Seasonal δS variations in two high elevation snow pits measured by S-S double spike thermal ionization mass spectrometry     

Jacqueline L. Mann  Christopher A. Shuman  Karl J. Kreutz 《Geochimica et cosmochimica acta》2008,72(15):3907-3927

δ³⁴S and sulfate concentrations were determined in snow pit samples using a thermal ionization mass spectrometric technique capable of 0.2‰ accuracy and requires ≈5 μg (0.16 μmol) natural S. The technique utilizes a ³³S-³⁶S double spike for instrumental mass fractionation correction, and has been applied to snow pit samples collected from the Inilchek Glacier, Kyrgyzstan and from Summit, Greenland. These δ³⁴S determinations provide the first high-resolution seasonal data for these sites, and are used to estimate seasonal sulfate sources. Deuterium (δD) and oxygen (δ¹⁸O) isotope data show that the Inilchek and Summit snow pit samples represent precipitation over ≈20 months.The δ³⁴S values for the Inilchek ranged from +2.6 ± 0.4‰ to +7.6 ± 0.4‰ on sample sizes ranging from 0.3 to 1.8 μmol S. δ³⁴S values for Greenland ranged from +3.6 ± 0.7‰ to +13.3 ± 5‰ for sample sizes ranging from 0.05 to 0.29 μmol S. The concentration ranged from 92.6 ± 0.4 to 1049 ± 4 ng/g for the Inilchek and 18 ± 9 to 93 ± 6 ng/g for the Greenland snow pit. Anthropogenic sulfate dominates throughout the sampled time interval for both sites based on mass balance considerations. Additionally, both sites exhibit a seasonal signature in both δ³⁴S and concentration. The thermal ionization mass spectrometric technique has three advantages compared to gas source isotopic methods: (1) sample size requirements of this technique are 10-fold less permitting access to the higher resolution S isotope record of low concentration snow and ice, (2) the double spike technique permits δ³⁴S and S concentration to be determined simultaneously, and (3) the double spike is an internal standard.  相似文献   

Roles of Biogeochemical Processes in the Oceanic Carbon Cycle Described with a Simple Coupled Physical-Biogeochemical Model   总被引：1，自引：0，他引：1  

Masahiko?FujiiEmail author  Motoyoshi?Ikeda  Yasuhiro?Yamanaka 《Journal of Oceanography》2005,61(5):803-815

To evaluate the contribution of biogeochemical processes to the oceanic carbon cycle and to calculate the ratio of calcium carbonate to organic carbon downward export, we have incorporated biological and alkalinity pumps in the yoked high-latitude exchange/interior diffusion-advection (YOLDA) model. The biogeochemical processes are represented by four parameters. The values of the parameters are tuned so that the model can reproduce the observed phosphate and alkalinity distributions in each oceanic region. The sensitivity of the model to the biogeochemical parameters shows that biological production rates in the euphotic zone and decomposition depths of particulate matters significantly influence horizontal and vertical distributions of biogeochemical substances. The modeled vertical fluxes of particulate organic phosphorus and calcium carbonate are converted to vertical carbon fluxes by the biological pump and the alkalinity pump, respectively. The downward carbon flux from the surface layer to the deep layer in the entire region is estimated to be 3.36 PgC/yr, which consists of 2.93 PgC/yr from the biological pump and 0.43 PgC/yr from the alkalinity pump, which is consistent with previous studies. The modeled rain ratio is higher with depth and higher in the Pacific and Indian Oceans than in the Atlantic Ocean. The global rain ratio at the surface layer is calculated to be 0.14 to 0.15. This value lies between the lower and higher ends of the previous estimates, which range widely from 0.05 to 0.25. This study indicates that the rain ratio is unlikely to be higher than 0.15, at least in the surface waters.  相似文献   

A nitrate and silicate budget in the equatorial Pacific Ocean: a coupled physical–biological model study     

M. -S. Jiang  F. Chai  R. C. Dugdale  F. P. Wilkerson  T. -H. Peng  R. T. Barber   《Deep Sea Research Part II: Topical Studies in Oceanography》2003,50(22-26):2971

A coupled physical–biological model was developed to simulate the low-silicate, high-nitrate, and low-chlorophyll (LSHNLC) conditions in the equatorial Pacific Ocean and used to compute a detailed budget in the Wyrtki box (5°N–5°S, 180–90°W) for the major sources and cycling of nitrogen and silicon in the equatorial Pacific. With the incorporation of biogenic silicon dissolution, NH₄ regeneration from organic nitrogen and nitrification of ammonia in the model, we show that silicon recycling in the upper ocean is less efficient than nitrogen. As the major source of nutrients to the equatorial Pacific, the Equatorial Undercurrent provides slightly less Si(OH)₄ than NO₃ to the upwelling zone, which is defined as 2.5°N–2.5°S. As a result, the equatorial upwelling supplies less Si(OH)₄ than NO₃ into the euphotic zone in the Wyrtki box, having a Si/N supply ratio of about 0.85 (2.5 vs. 2.96 mmolm⁻² day⁻¹). More Si(OH)₄ than NO₃ is taken up with a Si/N ratio of 1.17 (2.72 vs. 2.33 mmolm⁻² day⁻¹) within the euphotic zone. The difference between upwelling supply and biological uptake is balanced by nutrient regeneration and horizontal advection. Excluding regeneration, the net silicate and nitrate uptakes are nearly equal (1.76 vs. 1.84 mmolm⁻² day⁻¹). However, biogenic silica export production is slightly higher than organic nitrogen (1.74 vs. 1.59 mmolm⁻² day⁻¹) following a 1.1 Si/N ratio. In the central equatorial Pacific, low silicate concentrations limit diatom growth; therefore non-diatom new production accounts for most of the new production. Higher silicate supply in the east maintains elevated diatom growth rates and new production associated with diatoms dominate upwelling zone. In contrast, the new production associated with small phytoplankton is nearly constant or decreases eastward along the equator. The total new production has a higher rate in the east than in the west, following the pattern of surface silicate. This suggests that silicate regulates the diatom production, total new production, and thereby carbon cycle in this area. The modeled mean primary production is 48.4 mmolCm⁻² day⁻¹, representing the lower end of direct field measurements, while new production is 15.0 mmolCm⁻² day⁻¹, which compares well with previous estimates.  相似文献   

Several significant hydrographic characteristics and their formation mechanism in the South China Sea during the spring and summer of 1998   总被引：1，自引：1，他引：1  

Xu Jianping  Chai Fei  Liu Zenghong  Zhu Bokang 《海洋学报(英文版)》2003,22(4):491-502

INTRODUCTIONTheSCSisthelargestmarginseainthewestoftheNorthPacificOcean .Theprevailingwindinwinterisnortheast,whileinsummeritissouthwest .Itisstilluncertainthathowthecirculationandtemperature -salinityfieldassociatewiththemonsoonforcingandaccompanywithseveralkindsofvariationsbeforeorafterthesummermonsoonburst .DuringSECMEXin 1 998,twointensiveobservationperiods (IOP)havebeencarriedoutntheSCS (Fig 1 ) :IOP1 ,from 1 0Aprilto 5May ;IOP2 ,from 1 2JunetoJuly 6 ,inordertounderstandthe…  相似文献   

Evidence for the grazing hypothesis: Grazing reduces phytoplankton responses of the HNLC ecosystem to iron enrichment in the western subarctic pacific (SEEDS II)     

《Journal of Oceanography》2007,63(6):983-994

A mesoscale iron-enrichment study (SEEDS II) was carried out in the western subarctic Pacific in the summer of 2004. The iron patch was traced for 26 days, which included observations of the development and the decline of the bloom by mapping with sulfur hexafluoride. The experiment was conducted at almost the same location and the same season as SEEDS (previous iron-enrichment experiment). However, the results were very different between SEEDS and SEEDS II. A high accumulation of phytoplankton biomass (∼18 mg chl m⁻³) was characteristic of SEEDS. In contrast, in SEEDS II, the surface chlorophyll-a accumulation was lower, 0.8 to 2.48 mg m⁻³, with no prominent diatom bloom. Photosynthetic competence in terms of F _v/F _m for the total phytoplankton community in the surface waters increased after the iron enrichments and returned to the ambient level by day 20. These results suggest that the photosynthetic physiology of the phytoplankton assemblage was improved by the iron enrichments and returned to an iron-stressed condition during the declining phase of the bloom. Pico-phytoplankton (<2 μm) became dominant in the chlorophyll-a size distribution after the bloom. We observed a nitrate drawdown of 3.8 μM in the patch (day 21), but there was no difference in silicic acid concentration between inside and outside the patch. Mesozooplankton (copepod) biomass was three to five times higher during the bloom-development phase in SEEDS II than in SEEDS. The copepod biomass increased exponentially. The grazing rate estimation indicates that the copepod grazing prevented the formation of an extensive diatom bloom, which was observed in SEEDS, and led to the change to a pico-phytoplankton dominated community towards the end of the experiment.  相似文献   

Stratigraphy of total metals in PIRLA sediment cores   总被引：1，自引：0，他引：1  

Stephen A. Norton  Ray W. Bienert Jr.  Michael W. Binford  Jeffrey S. Kahl 《Journal of Paleolimnology》1992,7(3):191-214

Sediment cores from 30 low-alkalinity lakes in northern New England (NE), New York (NY), the northern Great Lakes States (NGLS) of Minnesota, Michigan, and Wisconsin, and Florida (FL) have been dated by ²¹⁰Pb and analyzed for water and organic content, eight major elements (Al, Ti, Fe, Mn, Ca, Mg, Na, K) plus four trace metals (Pb, Zn, Cu, and V). Variations in the percentages of major elements through time are dominated by long-term independent variations in the abundance of SiO₂, FeO, and to a lesser extent Ca and Al. Additional variations are caused by varying proportions of inorganic matter. Major variations in chemistry are generally unrelated to documented distrubances in the watersheds; most disturbances are minor fires or selective logging.Accelerated accumulation of Pb from atmospheric sources into sediment first occurs in sediment dated between 1800 and 1850 in NY and NE, slightly later in the NGLS region, and about 1900 in FL. Modern accumulation rates in all areas are comparable (ca. 1 to 4 g cm^–2 yr^–1). Accumulation rates of Pb in some lakes have declined significantly from 1975 to 1985. Atmospheric deposition of anthropogenic Zn and Cu is also indicated by generally increasing accumulation rates in sediment cores, but the record is not as clear nor are chemical profiles in all lakes parallel to the trends in atmospheric emissions inferred on the basis of fossil fuel consumption, smelting, and other industrial activities. Inter-lake variations in profiles of Cu and Zn are large. Vanadium accumulation rates increase by the 1940s in NY and NE, but not until the 1950s in the NGLS region. This timing correlates with regional trends in the combustion of fuel oil, a major source of atmospheric V.Acidification of some of the lakes is suggested by decreases in the concentration and accumulation rates of Mn, Ca, and Zn in recent sediment, relative to other elements of catchment origin. The decreases generally occur slightly before the onset of acidification as indicated by diatoms. Increased sediment accumulation rates for Fe may indicate the acidification of watershed soils. The use of the accumulation rate of TiO₂ as an indicator of rates of erosion and for normalization of trace metal accumulation rates is in question for lakes where the flux of TiO₂ from the atmosphere varies and is a significant fraction of the total flux of TiO₂ to the sediment.This is the thirteenth of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D. F. Charles and D. R. Whitehead are guest editors for this series.  相似文献   

The history and impact of air pollution at Čertovo Lake,southwestern Czech Republic     

Josef Vesely  Heather Almquist-Jacobson  Lisa M. Miller  Stephen A. Norton  Peter Appleby  Aruna S. Dixit  John P. Smol 《Journal of Paleolimnology》1993,8(3):211-231

This multi-disciplinary investigation documents the longterm effects of atmospheric pollution of metals and acids on a geologically sensitive catchment in the umava Mountains, southwestern Czech Republic, a region with a long history of human disturbance. A 30 cm long sediment core (I) from ertovo Lake was analyzed for natural and artifical radionuclides, metals, diatoms, chrysophytes, and pollen in sediments accumulated during the last 200 years. A second core (II), extending to 95 cm, included sediment judged to be free of atmospheric deposition of pollutants associated with the Industrial Revolution. Chronostratigraphic markers include several changes in the pollen assemblages corresponding to well-documented changes in land-use, and distinct distributions of ¹³⁷Cs, ¹³⁴Cs and ²⁴¹Am from weapons testing and the 1986 nuclear accident at Chernobyl, Russia. These markers corroborate the ²¹⁰Pb dating and, together, produce a reliable chronology extending back nearly to 1800 A.D.Stratigraphic profiles of Cu, Pb, and Zn in Core I are unlike any previously reported in the literature. Concentrations of Cu, Pb, and Zn remain generally above 100, 400, and 200 g g^-1, respectively, for the 200 years represented by Core I. These values are unusually high for sediments from a watershed with no known heavy-metal ore bodies. Accumulation rates for Cu, Pb, and Zn, which include both atmospheric and watershed contributions, are also high (ca 1, > 1 and > 1 g cm^-2 yr^-1, respectively) for the same period, although the anthropogenic contribution of Zn rose from nearly zero at 1800 A.D. The Cu and Pb accumulation rates rose dramatically about 1640 A.D.Accumulation rates of anthropogenically-derived Be, a relatively abundant element in the soft coals of the region, are also elevated by about 0.01 g cm^-2 yr^-1 in sediments of this period. Vanadium accumulation rates increased only since 1980 A.D., presumably along with increased consumption of oil.Diatom assemblages illustrate that the lake was acidic (pH between 4.5 and 5) through at least the past 200 years. The pH declined significantly (from ca 5 to 4) between 1960 and 1985 with a slight increase to 4.5 in the last few years. Recent diatom and chrysophyte assemblages suggest high trace metal concentrations, consistent with the present lake-water chemistry.  相似文献   

Fossil-pollen evidence for abrupt climate changes during the past 18 000 years in eastern North America     

Eric C Grimm  George L Jacobson Jr 《Climate Dynamics》1992,6(3-4):179-184

A quantitative measure of the rate at which fossil-pollen abundances changed over the last 18 000 years at 18 sites spread across eastern North America distinguishes local from regionally synchronous changes. Abrupt regional changes occurred at most sites in late-glacial time (at 13700, 12 300, and 10000 radiocarbon yr BP) and during the last 1000 years. The record of abrupt late-glacial vegetation changes in eastern North America correlates well with abrupt global changes in ice-sheet volume, mountain snow-lines, North Atlantic deep-water production, atmospheric CO₂, and atmospheric dust, although the palynological signal varies from site to site. Changes in vegetation during most of the Holocene, although locally significant, were not regionally synchronous. The analysis reveals non-alpine evidence for Neoglacial/Little Ice Age climate change during the last 1000 years, which was the only time during the Holocene when climate change was of sufficient magnitude to cause a synchronous vegetational response throughout the subcontinent. During the two millennia preceding this widespread synchronous change, the rate of change at all sites was low and the average rate of change was the lowest of the Holocene.Contribution to Clima Locarno Past and Present Climate Dynamics; Conference September 1990, Swiss Academy of Sciences — National Climate Program  相似文献   

Porphyroblast rotation during crenulation cleavage development: an example from the aureole of the Mooselookmeguntic pluton, Maine, USA   总被引：1，自引：0，他引：1  

S. E. JOHNSON  M. E. DUPEE  C. V. GUIDOTTI 《Journal of Metamorphic Geology》2006,24(1):55-73

In the low‐pressure, high‐temperature metamorphic rocks of western Maine, USA, staurolite porphyroblasts grew at c. 400 Ma, very late during the regional orogenesis. These porphyroblasts, which preserve straight inclusion trails with small thin‐section‐scale variation in pitch, were subsequently involved in the strain and metamorphic aureole of the c. 370 Ma Mooselookmeguntic pluton. The aureole shows a progressive fabric intensity gradient from effectively zero emplacement‐related deformation at the outer edge of the aureole ～2900 m (map distance) from the pluton margin to the development of a pervasive emplacement‐related foliation adjacent to the pluton. The development of this pervasive foliation spanned all stages of crenulation cleavage development, which are preserved at different distances from the pluton. The spread of inclusion‐trail pitches in the staurolite porphyroblasts, as measured in two‐dimensional (2‐D) thin sections, increases nonlinearly from ～16° to 75° with increasing strain in the aureole. These data provide clear evidence for rotation of the staurolite porphyroblasts relative to one another and to the developing crenulation cleavage. The data spread is qualitatively modelled for both pure and simple shear, and both solutions match the data reasonably well. The spread of inclusion‐trail orientations (40–75°) in the moderately to highly strained rocks is similar to the spread reported in several previous studies. We consider it likely that the sample‐scale spread in these previous studies is also the result of porphyroblast rotation relative to one another. However, the average inclusion‐trail orientation for a single sample may, in at least some instances, reflect the original orientation of the overgrown foliation.  相似文献   

Controls on low-pressure anatexis   总被引：2，自引：0，他引：2  

C. C. GERBI  S. E. JOHNSON  P. O. KOONS 《Journal of Metamorphic Geology》2006,24(2):107-118

Low-pressure anatexis, whereby rocks melt in place after passing through the andalusite stability field, develops under more restricted conditions than does low-pressure metamorphism. Our thermal modelling and review of published work indicate that the following mechanisms, operating alone, may induce anatexis in typical pelitic rocks without inducing wholesale melting in the lower crust: (i) magmatic advection by pervasive flow; (ii) crustal-scale detachment faulting; and (iii) the presence of a high heat-producing layer. Of these, only magmatic advection by pervasive flow and crustal-scale detachment faulting have been shown quantitatively to provide sufficient heat to cause widespread melting. Combinations of the above mechanisms with pluton-scale magmatic advection, shear heating, removal of the lithospheric mantle, or with each other provide additional means of developing suitable high temperatures at shallow crustal levels to generate low-pressure anatexis.  相似文献