Zircon U-Pb and oxygen isotope evidence for a large-scale O depletion event in igneous rocks during the Neoproterozoic     

Yong-Fei Zheng  Yuan-Bao Wu  Fu-Kun Chen  Long Li 《Geochimica et cosmochimica acta》2004,68(20):4145-4165

Oxygen isotope analysis and U-Pb dating were carried out on zircons from granite, granitic gneiss and eclogite in the Dabie-Sulu orogenic belt of east-central China. The results show a wide variation in zircon δ¹⁸O values from −10.9 to 8.5‰. Most of the values are lower than normal mantle zircon and almost half have prominently negative values. The low δ¹⁸O zircons have protolith ages of 700 to 800 Ma and metamorphic ages of 205 to 250 Ma, respectively. Fluid availability within the metaigneous rocks dictates the extent of metamorphic recrystallization and overgrowth. The igneous zircons have preserved their magmatic zoning and middle Neoproterozoic U-Pb age during the Triassic metamorphism, indicating low fluid availability. Widespread low δ¹⁸O values are identified in the magmatic zircons of middle Neoproterozoic age, within an outcrop area of over 20,000 km² along the northern edge of the South China Block. The low δ¹⁸O zircons record the presence of large volumes of low δ¹⁸O igneous rocks that were derived from remelting of meteoric-hydrothermally altered rocks at some time between 700 and 800 Ma.The U-Pb ages for metaigneous protoliths and granites are correlated not only with the timing of rifting accompanying the breakup of Rodinia, but also with contemporary glacial deposits in the South China Block at paleolatitudes of 30 to 40°N. Melting of glacial ice and snow is suggested, instead of the direct involvement of meteoric water, to produce the low δ¹⁸O fluid with oxygen isotopic signatures like the cold-climate meteoric water. The rifting created conditions favorable to anatexis of meteoric-hydrothermally altered rocks. Glaciated regions supplied copious water for the water-rock interaction during magma emplacement along rifting zones. Both rifting and glaciation favored the generation of the low δ¹⁸O magmas in the region. The low δ¹⁸O zircons are thus interpreted to have crystallized from the low δ¹⁸O magmas of middle Neoproterozoic age, and onset of the generation of low δ¹⁸O magmas in the northern margin of the South China Block is estimated to occur at about 758 ± 15 Ma. The large-scale remelting of hydrothermally altered crust not only results from repetitive emplacement of mafic magmas along the rifting zones with protracted episodes of water-rock interaction, but also involves rift systems that rapidly introduce large volumes of fluid through confined pathways and traps in a short space of time in response to tectonic triggers. Occurrence of the large-scale ¹⁸O depletion during the middle Neoproterozoic may be a manifestation of the cold paleoclimate related to the snowball Earth event.  相似文献   

Transformation of garnet epidote amphibolite to eclogite, western Dabie Mountains, China   总被引：8，自引：0，他引：8  

J. Liu  K. Ye 《Journal of Metamorphic Geology》2004,22(5):383-394

Omphacite and garnet coronas around amphibole occur in amphibolites in the Hong'an area, western Dabie Mountains, China. These amphibolites consist of an epidote–amphibolite facies assemblage of amphibole, garnet, albite, clinozoisite, paragonite, ilmenite and quartz, which is incompletely overprinted by an eclogite facies assemblage of garnet, omphacite and rutile. Coronas around amphibole can be divided into three types: an omphacite corona; a garnet–omphacite–rutile corona; and, a garnet–omphacite corona with less rutile. Chemographic analysis for local reaction domains in combination with petrographical observations show that reactions Amp + Ab + Pg = Omp +Czo + Qtz + H₂O, and Amp + Ab = Omp ± Czo + Qtz + H₂O may lead to the development of omphacite coronas. The garnet–omphacite–rutile corona was formed from the reaction Amp + Ab + Czo + Ilm ± Qtz = Omp + Grt + Rt + H₂O. In garnet–omphacite coronas, the garnet corona grew during an early stage of epidote amphibolite facies metamorphism, whereas omphacite probably formed by the reactions forming the omphacite corona during the eclogite facies stage. It is estimated that these reactions occurred at 0.8–1.4 GPa and 480–610 °C using the garnet–clinopyroxene thermometer and omphacite barometer in the presence of albite.  相似文献   

Retrograded textures and associated mass transfer: evidence for aqueous fluid action during exhumation of the Qinglongshan eclogite, Southern Sulu ultrahigh pressure metamorphic terrane, eastern China   总被引：6，自引：0，他引：6  

T. N. Yang 《Journal of Metamorphic Geology》2004,22(7):653-669

The Qinglongshan eclogites in the Southern Sulu ultrahigh pressure metamorphic (UHPM) terrane show very different retrograded textures from their counterparts in the Northern Sulu terrane, implying a different thermal history. Scanning electron and optical microscope observations indicate that the peak assemblage of the Qinglongshan eclogite is anhydrous, composed of Grt + OmpI + Rt + (Ky + coesite). These primary minerals were replaced by second and third stage minerals, resulting in symplectite pseudomorphs or coronas. The following relationships are inferred: OmpI → OmpII + Ab + Fe‐oxide symplectite (type I) and Rt → Rt + Ilm intergrowth; and, Ky → Pg, OmpII (+Pl) → Amp (+Pl) symplectite (type II), and Grt → Prg (+Fe‐oxide). Mineral chemistry and mass‐balance demonstrate that the pseudomorphed textures were developed by metasomatism involving dissolution and precipitation intensified by fluids along grain boundaries. The formation of symplectite type I produced Fe, Mg and Na but consumed Ca and Si. The Mg and Fe diffused to garnet where exchange of (Mg, Fe) with Ca of the garnet resulted in compositional zonation with decreased Ca towards the edge of garnet grains where Ca was consumed during symplectite formation. The replacement of kyanite by paragonite consumed the extra Na. In the later stage, fluid infiltration partially transformed symplectite type I to type II, and narrow rims of pargasite resorbed garnet from their boundaries. Mass balance suggests that the transformation and resorption would have been coupled during fluid infiltration. In the latest stage, epidote and quartz were precipitated at very late stage as a result of fluid activity along microfractures. Tentative P–T conditions based on mineral reactions and thermocalc software suggest that the retrograded eclogite did not record the granulite facies retrograde evolution characteristic of eclogites from the Northern Sulu terrane. The difference in retrograde evolution between the Southern and Northern Sulu eclogites suggests a different exhumation history.  相似文献   

Accurate U-Pb Age and Trace Element Determinations of Zircon by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry   总被引：190，自引：0，他引：190  

Honglin Yuan  Shan Gao  Xiaoming Liu  Huiming Li  Detlef Günther  Fuyuan Wu 《Geostandards and Geoanalytical Research》2004,28(3):353-370

Various zircons of Proterozoic to Oligocene ages (1060-31 Ma) were analysed by laser ablation-inductively coupled plasma-mass spectrometry. Calibration was performed using Harvard reference zircon 91500 or Australian National University reference zircon TEMORA 1 as external calibrant. The results agree with those obtained by SIMS within 2s error. Twenty-four trace and rare earth elements (P, Ti, Cr, Y, Nb, fourteen REE, Hf, Ta, Pb, Th and U) were analysed on four fragments of zircon 91500. NIST SRM 610 was used as the reference material and ²⁹Si was used as internal calibrant. Based on determinations of four fragments, this zircon shows significant intra-and inter-fragment variations in the range from 10% to 85% on a scale of 120 μm, with the variation of REE concentrations up to 38.7%, although the chondrite-normalised REE distributions are very similar. In contrast, the determined age values for zircon 91500 agree with TIMS data and are homogeneous within 8.7 Ma (2 s ). A two-stage ablation strategy was developed for optimising U-Pb age determinations with satisfactory trace element and REE results. The first cycle of ablation was used to collect data for age determination only, which was followed by continuous ablation on the same spot to determine REE and trace element concentrations. Based on this procedure, it was possible to measure zircon ages as low as 30.37 0.39 Ma (MSWD = 1.4; 2 s ). Other examples for older zircons are also given.  相似文献   

Crustal structure of the southern Dabie ultrahigh-pressure orogen and Yangtze foreland from deep seismic reflection profiling   总被引：8，自引：0，他引：8  

Shuwen Dong  Rui Gao  Bolin Cong †  Zhongyan Zhao  Xiaochun Liu  Sanzhong Li  Qiusheng Li  Dongding Huang 《地学学报》2004,16(6):319-324

A new 140‐km‐long seismic reflection profile provides a high‐resolution crustal‐scale image of the southern Dabieshan high‐pressure (HP) metamorphic belt and the Yangtze foreland fold‐and‐thrust belt. The seismic image of the stacked section shows that the southern Dabieshan metamorphic terrane and Yangtze foreland belt are separated by a large north‐dipping fault. In the foreland the upper crust is dominated by a series of folds and thrusts formed during the collisional stage in the mid‐Triassic; it was reworked by crustal extension resulting in the formation of a late Jurassic and Cretaceous red‐bed basin. The southern Dabieshan profile shows stacked crustal slabs developed along the margin of the collisional orogenic belt. The Moho reflectors at 10–11 s (～30–33 km) are seismically prominent and segmented by a number of south‐verging thrusts that were probably developed by foreland‐directed thrusting of the deeply subducted continental crust during exhumation. The seismic reflection profile suggests that structures related to the Triassic–Jurassic subduction and exhumation of the Yangtze plate are preserved despite the severe crustal extension superimposed during the late Mesozoic and Cenozoic.  相似文献   

Genesis of Kanggur Gold Deposit in Eastern Tianshan Orogenic Belt, NW China: Fluid Inclusion and Oxygen and Hydrogen Isotope Constraints   总被引：3，自引：0，他引：3  

Zhiliang Wang    Neng Jiang  Yitian Wang    Jingwen Mao  Jianmin Yang 《Resource Geology》2004,54(2):177-185

Abstract. Primary fluid inclusions in quartz and carbonates from the Kanggur gold deposit are dominated by aqueous inclusions, with subsidiary CO₂-H₂O inclusions that have a constant range in CO₂ content (10–20 vol %). Microthermometric results indicate that total homogenization temperatures have a wide but similar range for both aqueous inclusions (120 to 310C) and CO₂-H₂O inclusions (140 to 340C). Estimates of fluid salinity for CO₂-H₂O inclusions are quite restricted (5.9∼10.3 equiv. wt% NaCl), whereas aqueous inclusions show much wider salinity ranging from 2.2 to 15.6 equivalent wt %NaCl.
The 6D values of fluid inclusions in carbonates vary from -45 to -61 %, in well accord with the published δD values of fluid inclusions in quartz (-46 to -66 %). Most of the δ¹⁸O and δD values of the ore-forming fluids can be achieved by exchanged meteoric water after isotopic equilibration with wall rock by fluid/rock interaction at a low water/rock ratio. However, the exchanged meteoric water alone cannot explain the full range of δ¹⁸O and δD values, magmatic and/or meta-morphic water should also be involved. The wide salinity in aqueous inclusions may also result from mixing of meteoric water and magmatic and/or metamorphic water.  相似文献   

Methane-rich fluid inclusions in skarn near the giant REE–Nb–Fe deposit at Bayan Obo, Northern China     

Hong-Rui Fan  Yi-Han Xie  Kai-Yi Wang  Simon A. Wilde 《Ore Geology Reviews》2004,25(3-4):301-309

We report fluid inclusion data for skarn, formed at the contact between Hercynian granitoids and dolomite of the Proterozoic Bayan Obo Group, in the vicinity of Bayan Obo REE–Nb–Fe deposit, Inner Mongolia, China. Three types of fluid inclusions are identified: two-phase CH₄-rich, three-phase liquid–vapour–solid and two-phase aqueous inclusions. Using microthermometry and laser Raman microprobe analysis to calculate isochores for CH₄-bearing inclusions, we estimate fluid trapping conditions at T=280 to 344 °C and P<1 to 2.3 kbar. Such conditions are compatible with formation of CH₄ inclusions as a result of reaction between graphite in the country rocks (black slate sequence) and fluids derived from magma. The lack of carbonaceous material in the inclusions supports the hypothesis that CH₄ was generated during fluid migration rather than by in situ reaction. In contrast to the skarn, and despite the fact that similar graphite-bearing slates are found in the host rocks, no CH₄-bearing inclusions have been so far reported from Bayan Obo REE ores. We therefore conclude that the skarn-forming fluids in the contact aureole of the Hercynian granitoids were not involved at any stage in the formation of the Bayan Obo deposit.  相似文献   

Continental crustal growth and the supercontinental cycle: evidence from the Central Asian Orogenic Belt   总被引：15，自引：0，他引：15  

Dawei Hong  Jisheng Zhang  Tao Wang  Shiguang Wang  Xilin Xie 《Journal of Asian Earth Sciences》2004,23(5):799

Studies of supercontinental cycle are mainly concentrated on the assembly, breakup and dispersal of supercontinents, and studies of continental crustal growth largely on the growth and loss (recycling) of the crust. These two problems have long been studied separately from each other. The Paleozoic–Mesozoic granites in the Central Asian Orogenic Belt have commonly positive Nd values, implying large-scale continental crustal growth in the Phanerozoic. They coincided temporally and spatially with the Phanerozoic Pangea supercontinental cycle, and overlapped in space with the P-wave high-V anomalies and calculated positions of subducted slabs for the last 180 Ma, all this suggests that the Phanerozoic Laurasia supercontinental assembly was accompanied by large-scale continental crustal growth in central Asia. Based on these observations, this paper proposes that there may be close and original correlations between a supercontinental cycle, continental crustal growth and catastrophic slab avalanches in the mantle. In this model we suggest that rapid continental crustal growth occurred during supercontinent assembly, whereas during supercontinental breakup and dispersal new additions of the crust were balanced by losses, resulting in a steady state system. Supercontinental cycle and continental crustal growth are both governed by changing patterns of mantle convection.  相似文献   

Pelecinid wasps (Insecta, Hymenoptera, Proctotrupoidea) from the Cretaceous of Russia and Mongolia     

Haichun Zhang  A.P. Rasnitsyn   《Cretaceous Research》2004,25(6):807-825

Thirteen new species referable to four genera, of which one is new, from the Cretaceous of Russia and Mongolia are established herein and assigned to the family Pelecinidae. Among the four genera, Protopelecinus gen. nov., including four new species, is referred to the subfamily Pelecininae, while Iscopinus Kozlov, including three new species, Eopelecinus Zhang, Rasnitsyn and Zhang, including five new species, and Scorpiopelecinus laetus sp. nov. are assigned to the subfamily Iscopininae. Of these new taxa, eight, namely Protopelecinus regularis, P. furtivus, Iscopinus simplex, ?I. suspectus, Eopelecinus exquisitus, E. scorpioideus, E. rudis and Scorpiopelecinus laetus, are from the Lower Cretaceous Zaza Formation of Baissa, Transbaikalia, Russia; two, E. minutus and E. fragilis, are from the basal Lower Cretaceous Tsagan-Tsab Formation of Khutel-Khara, Mongolia; two, P. dubius and P. deformis, are from the Lower Cretaceous (Aptian?) of Bon Tsagan, Mongolia; and one, I. separatus, is from the Upper Cretaceous (Cenomanian) Ola Formation of Obeshchayushchiy, Russia. A key to fossil pelecinid wasps is provided and a morphological analysis shows that the Pelecinidae might be paraphyletic with respect to the Proctotrupidae. The Chinese insect fauna from both the Yixian and Laiyang formations is dominated by Eopelecinus and Sinopelecinus whereas the Siberian + Mongolian fauna from the Zaza and Tsagan-Tsab formations is dominated by Eopelecinus and Iscopinus. Hence, Eopelecinus is common to both. The differences between the two faunas are likely to be the result of geographical variation in populations.  相似文献   

Revision of the conchostracan genera Cratostracus and Porostracus from Cretaceous deposits in north-east China     

Gang Li  David J. Batten   《Cretaceous Research》2004,25(6):919-926

The diagnoses of the conchostracan genera Cratostracus and Porostracus are revised following a re-examination of their type species under a scanning electron microscope. In Cratostracus each growth line has a serrated lower margin. Radial lirae branch into smaller ridges that merge with each other to give the upper part of each growth band in the ventral region of the carapace a slightly undulating surface. Cross-bars are present between these lirae. In Porostracus the radial lirae on the growth bands near the umbo are long and relatively widely spaced. There is a fine reticulum between them in the umbonal part of the carapace and cross-bars on the ventral surface. The ornament of Porostracus indicates that it can be assigned to the family Halysestheriidae rather than to the Afrograptidae, in which it has been placed previously. Morphological analysis of most of the species of the two genera and closely related Orthestheria (Migransia) under the scanning electron microscope is required before their stratigraphic potential can be fully realized.  相似文献