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1.
南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪 总被引：1，自引：1，他引：0
The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage. 相似文献
2.
南黄海盆地特殊的地震地质条件导致准确获得海相地层速度存在困难。基于本区的多道地震资料,联合使用多数据质控速度分析、初至波层析反演及层控网格层析反演3种方法,提取出了较为可靠的海相中-古生界速度信息。结合提取的地震速度及下扬子区已有钻井信息,总结了南黄海主要海相地层的速度分布。本区海相地层速度整体呈高低相间分布结构,存在速度的突变和倒转。海相下构造层速度高,不同地层间速度差异较小。由于海相下构造层无钻井资料约束,获得的速度信息仍存在不确定性。 相似文献
3.
崂山隆起位于南黄海盆地中部,海相中-古生界分布广泛且厚度大,其构造演化经历了加里东、海西、印支、燕山和喜山等多期构造运动,早期油气聚集可能在后期受到不同程度的破坏,因此,油气保存条件是崂山隆起油气勘探能否取得突破的关键因素。通过综合分析构造运动中抬升剥蚀作用和断裂作用与油气保存的关系,以及盖层条件与油气保存的关系,探讨崂山隆起内部油气保存条件的差异性以指导该区油气勘探。结果表明:崂山隆起呈差异性油气保存特点,位于崂山隆起中南部的高石稳定带是一个早期断裂不发育的弱变形区,后期构造运动改造破坏程度较弱,特别是下古生界具备较为优越的生储盖组合,构造多以断背斜和低幅宽缓背斜为主,发育多个大型圈闭,岩浆活动相对较弱,油气保存条件较为优越;而崂山隆起北部的青峰变形带断裂系统发育,地层褶皱变形强烈,单个圈闭规模较小,油气保存条件相对较差;高石稳定带中南部是进一步油气勘探和调查参数井钻探的重点目标区。 相似文献
4.
A 43 cm long E271 sediment core collected near the East Pacific Rise(EPR) at 13°N were studied to investigate the origin of smectite for understanding better the geochemical behavior of hydrothermal material after deposition.E271 sediments are typical metalliferous sediments. After removal of organic matter, carbonate, biogenic opal,and Fe-Mn oxide by a series of chemical procedures, clay minerals(2 μm) were investigated by X-ray diffraction,chemical analysis and Si isotope analysis. Due to the influence of seafloor hydrothermal activity and close to continent, the sources of clay minerals are complex. Illite, chlorite and kaolinite are suggested to be transported from either North or Central America by rivers or winds, but smectite is authigenic. It is enriched in iron, and its contents are highest in clay minerals. Data show that smectite is most likely formed by the reaction of hydrothermal Fe-oxyhydroxide with silica and seawater in metalliferous sediments. The Si that participates in this reaction may be derived from siliceous microfossils(diatoms or radiolarians), hydrothermal fluids, or detrital mineral phases. And their δ30 Si values are higher than those of authigenic smectites, which implies that a Si isotope fractionation occurs during the formation because of the selective absorption of light Si isotopes onto Feoxyhydroxides. Sm/Fe mass ratios(a proxy for overall REE/Fe ratio) in E271 clay minerals are lower than those in metalliferous sediments, as well as distal hydrothermal plume particles and terrigenous clay minerals. This result suggests that some REE are lost during the smectite formation, perhaps because their large ionic radii of REE scavenged by Fe-oxyhydroxides preclude substitution in either tetrahedral or octahedral lattice sites of this mineral structure, which decreases the value of metalliferous sediments as a potential resource for REE. 相似文献
5.
对山东半岛南部近岸海域的106个表层沉积物样品及大沽河、五龙河和乳山河的94个表层沉积物样品进行碎屑矿物分析,系统地研究了碎屑矿物的分布特征及物源指示。研究区共鉴定出40种重矿物和13种轻矿物,重矿物以普通角闪石、绿帘石、黑云母和自生黄铁矿为主,轻矿物以石英、斜长石、钾长石和风化云母为主。根据碎屑矿物组合特征,将研究区分为4个矿物区:Ⅰ区为胶州湾口至崂山头的附近海域;Ⅱ_1亚区为丁字湾和鳌山湾附近水深约15m以浅的海域,Ⅱ_2亚区为研究区东南部水深20m的远岸区;Ⅲ区处于Ⅱ区和Ⅳ区的过渡带;Ⅳ区为乳山口西南部近岸海域。Ⅰ区和Ⅱ区的矿物组合均为普通角闪石-绿帘石-石英-长石,Ⅰ区和Ⅱ_1亚区受大沽河、五龙河和乳山河输入的物质及沿岸基岩、岛屿风化碎屑的影响较大,Ⅱ_2亚区主要为晚更新世低海平面时形成的陆架残留沉积。Ⅲ区矿物组合为普通角闪石-石英-长石-片状矿物,Ⅳ区矿物组合为云母类-自生黄铁矿-普通角闪石-石英,Ⅲ区、Ⅳ区物源多样,黄河物质对两区贡献显著。 相似文献
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台风作为事件性的强动力因素,其对河口海域沉积环境的影响目前研究较少,开展典型台风事件对长江口外海域悬浮体分布的影响研究对于深入理解长江径流挟带陆源物质向东海陆架扩散机制等具有重要意义。利用2015年09号台风"灿鸿"过境前后长江口外海域现场调查数据,分析台风前后长江口外水体结构和悬浮体粒度分布变化,结合同期环境观测数据与开源数据,阐明台风对河口外海域悬浮体分布的影响机制。结果表明:长江口外海域悬浮体中细颗粒组分(≤ 128μm)主要为无机矿物颗粒,而粗颗粒组分(>128μm)主要是生源有机颗粒。生源有机粗颗粒主要分布于中上层水体,而无机细颗粒主要分布于底层水体,使得长江口外海域悬浮体平均粒径分布呈双层结构。台风前后悬浮体粒度分布变化反映了台风对长江口外海域物理和生物过程的双重影响,其中物理过程主要影响无机细颗粒分布变化,生物过程主要影响有机粗颗粒。台风期间强烈的偏北风使得长江冲淡水在口门外海域由东北输运转为往东输运,与长江冲淡水输运方向一致的表层无机细颗粒在台风后输运方向同样往东。另外,台风作用在河口区产生的下降流将12250-4站位底部再悬浮的泥质沉积物向东搬运至12300-4站,导致12300-4站底层悬浮体浓度增加、粒度变细。台风过境还造成长江口外海域初级生产力提高,而浮游植物生长对悬浮体中有机粗颗粒的形成有促进作用,使得口门外海域上层水体中有机粗颗粒体积浓度升高。长江口外海域由于台风过境导致悬浮体中无机细颗粒和生源有机颗粒含量均增加,使得其平均粒径整体变化不大。 相似文献
7.
根据随钻测录井实时地质导向和大斜度、水平井评价成图技术需求，针对传统绘图方法存在的弊端，提出了将测录井信息、井眼轨迹和地质模型进行二维分解的实时绘图方法。针对二维分解绘图方法绘图时空复杂度较高的问题，给出了不同事件驱动下的局部实时计算和拷屏重绘算法，控制了对CPU和内存的消耗、提高了绘图效率，消除了实时绘图的闪烁和卡顿现象。应用实例表明，二维分解实时绘图方法能够实现大尺度随钻测录井地质导向图形的流畅、无卡顿实时绘图，可提高大斜度、水平井储层模型评价的刻画精度和时效。 相似文献
8.
台湾利吉混杂岩位于吕宋岛弧与欧亚大陆发生碰撞(弧陆碰撞)关键地带,是菲律宾海板块和欧亚板块结合带重点研究的区域,其中出露的蛇纹岩可以为研究弧陆碰撞造山过程提供重要细节信息。利吉混杂岩中蛇纹岩岩块原岩为橄榄岩,通过锆石U-Pb年代学分析,得到代表洋壳年龄的橄榄岩形成年龄为17.7±0.5Ma,结合南海洋壳、菲律宾海洋壳年龄和构造背景,判断利吉混杂岩中的蛇纹岩(蛇纹石化橄榄岩)来自马尼拉俯冲系统的弧前盆地,是在利吉混杂岩形成过程中经第二次逆冲混入利吉混杂岩系统的。明确蛇纹岩岩块来源可以为利吉混杂岩形成提供细节信息,为研究弧陆碰撞造山活动和板块运动提供可靠依据。 相似文献
9.
碳酸盐岩中稀土元素的含量、配分模式及元素异常记录了周围沉积水体的特征,能够很好地指示古海洋及沉积环境。珊瑚具有的高分辨率和稀土元素的高稳定性的特点,能够忠实地记录周围海水的地球化学特征。本文以南海西沙宣德环礁永兴岛142～84 ka发育的珊瑚礁为研究对象,通过主微量元素含量,尤其是稀土元素含量及其配分图解,判断珊瑚礁形成时周围水体的特征。结果表明自142 ka以来,永兴岛大部分珊瑚礁具有正常海相碳酸盐岩的稀土配分特征,表现为LREE亏损,Ce负异常及高的Y/Ho比值,表明周围水体属于开阔的浅海,但是位于23 m处(年龄为114 ka)的滨珊瑚骨骼格架除了有正常海相碳酸盐岩的特征外,还具有明显的Eu正异常,这表明其形成时有热液流体的加入。经过模型计算,认为在滨珊瑚骨骼格架的生长阶段,至少有0.1%的热液加入周围的海水中。通过资料查询和年龄对比,认为这些热液可能与高尖石岛或海南岛火山活动有关。 相似文献
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以冲绳海槽伊平屋北热液区附近两个站位(HOBAB2-T3和HOBAB2-T6)的浮岩为研究对象,分别对充填沉积物的浮岩(T3-D、T6-D)和去除沉积物的浮岩(T3-C、T6-C)进行扫描电镜观察、矿物组成和微量元素组成的对比分析。结果表明,浮岩气孔充填的沉积物主要来源于冲绳海槽内碎屑沉积物的混入,其中气孔较小的T3浮岩中充填的沉积物组成主要为伊利石和石英,而气孔较大的T6浮岩中充填的沉积物组成主要为石英和长石,代表了海槽内沉积物的一般矿物组成。邻近热液区的T3浮岩气孔中的沉积物含有异常高含量的Pb(101μg/g)、Zn(196μg/g)、Cu(47μg/g)等金属元素,代表强烈的热液活动信号;距热液区稍远的T6浮岩气孔中沉积物也表现出Pb、Cu等元素含量的异常特征,可能代表较弱的热液活动信号。这说明海底热液区附近的浮岩气孔中充填的沉积物可以记录热液活动的信息,这对寻找浮岩分布区新的热液活动具有重要的指示意义。 相似文献