有机质碳同位素热力学分馏与天然气碳同位素组成     

王晓锋  刘文汇  徐永昌  郑建京  张殿伟 《沉积学报》2012,30(3):588-593

干酪根中不同结构和官能团具有不同的碳同位素组成,这种差异可以用有机质碳同位素热力学同位素因子（β因子）进行预测。煤岩模拟实验产物中,δ13CCO2相对烃类气体而言明显偏重,这与干酪根中羧基的β13C较大有关。含水实验产物的δ13CCO2轻于无水实验产物的δ13CCO2是由于含水实验中所增加CO2的碳同位素组成相对较轻造成的,含水实验增加的CO2产率是由β13C相对较小的部分亚甲基碳通过断裂、氢转移、以及与水反应转变而来。模拟实验低温阶段（≤300℃）,甲氧基中的甲基断裂可能的甲烷形成的主要方式。而甲氧基的β13C大于甲基,所以低温阶段出现了甲烷碳同位素组成先较重后变轻的现象。  相似文献   

阿拉善地块前中生代构造归属的新认识   总被引：4，自引：0，他引：4  

杨振宇  袁伟  仝亚博  刘静  王艳 《地球学报》2014,35(6):673-681

阿拉善地块的构造归属长期以来存在争议。我们对阿拉善地块东南部牛首山地区中—晚泥盆世砂岩的物源开展碎屑锆石U-Pb年代学与Hf同位素研究。碎屑锆石U-Pb年龄谱主要分布在5个区间:0.4—0.7 Ga,1.0—1.3 Ga,1.5—1.8 Ga,2.4—2.8 Ga和3.0 Ga,并获得一颗年龄为(4022±17)Ma的冥古宙锆石。2.4—2.7 Ga、3.0 Ga碎屑锆石和它们对应的εHf(t)值明显不同于华北板块同时代碎屑锆石,暗示着阿拉善地块与华北板块中—晚泥盆世并未相连。同时,我们还对地块东部的早石炭世、晚二叠世和早中三叠世地层开展了详细的古地磁研究,获得了相应的视极移曲线。我们结合碎屑锆石年代学和古地磁学研究,提出阿拉善地块前中生代与柴达木—塔里木地块具有亲缘性,而很可能与华北地块分离。印支运动使阿拉善地块相对于华北发生了32度的逆时针旋转,正是这一旋转运动使河西走廊—阿拉善地块最终与华北地块拼合形成了统一地块。  相似文献   

Group classification of mixed oils in central Junggar Basin,Northwest China and their migration     

Xulong Wang  Xinpu Shi  Jian Cao  Wenfang Lan  Guoliang Tao  Wenxuan Hu  Suping Yao 《中国地球化学学报》2010,29(4):375-382

The produced oils in central Junggar Basin are commonly mixed in origin. In this paper, in order to reveal this complexity and thereby provide valuable clues to the study of oil source and formation mechanism, genetic groups of the mixed oils were classified and their migration/accumulation was investigated. Based on the artificial oil mixing experiments, some representative biomarkers of the mixed oils showed varying tendencies according to mixing ratios of the oils. Hence, these biomarkers are useful for determining the origin of the mixed oils. According to the criteria, oils in the area were divided into four basic groups, i.e., the Lower Permian Fengcheng oil, the Middle Permian Lower Wuerhe oil, the Jurassic source derived oil, and the mixed oil (including the Lower and Middle Permian mixed oil and the Permian and Jurassic mixed oil). Oil migration and accumulation were discussed in combination with the geological background.  相似文献   

普光气田长兴组白云岩地球化学特征及其成因意义   总被引：3，自引：0，他引：3  

李志明  徐二社  范明  杨琦  余晓露  鲍云杰  陈红宇 《地球化学》2010,39(4):371-380

普光气田区长兴组白云岩的矿物组成与地球化学特征研究表明,自东南向西北方向,由普光8井至普光5井至普光6井,长兴组白云岩白云石颗粒的结晶程度和有序度总体上逐渐变高,其Fe、Mn、AI、K、Na、Sr含量及Mg^2＋／Ca^2＋比值总体呈降低的趋势;而氧同位素值逐渐降低,碳同位素值略增高,两者具负相关关系,这反映出白云石化作用与混合水无关;普光6井结晶白云岩87Sr／86Sr比值高于晚二叠世末古海水,说明白云石化流体并非长兴期古海水。研究认为长兴组泥-微晶白云岩由长兴期蒸发浓缩形成的高镁卤水交代灰泥丘而形成,属准同生白云石化作用成因,为非-差储层;结晶白云岩及碎裂化白云岩的白云石化流体应来自二叠纪高盐度海源地层水。属埋藏成因,可为优质储层。  相似文献   

Methane microseepage from different sectors of the Yakela condensed gas field in Tarim Basin,Xinjiang, China     

Junhong Tang  Haoyong Yin  Guojian Wang  Yueyuan Chen 《Applied Geochemistry》2010

Methane microseepage is the result of natural gas migration from subsurface hydrocarbon accumulations to the Earth’s surface, and it is quite common in commercial petroleum fields. While the role of microseepage as a pathfinder in petroleum exploration has been known for about 80 a, its significance as an atmospheric CH₄ source has only recently been studied, and flux data are currently available only in the USA and Europe. With the aim of increasing the global data-set and better understanding flux magnitudes and variabilities, microseepage is now being extensively studied in China. A static flux chamber method was recently applied to study microseepage emissions into the atmosphere in four different sectors of the Yakela condensed gas field in Tarim Basin, Xinjiang, China, and specifically in: (a) a faulted sector, across the Luntai fault systems; (b) an oil–water interface sector, at the northern margin of the field; (c) an oil–gas interface sector, in the middle of the field; (d) an external area, outside the northern gas field boundaries. The results show that positive CH₄ fluxes are pervasive in all sectors and therefore, only part of the CH₄ migrating from the deep oil–gas reservoirs is consumed in the soil by methanotrophic oxidation. The intensity of gas seepage seems to be controlled by subsurface geologic settings and lateral variabilities of natural gas pressure in the condensed gas field. The highest CH₄ fluxes, up to ∼14 mg m⁻² d⁻¹ (mean of 7.55 mg m⁻² d⁻¹) with higher spatial variability (standard deviation, σ: 2.58 mg m⁻² d⁻¹), occur in the Luntai fault sector. Merhane flux was lower in the oil–water area (mean of 0.53 mg m⁻² d⁻¹) and the external area (mean of 1.55 mg m⁻² d⁻¹), and at the intermediate level in the gas–oil sector (mean of 2.89 mg m⁻² d⁻¹). These values are consistent with microseepage data reported for petroleum basins in the USA and Europe. The build-up of methane concentration in the flux chambers is always coupled with an enrichment of ¹³C, from δ¹³C₁ of −46‰ to −42.5‰ (VPDB), which demonstrates that seeping methane is thermogenic, as that occurring in the deep Yakela reservoir. Daily variations of microseepage are very low, with minima in the afternoon, corresponding to higher soil temperature (and higher methanotrophic consumption), and maxima in the early morning (when soil temperatures are lowest). A preliminary and rough estimate of the total amount of CH₄ exhaled from the Yakela field is in the order of 10² tonnes a⁻¹.  相似文献   

鄂尔多斯盆地油气发现历史回顾与经验教训(二)——从盆地风格看盆地油气勘探前景   总被引：1，自引：1，他引：0  

孙肇才 《地质力学学报》2010,16(3):237-245

鄂尔多斯(陕甘宁)盆地是中国近代找油最早的地区之一。因长期不认识前陆盆地结构特点,加之主要勘探目标层三叠系延长组超低孔渗,因而油气勘探工作长期处于"孔孔见油,孔孔不流"的苦恼中。近二十年来,伴随着压裂技术及三角洲认识的开辟,前陆找油气相继在中国西部几个大盆地中都取得了进展。不过中国对前陆盆地的研究尚处于中早期阶段,应从前陆共性进一步加强研究,中国西部前陆油气勘探进一步繁荣是理所当然的趋势。  相似文献   

川东北普光气田鲕粒白云岩储层粒内溶孔的成因   总被引：5，自引：1，他引：4  

王恕一  蒋小琼  管宏林  鲍云杰 《沉积学报》2010,28(1):10-16

普光2井下三叠统飞仙关组储层鲕粒白云岩中,常见铸模孔、新月形、半月形溶孔和环状溶孔,溶孔常具定向特征,前人多认为这些溶孔为早期成岩的大气淡水溶蚀。研究发现,这些溶孔常与压性缝、碎裂（粒）化伴生,而溶孔无明显变形,表明是形成于构造挤压之后的埋藏溶孔。埋藏溶孔有二期,一期中有沥青充填,另一期无沥青充填,前者形成于石油侵位之前,后者形成于侵位石油演化为沥青之后。研究认为:构造挤压作用于岩石时,应力首先使鲕粒中结构薄弱点—同心圈层之间产生裂缝,当应力集中于上端,使鲕粒上端优先沿同心圈层发育裂缝,随应力增大裂缝沿同心圈层向下延伸,乃至形成圆形“脱壳”裂缝,在后期酸性流体进入时沿这些裂缝优先产生溶蚀,形成偏于上端的定向溶孔,以及沿同心圈向下溶蚀形成新月形、环状溶孔,挤压和（或）溶蚀更强,则发育成铸模孔。  相似文献   

川北地区大安寨段页岩油气源、储特征及富集层段优选     

刘忠宝  李倩文  刘光祥  李鹏  陈斐然  郝景宇  张文涛 《地质学报》2023,97(10):3421-3437

为查明川北地区大安寨段页岩油气烃源、储集特征及富集有利层段,以岩芯观察描述为基础,以岩石学与矿物学、有机地球化学及页岩储层表征等理论方法与技术为指导,开展了大安寨段二亚段纵向上4个小层岩相、烃源、储集特征的精细表征与差异性对比研究,优选出了页岩油气富集有利层段,并提出勘探研究建议。研究结果表明：大安寨段二亚段富含（泥质）介壳灰岩、（泥质纹层状）粉细砂岩2种夹层,低—中碳黏土质页岩、中碳纹层—薄层状介壳页岩、低碳（纹层状）粉砂质页岩、低碳粉砂质介壳灰质页岩4种页岩岩相;②小层以中碳黏土质页岩、中碳纹层状介壳页岩为主,夹层相对少,页岩连续性较好;而④小层以中碳纹层状介壳页岩夹介壳灰岩为主,不同尺度介壳灰岩夹层多。页岩有机显微组分整体以镜质组为主,②、④小层固体沥青较发育,自下而上有机质类型发生6次变化,依次为Ⅲ—Ⅱ2—Ⅲ—Ⅱ2—Ⅱ1—Ⅱ2;②小层与④小层生油气能力相对较好,④小层略好于②小层。页岩储集物性明显好于夹层,②小层和④小层页岩生烃能力相对好,有机质孔较发育,含气量相对高,页岩烃源—储集—含（油）气性匹配关系相对好,评价认为大安寨段二亚段上部④小层纹层状介壳页岩段为最佳页岩油气富集层段,其次为下部②小层黏土质页岩层段。基于研究区大安寨段二亚段沉积非均质性强、含油气性好的层段时空分布不稳定的特点,建议重视砂、泥、灰混积差异,加强以小层为单元的岩相（组合）时空分布规律研究;重视保存条件与含气性差异,加强常规—非常规一体油气勘探选区、选层研究。  相似文献   

张八岭群火山岩地球化学特征及其构造学意义          下载免费PDF全文

高长林  方成名 《江苏地质》2011,35(3):236-240

安徽滁州张八岭地区的张八岭群分为2组。一是下部北将军组,以千枚岩和片岩为主;二是上部西冷岩组,主要为一套变质火山岩系。张八岭岩群的细碧-石英角斑岩系主要发育于西冷岩组中,具多旋回特点。细碧-石英角斑岩系以石英角斑岩为主,细碧岩次之,角斑岩类稀少。该岩系的火山岩富碱、富钠,具双峰值特征,其主量元素、微量元素和稀土元素地球化学特征表明,它形成于非造山张性环境,为裂陷槽,是与晚元古代罗迪尼亚(Rodinia)超大陆裂解有关的岩浆作用的产物。  相似文献   

哈萨克斯坦M盆地平衡剖面复原及其在油气成藏研究中的应用     

刘景东  蒋有录  孔令强 《地质科技情报》2011,30(6):94-98,104

平衡剖面不仅可以用于评价和检验地震解释剖面、分析盆地构造演化,还有助于分析油气的动态成藏过程.对哈萨克斯坦M盆地的主干地震剖面进行了平衡剖面恢复,分析了盆地的构造演化特征及构造发育对油气成藏的影响.研究结果表明,M盆地中新生代地质演化具有明显的阶段性,早、中侏罗世为盆地断陷伸展、沉积与沉降的主要时期,白垩纪主要为坳陷期...  相似文献