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51.
The Hahaigang W–Mo polymetallic skarn deposit is located in the central-eastern part of Gangdese tectono-magmatic belt in Lhasa terrane, Tibet. The deposit was discovered in 2007 with currently proven 46 million tons of WO3 ores, 12 million tons of Mo ores, and 1.31 million tons of combined Cu–Pb–Zn ores, at an average grade of 0.20% WO3, 0.07% Mo, 0.026% Cu, 0.49% Pb, and 3.1% Zn. Ore bodies occur in veins or disseminations, and are confined within the NE-striking Dalong fault zone which is hosted by the Lower-Permian Pangna Group of dominantly quartz sandstone and slate. Several granitic plutons are exposed in the area or known from drill-holes. Ages of these granitic plutons are determined by using zircon U–Pb LA–ICP–MS method. For example, the biotite monzogranite yields a 206Pb/238U–207Pb/238U concordia age of 58.66 ± 0.90 Ma and a weighted mean 206Pb/238U age of 57.02 ± 0.42 Ma. The granite porphyry yields a 206Pb/238U–207Pb/238U concordia age of 109.1 ± 8.9 Ma and a weighted mean 206Pb/238U age of 114.0 ± 2.6 Ma. The biotite monzogranite yields a weighted mean 206Pb/238U age of 56.1 ± 1.1 Ma. Re–Os isochron age of 63.2 ± 3.2 Ma from 5 molybdenite samples collected from the W–Mo skarn ores is also obtained in this study. The zircon U–Pb and molybdenite Re–Os geochronological data suggest that the W–Mo mineralization was not temporally associated with any of the dated igneous plutons. However, the molybdenite Re–Os age of 63.2 ± 3.2 Ma indicates that the W–Mo mineralization might have occurred during the main India–Eurasia collision that was initiated around 65 Ma. Microprobe analysis of ilvaite that occurs in two generations in the W–Mo skarn ores reveals a close relationship to Ca–Fe–F-rich hydrothermal fluids, which were probably derived from deeply-seated magmas. We suggest that ascent of the fluids was strictly controlled by the ore-controlling Dalong fault zone, and that chemical interaction and metasomatism between the fluids and the Lower-Permian Pangna quartz-feldspathic host rocks produced the ilvaite and the W–Mo polymetallic skarn deposit during the main India–Eurasia collision. Although the majority of the polymetallic deposits in the Gangdese belt are reported to be either pre- or post-main collision, it is evident from this study that the main collision also produced W–Mo polymetallic mineralization within the belt.  相似文献   
52.
Whether the formation of the isolated sand body deposition in the forebulge area of a foreland basin system is structure- or deposition-controlled has puzzled geologists for decades, although sand body deposition is generally believed to be indicative of the position of the flexural forebulge in a foreland basin. The formation of a modern sand body in the forebulge area is thus examined by multi-scale geophysical observations based on combined reflection seismic profiles and compressed high-intensity radar pulse (CHIRP) profiles across the sand deposition along the forebulge of the Western Taiwan Foreland Basin (WTFB), which is a Late Miocene-present foreland basin in the overfilled stage. These profiles suggest that the accumulation of the sand deposits along the forebulge of the WTFB is not directly associated with forebulge faultings. The relief map of the forebulge deposit substratum shows a northwestward tilting slope, and the isopach of the forebulge sand body indicates that a large part of the sand body accumulated along the axis of the Taiwan Strait and the subdued forebulge of the WTFB. The difference between the prevailing directions of tidal currents between the Taiwan Strait and the East China Sea reflects the probable sedimentary influence of the cratonward migrating fold-thrust belt within a foreland shelf. We suggest that the formation and distribution of the sand deposits along the forebulge of the WTFB are generally controlled not only by the transverse downslope sedimentation but also longitudinal hydrodynamic processes at distal parts of the foreland basin. Our explanation provides a plausible tectono-sedimentary cause of the sand body deposition in the forebulge area in an overfilled foreland basin. The sedimentary dynamics of the sand body in the Taiwan Strait may be applicable for understanding the formation of isolated sand bodies in the distal part of the Cretaceous Western Interior Foreland Basin.  相似文献   
53.
The Archaean Earth is considered to have been characterized by microcontinents that formed, dominantly, through the accretion of oceanic arcs and plateaus. The North China Craton (NCC) provides a typical case where at least seven ancient microcontinental nuclei with distinct lithological features and independent tectonic histories were amalgamated into the cratonic framework at the end of the Archaean. Here we investigate a suite of magmatic rocks developed at the periphery of one of these microblocks, the Jiaoliao Block that forms part of the composite Eastern Block of the NCC. We present petrological, geochemical and zircon U–Pb geochronological data from the Taipingzhai charnockite suite, and associated amphibolites, metagabbros and orthogneisses from the Qianxi Complex. Geochemically the rocks show a wide range of SiO2 (charnockite suite: 52.57–75.50 wt.%; metagabbro: 43.71 wt.%; amphibolite: 50.24 wt.%; garnet-bearing biotite: 63.73 wt.%), and MgO (charnockite suite: 0.89–5.01 wt.%; metagabbro: 3.99 wt.%; amphibolite: 6.23 wt.%; garnet-bearing biotite: 2.08 wt.%). The composition of the felsic units straddle from diorite through syeno-diorite to granite with both alkalic and subalkalic affinity, with dominantly magnesian composition and arc-related features. Their immobile trace element relationships suggest calc-alkaline affinity. They show positive Pb, Ba, La, Nd, and Gd and negative Nb, Ta, Sr, Th and Ti anomalies with slightly negative anomalies of Ce and Y, attesting to arc-related features. In tectonic classification diagrams, the rocks plot in the VAG + syn-COLG field or the VAG area suggesting subduction-related origin.The dominant population of zircons in all these rocks displays magmatic crystallization features including high Th/U values with core-rims textures indicating subsequent thermal events. The zircon U–Pb data yield upper intercept ages of 2587 ± 10 Ma to 2543 ± 17 Ma and 207Pb/206Pb mean ages of 2578 ± 7.3 Ma to 2536 ± 8 Ma for the charnockite suite, marking the timing of emplacement of the arc magmas. The overgrowth rims as well as discrete neoformed grains are interpreted as dating subsequent metamorphism and yield 207Pb/206Pb ages between 2533 Ma to 2490 Ma. Zircons in the metagabbro preserve upper intercept ages of 2556 ± 20 Ma representing the crystallization age of this rock. The younger ages of 2449 ± 58 Ma (upper intercept age) and 1845 ± 25 Ma (207Pb/206Pb spot age) are interpreted to represent subsequent multiple thermal events in this area. Zircons in the amphibolite preserve the 207Pb/206Pb mean age of 2539 ± 9 Ma, representing the crystallization age of this rock. The garnet-bearing biotite gneiss shows an upper intercept age of 2562 ± 10 Ma (MSWD = 0.66; N = 36) and the 207Pb/206Pb mean age of 2561 ± 9 Ma (MSWD = 0.63; N = 33) which is taken to represent the crystallization age of this rock. Some inherited zircons are also identified with 207Pb/206Pb ages of 2664 ± 26 Ma and 2628 ± 26 Ma. Zircon Lu–Hf data show dominantly positive εHf(t) values and combined with crustal residence ages, the results suggest Mesoarchean to Neoarchean juvenile crust formation in the NCC. We interpret the data presented here to represent a phase of major late Neoarchaean arc magmatism along the western margin of the Jiaoliao Block related to the birth of microcontinental nuclei within the NCC. Our data suggest that the Western and Eastern Blocks might not have existed as discrete crustal blocks, and that the construction of the NCC is a result of the assembly of several microblocks or terranes at the end of Archaean. Similar Archean cratonic nuclei in other regions of the world might have formed part of a primitive supercontinent in the early Earth.  相似文献   
54.
Despite widespread evidence for atmospheric dust deposition prior to the Quaternary, quantitative rate data remains sparse. As dust influences both climate and biological productivity, the absence of quantitative dust data limits the comprehensiveness of models of pre-Quaternary climate and biogeochemical cycles. Here, we propose that inorganic matter contained in coal primarily records atmospheric dust deposition. To test this, we use the average concentration of inorganic matter in Permian coal to map global patterns and deposition rates of atmospheric dust over Pangea. The dust accumulation rate is calculated assuming Permian peat carbon accumulation rates in temperate climates were similar to Holocene rates and accounting for the loss of carbon during coalification. Coal-derived rates vary from 0.02 to 25 g m 2 year 1, values that fall within the present-day global range. A well-constrained East–West pattern of dust deposition corresponding to expected palaeoclimate gradients extends across Gondwana with maximum dust deposition rates occurring close to arid regions. A similar pattern is partially defined over the northern hemisphere. Patterns are consistent with the presence of two large global dust plumes centred on the tropics. The spatial patterns of dust deposition were also compared to dust cycle simulations for the Permian made with the Community Climate System Model version 3 (CCSM3). Key differences between the simulations and the coal data are the lack of evidence for an Antarctic dust source, higher than expected dust deposition over N and S China and greater dust deposition rates over Western Gondwana. This new coal-based dust accumulation rate data expands the pre-Neogene quantitative record of atmospheric dust and can help to inform and validate models of global circulation and biogeochemical cycles over the past 350 Myr.  相似文献   
55.
The Rhyacian (2300–2050 Ma) is a special era of the Paleoproterozoic represented by large layered intrusions in many cratons. It is well known that there are widespread igneous events at ~ 2100 Ma in the Eastern North China Craton; however, their tectonic environments are under debate: whether they were related to an intra-continental rifting or an arc/back-arc setting along a continental margin. These ~ 2100 Ma igneous events comprise several mafic dykes/sills, with some coeval A-type granites and volcanic events in several rifts; among them, the Haicheng mafic sills in the Liaohe rift are unique as their host rock, the Liaohe Group, bears the world's largest magnesium deposit. Most of the mafic sills are E-W-elongated at present coordinates. Exclusive of superimposition caused by deformation, the widths of the individuals are tens to hundreds of meters and the lengths are hundreds to thousands of meters. They have metamorphosed to an assemblage of plagioclase and hornblende, with minor quartz and accessory chlorite, epidote, apatite, ilmenite, and magnetite. However, relic gabbro and ophitic textures with mainly plagioclase and clinopyroxene are well-preserved. SIMS Pb–Pb dating on baddeleyites from one ~ 1000 m thick sill near Xialiulinzi village yields an average 207Pb/206Pb age of 2115 ± 3 Ma (n = 15, MSWD = 2.3), representing the timing of crystallization. SIMS U–Pb dating on zircon yields a similar forming age. They are tholeiitic in composition (MgO: 4.36–8.88 wt.%; SiO2: 45.76–53.39 wt.%), enriched in light rare earth elements ((La/Yb)N = 1.72–4.37) and large ion lithophile elements (i.e., Cs, Rb, Sr, and K) but depleted in high field strength elements (i.e., Nb, Ta, and Ti). These features were unlikely caused by crustal contamination during their emplacement, as there are little variations in Nb/La and Th/Nb. The rocks have experienced significant plagioclase-plus clinopyroxene-dominating fractional crystallization. Their enriched Sr–Nd isotope characteristics (87Sr/86Srt = 0.703 ~ 0.705, εNdt =  1.9 ~ 0.6) and trace element patterns indicate that their source(s) could be the ancient subcontinental lithospheric mantle; and this source is similar to those coeval sills from other parts of the craton. Their arc-like trace element features could be inherited from their source regions formed via a subduction process at the late Archean rather than at the middle-late Paleoproterozoic. These sill swarms, throughout the craton, might have developed in an integrated intra-continental rift system at ~ 2100 Ma.  相似文献   
56.
In this contribution I presents definitions of mineral systems, followed by a proposed classification of mineral deposits. The concept of mineral systems has been tackled by various authors within the framework of genetic models with the aim of improving the targeting of new deposits in green field areas. A mineral system has to be considered taking into account, by and large, space-time patterns or trends of mineralisation at the regional scale, their tectonic controls and related metallogenic belts. This leads to a suggested classification of mineral systems, together with a summary of previous ideas on what is, without doubt, a kind of “mine field”, because if a classification is based on genetic processes, these can be extremely complex due to the fact that ore genesis usually involves a number of interactive processes. The classification presented is based on magmatic, magmatic-hydrothermal, sedimentary-hydrothermal, non-magmatic, and mechanical-residual processes.An overview of plate tectonics (convergent and divergent margins) is discussed next. Convergent plate margins are characterised by a tectonic plate subducting beneath a lower density plate. Convergent plate margins have landward of a deep trench, a subduction–accretion complex, a magmatic arc and a foreland thrust belt. An important feature is the subduction angle: a steep angle of descent, is exemplified by the Mariana, or Tonga–Kermadec subduction systems, conducive to porphyry-high-sulphidation epithermal systems, whereas in an intra-arc rift systems with spreading centres is conducive to the generation of massive sulphide deposits of kuroko affinity. A shallower subduction zone is the domain of large porphyry Cu–Mo and epithermal deposits. The implications of this difference in terms of metallogenesis are extremely important. Continent–continent, arc–continent, arc–arc, amalgamation of drifting microcontinents, and oceanic collision events are considered to be a major factor in uplift, the inception of fold-and-thrust belts and high P metamorphism. Examples are the Alpine–Himalayan orogenic belt formed by the closure of the Tethys oceanic basins and the great Central Asian Orogenic Belt (CAOB), a giant accretionary collage of island arcs and continental fragments. The closing of oceanic basins, and the accretion of allochthonous terranes, result in the emplacement of ophiolites by the obduction process. Divergent plates include mid-ocean ridges, passive margins and various forms of continental rifting. At mid-ocean spreading centres, magma chambers are just below the spreading centre. Once the oceanic crust moves away from the ridge it is either consumed in a subduction zone, or it may be accreted to continental margins, or island arcs. Spreading centres also form in back arc marginal basins. Transform settings include transtensional with a component of tension due to oblique divergence, transform or strike–slip sensu stricto and transpressive with a component of compression due to oblique convergence. Strike–slip faults that form during extensional processes lead to the formation of pull-apart basins.Mineral systems that form at convergent margins, the topic of this special issue, are succinctly introduced in Table 1, Table 2, Table 3, Table 4, Table 5, Table 6, Table 7, as follows: principal geological features of selected mineral systems at convergent plate margins and back-arcs (Table 1); their recognition criteria (Table 2); principal geological features of selected ore deposits of back-arc basins and post-subduction rifting (Table 3) and of subduction-related magmatic arcs (Table 4), their respective recognition criteria (Table 5); accretionary and collisional tectonics and associated mineral systems (Table 6); principal geological features and associated mineral systems of transform faults (Table 7).  相似文献   
57.
The Koru and Tesbihdere mining districts in Biga Peninsula, Northwestern Turkey, consist of twelve deposits covering approximately 12 km2. The epithermal Au-Ag enriched base metal veins and associated low-grade breccia and stockwork at Koru and Tesbihdere are hosted by Oligocene subaerial and calc-alkaline volcanic rocks including basaltic andesite lavas, dacitic lava-tuffs, rhyolitic lava-domes and tuffs. NW- to N-trending strike-slip faults and E- and NE-trending faults constitute the most important ore-controlling structures in the Koru and Tesbihdere districts respectively. In the Koru mining district, galena is the dominant ore mineral in barite-quartz veins containing sphalerite, chalcopyrite, pyrite, bornite, enargite and tennantite. According to base metal content, the Tesbihdere mining district can be subdivided into sphalerite-galena dominated Tesbihdere mineralization and chalcopyrite-pyrite dominated Bakır and Kuyu Zones mineralization. Gold is present in small quantities with maximum 3.14 g/t Au values either as free grains in quartz or as micro inclusions in pyrite and galena. The most widespread silver minerals are polybasite, pearceite, argentite and native silver which commonly occur as replacements of galena, sphalerite and pyrite, and other sulfides, or as fillings of microfractures in sulfides and quartz.Microthermometric measurements of primary liquid-rich fluid inclusions in sphalerite, barite and quartz in Koru indicate that the veins were formed at temperatures between 407 and 146 °C from fluids with salinities between 0.7 and 12.5 wt.% equiv. NaCl. Barite from the Tahtalıkuyu, Kuyutaşı and 5th Viraj mineralization show the highest homogenization temperatures. Fluid inclusion data for ore-stage quartz and sphalerite from the Tesbihdere mining district, indicate that these minerals were deposited at temperatures between 387 and 232 °C from more diluted fluids with moderate salinities between 0.2 and 10.6 wt.% NaCl equiv. Tahtalıkuyu and 5th Viraj mineralization show only boiling trends while Kuyutaşı, Tesbihdere, Bakır and Kuyu Zones mineralization show both boiling and isothermal mixing trends. The O and H isotope compositions of ore fluids from the Tahtalıkuyu (δ18O =  1.40 to 0.25‰; δD =  72.49 to − 52.68‰) and Kuyutaşı (δ18O =  2.29 to 3.59‰; δD =  90.70 to − 70.93‰) mineralization indicate that there was a major contribution from a magmatic component to ore genesis. Based on 9 quartz samples associated with orebodies at the Tesbihdere mining district, the relatively higher δ18O and lower δD isotope compositions from hydrothermal fluids could be attributed to a relatively dilute fluid derived by the mixing with meteoric water. The Pb isotope compositions also reveal that most of the lead in both mining districts is derived from the Oligocene-Miocene magmatic rocks, possibly with smaller contributions from the Eocene magmatic rocks.  相似文献   
58.
Earth’s lithosphere is heterogeneous in rheology on a wide range of observation scales. When subjected to a tectonic deformation, the incurred flow field can vary significantly from one rheologically distinct element to another and the flow field in an individual element is generally different from the bulk averaged flow field. Kinematic and mechanical models for high-strain zones provide the relations between prescribed tectonic boundary conditions and the resulting bulk flow field. They do not determine how structures and fabrics observed on local and small scales form. To bridge the scale gap between the bulk flow field and minor structures, Eshelby’s formalism extended for general power-law viscous materials is shown to be a powerful means. This paper first gives a complete presentation of Eshelby’s formalism, from the classic elastic inclusion problem, to Newtonian viscous materials, and to the most general case of a power-law viscous inhomogeneity embedded in a general power-law viscous medium. The formulation is then implemented numerically. The implications and potential applications of the approach are discussed. It is concluded that the general Eshelby formalism together with the self-consistent method is a powerful and physically sound means to tackle large plastic deformation of Earth’s lithosphere.  相似文献   
59.
The Zhibula Cu skarn deposit contains 0.32 Mt. Cu metal with an average grade of 1.64% and is located in the Gangdese porphyry copper belt in southern Tibet. The deposit is a typical metasomatic skarn that is related to the interaction of magmatic–hydrothermal fluids and calcareous host rock. Stratiform skarn orebodies occur at the contact between tuff and marble in the Lower Jurassic Yeba Formation. Alteration zones generally grade from a fresh tuff to a garnet-bearing tuff, a garnet pyroxene skarn, and finally to a wollastonite marble. Minor endoskarn alteration zonations are also observed in the causative intrusion, which grade from a fresh granodiorite to a weakly chlorite-altered granodiorite, a green diopside-bearing granodiorite, and to a dark red-brown garnet-bearing granodiorite. Prograde minerals, which were identified by electron probe microanalysis include andradite–grossularite of various colors (e.g., red, green, and yellow) and green diopside. Retrograde metamorphic minerals overprint the prograde skarn, and are mainly composed of epidote, quartz, and chlorite. The ore minerals consist of chalcopyrite and bornite, followed by magnetite, molybdenite, pyrite, pyrrhotite, galena, and sphalerite. Three types of fluid inclusions are recognized in the Zhibula deposit, including liquid-rich two-phase inclusions (type L), vapor-rich two-phase inclusions (type V), and daughter mineral-bearing three-phase inclusions (type S). As the skarn formation evolved from prograde (stage I) to early retrograde (stage II) and later retrograde (stage III), the ore-forming fluids correspondingly evolved from high temperature (405–667 °C), high salinity (up to 44.0 wt.% NaCl equiv.), and high pressure (500–600 bar) to low-moderate temperature (194–420 °C), moderate-high salinity (10.1–18.3 and 30.0–44.2 wt.% NaCl equiv.), and low-moderate pressure (250–350 bar). Isotopic data of δ34S (− 0.1‰ to − 6.8‰, estimated δ34Sfluids =  0.7‰), δDH2O (− 91‰ to − 159‰), and δ18OH2O (1.5‰ to 9.2‰) suggest that the ore-forming fluid and material came from magmatic–hydrothermal fluids that were associated with Miocene Zhibula intrusions. Fluid immiscibility likely occurred at the stage I and stage II during the formation of the skarn and mineralization. Fluid boiling occurred during the stage III, which is the most important Cu deposition mechanism for the Zhibula deposit.  相似文献   
60.
The Campiglia Marittima Fe-Cu-Zn-Pb(-Ag) skarn deposit has long been regarded as a reference example of an exoskarn showing a symmetric outward mineralogical zoning of both skarn and ore minerals with respect to an axial mafic porphyry dike. Detailed field and underground mapping, along with three-dimensional reconstruction of the geometries of skarn and magmatic bodies, integrated with new petrographic, mineralogical and geochemical data, argue against this model. The shapes of the skarn bodies and the growth versors of skarn minerals in particular, are ascribed to the focusing of metasomatic fluids in sigmoid-shaped volumes of fractured host marble. After skarn formation, a mafic magma was emplaced, forming dikelets and filling residual pockets in the skarn. Field evidence and geochemical data show that the “hot” mafic magma interacted with the previously formed Zn-Pb(-Ag) skarn, triggering textural reworking and chemical redistribution of Zn-Pb sulfides as well as contributing to a late Fe-Cu mineralization. Campiglia Marittima skarn-ore system behaved at odd: a telescoping process is recorded, yet in a reverse way.  相似文献   
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