中国大别山东南缘首次发现大坝陨坑构造   总被引：2，自引：0，他引：2  

向缉熙  许林根  向钒  石乾华吴思本  张新元张宜勇 《中国地质》2008,35(5):869-878

简介首次在大别山东南缘安徽省境内发现的大坝陨坑构造。经初步评价,知陨坑呈椭圆形,长轴呈北北东向,长约19km,短轴长约12km,最大坑深约2km,是一个有中央隆起区的复杂型陨坑。在卫片上陨坑显示环形影像,地貌形态为一洼地。陨坑基座保存尚好,可对它直观和追索陨坑构造边界。形成于230Ma左右的各类撞击变质岩石系列齐全,其中含有柯石英等典型的撞击变质矿物及撞击碎理等超微构造,特别是在陨坑基座内壁普遍发现有鉴别陨坑构造最可靠的标志——干裂自角砾岩,都证明大坝环形影像是一个典型的陨星撞击坑构造。它的发现,具有很大的科学及经济意义,对今后褶皱山区寻找和研究陨坑构造具有示范和指导作用,同时大大丰富了建设大别山世界地质公园的地质依据。无庸置疑此发现将促进大别山旅游业的发展及陨星撞击科普知识的传播。  相似文献   

Calculating Pollution Indices by Heavy Metals in Ecological Geochemistry Assessment and a Case Study in Parks of Beijing   总被引：4，自引：0，他引：4  

龚庆杰  邓军  向运川  王庆飞  杨立强 《中国地质大学学报(英文版)》2008,19(3)

Pollution index is a powerful tool for ecological geochemistry assessment. The commonly used pollution indices by heavy metals in soils and sediments were classified as two types of single index and integrated index in an algorithm point of view. Four single indices of contamination factor (or concentration factor), ecological risk factor, enrichment factor, and index of geo-accumulation were illustrated, and the reference values for calculating single indices were distinguished into background levels and threshold pollution values. Eight integrated indices were divided into two groups. One group is suitable for the normal distribution single indices including the sum, average, weighted average,vector modulus, and Nemerow pollution indices, and the other for log-normal distribution including the product, root of product, and weighted power product pollution indices. Using background levels as reference values, five contamination classes were divided, and the terminologies are suggested for the single and integrated indices to unify the assessment results. Software of EGAPI was developed in a single document interface to calculate the four single and eight integrated indices by heavy metals to assess the quality of soil and sediment ecological geochemistry. Pollution indices by heavy metals of Cu,Pb, and Zn in soils in parks of Beijing were calculated using EGAPI software, and these five contamination classes and terminologies suggested in this study were evaluated and used. Results ofintegrated indices of Cu, Pb, and Zn in soils indicated that the soil qualities are unpolluted as a whole and varied from low polluted to unpolluted status from the center to the outskirts of Beijing City.  相似文献   

Geochemical Mapping: With Special Emphasis on Analytical Requirements     

XIE Xuejing  CHENG Hangxin  LIU Dawen 《《地质学报》英文版》2008,82(2):451-462

More than 40 national and regional geochemical mapping projects in the world carried out from 1973 to 1988 do not conform to common standards. In particular they have many analytical deficiencies. In the period 1988 to 1992, the International Geochemical Mapping project （Project 259 of UNESCO＇s IGCP Program） prepared recommendations designed to standardize geochemical mapping methods. The analytical requirements are an essential component of the overall recommendations. They included the following： 71 elements should be analyzed in future mapping projects; the detection limits of trace and ultratrace elements must be lower than the corresponding crustal abundances; and the Chinese GSD and Canadian STSD standard sample series should be used for the correlation of global data. A proposal was also made to collect 5000 composite samples, at very low sampling densities to cover the whole Earth＇s land surface. In 1997 an IUGS Working Group on Global Geochemical Baselines was formed to continue the work which began with IGCP 259. From 1997 up to now, new progress has been made especially in China and FOREGS countries under the aegis of this working group, including the study of suitable sampling media, development of a multi-element analytical system, new proficiency test for selection of competent laboratories and role of wide-spaced mapping in mineral exploration. One of the major problems awaiting solution has been the inability of many laboratories to meet the IGCP recommendations to generate high quality geochemical maps. Fortunately several laboratories in China and Europe have demonstrated an ability to meet the requirements and they will be well placed to render technical assistance to other countries.  相似文献   

Late Neoproterozoic,Ordovician and Carboniferous events recorded in monazites from southern-central Madagascar     

《Precambrian Research》2006,144(3-4):278-296

The evolution of the basement of southern Madagascar north and south of the Ranotsara shear zone was investigated using (U + Th)/Pb electron probe monazite age dating in combination with petrographic constraints. Several monazite grains show a stepwise progression of younger ages towards the rim indicating partial and complete resetting during tectonic, metamorphic and/or fluid events. The oldest ages, ranging from 630–2400 Ma, occur relatively rare in relic cores. A first, clear age-population is dated at 550–560 Ma. Most ages fall in two populations at 420–460 and 490–500 Ma, which in some samples overlap in error. We interprete these ages as dating low-pressure and high-temperature metamorphism. We have also clear evidence for Carboniferous (300–310 Ma) monazite overgrowth rims, which can not directly be related to macroscopic structures or metamorphic parageneses. In combination with literature data, we propose that the observed monazite age populations are related to Gondwana amalgamation and subsequent rifting events during the break up of Gondwana. Our study confirms that only the electron or ion microprobe yields sufficient spatial resolution to date individual shells of multiple zoned monazites in the polymetamorphic basement of Madagascar.  相似文献   

中酸性岩浆体系成矿流体及微量元素地球化学特征   总被引：5，自引：0，他引：5       下载免费PDF全文

李剑  吕志成董方浏 《中国地质》2005,32(4):614-624

从流体成矿作用角度出发，与酸性岩浆体系有关的成矿流体可以分为：酸性岩浆硅酸盐熔融体，岩浆一热液过渡阶段硅酸盐熔融体及其分异的流体，酸性岩浆熔体分异形成的热水成矿溶液。酸性岩浆体系主要提供热源和部分矿质，其提供的热源驱动地下水淋滤、萃取围岩中的成矿物质形成地下水热液成矿流体。变质岩混合岩化形成花岗质岩浆过程中所形成的混合岩化成矿流体。在此基础上，讨论了上述不同成矿流体的微量元素地球化学特征及其对成矿的控制作用。  相似文献   

区域地球化学数据的归一化处理及应用   总被引：11，自引：0，他引：11  

刘大文 《物探与化探》2004,28(3):273-275,279

介绍了一种简单的勘查地球化学数据调整方法———归一化,该方法采用各批或各区块差异数据的平均值或中位数的衬值乘以参照值以获得元素的视含量,用于调整不同分析批次之间的系统误差,或不同背景区数据的差异;用2个实例详细介绍了该方法的应用效果。  相似文献   

Scanning electron microscopy cathodoluminescence of quartz: Principles,techniques and applications in ore geology     

《Ore Geology Reviews》2015

Scanning electron microscopy cathodoluminescence (SEM-CL) of quartz has been a prevalent research technique in porphyry and epithermal systems for the past two decades. Quartz from specific geological environments reveals unique textures in SEM-CL, which can be used to constrain the evolution of these ore-bearing systems when complemented by fluid inclusion, hyperspectral mapping, and trace element studies. We review SEM-CL principles and instrumentation, sample preparation and handling, and experimental conditions of quartz SEM-CL imaging that result in the high quality CL images. The effects of sample polishing, accelerating voltage, beam spot size, working distance, vacuum conditions, image acquisition, and post-processing were examined through experimental trial. For the XL 30 ESEM and the attached Gatan PanaCL detector used, the optimum experimental conditions to obtain high quality panochromatic SEM-CL images of quartz at high vacuum mode for carbon-coated conductive samples are as follows: 15 kV accelerating voltage, relative beam spot size 6 (approximately 500 nm in diameter), HT − 570 V to − 580 V photomultiplier tube (PMT) voltage. Low vacuum mode (with chamber H₂O vapor pressure from 0.1 to 1.0 Torr) working conditions are similar to the conditions at high vacuum mode except the PMT voltage should be reduced to − 550 V to − 560 V. Working distances vary based on the position of user's retractable CL detector. The sample surface should be as close as possible to the CL detector, but a 1 mm clearance between the detector and the sample surface is recommended to prevent detector from possible damage by the sample. Several minutes of beam exposure prior to image acquisition at 320 second scan speeds at 50×–1500× magnifications is recommended to generate the greatest CL emission. Monochromatic CL imaging requires three scans over the same area using red, green, and blue optical filters that can be merged to produce a “true color” image. The red and green filters require stronger PMT voltages to produce sufficient CL emissions by an increase of − 200 V to − 300 V and − 150 V to − 200 V, respectively, from the PMT voltage used for panochromatic imaging. Special attention is given to the challenges associated with imaging hydrothermal quartz veining in ore deposits and the value of CL data as a foundation for geochemical studies. SEM-CL imaging of vein quartz is explored through case studies of the Red Hills Porphyry Cu –Mo Deposit, Texas, USA, and the Ertsberg–Grasberg Cu–Au District, Papua, Indonesia to aid in vein paragenesis. The most common application of quartz SEM-CL in ore geology is to reveal the relative timing of mineral precipitation, mineral dissolution, and inherited structural features. Understanding of temporal relations among these events makes it possible to select specific generations of quartz within a vein for further studies such as the TitaniQ thermometry and fluid inclusion microthermometry in order to establish T–P–X fluctuations throughout the development of a hydrothermal system.  相似文献   

Highly fractionated Late Triassic I-type granites and related molybdenum mineralization in the Qinling orogenic belt: Geochemical and U–Pb–Hf and Re–Os isotope constraints     

《Ore Geology Reviews》2014

We present new data on the highly fractionated Late Triassic I-type Liyuantang granite, which is located in the middle segment of the South Qinling Subzone of central China and is associated with molybdenum mineralization. Zircon U–Pb dating indicates that the granite was emplaced at 210.1 ± 1.9 Ma, with a single zircon containing an inherited core that yielded an age of 449.8 ± 7.1 Ma. Magmatic zircons from the granite have ε_Hf(t) values of − 4.0 to + 1.5, whereas the inherited zircon core has a ε_Hf(t) value of − 5.3. Calculated Hf model ages of crust formation are indicative of substantial contributions from melting of Proterozoic crust that ranges in age from 1501 to 1155 Ma. The granite contains high concentrations of Si, Al, Na, and K, is enriched in Rb, Th, and U, has elevated Rb/Sr and Ga/Al ratios, and is depleted in Ti, Fe, Mn, Mg, Ca, and P, with significantly negative Eu anomalies (δEu = 0.33–0.50), similar to other highly fractionated I-type granites. These data indicate that the magmas that formed the Liyuantang pluton were produced during partial melting of Proterozoic garnet-absent quartz amphibolites. The magmas then fractionated apatite, feldspar, Ti-bearing phases, biotite, and hornblende prior to emplacement.Re–Os isotope analysis of molybdenite from the study area yields a mineralization age of 200.9 ± 6.2 Ma, suggesting that the Liyuantang molybdenum deposit formed during a previously unrecognized mineralization event. The present results, together with previous data, demonstrate that highly fractionated I-type granites associated with the second pulse of magmatism in the South Qinling subzone should be considered highly prospective for mineral exploration, focusing on Triassic–Early Jurassic granitoids.  相似文献   

Alteration and mineralization at the Zhibula Cu skarn deposit,Gangdese belt,Tibet     

《Ore Geology Reviews》2016

The Zhibula Cu skarn deposit contains 0.32 Mt. Cu metal with an average grade of 1.64% and is located in the Gangdese porphyry copper belt in southern Tibet. The deposit is a typical metasomatic skarn that is related to the interaction of magmatic–hydrothermal fluids and calcareous host rock. Stratiform skarn orebodies occur at the contact between tuff and marble in the Lower Jurassic Yeba Formation. Alteration zones generally grade from a fresh tuff to a garnet-bearing tuff, a garnet pyroxene skarn, and finally to a wollastonite marble. Minor endoskarn alteration zonations are also observed in the causative intrusion, which grade from a fresh granodiorite to a weakly chlorite-altered granodiorite, a green diopside-bearing granodiorite, and to a dark red-brown garnet-bearing granodiorite. Prograde minerals, which were identified by electron probe microanalysis include andradite–grossularite of various colors (e.g., red, green, and yellow) and green diopside. Retrograde metamorphic minerals overprint the prograde skarn, and are mainly composed of epidote, quartz, and chlorite. The ore minerals consist of chalcopyrite and bornite, followed by magnetite, molybdenite, pyrite, pyrrhotite, galena, and sphalerite. Three types of fluid inclusions are recognized in the Zhibula deposit, including liquid-rich two-phase inclusions (type L), vapor-rich two-phase inclusions (type V), and daughter mineral-bearing three-phase inclusions (type S). As the skarn formation evolved from prograde (stage I) to early retrograde (stage II) and later retrograde (stage III), the ore-forming fluids correspondingly evolved from high temperature (405–667 °C), high salinity (up to 44.0 wt.% NaCl equiv.), and high pressure (500–600 bar) to low-moderate temperature (194–420 °C), moderate-high salinity (10.1–18.3 and 30.0–44.2 wt.% NaCl equiv.), and low-moderate pressure (250–350 bar). Isotopic data of δ³⁴S (− 0.1‰ to − 6.8‰, estimated δ³⁴S_fluids = − 0.7‰), δD_H2O (− 91‰ to − 159‰), and δ¹⁸O_H2O (1.5‰ to 9.2‰) suggest that the ore-forming fluid and material came from magmatic–hydrothermal fluids that were associated with Miocene Zhibula intrusions. Fluid immiscibility likely occurred at the stage I and stage II during the formation of the skarn and mineralization. Fluid boiling occurred during the stage III, which is the most important Cu deposition mechanism for the Zhibula deposit.  相似文献   

基于光谱特征的月球岩性分类方法研究——以Apollo 16登月区域为例     

陈建平  王翔  高光大  姚美娟 《岩石学报》2016,32(1):77-86

利用NASA行星数据系统提供Apollo计划登月点采样线路影像数据,通过与嫦娥二号CCD数据、印度M~3数据空间校正获得采样路线坐标。开展嫦娥二号CCD数据与印度M~3数据MAP(后验概率)融合并选择Apollo 15、Apollo 16-62231的LSCC测得的标准岩石双向反射率光谱与M~3、嫦娥二号进行交叉定标。本文采用月球岩石光谱谱型全特征分析方法,选取涵盖Apollo计划登月获取的36个基站主要岩性87种、285件岩石样品,利用校正后的M~3数据分析月球典型岩石各阶吸收反射特征,建立月球典型岩石标准遥感影像光谱库,此后应用Apollo 623个岩石样品进行对比得到很好结果,同时完成Apollo 16登月点周围领域岩性分布图,并讨论了研究区的岩石成因,Apollo 16区域形成于高地大撞击,在早期的研究中已经被用于划分月球年代,本文方法对于月球岩石类别研究与理解月球的岩浆演化具有重要的研究价值。  相似文献