compulsory method. Distributed samples were obtained from a real water extract spiked with a target concentration of 0.4 µg/mL sum of SCCP, i.e. the environmental quality target level according to the Water Framework Directive. The interlaboratory trial included the calibration, a column chromatographic clean up, a concentration step and an integration of chromatographic unresolved humps as well as the quantification with multiple linear regression. Reproducibility standard deviations between 21.5 and 22.9% were achieved by 17 participating laboratories from four countries. The method outlined no significant difference of the results between the standard solution and a real water matrix extract. On the basis of this succeeded preliminary interlaboratory trial the final interlaboratory trial for validation of ISO 12010 was prepared in autumn 2010.  相似文献   

The Earth’s tungsten budget during mantle melting and crust formation   总被引：1，自引：0，他引：1  

S. König  C. Münker  H. Paulick  M. Lagos  A. Büchl 《Geochimica et cosmochimica acta》2011,75(8):2119-17609

During silicate melting on Earth, W is one of the most incompatible trace elements, similar to Th, Ba or U. As W is also moderately siderophile during metal segregation, ratios of W and the lithophile Th and U in silicate rocks have therefore been used to constrain the W abundance of the Earth’s mantle and the Hf-W age of core formation. This study presents high-precision W concentration data obtained by isotope dilution for samples covering important silicate reservoirs on Earth. The data reveal significant fractionations of W from other highly incompatible lithophile elements such as Th, U, and Ta. Many arc lavas exhibit a selective enrichment of W relative to Th, U, and Nb-Ta, reflecting W enrichment in the sub-arc mantle via fluid-like components derived from subducting plates. In contrast, during enrichment by melt-like subduction components, W is generally slightly depleted relative to Th and U, but is still enriched relative to Ta. Hence, all arc rocks and the continental crust exhibit uniformly low Ta/W (ca. 1), whereas W/Th and W/U may show opposite fractionation trends, depending on the role of fluid- and melt-like subduction components. Further high-precision W data for OIBs and MORBs reveal a systematic depletion of W in both rock types relative to other HFSE, resulting in high Ta/W that are complementary to the low Ta/W observed in arc rocks and the continental crust. Similar to previous interpretations based on Nb/U and Ce/Pb systematics, our Ta/W data confirm a depletion of the depleted upper mantle (DM) in fluid mobile elements relative to the primitive mantle (PRIMA). The abundance of W in the depleted upper mantle relative to other immobile and highly incompatible elements such as Nb and Ta is therefore not representative of the bulk silicate Earth. Based on mass balance calculations using Ta-W systematics in the major silicate reservoirs, the W abundance of the Earth’s primitive mantle can be constrained to 12 ppb, resulting in revised ratios of W-U and W-Th of 0.53 and 0.14, respectively. The newly constrained Hf-W ratio of the silicate Earth is 25.8, significantly higher than previously estimated (18.7) and overlaps within error the Hf-W ratio proposed for the Moon (ca. 24.9). The ¹⁸²Hf-¹⁸²W model age for the formation of the Earth’s core that is inferred from the ¹⁸²W abundance and the Hf/W of the silicate Earth is therefore younger than previously calculated, by up to 5 Myrs after solar system formation depending on the accretion models used. The similar Hf/W ratios and ¹⁸²W compositions of the Earth and the silicate Moon suggest a strong link between the Moon forming giant impact and final metal-silicate equilibration on the Earth.  相似文献   

Early Palaeozoic deep subduction of continental crust in the Kyrgyz North Tianshan: evidence from Lu–Hf garnet geochronology and petrology of mafic dikes     

Yamirka Rojas-Agramonte  Daniel Herwartz  Antonio García-Casco  Alfred Kröner  Dmitriy V. Alexeiev  Reiner Klemd  Stephan Buhre  Matthias Barth 《Contributions to Mineralogy and Petrology》2013,166(2):525-543

High-pressure and ultrahigh-pressure (UHP) eclogite-bearing metamorphic assemblages in the North Tianshan of Kyrgyzstan are known from the Aktyuz and Makbal areas, where eclogites and garnet amphibolites are associated with continental rocks such as granitoid gneisses in Aktyuz and shallow-water clastic (passive margin?) metasediments in Makbal. We present the first Lu–Hf isotope data for an eclogite and two garnet amphibolite samples from the two metamorphic terranes which, combined with petrological analysis, tightly constrain the age of high-pressure metamorphism in the Kyrgyz North Tianshan. A five-point isochron for an Aktyuz eclogite sample provides a Lu–Hf age of 474.3 ± 2.2 Ma, and a four-point isochron on a Makbal sample corresponds to 470.1 ± 2.5 Ma. A prograde, subduction-related path is inferred for both samples with peak P–T conditions ranging from 1.4 to 1.6 GPa and 610–620 °C. A further Makbal sample provided a significantly older Lu–Hf age of 486 ± 5.4 Ma, most likely due to late alteration in the sample (late addition of unradiogenic Hf). We conclude that garnet growth in all three samples occurred around ca. 474 Ma and that these rocks likely experienced UHP metamorphism contemporaneously. Our results support previous geochronological evidence for an Early Ordovician collision belt in the North Tianshan and allow refinement of a tectonic model involving subduction of thinned continental crust to considerable depth along the margin of a small microcontinent.  相似文献   

Quasistatic propagation of a normal fault: A fracture mechanics model     

《Journal of Structural Geology》1988,10(3):249-262

We have carried out boundary element calculations to simulate quasistatic propagation of a normal fault in the earth's crust under a horizontal tensile loading. Byerlee's frictional law is employed to describe the mechanical behavior of the fault surface. We hypothesize that in order for a normal fault to grow quasistatically, the mixed-mode effective shear stress intensity factor must exceed a threshold value (fracture toughness), a crustal material property. We suggest that the fault grows in a direction of local maximum shear stress. The direction of fault propagation thus depends on the ratio of tensile and shear stress intensity factors. A listric normal fault is likely to form in crustal material with a small shear fracture toughness. A listric normal fault is also more likely to form in crustal material with a high degree of plasticity.The propagation trajectory of an incrementally growing normal fault is examined. As the normal fault extends to a greater depth, the shear stress intensity factor drops, owing to an increase in fault surface friction. The equilibrium depth to which a normal fault will grow is controlled by the far field loading and the fracture mechanical property of the crustal material. The decrease of shear stress intensity with fault length also stabilizes the fault growth.  相似文献   

Quaternary mud turbidites from the South Shetland Trench (West Antarctica): recognition and implications for turbidite facies modelling     

SZCZEPAN J. POREBSKI  DIETER MEISCHNER†  KRZYSZTOF GÖRLICH 《Sedimentology》1991,38(4):691-715

A piston core from the basinal part (depth of 5188 m) of the South Shetland Trench (West Antarctica) yielded a terrigenous mud section 11 m long, which can be subdivided with great precision into turbidite and hemipelagite layers. Mud turbidites (mean bed thickness = 44 cm) alternate regularly with, and are best distinguishable from, their hemipelagite host (mean bed thickness = 17 cm) by the following features: (i) sharp basal contacts; (ii) terrigenous sand-free textures (except basal, well-sorted silt laminae) and the absence of outsized (ice-rafted) components; (iii) a laminated, little to non-bioturbated internal structure; (iv) distinct textural and compositional grading; and (v) marked steps on water-content and sediment-density logs. Mud turbidites recovered from the South Shetland Trench differ from an earlier model mud-turbidite sequence by their: (i) excessive (about six times larger) bed thickness; (ii) complex internal organization, manifested in multiple repetitions (up to four) of the same structural interval(s) in sequential or nonsequential order; (iii) distinctive very fine-grained cap of highly porous clay, rich in fragments of siliceous biogenics; (iv) widespread zones of penesyndepositional deformation; and (v) evidence of flow reversals. These features are interpreted to record deposition from large, muddy turbidity currents subjected to flow transformations, including soliton- and/or seiche-related reversals, induced by ponding and interactions of the flow with the topographical confinements of the trench. It is concluded that‘contained’muddy turbidites cannot be adequately modelled using published sequences. Differentiation of single-model and‘contained’mud turbidites offers obvious advantages in basin analysis and in understanding the plethora of turbidity current-related depositional mechanisms of deep-sea mud.  相似文献   

Diagenetische Entwicklung und faziesabhängige Na-Verteilung in Karbonat-Gesteinen Sloweniens     

B. Ogorelec Dipl.-Ing. geol.  Prof. Dr. P. Rothe 《International Journal of Earth Sciences》1979,68(3):965-978

Kurzfassung Natrium-Gehalte aus Karbonat-Profilen von Perm, Trias und Jura Sloweniens lassen sich mit deren lithofaziellen Parametern korrelieren. Etwa 650 Kalksteine und Dolomite aus 12 Profilen verschiedener Lokalitäten wurden auf Na analysiert und parallel dazu die Lithofazies bestimmt.Die Na-Gehalte der Kalksteine reichen von 30–240 ppm, die der Dolomite von 80 bis 550 ppm.Die höchsten Na-Gehalte in Kalksteinen (80–240 ppm) wurden in oberpermischen Kalksteinen aus evaporitischem Milieu gefunden, die niedrigsten (30–90 ppm) in Jura-Kalken des offenen Schelfbereiches.Die Na-Gehalte der untersuchten Dolomite sind allgemein höher; sie erreichen die höchsten Werte in einem frühdiagenetischen Obertrias-Dolomit, für dessen Entstehung supratidale Bedingungen angenommen werden.Spätdiagenetische Prozesse, besonders die späte Dolomitisierung, führten meist zu einer deutlich erfaßbaren Verarmung der Gesteine an Natrium, wobei Werte bis etwa 50 ppm erreicht werden.

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Sodium Contents of Permian, Triassic and Jurassic carbonates of Slovenia are correlated with the lithofacies of the rocks. About 650 samples of both limestones and dolostones were studied from 12 profiles of different localities.Sodium contents are 30 to 240 ppm Na in limestones, and 80 to 550 ppm Na in dolostones.Within limestones the highest sodium contents (80–240 ppm Na) were found from Upper Permian rocks which were formed in an evaporitic environment. The lowermost sodium concentrations (30–90 ppm Na) occur within Jurassic limestones from an open shelf environment.Within dolostones the sodium concentrations are generally higher than in limestones. They were found highest within early diagenetic, probably supratidal dolostones of Upper Triassic age.Influence of late diagenesis, particularly late diagenetic formation of saccharoidal dolomite, leads to a considerable decrease of sodium within the rocks. Concentrations of about 50 ppm Na are common.

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Résumé Il existe une corrélation entre les concentrations de Na et la lithofaciès des carbonates. On a analysé environ 650 échantillons de calcaire et de dolomie provenant de 12 profils de Slovenie, et appartenant stratigraphiquement au Permien, au Triassique et au Jurassique. Parallèlement aux analyses de Na on a microscopiquement déterminé la lithofaciès des roches.Dans les calcaires, les concentrations de Na varient entre 30 et 240 ppm; celles des dolomies, entre 80 et 550 ppm. Les teneurs en Na les plus élevées trouvées dans les calcaires (80–240 ppm) proviennent du Permien supérieur, d'un milieu évaporitique; les plus basses, dans des calcaires jurassiques d'un milieu ouvert de la marge continentale.Dans les dolomies, les concentrations du Na sont généralement plus élevées que dans les calcaires d'une faciès comparable. C'est une dolomie du Triassique supérieur, dont la genèse est considérée comme supratidale et précoce, qui a la concentration la plus haute.Une diagenèse tardive, surtout une dolomitisation tardive à faciès saccharoidal ont diminué considérablement la teneur en Na des roches qui se situe environs de 50 ppm.

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Reply to Hüneke’s (2005) comment     

H. Huckriede  K. Wemmer 《International Journal of Earth Sciences》2006,95(1):173-175

Hüneke (Int J Earth Sci 2005) gives a new interpretation of the tectonic setting of five ⁴⁰K/⁴⁰Ar analyses published by Huckriede et al. (Int J Earth Sci 93: 414–431, 2004). In this context, Hüneke discusses the significance and provenance of Late Proterozoic ⁴⁰K/⁴⁰Ar-cooling ages of detrital muscovites from pre-flysch sediments of the Blankenburg and Harzgerode Zones (Harz Mountains). Hüneke’s reinterpretation is based on a wrong concept concerning the extend of the Blankenburg Zone. This wrong concept originates from the incorrect distinction between the greywackes of the Tanne Zone and the greywackes of the Gießen-Harz Nappe. These greywackes can be easily distinguished by petrographic methods. Hüneke additionally defends the assumption that large areas of the eastern Harz Mountains consist of Viséan olistostromes. There is no need for an extended discussion of this topic because Hüneke presents no arguments.  相似文献   

Evidence of an impact origin for the Azuara structure (Spain)     

K. Ernstson  W. Hammann  J. Fiebag  G. Graup 《Earth and Planetary Science Letters》1985,74(4):361-370

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Calcium isotopes in fossil bones and teeth — Diagenetic versus biogenic origin     

Alexander Heuser  Thomas Tütken  Stephen J.G. Galer 《Geochimica et cosmochimica acta》2011,75(12):3419-8

We present the first systematic study of Ca isotopes (δ^44/40Ca) in Late Triassic to Late Cretaceous dinosaur bones and teeth (enamel and dentin) from sympatric herbivorous and carnivorous dinosaurs. The samples derive from five different localities, and data from embedding sediments are also presented. Additional δ^44/40Ca in skeletal tissues from modern reptiles and birds (avian dinosaurs) were measured for comparison in order to examine whether the original Ca isotopic composition in dinosaur skeletal apatite was preserved or might have changed during the diagenesis and fossilization process.δ^44/40Ca of fossil skeletal tissues range from −1.62‰ (Tyrannosaurus rex enamel) to +1.08‰ (Brachiosaurus brancai bone), while values in modern archosaur bones and teeth range from −1.63‰ (caiman enamel) to −0.37‰ (ostrich bone). The average δ^44/40Ca of the three types of fossil skeletal tissue analyzed - bone, dentin and enamel - show some systematic differences: while δ^44/40Ca in bone exhibits the highest values, while δ^44/40Ca in enamel has the lowest values, and dentin δ^44/40Ca falls in between. Values of δ^44/40Ca in the remains of herbivorous dinosaurs (0.1-1.1‰) are generally higher than those of bones of modern mammalian herbivores (−2.6‰ to −0.8‰) and from modern herbivorous archosaurs, which exhibit intermediate δ^44/40Ca (−0.8‰ to −0.4‰). These systematic isotopic shifts may reflect physiological differences between dinosaurs, mammals and reptiles representing different taxonomic groups of vertebrates.Systematic offsets in skeletal apatite δ^44/40Ca between herbivorous and carnivorous dinosaurs are not obvious, indicating a lack of a clear-cut Trophic Level Effect (TLE) shift between herbivores and carnivores in dinosaurs. This observation can be explained if the carnivorous dinosaurs in this study fed mainly on soft tissues from their prey and did not ingest hard (calcified) tissue to much extent. The most striking indication that the primary δ^44/40Ca is actually preserved in most of the fossil teeth is a difference in δ^44/40Ca of about 0.35 ± 0.10‰ (1SD) between dentin and enamel, based upon 11 of 16 analyzed dentin-enamel pairs. This difference is close to that found in modern reptiles (0.28 ± 0.05‰), and strongly suggests that this tell-tale signature is a primary feature of the fossilized dinosaur material as well. Furthermore, simple mass balance calculations show that changes of the original δ^44/40Ca in bones and teeth by diagenetically-formed calcium-bearing minerals are either small or would require implausible high original δ^44/40Ca values in the skeletal apatite.  相似文献   

A new azhdarchoid pterosaur from the Cenomanian (Late Cretaceous) of Lebanon     

Ross A. Elgin  Eberhard Frey 《Swiss Journal of Geoscience》2011,104(1):21-33

A new pterosaur, Microtuban altivolans gen. et sp. nov., is described from the Sannine Formation of northern Lebanon. The specimen is the first pterosaur from the Early Cenomanian (Late Cretaceous) locality of Hjoûla and is regarded as the most complete pterosaur fossil discovered from Africa. While postcranial characters indicate a possible relationship with members of the Thalassodromidae or Chaoyangopteridae, the specimen possesses an exceptionally short wing-finger phalanx 4, forming only 1.1% of the total length of the wing-finger. Its appearance along with an unnamed ornithocheiroid from the slightly younger locality of Hâqel suggests that a number of pterosaur taxa existed within the local area, perhaps living on exposed carbonate platforms.  相似文献