A new approach for the development and management of brackish karst springs     

Athanasios Maramathas 《Hydrogeology Journal》2006,14(7):1360-1366

A new approach to the method of artificial upraising of the water outlet point, for management and development of brackish karst springs, uses the MODKARST model. Brackish karst springs simulation can be used to estimate the necessary upraising of the spring elevation, so that sea-water intrusion is blocked. The consequent freshwater loss to the sea, due to this upraising, can also be estimated. The method has been applied to the periodically brackish karst Almiros spring at Heraklion of Crete, Greece. The spring simulation showed that the sea-water intrusion could be prevented through an artificial upraising of the water-outlet point, realized by the construction of a dam. The exact upraising has been estimated. Freshwater loss to the sea because of this upraising has also been estimated. The model could also be used as a tool for the management of the spring. For example, it was used to assess management options for the spring during the depletion period of the year 1994. The best scenario for the development of the spring during this period has been estimated.  相似文献   

Kinetics of Mn(II) oxidation by Leptothrix discophora SS1     

Jinghao ZhangLeonard W Lion  Yarrow M Nelson  Michael L ShulerWilliam C Ghiorse 《Geochimica et cosmochimica acta》2002,66(5):773-781

The kinetics of Mn(II) oxidation by the bacterium Leptothrix discophora SS1 was investigated in this research. Cells were grown in a minimal mineral salts medium in which chemical speciation was well defined. Mn(II) oxidation was observed in a bioreactor under controlled conditions with pH, O₂, and temperature regulation. Mn(II) oxidation experiments were performed at cell concentrations between 24 mg/L and 35 mg/L, over a pH range from 6 to 8.5, between temperatures of 10°C and 40°C, over a dissolved oxygen range of 0 to 8.05 mg/L, and with L. discophora SS1 cells that were grown in the presence of Cu concentrations ranging from zero to 0.1 μM. Mn(II) oxidation rates were determined when the cultures grew to stationary phase and were found to be directly proportional to O₂ and cell concentrations over the ranges investigated. The optimum pH for Mn(II) oxidation was approximately 7.5, and the optimum temperature was 30°C. A Cu level as low as 0.02 μM was found to inhibit the growth rate and yield of L. discophora SS1 observed in shake flasks, while Cu levels between 0.02 and 0.1 μM stimulated the Mn(II) oxidation rate observed in bioreactors. An overall rate law for Mn(II) oxidation by L. discophora as a function of pH, temperature, dissolved oxygen concentration (D.O.), and Cu concentration is proposed. At circumneutral pH, the rate of biologically mediated Mn(II) oxidation is likely to exceed homogeneous abiotic Mn(II) oxidation at relatively low (≈μg/L) concentrations of Mn oxidizing bacteria.  相似文献   

Photochemistry of N2O4 Adsorbed on Ice Surfaces at 193 nm     

Akio Susa  Seiichiro Koda 《Journal of Atmospheric Chemistry》2003,45(2):197-217

A multi-layer deposited ice film was prepared through water vapor deposition on a Ni plate in a vacuum chamber at 90 K, and was used as it was or after annealing at 140 K. NO₂ was adsorbed as N₂O₄ approximately 90 K on the ice film prepared as above, and irradiated by 193 nm excimer laser light. The time-of-flight (TOF) spectra of the desorbed species, i.e., NO₂, NO, O₂ and O, were measured by a quadrupole mass spectrometer. The photochemical process obeyed an one-photon process. The relative yields of the products and their TOF spectra were dependent on the preparation condition of the ice film and also varied with the continuation of the laser irradiation. From the ice film annealed at 140 K, NO₂, NO and O₂ were desorbed with an approximate ratio of 1:1:0.01. From the non-annealed film, the relative yield of NO₂ was much smaller than that of NO. The TOF spectrum of NO from the non-annealed ice film consisted of distinctly different two components corresponding to the 1700 and 100 K translational temperature, respectively. The fast component was lost when additional ice was deposited on the adsorbed N₂O₄. NO was supposed to be a predissociation product from the electronically excited NO₂ prepared through the photodissociation of N₂O₄.  相似文献   

甲醛还原Pt/TiO₂催化剂用于温和条件下高效催化氧化甲醛（英文）     

陈铧耀  芮泽宝  纪红兵 《甘肃地质》1997,(1):188-196

通过浸渍法(IM)和沉积-沉淀(DP)法制备了一系列Pt/TiO2P25)催化剂,并分别用甲醛溶液和氢气还原处理催化剂.利用原位红外监测催化剂表面吸附物种在反应过程中的变化,探究了催化剂制备和还原条件及Pt负载量对催化剂结构和催化氧化甲醛活性的影响.结果显示,用DP法制备并用甲醛还原的Pt/P25催化剂中Pt颗粒分散均匀,并具有合适的粒径和高浓度的表面活性氧,显示出良好的甲醛氧化活性.在空速30 000 ml/(g·h)、反应温度30°C和甲醛初始浓度50 mg/m的条件下,0.4%Pt/P25(DP-HCHO)上的甲醛转化率达到98%,并能稳定运行100 h以上.相比之下,Pt/P25(DP-H2)由于表面活性氧较少,不利于甲酸盐氧化,活性较低.Pt/P25(IM-H2)虽然具有高浓度的表面活性氧,却同时具有最大的Pt颗粒粒径,在甲醛转化为甲酸盐和甲酸盐氧化两步反应中的活性均较差,因而甲醛氧化活性最差.  相似文献   

Bearing capacity of rock over mined cavities in Nottingham   总被引：1，自引：0，他引：1  

A.C Waltham  G.M Swift 《Engineering Geology》2004,75(1):15-31

A significant geohazard is created in Nottingham, UK, by hundreds of man-made caves cut in the weak sandstone beneath the city centre. Stability of the caves has been assessed by a single full-scale loading test, by numerical modelling with FLAC and by physical modelling in plaster. For typical caves 4 m wide, bearing capacity of the rock roof rises from 2 MPa where it is 1 m thick to 8 MPa where 3 m thick. Stability decreases over wider caves and where the loading pad edge is over the edge of the cave. Numerical modelling of a very wide cave revealed the failure mechanisms and also showed that an internal support wall increased roof bearing capacity by 50%. Local building regulations that require 3-5 m of rock cover over the sandstone caves appear to be conservative. In stronger rocks, including karstic limestone, a guideline that cover thickness exceeds 70% of the cave width appears to be appropriate.  相似文献   

Microorganisms in Lianxian lateritic gold deposit in Guangdong and their effects on leaching of heavy metals     

陈炳辉刘琥琥  毋福海徐文烈 《中国地球化学学报》2005,24(2):144-148

Microorganisms in the lateritic profiles of the Lianxian gold deposit in Guangdong were cultured, isolated and identified. The microorganisms include bacteria such as Bacillus, Enterobacter, Pseudomonas, Lactobacillus, Actinetobacter, Aeromona, Listeria, Agrobacteriura, Cotyttebacteriurn, and Moraxella, fungi such as Penicillium, Alter naria, Cladosporium, Saccharcornyces, Mucor, and the chemoautotrophic Thiobacillu.~. It is shown in a leaching experiment that the microorganisms can accelerate the leaching of Cu, Cd, Zn, and that the G- bacteria are most efficient for leaching Cu, Zn and the G^ bacteria are better for leaching Cd.  相似文献   

Effect of the addition of gypsum- and lime-rich industrial by-products on Cd,Cu and Pb availability and leachability in metal-spiked acid soils     

《Applied Geochemistry》2005,20(2):397-408

In situ stabilization of metals in contaminated soils by addition of industrial by-products is an attractive remediation technique. In this work, mixtures of metal-spiked (Cd, Cu and Pb) samples from the Ap horizons of two acid soils and solid samples of 4 industrial by-products (red gypsum, phosphogypsum, sugar foam and dolomitic residue) were incubated in order to assess the efficiency of the by-products for the in situ remediation of contaminated soils. Single (DTPA extraction and TCLP test) and sequential chemical extraction procedures were used to examine the availability and potential mobility of the metals retained as a result of the treatments. Both the sugar foam and dolomitic residue reduced the availability and mobility of Cd, Cu and to a lesser extent, Pb. On the other hand, red gypsum and phosphogypsum proved effective in immobilizing Pb and, to a lesser extent, Cu. However, both gypsum-like by-products were not so effective in reducing Cd availability and mobility.  相似文献   

Oldest rocks,earliest life,heaviest impacts,and the Hadean–Archaean transition     

《Applied Geochemistry》2005,20(5):819-824

  相似文献   

Arsenic readily released to pore waters from buried mill tailings     

《Applied Geochemistry》2005,20(5):947-959

At the McClean Lake Operation in the Athabasca Basin of northern Saskatchewan, the untreated acid raffinate solutions associated with U mill tailings contain up to 700 mg/L dissolved As. To reduce the concentration of As and other contaminants in acid tailing slurries at the JEB mill at McClean Lake, ferric sulfate may be added to the acid raffinates to assure that their molar Fe/As ratio equals or exceeds 3. Tailings slurries are then neutralized with lime to pH 4, and subsequently to pH 7–8. The neutralized tailings contain minerals from the original ore, which are chiefly quartz, illite, kaolinite and chlorite, and precipitated (secondary) minerals that include gypsum, scorodite, annabergite, hydrobasaluminite and ferrihydrite. Most of the As is associated with the secondary arsenate minerals, scorodite and annabergite. However, a few percent is adsorbed and/or co-precipitated, mainly by ferrihydrite. Of major concern to provincial and federal regulators is the risk that significant amounts of As might be released from the tailings to pore waters after their subaqueous disposal in the tailings management facility. A laboratory study was performed to address this issue, measuring readily desorbed As using a method known as equilibrium partitioning in closed systems (EPICS). The EPICS method was selected because it employs a leaching solution that, except for its As concentration, is identical in composition to the neutralized raffinate in contact with the tailings. Laboratory experiments and modeling results demonstrated that the As that could be readily released to pore waters is about 0.2% of the total As in the tailings. Long-term, such releases may contribute no more than a few mg/L of dissolved As to tailings pore waters.  相似文献   

Differentiating dilution and retention processes in mine effluent remediation within a natural wetland on the Zambian Copperbelt     

《Applied Geochemistry》2005,20(7):1241-1257

The use of wetlands to treat mine effluent has grown in popularity over the past two decades, although the processes by which the natural systems function are often poorly understood. This field-scale investigation utilises daily data over a 9-month period in assessing the processes leading to the remediation of mine effluent within a natural wetland on the Zambian Copperbelt. The study differentiates effluent remediation through dilution from pollutant retention. Decreased wetland outflow concentrations of SO₄ and Na are due to dilution only, while Co (50%) and especially Cu (83%) are retained within the wetland. Retention was linked to adsorption onto new or primed surfaces during an initial period of effluent release into the system and to processes related to pH buffering to 7.5. The wetland’s acid buffering capacity was largely the result of carbonate-rich groundwater discharge into the wetland. Although this buffering capacity likely shows little seasonal fluctuation (20–80 kmol/day), the impact of acidic effluent input on the wetland itself probably varies markedly between seasons, owing to the temporal and spatial characteristics of discharge from the catchment’s aquifers. Assessment of other natural wetlands in the region indicated that some (circa 15%) showed similar catchment size, hydrochemical and hydrogeological characteristics as those of the New Dam wetland, likely demonstrating a similar effluent remediation potential as that described here.  相似文献