Synthesis of zeolites using fly ash and their application in removing heavy metals from waters   总被引：1，自引：0，他引：1  

王焰新  郭永龙  杨志华  蔡鹤生  Xavier Querol 《中国科学D辑(英文版)》2003,46(9):967-976

Fly ash is the solid waste of thermal power plants where coal is used as fuel, and its management and utilization have been of environmental concern for decades. Since the technique of synthesizing zeolite from coal fly ash was introduced by Holler[1] (19…  相似文献   

煤田火区烧变岩光谱特征分析及其信息提取   总被引：1，自引：0，他引：1  

祝善友  韩作振  张光超 《国土资源遥感》2003,14(2):55-58

中国北方煤田煤层自燃现象非常严重.利用遥感手段可以快速实现火区的动态监测,及时为灭火工程提供信息.烧变岩作为火区的地表指示性特征,是火区解译最直观的信息.本文从烧变岩的反射光谱曲线特征入手,对几种提取烧变岩信息的方法进行比较,从而确定解译烧变岩的最佳方法,为圈定火区的范围和位置奠定基础.  相似文献   

Surface analysis of pyrite in the No. 9 coal seam, Wuda Coalfield, Inner Mongolia, China, using high-resolution time-of-flight secondary ion mass-spectrometry   总被引：1，自引：0，他引：1  

Shifeng Dai  Xiaoqiang Hou  Deyi Ren  Yuegang Tang   《International Journal of Coal Geology》2003,55(2-4):139-150

The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (S_t,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe⁺ (⁵⁴Fe⁺, ⁵⁶Fe⁺, ⁵⁷Fe⁺), other fragment ions were detected in bacteriogenic pyrites, such as ²⁷Al⁺, Si⁺ (²⁸Si⁺, ²⁹Si⁺, ³⁰Si⁺), ⁴⁰Ca⁺, Cu⁺ (⁶³Cu⁺, ⁶⁵Cu⁺), Zn⁺ (⁶⁴Zn⁺, ⁶⁶Zn⁺, ⁶⁷Zn⁺, ⁶⁸Zn⁺), Ni⁺ (⁵⁸Ni⁺, ⁶⁰Ni⁺, ⁶²Ni⁺), and C₃H₇⁺. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as ²⁷Al⁺, ²⁸Si⁺, ²⁹Si⁺, AlO⁺, CH₂⁺, C₃H₃⁺, C₃H₅⁺, and C₄H₇⁺, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of ²⁸Si⁺ and ²⁷Al⁺ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest ²⁸Si⁺/²³Na⁺ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C₃H₃⁺, C₃H₅⁺, C₃H₇⁺, and C₄H₇⁺, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P⁺ peak was observed only in the fracture-filling pyrite and the highest ²⁸Si⁺/²³Na⁺ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger ⁴⁰Ca⁺ in nodular pyrite than other pyrite forms shows seawater influence during its formation.  相似文献   

应用地理信息系统处理地质信息的探讨——以在河北省晚古生代岩相古地理研究中的应用为例     

窦建伟  邵龙义  张鹏飞  武清海  孟逢源 《沉积与特提斯地质》1997,17(5):57-64

本文介绍了ＧＩＳ的基本概念原理，分析了应用ＧＩＳ处理地质信息的可行性和优越性，并以在河北晚古生代岩相古地理研究中的应用为实例，介绍了应用ＧＩＳ处理分析地质信息的一般方法。最后分析了ＧＩＳ处理地质信息方面还存在的一些问题，笔者认为，随着ＧＩＳ技术及其基础学科的不断发展，ＧＩＳ在处理地质信息方面将显示出更大的潜力  相似文献   

Mineralogy and geochemistry of a Late Permian coal in the Dafang Coalfield, Guizhou, China: influence from siliceous and iron-rich calcic hydrothermal fluids   总被引：16，自引：2，他引：16  

Shifeng Dai  Chen-Lin Chou  Mei Yue  Kunli Luo  Deyi Ren   《International Journal of Coal Geology》2005,61(3-4):241-258

This paper describes the influence of siliceous and iron-rich calcic low-temperature hydrothermal fluids (LTHF) on the mineralogy and geochemistry of the Late Permian No. 11 Coal (anthracitic, R_r=2.85%) in the Dafang Coalfield in northwestern Guizhou Province, China. The No. 11 Coal has high contents of vein ankerite (10.2 vol.%) and vein quartz (11.4 vol.%), with formation temperatures of 85 and 180 °C, respectively, indicating that vein ankerite and vein quartz were derived from low-temperature calcic and siliceous hydrothermal fluids in two epigenetic episodes. The vein quartz appears to have formed earlier than vein ankerite did, and at least three distinct stages of ankerite formation with different Ca/Sr and Fe/Mn ratios were observed.The two types of mineral veins are sources of different suites of major and trace metals. Scanning electron microscope and sequential extraction studies show that, in addition to Fe, Mg, and Ca, vein ankerite is the dominant source of Mn, Cu, Ni, Pb, and Zn in the coal, and the contents of these five elements are as high as 0.09% and 74.0, 33.6, 185, and 289 μg/g, respectively. In contrast, vein quartz is the main carrier mineral for platinum-group elements (PGEs) Pd, Pt, and Ir in the coal, and the contents of Pd, Pt, and Ir are 1.57, 0.15, and 0.007 μg/g, respectively. Sequential extraction showed a high PGE content in the silicate fraction, up to 10.4 μg/g Pd, 1.23 μg/g Pt, and 0.05 μg/g Ir, respectively. It is concluded that the formation of ankerite and quartz and the anomalous enrichment of trace elements in the No. 11 Coal in the Dafang Coalfield, Guizhou, result from the influx of calcic and siliceous low-temperature hydrothermal fluids.  相似文献   

Concentration and distribution of elements in Late Permian coals from western Guizhou Province,China     

《International Journal of Coal Geology》2005,61(1-2):119-137

With the aim of better understanding geochemistry of coal, 71 Late Permian whole-seam coal channel samples from western Guizhou Province, Southwest China were studied and 57 elements in them were determined. The contents of Al, Ca, Co, Cr, Cu, Fe, Ga, Hf, K, Li, Mn, Mo, Nb, Ni, Sn, Ta, Ti, Th, U, V, Zr, and REEs in the Late Permian coals from western Guizhou Province are higher than the arithmetic means for the corresponding elements in the US coals, whereas As, Ba, Br, F, Hg, P, Se, and Tl are lower. Compared to common Chinese coals, the contents of Co, Cr, Cu, Ga, Hf, Li, Mn, Mo, Ni, Sc, Sn, Ti, U, V, Zn, and Zr in western Guizhou coals are higher, and As, F, Hg, Rb, Sb, Tl, and W are lower. Five groups of elements may be classified according to their mode of occurrence in coal: The first two, Group A, Tm–Yb–Lu–Y–Er–Ho–Dy–Tb–Ce–La–Nd–Pr–Gd–Sm, and Group B, As–Sr–K–Rb–Ba–F–Ash–Si–Sn–Ga–Hf–Al–Ta–Zr–Be–Th–Na, have high positive correlation coefficients with ash yield and they show mainly inorganic affinity. Some elements from Group B, such as Ba, Be, Ga, Hf, and Th, are also characterized by significant aluminosilicate affinity. In addition, arsenic also exhibits high sulfide affinity (r_S–Fe>0.5). The elements, which have negative or lower positive correlation coefficients with ash yield (with exceptions of Bi, Cs, Nb, Mn, Se, and Ti), are grouped in other four associations: Group C, Cr–V–Mo–U–Cd–Tl; Group D, Hg–Li–Sc–Ti–Eu–Nb–Cs–W; Group E, Bi–Sb; and Group F, Co–Ni–Cu–Pb–Zn–Mg–Se–Ca–Mn–S–Fe. The correlation coefficients of some elements, including Co, Cr, Cu, Fe, Hg, Li, Mo, Ni, P, S, Sc, U, V, and Zn, with ash yield are below the statistically significant value. Only Cr and Cu are negatively correlated to ash yield (−0.07 and −0.01, respectively), showing intermediate (organic and inorganic) affinity. Manganese and Fe are characterized by carbonate affinity probably due to high content of epigenetic veined ankerite in some coals. Phosphorus has low correlation coefficients with any other elements and is not included in these six associations. There are five possible genetic types of enrichment of elements in coal from western Guizhou Province: source rock, volcanic ash, low-temperature hydrothermal fluid, groundwater, and magmatic hydrothermal inputs.  相似文献   

Hydro-geochemical and isotopic fluid evolution of the Los Azufres geothermal field,Central Mexico     

《Applied Geochemistry》2005,20(1):23-39

Hydrothermal alteration at Los Azufres geothermal field is mostly propylitic with a progressive dehydration with depth and temperature increase. Argillic and advanced argillic zones overlie the propylitic zone owing to the activity of gases in the system. The deepest fluid inclusions (proto-fluid) are liquid-rich with low salinity, with NaCl dominant fluid type and ice melting temperatures (T_mi) near zero (0 °C), and salinities of 0.8 wt% NaCl equivalent. The homogenization temperature (T_h)  = 325 ± 5 °C. The boiling zone shows T_h = ±300 °C and apparent salinities between 1 and 4.9 wt% NaCl equivalent, implying a vaporization process and a very important participation of non-condensable gases (NCGs), mostly CO₂. Positive clathrate melting temperatures (fusion) with T_h = 150 °C are observed in the upper part of the geothermal reservoir (from 0 to 700 m depth). These could well be the evidence of a high gas concentration. The current water produced at the geothermal wells is NaCl rich (geothermal brine) and is fully equilibrated with the host rock at temperatures between T = 300 and 340 °C. The hot spring waters are acid-sulfate, indicating that they are derived from meteoric water heated by geothermal steam. The NCGs related to the steam dominant zone are composed mostly of CO₂ (80–98% of all the gases). The gases represent between 2 and 9 wt% of the total mass of the fluid of the reservoir.The authors interpret the evolution of this system as deep liquid water boiling when ascending through fractures connected to the surface. Boiling is caused by a drop of pressure, which favors an increase in the steam phase within the brine ascending towards the surface. During this ascent, the fluid becomes steam-dominant in the shallowest zone, and mixes with meteoric water in perched aquifers. Stable isotope compositions (δ¹⁸O–δD) of the geothermal brine indicate mixing between meteoric water and a minor magmatic component. The enrichment in δ¹⁸O is due to the rock–water interaction at relatively high temperatures. δ¹³C stable isotope data show a magmatic source with a minor meteoric contribution for CO₂. The initial isotopic value δ³⁴S_RES = −2.3‰, which implies a magmatic source. More negative values are observed for shallow pyrite and range from δ³⁴S (FeS₂) = −4‰ to −4.9‰, indicating boiling. The same fractionation tendencies are observed for fluids in the reservoir from results for δ¹⁸O.  相似文献   

Displacement velocity effects on rock fracture shear strengths     

《Journal of Structural Geology》2016

Triaxial shear tests are performed to assess the effects of displacement velocity and confining pressure on shear strengths and dilations of tension-induced fractures and smooth saw-cut surfaces prepared in granite, sandstone and marl specimens. A polyaxial load frame is used to apply confining pressures between 1 and 18 MPa with displacement velocities ranging from 1.15 × 10⁻⁵ to 1.15 × 10⁻² mm/s. The results indicate that the shearing resistances of smooth saw-cut surfaces tend to be independent of the displacement velocity and confining pressure. Under each confinement the peak and residual shear strengths and dilation rates of rough fractures increase with displacement velocities. The sheared-off areas increase when the confining pressure increases, and the displacement rate decreases. The velocity-dependent shear strengths tend to act more under high confining pressures for the rough fractures in strong rock (granite) than for the smoother fractures in weaker rocks (sandstone and marl). An empirical criterion that explicitly incorporates the effects of shear velocity is proposed to describe the peak and residual shear strengths. The criterion fits well to the test results for the three tested rocks.  相似文献   

Deciphering As and Cu cycling in sediment pore waters in a large marina (Port Camargue,southern France) using a multi-tracer (Fe,Mn, U,Mo) approach     

《Applied Geochemistry》2016

The sediments of the Port Camargue marina (South of France) are highly polluted by Cu and As (Briant et al., 2013). The dynamics of these pollutants in pore waters was investigated using redox tracers (sulfides, Fe, Mn, U, Mo) to better constrain the redox conditions.In summer, pore water profiles showed a steep redox gradient in the top 24 cm with the reduction of Fe and Mn oxy-hydroxides at the sediment water interface (SWI) and of sulfate immediately below. Below a depth of 24 cm, the Fe, Mn, Mo and U profiles in pore waters reflected Fe and Mn reducing conditions and, unlike in the overlying levels, sulfidic conditions were not observed. This unusual redox zonation was attributed to the occurrence of two distinct sediment layers: an upper layer comprising muddy organic-rich sediments underlain by a layer of relatively sandy and organic-poor sediments. The sandy sediments were in place before the building of the marina, whereas the muddy layer was deposited later. In the muddy layer, large quantities of Fe and Mo were removed in summer linked to the formation of insoluble sulfide phases. Mn, which can adsorb on Fe-sulfides or precipitate with carbonates, was also removed from pore waters. Uranium was removed probably through reduction and adsorption onto particles. In winter, in the absence of detectable pore water sulfides, removal of Mo was moderate compared to summer.Cu was released into solution at the sediment water interface but was efficiently trapped by the muddy layer, probably by precipitation with sulfides. Due to efficient trapping, today the Cu sediment profile reflects the increase in its use as a biocide in antifouling paints over the last 40 years.In the sandy layer, Fe, Mn, Mo and As were released into solution and diffused toward the top of the profile. They precipitated at the boundary between the muddy and sandy layers. This precipitation accounts for the high (75 μg g⁻¹) As concentrations measured in the sediments at a depth of 24 cm.  相似文献   

崖南凹陷Y1井崖三段煤系烃源岩发育规律     

张春良  沈玉林  秦勇  赵志刚  杨柳  谢国梁 《沉积学报》2016,34(5):1003-1010

基于Y1井煤系烃源岩样品微量元素分析、煤岩显微组分及热解测试结果,结合小波分析的米氏旋回划分结果,系统研究了崖南凹陷Y1井崖三段煤系烃源岩特征及发育规律。研究表明:①以104和260尺度结合岩芯沉积序列及地球化学测试结果,将崖三段划分为2个中期和5个短期米氏旋回,垂向上表现为旋回厚度及烃源岩比例向上增大的趋势,中期旋回上部为烃源岩优势发育层位,其中ⅠA2、ⅠA3和ⅠB2为煤系烃源岩发育的优势旋回;②煤系烃源岩有机显微组分表现为富镜质组、贫惰质组、贫壳质组+腐泥组,镜质组含量为44%~100%,平均为83%,以基质镜质体及镜屑体为主,烃源岩类型以Ⅲ型（腐殖型）有机质为主,少量为Ⅱ₂型（腐泥-腐殖型）有机质,烃源岩以产气为主,其成熟度较低,R_o值平均为1.12%,处于生烃阶段初期;③煤系烃源岩发育受多种因素控制,其中断陷盆地向坳陷盆地的转化时期是成煤的关键构造时期、强烈进积作用使得煤系烃源岩保存不全、区域海平面上升时期是成煤的关键时期、短期旋回小波曲线右偏拐点处为煤系烃源岩相对发育层位。  相似文献