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21.
22.
The distribution of redox sensitive elements (U, As,Sb, Mo and V) has been investigated in Lake Balatonand two man-made reservoirs (Lake Kis-Balaton-1 andKis-Balaton-2) built along the River Zala, the mainriver discharging into it. These elements underwentremoval in Lake Kis Balaton-2 (KB-2) during anoxicconditions (May and September).Similarities were found between the distributions ofdissolved As and Sb. Both elements had elevateddissolved concentrations in Lake Kis-Balaton-1 (KB-1)and in Lake Balaton in September. This increasedmobility could be due to a change of speciation (viareduction and the formation of methylated species).Such changes in speciation are well documented in theliterature and are generally enhanced during periodsof warmth and high primary productivity.Dissolved V and Mo distributions also showedsimilarities with higher concentrations in LakeBalaton than in other parts of the system.Although removal is not clearly detected from thedissolved concentrations, U, As, Sb and Mo aresignificantly enriched in the organic-rich sedimentsof Lake KB-1, while V is mainly associated with thealumino-silicate fraction. In Lake KB-1, theconcentrations of all elements in SPM (suspendedparticulate matter) are lower than in the depositedsediments (except for As) suggesting that enrichmentprocesses are occuring in the deposited sediments.Additionnally the cycling of As and Mo can be alsopartly controlled by uptake and scavenging processesin the water column, as suggested by the elevated Asand Mo concentrations observed in SPM seasonnally forAs in Lake KB-1 and at Z.mouth-1 station and for Mo atZ.mouth-1 station and Lake Balaton.  相似文献   
23.
 Marine contamination of groundwater may be caused by seawater intrusion and by salt spray. The role of both processes was studied in the Cyclades archipelago on four small islands (45–195 km2) whose aquifers consist essentially of fractured, weathered metamorphic rocks. Annual rainfall ranges from 400 to 650 mm and precipitation has high total dissolved solids contents of 45–223 mg l–1. The chemical characteristics of the groundwater, whose salinity is from 0.4 to 22 g l–1, are strongly influenced by seawater intrusion. However, the effect of atmospheric input is shown in certain water sampling locations on high ground elevation where the dissolved chloride contents may attain 200 mg l–1. Received: 14 November 1995 · Accepted: 9 September 1996  相似文献   
24.
Sr and Nd isotopic compositions of one trachyte, eight phonolites and five basalts have been measured. The isotopic characteristics of the trachyte can be explained by a combined assimilation–fractional crystallization process within an upper crustal magmatic chamber. Some phonolites display isotopic signatures identical to basalts, suggesting that they have been protected against any crustal assimilation during their formation. Some others have low Sr contents, whereas they are enriched in radiogenic Sr (0.70451<87Sr/86Sri<0.71192), and display basaltic 143Nd/144Nd ratios. Both observations could be explained by very strong alkali feldspar fractionation and by subsequent very low assimilation of surrounding rocks (between 0.3 and 4%) during intrusion. To cite this article: J.-M. Dautria et al., C. R. Geoscience 336 (2004).  相似文献   
25.
We present a new three-dimensional SV-wave velocity model for the upper mantle beneath South America and the surrounding oceans, built from the waveform inversion of 5850 Rayleigh wave seismograms. The dense path coverage and the use of higher modes to supplement the fundamental mode of surface waves allow us to constrain seismic heterogeneities with horizontal wavelengths of a few hundred kilometres in the uppermost 400 km of the mantle.The large scale features of our tomographic model confirm previous results from global and regional tomographic studies (e.g. the depth extent of the high velocity cratonic roots down to about 200–250 km).Several new features are highlighted in our model. Down to 100 km depth, the high velocity lid beneath the Amazonian craton is separated in two parts associated with the Guyana and Guapore shields, suggesting that the rifting episode responsible for the formation of the Amazon basin has involved a significant part of the lithosphere. Along the Andean subduction belt, the structure of the high velocity anomaly associated with the sudbduction of the Nazca plate beneath the South American plate reflects the along-strike variation in dip of the subducting plate. Slow velocities are observed down to about 100 km and 150 km at the intersection of the Carnegie and Chile ridges with the continent and are likely to represent the thermal anomalies associated with the subducted ridges. These lowered velocities might correspond to zones of weakness in the subducted plate and may have led to the formation of “slab windows” developed through unzipping of the subducted ridges; these windows might accommodate a transfer of asthenospheric mantle from the Pacific to the Atlantic ocean. From 150 to 250 km depth, the subducting Nazca plate is associated with high seismic velocities between 5°S and 37°S. We find high seismic velocities beneath the Paraná basin down to about 200 km depth, underlain by a low velocity anomaly in the depth range 200–400 km located beneath the Ponta Grossa arc at the southern tip of the basin. This high velocity anomaly is located southward of a narrow S-wave low velocity structure observed between 200 and 500–600 km depth in body wave studies, but irresolvable with our long period datasets. Both anomalies point to a model in which several, possibly diachronous, plumes have risen to the surface to generate the Paraná large igneous province (LIP).  相似文献   
26.
We review studies of the Holocene and Late Pleistocene stratigraphy of eastern Iran to infer past changes in the environment within this presently arid region. We build a scenario of widespread, and presumably climatically driven, evolution of the landscape through the Holocene. Six sites, covering a 10° range in latitude, indicate a regional abandonment of alluvial fan surfaces at ~10 ± 3 ka, with the younger (~9 ka) end of this age range supported by several of the best-constrained studies. Incision of rivers into the fan surfaces has occurred in discrete stages in the early to mid-Holocene (~9–7 ka) leading to the formation of flights of river terraces. Detailed records of lakebed deposition in the presently arid interior of Iran are rare, though the available data indicate lake highstand conditions at <7.8 ka at South Golbaf in SE Iran and at < 8.7 ± 1.1 ka at the Nimbluk plain in NE Iran. The major periods of Holocene landscape development hence correlate with a period of time where water was more abundant than at present, with incision of rivers into thick alluvial deposits possibly occurring due to a combination of decreased sediment supply and high levels of precipitation, and with the formation of inset river terraces possibly responding to century-scale fluctuations in precipitation. No major geomorphic changes are identified within the later part of the Holocene, from which we infer that increased aridity has slowed evolution of the landscape. A decrease in precipitation in the mid-Holocene may have had a detrimental effect on bronze age societies in eastern Iran as has been inferred elsewhere in the eastern Mediterranean region. The pre-Holocene environmental changes in eastern Iran are less well constrained, though there are suggestions of alluvial fan abandonment at 40–60 ka, at ~80 ka, and at ~120 ka.  相似文献   
27.
Tsavorite, the vanadian variety of green grossular, is a high value economic gemstone. It is hosted exclusively in the metasedimentary formations from the Neoproterozoic Metamorphic Mozambique Belt. The deposits are mined in Kenya, Tanzania and Madagascar and other occurrences are located in Pakistan and East Antarctica. They are located within metasomatized graphitic rocks such as graphitic gneiss and calc-silicates, intercalated with meta-evaporites. Tsavorite is found as primary deposits either in nodule (type I) or in quartz vein (type II), and in placers (type III). The primary mineralizations (types I and II) are controlled by lithostratigraphy and/or structure. For the African occurrences, the protoliths of the host-rocks were deposited at the beginning of the Neoproterozoic within a marine coastal sabkha environment, located at the margin of the Congo–Kalahari cratons in the Mozambique Ocean. During the East African–Antarctican Orogeny, the rocks underwent high amphibolite to granulite facies metamorphism and the formation of tsavorite deposits occurred between 650 and 550 Ma. The nodules of tsavorite were formed during prograde metamorphism, calcium coming from sulphates and carbonates, whereas alumina, silicates, vanadium and chromium probably came from clays and chlorite. The veins were formed during the deformation of the metasedimentary platform units which experienced shearing, leading to the formation of fault-filled veins. Metasomatism developed during retrograde metamorphism. The metasedimentary sequences are characterized by the presence of evaporitic minerals such as gypsum and anhydrite, and scapolite. Evaporites are essential as they provide calcium and permit the mobilization of all the chemical elements for tsavorite formation. The H2S–S8 metamorphic fluids characterized in primary fluid inclusions of tsavorites and the δ11B values of coeval dravite confirm the evaporitic origin of the fluids. The V2O3 and Cr2O3 contents of tsavorite range respectively from 0.05 to 7.5 wt.%, while their δ18O values are in the range of 9.5–21.1‰. The genetic model proposed for tsavorite is metamorphic, based on chemical reactions developed between an initial assemblage composed of gypsum and anhydrite, carbonates and organic matter deposited in a sabkha-like sedimentary basin.  相似文献   
28.
The structural study of the Saint-Laurent – La Jonquera pluton (Eastern Pyrenees), a Variscan composite laccolithic intrusion emplaced in metasedimentary and gneissic rocks of the Roc de Frausa dome, by means of the anisotropy of magnetic susceptibility (AMS) technique has allowed the determination of the nature and orientation of its magmatic fabrics. The magmatic foliation has a predominant NE–SW strike and the mean lineation is also NE–SW trending with a shallow plunge. A strain gradient is measured so that the tonalites to granodiorites that form the basal parts of the pluton, and are intruded into amphibolite-facies metamorphic rocks, recorded the highest anisotropies, whereas the monzogranites and leucogranites, emplaced into upper crustal, low-grade metamorphic rocks, are weakly deformed. These results point to the synkinematic sequential emplacement of multiple granitoid sheets, from less to more differentiated magmatic stages, during the Late Carboniferous D2 event characterized by an E–W-trending dextral transpression. The magmatic foliation appears locally disturbed by the effects of two tectonic events. The first of them (D3) produced mylonitization of granitoids along NW–SE retrograding shear zones and open folds in the host Ediacaran metasediments of the Roc de Frausa massif, likely during late Variscan times. Interference between D2 and D3 structures was responsible for the dome geometry of the whole Roc de Frausa massif. The second and last perturbation consisted of local southward tilting of the granitoids coupled to the Mesozoic–Cenozoic cover during the Alpine.  相似文献   
29.
Microstructural, electron backscatter diffraction (EBSD), and misorientation analyses of a migmatitic granulite-facies orthogneiss from the exhumed lower crust of a Cretaceous continental arc in Fiordland, New Zealand show how deformation was accommodated during and after episodes of melt infiltration and high-grade metamorphism. Microstructures in garnet, omphacite, plagioclase, and K-feldspar suggest that an early stage of deformation was achieved by dislocation creep of omphacite and plagioclase, with subsequent deformation becoming partitioned into plagioclase. Continued deformation after melt infiltration resulted in strain localization in the leucosome of the migmatite, where a change of plagioclase deformation mechanism promoted the onset of grain boundary sliding, most likely accommodated by diffusion creep, in fine recrystallized plagioclase grains. Our results suggest three distinctive transitions in the rheology of the lower crust of this continental arc, where initial weakening was primarily achieved by deformation of both omphacite and plagioclase. Subsequent strain localization in plagioclase of the leucosome indicates that the zones of former melt are weaker than the restite, and that changes in deformation mechanisms within plagioclase, and an evolution of its strength, primarily control the rheology of the lower crust during and after episodes of melting and magma addition.  相似文献   
30.
Upper Maastrichtian deposits formed in a nearshore subtidal environment within the Valdenoceda Formation (Castilian Ramp, North Iberian margin) are described together with two recently found selachian assemblages. Rare earth element concentrations (REE) have been used to assess the degree of taphonomic mixing and reworking, observing that it is minor or non-existent, and differences in degree of preservation and ecologic mixing can be explained by biostratinomic processes. The patterns of REE also helped to obtain a better understanding of the depositional environment, including the diagenetic history from burial to final degree of bone preservation.The fossil assemblages here described are close to that of the late Maastrichtian of Albaina (in the enclave of Condado de Treviño, Burgos), both in the Basque-Cantabrian Region, but their age may be slightly older (early late Maastrichtian). In total, the new assemblages consist of 17 taxa, assigned to 11 genera of shallow-water dwellers combined with individuals from the outer shelf. They represent cosmopolitan taxa (Squalicorax pristodontus, Serratolamna serrata and Rhombodus binkhorsti) together with local species (Rhinobatos echavei, Rhinobatos ibericus). Although there are not significant differences between Albaina and Quintanilla la Ojada faunas, the new assemblages add interesting taphonomic and geochemical information to the few existing uppermost Cretaceous deposits with fossil sharks in southwestern Europe.  相似文献   
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