Reconstruction of nearshore chemical conditions in the Mesoproterozoic: evidence from red and grey beds of the Yangzhuang formation,North China Craton     

Yu Zou  Dongna Liu  Hongwei Kuang  Changgui Song  Yuxiang Sun 《International Geology Review》2020,62(11):1433-1449

ABSTRACT

Mesoproterozoic red beds near ancient coasts have not aroused extensive interest. A new geochemical study of the alternating red and grey dolostones from the Yangzhuang Formation provides a better understanding of the redox conditions of nearshore sedimentary environments. In this contribution, whole-rock samples are characterized by positive correlations of rare earth elements (REE) vs. Th and Fe_T vs. Th and flat-type REE distribution patterns, indicating massive terrigenous input, which is considered to be inherited from felsic rocks. Relatively high (Fe_mag+Fe_ox)/Fe_T and Fe³⁺/Fe²⁺ ratios in red beds indicate more oxidized conditions in supratidal environments compared with the lower oxygen contents in intertidal environments. Under these two distinct chemical sedimentary conditions, acetic acid-leached red and grey samples both have HREE-depleted distributions, suggesting significant freshwater invasion. Moreover, limited terrigenous redox-sensitive elements (RSEs) can reach the coast where the red beds are deposited, whereas relatively high RSE enrichment factors originating from shallow oceans are recorded in grey beds. In the Mesoproterozoic, limited oxidative weathering, shallow seawater desalination, and low organic production occurred near the coast. Meanwhile, a prolonged period of low Mo and U availability preserved in carbonate minerals confirmed that marine oxygen levels failed to satisfy the deposition of offshore red beds. During the regression, potentially exposed sediments connected to atmospheric oxygen guaranteed the oxidation of iron and the formation of red beds, and these events were coupled with negative δ¹³C_carb shifts in the Yanliao rift zone.  相似文献   

Fluid inclusion and H–O isotope study of the Jiguanshan porphyry Mo deposit,Xilamulun Metallogenic Belt: implications for characteristics and evolution of ore-forming fluids     

Wang  Changhong  Wang  Keyong  Cai  Wenyan  Li  Jian  Liu  Hanlun  Wang  Yicun 《中国地球化学学报》2020,39(4):497-511

Acta Geochimica - We studied the fluid inclusions of the Jiguanshan Mo deposit in China, which is a large porphyry deposit located in the southern Xilamulun Metallogenic Belt. The irregular Mo ore...  相似文献   

福建煤系石墨资源状况和开发前景     

陈泉霖  程乔  邓瑞锦  林晓炎  王路  丁正云  李阳 《煤田地质与勘探》2020,48(1):12-17,26

福建省煤系石墨赋存于中二叠统童子岩组,是无烟煤受高温高压作用进一步变质而成,属隐晶质石墨。通过调查发现,福建省煤系石墨矿井、勘查区处于未开采或停采状态,开采矿区也多以煤炭开采的形式生产销售,造成资源浪费。为合理开发利用煤系石墨资源,采用d₀₀₂（碳层间距）-R₂（拉曼参数）模板鉴别煤系石墨并确定煤系石墨等级,结合区域构造的控制作用,划分了大田-漳平与永安-安溪石墨成矿区。在此基础上,综合实测数据和历年勘查资料分析,预测出永安长垇、永安下盖竹-甫弼-塘下洋、大田琼口-小溪洋-永安老鹰山、漳平可坑-乌石隔、漳平乌坑-华安福田5块煤系石墨资源远景区,其预测资源量8 196万t,展现了良好的开发前景。针对目前煤系石墨资源开发利用现状,提出“规范煤系石墨资源开采秩序、建立煤与煤系石墨鉴别指标并设立明确的煤矿与石墨矿权规范、优化石墨资源开发利用体系等”系列建议,以实现福建石墨产业结构协调化、技术高度化、产品系列化和价值链完整化。移动阅读   相似文献   

辽宁五龙金矿构造叠加晕研究   总被引：4，自引：0，他引：4  

俞炳 《地质与勘探》2020,56(5):898-914

五龙金矿是辽东矿集区的大型石英脉型金矿床,累计黄金储量超过80吨,平均品位为5.35g/t。随着开采量的增加,目前该矿床开采深度达近千米,保有储量不断减少,步入危机矿山行列,急需开展矿区深部找矿预测研究,实现寻找深部盲矿的有效突破。本次研究在前人研究工作的基础上,分析五龙金矿床矿石微量元素地球化学特征,运用相关分析、聚类分析、因子分析等多元统计方法,对五龙金矿构造叠加晕进行了系统研究。结果显示,五龙金矿成矿过程具有多期次和多阶段的特征,各指示元素在矿体轴向上具有前缘晕、近矿晕、与尾晕相互叠加的现象,该现象是深部盲矿预测的重要依据,反映了深部有盲矿存在的可能性。  相似文献   

深度学习在煤层气测井解释中的应用研究     

向旻 《地质与勘探》2020,56(6):1305-1312

将常规储层测井解释方法应用于煤层气储层测井解释,其效果存在一定的折扣。为了改善传统方法在煤层气测井解释中出现的问题,将深度学习的思想引入测井解释,提出受限玻尔兹曼机的数量、受限玻尔兹曼机隐含层神经元数量、分类阈值的确定方法,利用深度信念网络进行煤层识别及煤层气含气量的预测。实验结果表明：首先,在交会图法效果不好的情况下,通过深度信念网络进行煤层识别,继而对识别结果进行适当校正,煤层识别成功率可达到90%以上;其次,经过多种方法的对比,利用深度信念网络进行煤层气含气量预测的效果,要好于BP神经网络、多元回归统计以及Langmuir方程三种方法。深度学习改进了传统的BP神经网络,具备更强的复杂函数泛化能力,适用于煤层气测井解释,并具有进一步的推广价值。  相似文献   

Detrital record of late-stage silicic volcanism in the Emeishan large igneous province     

《Gondwana Research》2020

Silicic volcanic rocks generally constitute a minor, but key product to track the magmatic evolution in mafic rock dominated large igneous provinces (LIPs). However, for their generally late-stage nature of the silicic volcanic rocks they have a poor preservation potential due to extensive post-eruption erosion. We track the eroded volcanic rocks from the ∼260 Ma Emeishan LIP by analyzing the provenance of the LIP-derived sedimentary rocks. Sandstones from a cored succession of the Late Permian Longtan Formation in the northern Youjiang Basin are rich in volcanic rock fragments, and associated mudstones have low Al₂O₃/TiO₂ ratios. Detrital zircon grains from the Longtan Formation display typical unimodal U–Pb age spectra with a prominent peak at ca. 260 Ma. These detrital zircons show an overall geochemical affinity akin to those crystallized from within-plate/anorogenic magmas. Such petrological and geochemical characteristics are consistent with a dominant source from the Emeishan volcanic rocks. Through the sampled succession, zircon grains of ∼260 Ma from the lower Longtan Formation generally display lower U/Yb (most < 0.5) and Th/Nb (most < 10) ratios and higher εHf(t) values (mostly in the range of +3 to +8) than those from the upper part. A similar sequential variation has also been observed in the Shaiwa Formation, which is an offshore time-equivalent unit to the Longtan Formation. These consistent temporal variations through the sedimentary successions in the Youjiang Basin are interpreted to reflect erosional unroofing of the Emeishan LIP during the Late Permian. These results, integrated with previous studies on the rhyolites and trachytes in Emeishan LIP, reveal a fractional crystallization dominated petrogenetic process with diminishing crustal assimilation for the late-stage silicic volcanism.  相似文献   

Fluid inclusions,C-H-O-S-Pb isotope systematics,geochronology and geochemistry of the Budunhua Cu deposit,northeast China:Implications for ore genesis     

《地学前缘(英文版)》2020,11(4):1145-1161

The Budunhua Cu deposit is located in the Tuquan ore-concentrated area of the southern Great Xing'an Range,NE China.This deposit includes the southern Jinjiling and northern Kongqueshan ore blocks,separated by the Budunhua granitic pluton.Cu mineralization occurs mainly as stockworks or veins in the outer contact zone between tonalite porphyry and Permian metasandstone.The ore-forming process can be divided into four stages involving stage Ⅰ quartz-pyrite-arsenopyrite;stage Ⅱ quartz-pyrite-chalcopyrite-pyrrhotite;stage Ⅲ quartz--polynetallic sulfides;and stage IV quartz-calcite.Three types of fluid inclusions(FIs) can be distinguished in the Budunhua deposit:liquid-rich two-phase aqueous FIs(L-type),vapour-rich aqueous FIs(V-type),and daughter mineral-bearing multi-phase FIs(S-type).Quartz of stages Ⅰ-Ⅲ contains all types of FIs,whereas only L-type FIs are evident in stage Ⅳ veins.The coexisting V-and S-type FIs of stages Ⅰ-Ⅲ have similar homogenization temperatures but contrasting salinities,which indicates that fluid boiling occurred.The FIs of stages Ⅰ,Ⅱ,Ⅲ,and Ⅳyield homogenization temperatures of 265-396℃,245-350℃,200-300℃,and 90-228℃ with salinities of3.4-44.3 wt.%,2.9-40.2 wt.%,1.4-38.2 wt.%,and 0.9-9.2 wt.% NaCl eqv.,respectively.Ore-forming fluids of the Budunhua deposit are characterized by high temperatures,moderate salinities,and relatively oxidizing conditions typical of an H_2 O-NaCl fluid system.Mineralization in the Budunhua deposit occurred at a depth of0.3-1.5 km,with fluid boiling and mixing likely being responsible for ore precipitation.C-H-O-S-Pb isotope studies indicate a predominantly magmatic origin for the ore-forming fluids and materials.LA-ICP-MS zircon U-Pb analyses indicate that ore-forming tonalite porphyry and post-ore dioritic porphyrite were formed at 151.1±1.1 Ma and 129.9±1.9 Ma,respectively.Geochemical data imply that the primary magma of the tonalite porphyry formed through partial melting of Neoproterozoic lower crust.On the basis of available evidence,we suggest that the Budunhua deposit is a porphyry ore system that is spatially,temporally,and genetically associated with tonalite porphyry and formed in a post-collision extensional setting following closure of the Mongol-Okhotsk Ocean.  相似文献   

SHRIMP zircon geochronology and geochemistry of the Orlica-Śnieżnik gneisses (Variscan belt of Central Europe) and their tectonic implications     

《Geodinamica Acta》2000,13(5):293-312

The Orlica-Śnieżnik dome comprises large orthogneiss bodies interbedded with amphiblite-grade metasediments and minor metavolcanics. New U-Pb and Pb-Pb SHRIMP zircon ages for two major gneiss units of the dome, the Śnieżnik and Gierałtów gneiss, yielded similar ages of ca. 500 Ma. This is interpreted to reflect the magmatic crystallization age from the same or similar igneous precursors, in agreement with the geochemical characteristics of these rocks. Some zircon cores in both gneisses, interpreted to be inherited xenocrysts, have ages of ca. 530–540 Ma, and, additionally, of ca. 565 Ma and 2.6 Ga in the Śnieżnik gneiss. Igneous grains in both gneiss types have high-U rims, which are dark under cathodoluminescence. They are much better developed in the Gierałtów gneiss and they yield a well-defined weighted mean U-Pb age of 342 ± 6 Ma. These high-U rims are interpreted to have grown close to the peak of HT metamorphism which is responsible for the migmatitic texture of the Gierałtów gneiss. The Visean HT–LP metamorphism in the Orlica-Śnieżnik dome is interpreted as a result of rapid uplift and decompression due to overthrusting of high grade rocks over the Moravo-Silesian nappe pile. Our data support geodynamic models that ascribe a predominant influence in the tectonic evolution of the West Sudetes to the Variscan orogenic events. This is suggested by the inheritance of zircon xenocrysts from the Cadomian basement and by the Late Cambrian–Early Ordovician magmatic event, both typical of the Armorican terrane assemblage, as well as by the Early Carboniferous age of the metamorphism.  相似文献   

Index     

Unknown 《Ocean & Coastal Management》2000,43(12):VIII

  相似文献   

觉罗塔格南缘石炭系火山岩地球化学特征及其对古亚洲洋南缘构造演化的指示意义   总被引：4，自引：0，他引：4  

木合塔尔·扎日  尼加提·阿布都逊  吴兆宁 《地学前缘》2015,22(1):238-250

研究了觉罗塔格南缘石炭系雅满苏组与土古土布拉克组火山岩的主量元素、微量元素和Sr-Nd同位素特征。结果显示,雅满苏组(中)酸性熔岩属贫钾钙碱性岩浆系列,Mg#值介于0.49~0.51,ISr介于0.706 42~0.707 68、εNd(t)为3.28~5.49,富集轻稀土与大离子亲石元素、相对亏损重稀土与高场强元素,具中等负Eu异常(δEu=0.62~0.65),其形成可能与幔源基性岩浆结晶分异有关。土古土布拉克组中(酸)性火山岩属钙碱性-高钾钙碱性系列,Mg#值介于0.53~0.57,轻稀土相对富集,重稀土相对亏损,略具负铕异常(δEu=0.63~0.84),富集大离子亲石元素,相对亏损高场强元素,ISr介于0.703 71~0.708 47、εNd(t)为6.48~6.83,表明其母岩浆来源于受交代的富集岩石圈地幔楔。结合区域地质背景研究成果,认为它们形成于古亚洲洋壳向南俯冲的岛弧环境,并且早石炭世的雅满苏组火山岩代表不成熟的洋内岛弧的产物,而晚石炭世的土古土布拉克组火山岩是岛弧演化到相对成熟阶段的产物。这种物质成分和时空分布特征揭示的石炭纪该区壳幔岩石圈由北向南、由老到新明显增厚现象,为古亚洲洋南缘吐哈古洋壳当时在该处具有向南俯冲的极性提供了有力证据。  相似文献