A new low-interference characterization method for hydrocarbons occluded inside asphaltene structures     

《Applied Geochemistry》2006,21(5):833-838

Some hydrocarbons occluded inside asphaltene structures can be considered to be “original oil”, and are very important especially for severely post-altered crude oil in related geochemical studies such as oil/oil, oil/source correlation. The use of oxidising reagents could properly release these occluded hydrocarbons, and make possible direct study of these compounds without interference from the segments chemically bonded to the asphaltene molecule. Interference from adsorbed and/or co-precipitated compounds can be avoided by applying an asphaltene purification procedure.  相似文献   

Production of carbonate and silica nano-particles in stirred bead milling     

Yanmin Wang  Eric Forssberg 《International Journal of Mineral Processing》2006

This paper presents the experimental results of the mechanical production of silica and carbonate colloidal particles below 100 nm using two types of stirred bead mills (i.e., DCP Superflow 12 and PML H/V). It is shown that the stirred bead mill with very small beads can be used as an efficient equipment for the production of the colloidal particles in nanoscale from the feed materials of several microns in sizes at high energy consumptions. The DCP Superflow mill with high power densities is superior for the effective size reduction and production rate, compared to the conventional PML H/V mill with lower power densities. The smaller particles could be produced by the DCP Superflow mill at the same level of high energy inputs as from the PML H/V mill. The “grinding limit” for the processes in the mills has been discussed.  相似文献   

Petrogenesis of Cretaceous adakitic and shoshonitic igneous rocks in the Luzong area, Anhui Province (eastern China): Implications for geodynamics and Cu–Au mineralization     

Qiang Wang  Derek A. Wyman  Ji-Feng Xu  Zhen-Hua Zhao  Ping Jian  Xiao-Lin Xiong  Zhi-Wei Bao  Chao-Feng Li  Zheng-Hua Bai 《Lithos》2006,89(3-4):424-446

Both adakitic and shoshonitic igneous rocks in the Luzong area, Anhui Province, eastern China are associated with Cretaceous Cu–Au mineralization. The Shaxi quartz diorite porphyrites exhibit adakite-like geochemical features, such as light rare earth element (LREE) enrichment, heavy REE (HREE) depletion, high Al₂O₃, MgO, Sr, Sr / Y and La / Yb values, and low Y and Yb contents. They have low ε_Nd(t) values (− 3.46 to − 6.28) and high (⁸⁷Sr / ⁸⁶Sr)_i ratios (0.7051–0.7057). Sensitive High-Resolution Ion Microprobe (SHRIMP) zircon analyses indicate a crystallization age of 136 ± 3 Ma for the adakitic rocks. Most volcanic rocks and the majority of monzonites and syenites in the Luzong area are K-rich (or shoshonitic) and were also produced during the Cretaceous (140–125 Ma). They are enriched in LREE and large-ion lithophile elements, and depleted in Ti, and Nb and Ba and exhibit relatively lower ε_Nd(t) values ranging from − 4.65 to − 7.03 and relatively higher (⁸⁷Sr / ⁸⁶Sr)_i ratios varying between 0.7057 and 0.7062. The shoshonitic and adakitic rocks in the Luzong area have similar Pb isotopic compositions (²⁰⁶Pb / ²⁰⁴Pb = 17.90–18.83, ²⁰⁷Pb / ²⁰⁴Pb = 15.45–15.62 and ²⁰⁸Pb / ²⁰⁴Pb = 38.07–38.80). Geological data from the Luzong area suggest that the Cretaceous igneous rocks are distributed along NE fault zones (e.g., Tanlu and Yangtze River fault zones) in eastern China and were likely formed in an extensional setting within the Yangtze Block. The Shaxi adakitic rocks were probably derived by the partial melting of delaminated lower crust at pressures equivalent to crustal thickness of > 50 km (i.e., 1.5 GPa), possibly leaving rutile-bearing eclogitic residue. The shoshonitic magmas, in contrast, originated mainly from an enriched mantle metasomatized by subducted oceanic sediments. They underwent early high-pressure (> 1.5 GPa) fractional crystallization at the boundary between thickened (> 50 km) lower crust and lithospheric mantle and late low-pressure (< 1.5 GPa) fractional crystallization in the shallow (< 50 km) crust. The adakitic and shoshonitic rocks appear to be linked to an intra-continental extensional setting where partial melting of enriched mantle and delaminated lower crust was probably controlled by lithospheric thinning and upwelling of hot asthenosphere along NE fault zones (e.g., Tanlu and Yangtze River fault zones) in eastern China. Both the shoshonitic and adakitic magmas were fertile with respect to Cu–Au mineralization.  相似文献   

Dissolved trace elements in river water: spatial distribution and the influencing factor, a study for the Pearl River Delta Economic Zone, China   总被引：1，自引：0，他引：1  

T. P. Ouyang  Z. Y. Zhu  Y. Q. Kuang  N. S. Huang  J. J. Tan  G. Z. Guo  L. S. Gu  B. Sun 《Environmental Geology》2006,49(5):733-742

Twenty-nine water samples were collected from different river channels of the Pearl River Delta Economic Zone, China. An inductively coupled plasma-mass spectromonitor (ICP-MS) was used to measure concentrations of the trace elements in these samples. The results suggest that the average concentrations of rare earth elements in river water show an increasing trend from the West River, the North River, the rivers of the Pearl River Delta, and the Shenzhen River to the East River. Relatively high concentrations of heavy metals appear in the East River, the rivers of the Pearl River Delta and the Shenzhen River, while the West River and the North River have relatively low heavy metal concentrations. Trace element concentrations in samples collected near urban or industrial areas are much higher than those of samples collected from distant areas, away from urban and industrial areas. After natural conditions, human activities have significant influence on the trace element concentrations in river water. This trace element concentration’s spatial distribution in the river water from the Pearl River Delta Economic Zone is actually an integrated effect of natural conditions and human activity.  相似文献   

库车坳陷侏罗系煤成气动力学模拟研究   总被引：1，自引：0，他引：1  

周强  李贤庆  杨园园  田辉  申家贵 《中国煤田地质》2006,18(1):24-27

应用黄金管—高压釜封闭体系热模拟实验与GC、GC-IRMS分析技术,结合KINETICS专用软件,对库车坳陷侏罗系煤成气进行了动力学模拟研究。库车坳陷侏罗系煤具有高的产气性,在高演化阶段主要产甲烷气;侏罗系煤热解气甲烷碳同位素为-36‰～-25‰,乙烷碳同位素为-28‰～-16‰;甲烷、C2-C5气态烃的生成活化能分别为(47～64k)calm/ol、(55～72k)calm/ol,频率因子各为5.265×1013s-1、5.388×1018s-1。在此基础上,进一步探讨了克拉2气田天然气的成因。研究认为,克拉2气田天然气属阶段捕获的煤成气,主要聚集了5～1Ma时期的天然气,其成熟度Ro分布范围为1.3%～2.5%。  相似文献   

Zircon LA-ICP-MS U-Pb age, Ce^4＋/Ce^3＋ ratios and the geochemical features of the Machangqing complex associated with copper deposit     

梁华英  喻亨祥  莫测辉  张玉泉  谢应雯 《中国地球化学学报》2006,25(3):223-229

1IntroductionQuite a number of porphyry copper deposits havebeen found in the Cenozoic alkali-intrusions along theJinshajiang-Ailaoshan-Red River fault zone,whichconstitute the Cenozoic ore belt in China.The Cenozo-ic alkali-intrusive rocks are similar in…  相似文献   

华北东南部中生代岩石圈地幔性质、组成、富集过程及其形成机理   总被引：30，自引：7，他引：30  

张宏福周新华  范蔚茗孙敏 郭锋英基丰  汤艳杰张瑾 牛利锋 《岩石学报》2005,21(4):1271-1280

本文通过对我国华北东南部中生代幔源岩浆活动的时空分布规律及其地球化学特征的系统总结来进一步厘定该地区中生代岩石圈地幔的性质和组成,并通过与华北内部如鲁中地区中生代岩石圈地幔的对比研究探讨华北东部岩石圈的时空演化规律、富集过程及其形成机理。幔源岩石的 Sr-Nd-Ph 同位素特征表明华北东部中生代岩石圈地幔存在明显的时空不均匀性,其中心部位如鲁中地区以弱富集地幔为主体;而东南部如鲁西南和胶东地区则为类似 EM2型地幔(~(87)Sr/~(86)Sr_i 可高达0.7114)。华北东南部中生代岩石圈地幔随时间的演化特征也很明显。这些幔源岩石的地球化学特征和玄武岩中地幔岩捕虏体(橄榄岩和辉石岩)和捕虏晶(橄榄石和辉石)的组成和结构特征皆证明华北东南部中生代岩石圈地幔曾受到过富硅熔体的强烈改造。橄榄岩-熔体的相互反应是该区岩石圈改造和组成转变的重要方式,从而造成古生代高镁橄榄岩转变为晚中生代低镁橄榄岩和辉石岩。进入岩石圈地幔的熔体具下/中地壳物质重熔的特征,从而导致该区晚中生代岩石圈地幔的快速富集。有关华北东部中生代岩石圈减薄和改造的时限、过程和机制等问题也进行较详细的讨论。  相似文献   

川西北松潘-甘孜地块大石包组玄武岩成因及其形成构造背景   总被引：9，自引：0，他引：9  

肖龙  许继峰 《岩石学报》2005,21(6):1539-1545

川西北松潘-甘孜地块内二叠世大石包组玄武岩富集大离子亲石元素和高场强元素，具有与洋岛玄武岩相似的地球化学性质，形成于大陆板内环境。通过与典型峨眉山玄武岩之地球化学组成的对比研究，认为大石包玄武岩与峨眉山玄武岩中的高钛类玄武岩性质相同，两者具有一个共同的成因，即都是峨眉山地幔柱活动的产物。由此推测峨眉山玄武岩不仅分布在扬子地块内部，向西还有一定的延伸，同时暗示了峨眉山地幔柱头部可能具有比现在所认识的更大的规模。  相似文献   

新疆鄯善康古尔塔格蛇绿岩及其大地构造意义   总被引：4，自引：1，他引：4  

李文铅  夏斌吴国干  王核王冉 《岩石学报》2005,21(6):1617-1632

康古尔塔格蛇绿岩的岩石组合为变质橄榄岩-堆晶橄榄岩-辉长岩-斜长花岗岩-辉绿岩-玄武岩。方辉橄榄岩（蛇纹岩）、蛇纹石化辉石岩、蚀变辉长岩与特罗多斯蛇绿岩中同类型岩石类似，岩石总体低钾。变质橄榄岩MgO／（MgO＋TFeO）为0．834～0．866，TiO，（wt％）为0．02％，为SSZ型蛇绿岩的变质橄榄岩。玄武岩的构造环境判别显示其形成于边缘海盆。放射虫硅质岩的Al2O3／（Al2O3＋Fe2O3）值平均为0．047，MnO／TiO2比值平均为0．93，Ce具负异常，Ce／Ce^＊=0．548，Lan／Cen=1．661．表明放射虫硅质岩的形成环境与洋中脊有密切关系。该蛇绿岩位于塔里木板块和哈萨克斯坦-准噶尔板块的艾比湖-康古尔塔格缝合线上，为一套无序产出的古生代北天山洋在该区的古洋壳残片。  相似文献   

卫星遥感探讨杭州湾跨湖桥古文化消失原因   总被引：2，自引：2，他引：2  

王永江  姜晓玮 《国土资源遥感》2005,16(1):66-69

 8000 a前产生于杭州湾南部的跨湖桥史前灿烂文化，在辉煌了1000多a后，却神秘地消失了。针对这种消失，考古界还没有发 现确凿的原因。本文从卫星遥感角度，分析跨湖桥所处的地理、地貌特征，提出了钱塘江天文大潮冲毁跨湖桥文化的假说，希望这种 观点能够对跨湖桥这个难以用常规考古方法解决的史前文化消失问题提供一种有益的研究方法和思路。  相似文献