Tracking fluid flow during deep crustal anatexis: metasomatism of peridotites (Naxos, Greece)     

Yaron Katzir  John W. Valley  Alan Matthews  Michael J. Spicuzza 《Contributions to Mineralogy and Petrology》2002,142(6):700-713

Horizons of ultramafic lenses were metamorphosed with host felsic gneisses at upper amphibolite facies conditions during the M2 event on the island of Naxos, Greece. The synkinematic peak M2 Ol-Opx-Hbl-Chl-Spl assemblage of the Main, migmatite-associated, Ultramafic Horizon (MUH) retains mantle-like chemical and oxygen isotope compositions and thus shows no evidence of infiltration of fluids from the host rocks. A bimodal distribution of temperatures, grouped at 700 and 1,200 °C, is given by oxygen isotope Opx-Ol thermometry in the MUH meta-peridotites and indicates partial oxygen exchange during M2 superposed over previous mantle fractionation. The Agia Ultramafic Horizon (AUH), a coarser-grained and unfoliated peridotite, occurs within sillimanite gneisses in northwest Naxos and contains talc-enstatite and olivine domains. Recrystallization of the AUH peridotite during post-peak M2 infiltration of silica-rich, high '¹⁸O fluids is indicated by lack of deformation, increased activity of silica required to stabilize the talc-enstatite assemblage, extremely high '¹⁸O values of Ol and Opx and (¹⁸O_(Opx-Ol) temperatures of 520-650 °C. The source for these fluids is inferred to be aplitic and pegmatitic dikes emanating from the migmatitic core of Naxos and intruding the AUH. At peak M2 temperatures and during anatexis of gneisses, volumes of fluid were small and fluid composition was locally buffered in the deeper part of the Naxos section. Crystallization of melts within the migmatitic core released siliceous fluids and initiated an episode of retrograde hydrous metamorphism in the overlying sequences, as observed in the AUH.  相似文献   

The behavior of lithium and its isotopes in oilfield brines: evidence from the Heletz-Kokhav field, Israel   总被引：2，自引：0，他引：2  

Lui-Heung ChanAbraham Starinsky  Amitai Katz 《Geochimica et cosmochimica acta》2002,66(4):615-623

Twenty-four brine samples from the Heletz-Kokhav oilfield, Israel, have been analyzed for chemical composition and Li isotope ratios. The chemical composition of the brines, together with geological evidence, suggests derivation from (Messinian) seawater by evaporation that proceeded well into the gypsum stability field but failed to reach the stage of halite crystallization. The present salinity of the samples (18-47 g Cl/L) was achieved by dilution of the original evaporitic brine by local fresh waters. Like brines from other sedimentary basins, the Li/Cl ratios in the Heletz-Kokhav samples show a prominent Li enrichment (five-fold to eight-fold) relative to modern seawater. The isotopic ratios of Li, expressed in the δ ⁶Li notation, vary from −26.3 to −17.9‰, all values being significantly higher than that of modern seawater (−32‰) irrespective of their corresponding Li concentration (1.0-2.3 mg/L). The isotopic composition of Li and the Li/Cl ratio in the oilfield brines were acquired in two stages: (a) The original evaporated seawater gained isotopically light Li during the diagenetic interaction between the interstitial Messinian brine and the basin sediments. A parent brine with an elevated Li/Cl ratio was formed. The brine was later diluted in the oilfields. (b) The δ ⁶Li values of the final brines were determined during epigenetic interaction with the Heletz-Kokhav aquifer rocks. At the same time, the Li/Cl ratio inherited from stage (a) remained largely unchanged. This work represents the first use of lithium isotopic composition to elucidate the origin and evolution of formation waters in sedimentary basins.  相似文献   

Delaunay Tessellation Field Estimator analysis of the PSCz local Universe: density field and cosmic flow     

Emilio Romano-Díaz  Rien van de Weygaert 《Monthly notices of the Royal Astronomical Society》2007,382(1):2-28

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Erratum to Yehoshua Kolodny, Mordechai Stein, and Malka Machlus (2005), “Sea-rain-lake relation in the Last Glacial East Mediterranean revealed by δO-δC in Lake Lisan aragonites,” Geochimica et Cosmochimica Acta69 4045-4060     

Yehoshua Kolodny 《Geochimica et cosmochimica acta》2007,71(15):3926-3927

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The triple isotopic composition of oxygen in leaf water     

A. Landais  E. Barkan  B. Luz 《Geochimica et cosmochimica acta》2006,70(16):4105-4115

The isotopic composition of atmospheric O₂ depends on the rates of oxygen cycling in photosynthesis, respiration, photochemical reactions in the stratosphere and on δ¹⁷O and δ¹⁸O of ocean and leaf water. While most of the factors affecting δ¹⁷O and δ¹⁸O of air O₂ have been studied extensively in recent years, δ¹⁷O of leaf water—the substrate for all terrestrial photosynthesis—remained unknown. In order to understand the isotopic composition of atmospheric O₂ at present and in fossil air in ice cores, we studied leaf water in field experiments in Israel and in a European survey. We measured the difference in δ¹⁷O and δ¹⁸O between stem and leaf water, which is the result of isotope enrichment during transpiration. We calculated the slopes of the lines linking the isotopic compositions of stem and leaf water. The obtained slopes in ln(δ¹⁷O + 1) vs. ln(δ¹⁸O + 1) plots are characterized by very high precision (∼0.001) despite of relatively large differences between duplicates in both δ¹⁷O and δ¹⁸O (0.02-0.05‰). This is so because the errors in δ¹⁸O and δ¹⁷O are mass-dependent. The slope of the leaf transpiration process varied between 0.5111 ± 0.0013 and 0.5204 ± 0.0005, which is considerably smaller than the slope linking liquid water and vapor at equilibrium (0.529). We further found that the slope of the transpiration process decreases with atmospheric relative humidity (h) as 0.522-0.008 × h, for h in the range 0.3-1. This slope is neither influenced by the plant species, nor by the environmental conditions where plants grow nor does it show strong variations along long leaves.  相似文献   

Tracing end-member fluid sources in sub-surface iron mineralization and dolomitization along a proximal fault to the dead sea transform     

Yigal Erel  Nora Listovsky  Shimon Ilani 《Geochimica et cosmochimica acta》2006,70(22):5552-5570

Shear faults in Upper Cretaceous limestones of the central Negev desert adjacent to the Dead Sea Transform (DST) feature extensive ferruginous mineralization and dolomitization. This has been related to topographically driven flow of metalliferous groundwaters through an underlying clastic (Nubian Sandstone) aquifer and rise of the fluids up the fault zones. The present study combines Pb and Sr isotope measurements with detailed sampling and petrography at the eastern end of the Paran fault (Menuha Ridge) in order to identify the types of groundwater and the sources of enriched elements in this regional-scale sedimentary mineralization. Ferroan and non-ferroan dolomitization along the Paran fault caused significant enrichment of several elements (Mg, Cu, Mn, Ni, V, Zn, Pb, and U) and ⁸⁷Sr/⁸⁶Sr values that are significantly higher than the Upper Cretaceous limestone country rock. The non-ferroan dolomite and the ferroan dolomite sampled at three sites along the Menuha Ridge have similar ⁸⁷Sr/⁸⁶Sr values 0.7076-0.7089, and 0.7077-0.7086, respectively. Additionally, there is a positive correlation between Mg-content of the dolomites and their ⁸⁷Sr/⁸⁶Sr values. The isotopic composition of Sr and Pb of dolomite corresponds to the mineralogical type identified in the mineralized rock (non-ferroan dolomite, simple-zoned ferroan dolomite, and complex-zoned ferroan dolomite). The ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁶Pb/²⁰⁴Pb ratios of Fe oxides and dolomites from the three sites plot on a straight line, where the simple-zoned ferroan dolomite values are at the non-radiogenic end of the line and the complex-zoned ferroan dolomites at the radiogenic end. Both ²⁰⁶Pb/²⁰⁴Pb and ²⁰⁷Pb/²⁰⁴Pb ratios in dolomites and to a lesser degree in Fe-oxides suggest that a mixing between two end-members controls the behavior of Pb in the mineralization products along the Paran fault. Rather than a single fluid source, the study indicates that two types of metalliferous groundwaters were involved in the dolomitization and mineralization along the Paran fault. The first, and hitherto undocumented, fluid source is the Mg-rich Dead Sea Rift brine, migrating in the sub-surface before dolomitizing the carbonate bedrock. Migration of the brines took a deep path to the site of mineralization, with temperatures reaching 75 °C. Based on the geological history of the region, this probably took place in the Late Miocene-Early Pliocene interval. The second type of groundwater acquired its high solute concentrations from leaching igneous rocks and clastic sediments in the sub-surface, and infiltrated along the Paran fault, precipitating Fe-rich minerals and caused the first stage of dolomitization. This groundwater flowed at shallower depth than the DSR brines, and at lower temperatures (T ? 50 °C). The study shows that sedimentary mineralization in faults adjacent to active transform fault zones may arise from the combination of several different fluid flow regimes.  相似文献   

A possible new molecular mechanism of thundercloud electrification   总被引：1，自引：1，他引：1  

Pavel Jungwirth  Daniel Rosenfeld  Victoria Buch 《Atmospheric Research》2005,76(1-4):190

Thunderclouds are electrified when charge is transferred between small and large ice particles colliding in a cloud that contains strong updrafts. The small ice particles rise with one type of charge and the large ice particles fall and carry with them downward the other type of charge, which is most often negative, so that normally lightning lowers negative charge from cloud to the ground. While the collisional mechanism of thundercloud charging is well established, the nature of the charge transfer between the colliding ice particles is not very well understood on the atomic level, and no present theory can explain it in full detail. Here we propose a new charge separation mechanism that is based on molecular dynamics simulations of particle surfaces and collisions, keeping track of the individual charges as they move in the form of salt ions from one ice particle to another. Under normal conditions, when sulfates dominate as cloud condensation nuclei, this ionic mechanism is consistent with the prevailing negative charging of graupels in thunderclouds. Moreover, with dearth of sulfate anions, the present mechanism predicts a shift towards positive charging. This fits well to a large range of observations of enhanced positive lightning, connected with smoke rich in chlorides and nitrates, that could not be explained satisfactorily previously.  相似文献   

A viscoelastic damage rheology and rate- and state-dependent friction   总被引：1，自引：0，他引：1  

Vladimir Lyakhovsky  Yehuda Ben-Zion  Amotz Agnon 《Geophysical Journal International》2005,161(1):179-190

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Oxygen and hydrogen isotope study of high-pressure metagabbros and metabasalts (Cyclades, Greece): implications for the subduction of oceanic crust   总被引：1，自引：1，他引：0  

Benita Putlitz  Alan Matthews  John W. Valley 《Contributions to Mineralogy and Petrology》2000,138(2):114-126

Oxygen and hydrogen stable isotope ratios of eclogite-facies metagabbros and metabasalts from the Cycladic archipelago (Greece) document the scale and timing of fluid–rock interaction in subducted oceanic crust. Close similarities are found between the isotopic compositions of the high-pressure rocks and their ocean-floor equivalents. High-pressure minerals in metagabbros have low δ¹⁸O values: garnet 2.6 to 5.9‰, glaucophane 4.3 to 7.1‰; omphacite 3.5 to 6.2‰. Precursor actinolite that was formed during the hydrothermal alteration of the oceanic crust by seawater analyses at 3.7 to 6.3‰. These compositions are in the range of the δ¹⁸O values of unaltered igneous oceanic crust and high-temperature hydrothermally altered oceanic crust. In contrast, high-pressure metabasalts are characterised by ¹⁸O-enriched isotopic compositions (garnet 9.2 to 11.5‰, glaucophane 10.6 to 12.5‰, omphacite 10.2 to 12.8‰), which are consistent with the precursor basalts having undergone low-temperature alteration by seawater. D/H ratios of glaucophane and actinolite are also consistent with alteration by seawater. Remarkably constant oxygen isotope fractionations, compatible with isotopic equilibrium, are observed among high-pressure minerals, with Δ_{glaucophane−garnet} = 1.37 ± 0.24‰ and Δ_{omphacite−garnet} = 0.72 ± 0.24‰. For the estimated metamorphic temperature of 500 °C, these fractionations yield coefficients in the equation Δ = A * 10⁶/T ² (in Kelvin) of A_{glaucophane−garnet} = 0.87 ± 0.15 and A_{omphacite−garnet} = 0.72 ± 0.24. A fractionation of Δ_{glaucophane–actinolite} = 0.94 ± 0.21‰ is measured in metagabbros, and indicates that isotopic equilibrium was established during the metamorphic reaction in which glaucophane formed at the expense of actinolite. The preservation of the isotopic compositions of gabbroic and basaltic oceanic crust and the equilibrium fractionations among minerals shows that high-pressure metamorphism occurred at low water/rock ratios. The isotopic equilibrium is only observed at hand-specimen scale, at an outcrop scale isotopic compositional differences occur among adjacent rocks. This heterogeneity reflects metre-scale compositional variations that developed during hydrothermal alteration by seawater and were subsequently inherited by the high-pressure metamorphic rocks. Received: 4 January 1999 / Accepted: 7 July 1999  相似文献   

Compton dragged gamma-ray bursts: the spectrum     

Gabriele Ghisellini  Davide Lazzati  Annalisa Celotti  Martin J. Rees 《Monthly notices of the Royal Astronomical Society》2000,316(4):L45-L49

Recently several studies have jointly analysed data from different cosmological probes with the motivation of estimating cosmological parameters. Here we generalize this procedure to allow freedom in the relative weights of various probes. This is done by including in the joint χ ² function a set of 'hyper-parameters', which are dealt with using Bayesian considerations. The resulting algorithm, which assumes uniform priors on the log of the hyper-parameters, is very simple: instead of minimizing     (where     is per data set j ) we propose to minimize     (where N _j is the number of data points per data set j ). We illustrate the method by estimating the Hubble constant H ₀ from different sets of recent cosmic microwave background (CMB) experiments (including Saskatoon, Python V, MSAM1, TOCO and Boomerang ). The approach can be generalized for combinations of cosmic probes, and for other priors on the hyper-parameters.  相似文献