The influence of pH on Mg/Ca ratios is negligible at ambient seawater pH (8.1 to 8.3). However, we observe a dominating pH control on shell Mg/Ca when the pH of seawater is lower than 8.0. Sr/Ca in G. ruber shows a significant positive correlation with average growth rate. Presumably, part of the variability in shell Sr/Ca in the geological record is linked to changes in growth rates of foraminifera as a response to changing environmental conditions.  相似文献   
92.
Improving age-depth models of fluvio-lacustrine deposits using sedimentary proxies for accumulation rates     
《Quaternary Geochronology》2016
Lacustrine fills, including those of oxbow lakes in river floodplains, often hold valuable sedimentary and biological proxy records of palaeo-environmental change. Precise dating of accumulated sediments at levels throughout these records is crucial for interpretation and correlation of (proxy) data existing within the fills. Typically, dates are gathered from multiple sampled levels and their results are combined in age-depth models to estimate the ages of events identified between the datings. In this paper, a method of age-depth modelling is presented that varies the vertical accumulation rate of the lake fill based on continuous sedimentary data. In between Bayesian calibrated radiocarbon dates, this produces a modified non-linear age-depth relation based on sedimentology rather than linear or spline interpolation.The method is showcased on a core of an infilled palaeomeander at the floodplain edge of the river Rhine near Rheinberg (Germany). The sequence spans from ∼4.7 to 2.9 ka cal BP and consists of 5.5 m of laminated lacustrine, organo-clastic mud, covered by ∼1 m of peaty clay. Four radiocarbon dates provide direct dating control, mapping and dating in the wider surroundings provide additional control. The laminated, organo-clastic facies of the oxbow fill contains a record of nearby fluvial-geomorphological activity, including meander reconfiguration events and passage of rare large floods, recognized as fluctuations in coarseness and amount of allochthonous clastic sediment input. Continuous along-core sampling and measurement of loss-on-ignition (LOI) provided a fast way of expressing the variation in clastic sedimentation influx from the nearby river versus autochthonous organic deposition derived from biogenic production in the lake itself. This low-cost sedimentary proxy data feeds into the age-depth modelling. The sedimentology-modelled age-depth relation (re)produces the distinct lithological boundaries in the fill as marked changes in sedimentation rate. Especially the organo-clastic muddy facies subdivides in centennial intervals of relative faster and slower accumulation. For such intervals, sedimentation rates are produced that deviate 10–20% from that in simpler stepped linear age-models. For irregularly laminated muddy intervals of the oxbow fill – from which meaningful sampling for radiocarbon dating is more difficult than from peaty or slowly accumulating organic lake sediments – supplementing spotty radiocarbon sampling with continuous sedimentary proxy data creates more realistic age-depth modelling results.  相似文献   
93.
First results of convectively generated long-period Kelvin waves in the low-latitude mesosphere during Indian summer monsoon     
G.J. Bhagavathiammal  S. Sathishkumar  S. Sridharan  Manohar Lal  S. Gurubaran  K.U. Nair 《Journal of Atmospheric and Solar》2010,72(16):1204-1211
Spectral analysis of Tirunelveli (8.7°N, 77.8°E) MF radar winds for the year 2007 indicate the presence of long-period Kelvin waves with periods ~23 and ~16 days in the low-latitude mesosphere during Indian summer monsoon months. The dominant presence of these slow-phase speed waves at mesospheric altitudes motivated us to investigate their origin and vertical propagation characteristics. Space-time Fourier analysis of NCEP winds and OLR show the presence of these periodicities with zonal wavenumber 1 indicating that tropical convection is the potential source for these waves and westward phase of stratospheric QBO winds might have favoured these waves to reach the mesosphere.  相似文献   
94.
The spatial and temporal variability of sand erosion across a stabilizing coastal dune field   总被引:1,自引:1,他引:1  
NOAM LEVIN  GIORA J. KIDRON†  EYAL BEN-DOR 《Sedimentology》2006,53(4):697-715
This study aimed at quantifying the temporal and spatial variability in sand erosion and deposition over a coastal dune field in Israel. These were measured monthly over 2 years using 315 erosion pins over four transects that were placed perpendicular to the coastline. Vegetation cover was estimated based on aerial photographs and Landsat satellite images, whereas the relative height was based on a digital elevation model. These variables were calculated for the area upwind (south west) of the erosion pins, at various lengths, ranging from 15 to 400 m. Nine geomorphologic units were defined, five related to active units, and four to stabilized units. In active units at least 65% of the temporal variance in the annual absolute changes in sand level was explained by the index of Resultant Drift Potential, with most of the sand movement occurring during winter storms. Local rainfall had no apparent impact on sand mobility, due to the low coincidence of sand carrying winds and rainfall in Israel during the passage of frontal cyclones. As for the spatial variables, only a weak correlation was found between sand mobility with the distance from the coastline (R2 = 18%). Rather, sand erosion and deposition were influenced by vegetation cover and the relative height of an area of 100–200 m upwind. The values of Soil Adjusted Vegetation Index were significantly negatively correlated with annual absolute changes (R2 = 40%), whereas the relative height was significantly positively correlated (R2 = 36%). Applying a multiple regression model, 68% of the spatial variability in sand mobility was explained. The resulting map of sand activity clearly shows that at this stage of the stabilization process, most of the dunes are now disconnected, and movement of sand grains from the beach or between the dunes, is very limited. These methods can be applied into spatial and temporal models of sand mobility, thus assessing the impact of different management practices on coastal dunes.  相似文献   
95.
Evidence for a ∼ 200–100 ka meteorite impact in the Western Desert of Egypt     
《Earth and Planetary Science Letters》2007,253(3-4):378-388
In this study, we present evidence, in the form of unusual silicate glasses, for a meteorite impact event ∼ 200–100 ka in the Dakhleh Oasis, Western Desert, Egypt. These glasses, known locally as Dakhleh Glass, were derived from the shock melting of a series of unconsolidated sediments underlain by interbedded carbonates, sandstones and phosphate-rich lithologies. Hypervelocity impact in to a volatile-rich target resulted in the production of impact glasses with CaO and Al2O3 contents of up to ∼ 25 and 18 wt.%, respectively. Other notable properties include the presence of globules of immiscible calcite and pyrrhotite melt phases, shattered quartz grains, and fragments of silicified plant matter. Dating of geoarchaeological artefacts associated with the Dakhleh Glass support preliminary 40Ar/39Ar data, indicating a ∼ 200–100 ka age for the impact event. Geoarchaeological evidence indicates that archaic Homo sapiens and early modern humans continually inhabited this region of the Western Desert during this period. While it is unclear at present whether the Dakhleh Glass was formed during a cratering event or a large aerial burst, the effect on the environment and inhabitants of Dakhleh would have been catastrophic.  相似文献   
96.
The sedimentary and geochemical record of Neogene-Quaternary water bodies in the Dead Sea Basin - inferences for the regional paleoclimatic history     
Mordechai Stein 《Journal of Paleolimnology》2001,26(3):271-282
Several waterbodies occupied the tectonic depressions along the Dead Sea transform during the NeogeneQuaternary. The earliest of these water bodies was the marine Sedom lagoon, which produced the SedomDead Sea brine. After the disconnection of the Sedom lagoon from the open sea several lakes were developed in the Dead Sea basinJordan Valley. Lake Amora (Samra) that existed from early to late Pleistocene, Lake Lisan (~ 70–15 kyr B.P.), and the Holocene Dead Sea. The lacustrine water bodies in the Dead Sea basin behave as amplifier lakes whose size and depth reflect the changing climatic conditions in the region. Lake level and limnological conditions of Lake Amora are not yet known, nevertheless, the lake probably extended over a large part of the Dead Sea basin-Jordan Valley. Lake Lisan level changed between ~ 330 and ~ 150 meters below sea level (m b.s.l.). Its maximum elevation was reached at ~ 27–23 kyr B.P. during marine isotope stage 2. Its minimum elevation was reached at ~ 47–43 kyr during marine isotope stage 3. Lake Lisan began to recede at ~ 17–15 kyr B.P. and at 12–11 kyr B.P. the postLisan water body declined to its minimum level. During most of the Holocene the lake (paleoDead Sea) stabilized at ~ 400 m b.s.l.The limnological evolution of water bodies in the Dead Sea basin reflects the climatic conditions in the region during the late Pleistocene, which fluctuated between wetter and drier periods. During Lisan time these fluctuations appear to be modulated by the cold and warm cycles, respectively in the northern Hemisphere. This relation is less obvious in the postLisan water body, where the strongest lake drop appears to occur during the Younger Dryas cold event.  相似文献   
97.
Holocene climate variability and cultural evolution in the Near East from the Dead Sea sedimentary record   总被引:4,自引:2,他引:2  
Claudia Migowski  Mordechai Stein  Sushma Prasad  Jrg F.W. Negendank  Amotz Agnon 《Quaternary Research》2006,66(3):421-431
A comprehensive record of lake level changes in the Dead Sea has been reconstructed using multiple, well dated sediment cores recovered from the Dead Sea shore. Interpreting the lake level changes as monitors of precipitation in the Dead Sea drainage area and the regional eastern Mediterranean palaeoclimate, we document the presence of two major wet phases ( 10–8.6 and  5.6–3.5 cal kyr BP) and multiple abrupt arid events during the Holocene. The arid events in the Holocene Dead Sea appear to coincide with major breaks in the Near East cultural evolution (at  8.6, 8.2, 4.2, 3.5 cal kyr BP). Wetter periods are marked by the enlargement of smaller settlements and growth of farming communities in desert regions, suggesting a parallelism between climate and Near East cultural development.  相似文献   
98.
The salinity of hypersaline brines: Concepts and misconceptions     
David A. Anati 《International Journal of Salt Lake Research》1999,8(1):55-70
Some widespread misconceptions about salinity are pointed out, explained and commented on. Definitions, units, and methods of salinity determination recommended for brines of moderate salinities may become unsuitable for highly saline brines. Various salinity units are examined and commented on, and density at a precisely monitored temperature is chosen as the preferable “substitute parameter” for salinity determination of hypersaline brines. It is shown that ambient air density during pycnometric measurements must be known as accurately as required of the brine's density, and that its value must be added to the direct pycnometric measurement. Variations of atmospheric pressure at the time of pycnometry must be taken into account if greater than 15 mB. For a salinity accuracy of ±0.02 per mille, as required for some physical and chemical studies, the temperature of the sample during salinity measurement must be monitored with an accuracy of at least 0.04°C. A definite curve in the ρ-S plane, corresponding to the conversion of salinity to density at a fixed temperature, andvice-versa, does not exist if the brine is saturated in one of its salts. Non-linearity in the equation of state is shown to affect the surface level drop due to evaporation; the effect is negligible at low salinities, but a 10 per cent correction is already required at the salinity found in the northern Red Sea (41 per mille). Reliable reference points for the conversion of absolute salinity to density of highly saline brines are not known, at present, as accurately as desirable; pending the accurate determination of such reference points, a substantial dilution of hypersaline brines (for the purpose of adapting them to conductivity measurements) would multiply the error range by more than a hundred fold. On the other hand, a minute dilution of hypersaline brine samples to prevent salt crystal formation is possible and would not bring about any major increase of the error range in their density (salinity) determination.  相似文献   
99.
Modes of sapropel formation in the eastern Mediterranean: some constraints based on pyrite properties     
《Marine Geology》1999,153(1-4):199-219
Pyrite formation within and directly below sapropels in the eastern Mediterranean was governed by the relative rates of sulphide production and Fe liberation and supply to the organic-rich layers. At times of relatively high SO2−4 reduction, sulphide could diffuse downward from the sapropel and formed pyrite in underlying sediments. The sources of Fe for pyrite formation comprised detrital Fe and diagenetically liberated Fe(II) from sapropel-underlying sediments. In organic-rich sapropels, input of Fe from the water column via Fe sulphide formation in the water may have been important as well. Rapid pyrite formation at high saturation levels resulted in the formation of framboidal pyrite within the sapropels, whereas below the sapropels slow euhedral pyrite formation at low saturation levels occurred. δ34S values of pyrite are −33‰ to −50‰. Below the sapropels δ34S is lower than within the sapropels, as a result of increased sulphide re-oxidation at times of relatively high sulphide production and concentration when sulphide could escape from the sediment. The percentage of initially formed sulphide that was re-oxidized was estimated from organic carbon fluxes and burial efficiencies in the sediment. It ranges from 34% to 80%, varying significantly between sapropels. Increased palaeoproductivity as well as enhanced preservation contributed to magnified accumulation of organic matter in sapropels.  相似文献   
100.
Carbon and oxygen isotope study of the active water-carbonate system in a karstic Mediterranean cave: Implications for paleoclimate research in semiarid regions     
《Geochimica et cosmochimica acta》1996,60(2):337-347
In a semiarid climatic zone, such as the Eastern Mediterranean region, annual rainfall variations and fractionation processes in the epikarst zone exert a profound influence on the isotopic compositions of waters seeping into a cave. Consequently, the isotopic compositions of speleothems depositing from cave waters may show complex variations that need to be understood if they are to be exploited for paleoclimate studies. This is confirmed by a four-year study of the active carbonate-water system in the Soreq cave (Israel). The δ18O (SMOW) values of cave waters range from −6.3 to −3.5%.. The highest δ18O values occur at the end of the dry season in waters dripping from stalactites, and reflect evaporation processes in the epikarst zone, whereas the lowest values occur in rapidly dripping (fast-drip) waters at the peak of the rainy seasons. However, even fast-drip waters are about 1.5%. heavier than the rainfall above the cave, which is taken to reflect the mixing of fresh with residual evaporated water in the epikarst zone. δ13C (PDB) values of dissolved inorganic carbon (DIC) vary from −15.6 to −5.4%., with fast-drip waters having lower δ13C values (mostly −15.6 to −12%.) and higher DIC concentrations relative to pool and stalactite-drip water. The low δ13C values of fast-drip waters and their supersaturation with respect to calcium carbonate indicates that the seepage waters have dissolved both soil-CO2 derived from overlying C3-type vegetation and marine dolomite host rock.The δ18O (PDB) values of various types of present-day low-magnesium calcite (LMC) speleothems range from −6.5 to −4.3%. and δ13C values from −13 to −5.5%. and are not correlated with speleothem type. An analysis of δ18O values of present-day calcite rafts and pool waters shows that they form in oxygen isotope equilibrium. Similarly, the measured ranges of δ13C and δ18O values for all types of present-day speleothems are consistent with equilibrium deposition at cave temperatures. The δ13C–δ18O range of contemporary LMC thus reflects the variations in temperatures and isotopic compositions of the presentday cave waters. The 10%. variation in the δ13C values in waters can be modeled by a simple Rayleigh calculation of the carbon isotope fractionation accompanying CO2-degassing and carbonate precipitation. These variations may obscure the differences in the carbon isotopic composition of speleothems that could arise when vegetation cover changes from C3 to C4-type plants. This consideration emphasizes that it is necessary to characterize the full range of δ13C values associated with contemporaneous speleothems in order to clarify the effects of degassing from those due to differing vegetation types.Isotopic studies of a number of different types of fossil LMC speleothems show many of them to exhibit isotopic trends that are similar to those of present-day LMC, but others show both higher and lower δ18O ranges. In particular, the higher δ18O range has been shown by independent age-measurements to be associated with a period of drier conditions. The results of the study thus indicate that it is necessary to work on a well calibrated cave system in semiarid climates and that the fossil speleothem record should be obtained from different types of contemporaneous deposit in order to fully characterize the δ18O–δ13C range representative of any given climatic period.  相似文献   
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91.
Mg/Ca and Sr/Ca ratios were determined on a single species of planktonic foraminiferan, Globigerinoides ruber (white), collected from the Gulf of Eilat and cultured in seawater at five different salinities (32 to 44), five temperatures (18 to 30 °C) and four pH values (7.9 to 8.4). The Mg/Ca-temperature calibration of cultured G. ruber (with an exponential slope of 8 ± 3%/°C) agrees well with previously published calibrations from core-tops and sediment traps. However, the dependence of Mg/Ca on salinity (with an exponential slope of 5 ± 3%/psu) is also significant and should be included in the calibration equation. With this purpose, we calculated a calibration equation for G. ruber dependent on both temperature and salinity within the 95% confidence limits:
Mg/Ca(mmol/mol)=exp[0.06(±0.02)*S(psu)+0.08(±0.02)*T(°C)−2.8(±1.0)],R2=0.95
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