铁铝复合氧化物对土壤Mn、Pb和Cd有效性的影响   总被引：1，自引：0，他引：1  

任丽英  马家恒  徐振  胡长伟  王法社  高晓慧  庞雪 《矿物学报》2014,(3)

利用氧化物对土壤重金属的吸附特性,研究了添加铁铝复合氧化物对土壤Mn、Pb和Cd有效性的影响。结果表明,在土壤中添加氧化物后,土壤中3种重金属的交换态含量明显降低。14天时间,添加铁铝氧化物后,土壤中交换态Mn、Pb和Cd的含量分别降低了64.8%、52.9%和89.51%,可见铁铝氧化物明显降低了土壤中Mn、Pb和Cd的有效性。通过方程拟合,建立了氧化物对土壤中交换态Mn、Pb和Cd的吸附模型,其中以Elovich方程和权函数方程拟合度较好,其次是抛物线扩散方程。  相似文献   

新疆阿尔泰伟晶岩中绿柱石拉曼光谱特征研究——以可可托海3号脉与阿祖拜328、528号脉为例     

周天怡  陈衍景  张辉 《岩石矿物学杂志》2014,33(S2):77-84

本文对新疆可可托海3号伟晶岩脉中的绿柱石与阿祖拜328、528号伟晶岩脉中的宝石级绿柱石开展拉曼光谱对比研究,获得以下主要结论: ① 阿祖拜328、528号伟晶岩脉中宝石级绿柱石以富含Ⅰ型H₂O为特征,可可托海3号脉早期形成的结构带(Ⅰ-Ⅱ带)中绿柱石以及相对富H₂O岩浆体系中形成的绿柱石(Ⅳ带)以存在Ⅰ型H₂O为主,演化程度相对较高,岩浆体系中结晶的结构带(Ⅲ带)以及岩浆-热液过渡阶段体系形成的结构带(Ⅴ带)中绿柱石以含有Ⅱ型H₂O为特征; ② 在可可托海3号脉以及阿祖拜328号、528号脉绿柱石矿物中均发现冰晶石矿物包体,指示伟晶岩岩浆含有较高的F含量;③ 绿柱石通道水类型(Ⅰ型H₂O、Ⅱ型H₂O)及相对比例,是伟晶岩岩浆-热液演化过程及其形成条件的响应,在相对氧化的岩浆体系中主要形成绿柱石矿物,而相对还原的富H₂O岩浆体系更有利于海蓝宝石形成.  相似文献   

论长治盆地区域生态地球化学特征与农业发展前景     

唐华 《山西地质》2014,(4):60-62

通过对长治盆地区域地球化学化学特征的分析,为该地区土地规划、整理和开发利用,促进农业经济区划和种植结构调整,加快土地保护治理,制定经济社会科学和可持续发展提供依据。  相似文献   

梁家沟矿区土壤地球化学特征及找矿意义     

卢仁  梁涛  王福贵 《物探与化探》2014,(2):234-238

在1∶1万土壤地球化学测量的基础上,对梁家沟矿区的地球化学特征进行了初步分析,对元素的分布特征及单元素异常特征进行了研究,发现Ag、Pb、Mo、W为矿区具有一定潜力的找矿指标。结合矿区内异常元素组合特征、地球化学—地质成因和找矿远景分析,圈定矿区内冰冷沟、苇子沟和乔沟为找矿靶区。  相似文献   

土壤地球化学测量在博茨瓦纳中部地区的应用     

李飞  施泽明  裴云婧 《物探与化探》2014,(1):58-62

通过在博茨瓦纳中部区Tonota-Foley一带的找矿勘查,探讨土壤地球化学测量方法在博茨瓦纳热带干旱草原景观区的应用效果。利用该方法,在Tonota-Foley一带圈定出化探综合异常17处,通过对典型异常的查证工作,运用槽探工程,查明了异常源为方解石蛇纹岩体,说明土壤地球化学测量方法适用于博茨瓦纳中部地区的景观条件,圈定的异常准确、有效,该方法可在博茨瓦纳同类地区推广使用。  相似文献   

综合物化探方法在地质找矿“攻深找盲”中的应用     

时永志  ;李凯成 《物探与化探》2014,(5):910-915

物化探找矿方法面临着新形势下复杂地质条件中找矿的新挑战,单一物化探分析方法很难具有说服力,综合各种地质信息和勘探方法显得尤为重要。笔者结合河南省某矿床的找矿实践,介绍了高精度磁测、X荧光土壤分析和EH4测深等物化探综合分析方法,在工作区内发现了与成矿有关的物化探异常,经查证与地表地质现象吻合较好,说明该综合物化探评价技术方法在该矿床的应用是成功的,显示了其快速、高效和精准的特点。  相似文献   

Correlation analysis and partial least square modeling to quantify typical minerals with Chang＇E-3 visible and near-infrared imaging spectrometer＇s ground validation data     

LIU Bin  LIU Jianzhong  ZHANG Guangliang  LING Zongcheng  ZHANG Jiang  HE Zhiping  YANG Benyong  ZOU Yongliao 《中国地球化学学报》2014,33(1):86-94

In 2013, Chang＇E-3 program will develop lunar mineral resources in-situ detection. A Visible and Near-infrared Imaging Spectrometer （VNIS） has been selected as one payload of CE-3 lunar rover to achieve this goal. It is critical and urgent to evaluate VNIS＇ spectrum data quality and validate quantification methods for mineral composition before its launch. Ground validation experiment of VNIS was carried out to complete the two goals, by simulating CE-3 lunar rover＇s detection environment on lunar surface in the laboratory. Based on the hyperspectral reflectance data derived, Correlation Analysis and Partial Least Square （CA-PLS） algorithm is applied to predict abundance of four lunar typical minerals （pyroxene, plagioclase, ilmenite and olivine） in their mixture. We firstly selected a set of VNIS＇ spectral parameters which highly correlated with minerals＇ abundance by correlation analysis （CA）, and then stepwise regression method was used to find out spectral parameters which make the largest contri- butions to the mineral contents. At last, functions were derived to link minerals＇ abundance and spectral parameters by partial least square （PLS） algorithm. Not considering the effect of maturity, agglutinate and Fe~, we found that there are wonderful correlations between these four minerals and VNIS＇ spectral parameters, e.g. the abundance of pyroxene correlates positively with the mixture＇s absorption depth, the value of absorption depth added as the in- creasing of pyroxene＇s abundance. But the abundance of plagioclase correlates negatively with the spectral parame- ters of band ratio, the value of band ratio would decrease when the abundance of plagioclase increased. Similar to plagioclase, the abundance of ilmenite and olivine has a negative correlation with the mixture＇s reflectance data, if the abundance of ilmenite or olivine increase, the reflectance values of the mixture will decrease. Through model validation, better estimates of pyroxene, plagioclase and ilmenite＇s abundances are given. It is concluded that VNIS has the capability to be applied on lunar minerals＇ identification, and CA-PLS algorithm has the potential to be used on lunar surface＇s in-situ detection for minerals＇ abundance prediction.  相似文献   

Determination of trace and rare-earth elements in Chinese soil and clay reference materials by ICP-MS   总被引：2，自引：0，他引：2  

Ye Liu  Chunrong Diwu  Yan Zhao  Xiaoming Liu  Honglin Yuan  Jianqi Wang 《中国地球化学学报》2014,33(1):95-102

Inductively coupled plasma mass spectrometry(ICP-MS) has become a powerful tool for providing reliable analytical results in many laboratories around the word. In this study, the mixture of HF and HNO3 acids in high-temperature and high-pressure closed-vessel digestion technique were used to decompose some Chinese reference materials, and thirty seven elements were determined by ICP-MS. Most of the results for Chinese soil reference materials were found to be in reasonable agreement with the reference values, except Cs, Ta, Li, Ge, Zn, Nd, Tb and Ta whose values need to be revised. Their precisions were typically lower than 5% RSD. However, the Precisions of Chinese clay reference materials, especially for GBW03102 and GBW03102a, were significantly different with reference values, probably reflecting the existence of a coarser-grained fraction(70 μm) in samples, and the formation of fluorides in Al-rich samples during sample decomposition by using the mixture of HF and HNO3 acids. Moreover, thirty-seven trace elements covering the mass range from Li to U in four Chinese clay reference materials were firstly provided with good precision and accuracy in this study.  相似文献   

Mobilization and redistribution of elements in soils developed from extreme weathering basalt on Hainan Island   总被引：1，自引：0，他引：1  

Jianwu Li  Ganlin Zhang  Zitong Gong 《中国地球化学学报》2014,33(3):262-271

Major, trace and organic elements of a South China were reported to investigate elements laterite profile developed on Neogene basalt on Hainan Island, mobilization and redistribution in tropical regions. The results indicate that strong acid environment and organic matter （OM） can remarkably improve the transfer of insoluble elements. Among all the elements, Th is the least mobile. As for the general conservative elements during incipient chemical weathering, such as Ti, Zr, Hf and Nb, the removals are up to 30%-40% in the upper profile. And for Fe, A1, Cu and Ni, that tend to be combined with secondary minerals and to be retained in temperate zone, they are re- moved from the upper profile, transferred downwards, and then precipitated in the lower profile. In addition, atmos- pheric inputs, including sea salt aerosols and dust, have a profound effect on the budgets of elements that are susceptible to leaching losses （e.g. K, Na and Sr）. Excluding the possibilities of groundwater and erosion, the remarkable increase of K, Na and Sr concentrations in the upper profile, together with dramatically upward increasing trends of the percentage changes of Sr/Th, K/Th and Na/Th ratios, show that atmospheric inputs, especially sea salt aerosols, contribute much extraneous seawater derived elements, such as K, Na and Sr to the soils. The overall elemental be- haviors in this profile suggest that organic matter and atmospheric inputs play a very important role in the mobiliza- tion and redistribution of elements during extreme weathering in tropical regions.  相似文献   

Geochemical process of fluorine in soil     

Xiaojing Liu  Binbin Wang  Baoshan Zheng 《中国地球化学学报》2014,33(3):277-279

Fluorine is in the dynamic balance of two geochemical processes, enrichment and leaching, reflecting the adsorption and desorption of fluoride by clay minerals, respectively. The two geochemical processes of fluorine in soil are influenced by factors including geochemical characteristics of soil and clay minerals, pH and sanity of soil solutions, climate, grazing and agriculture activities. Main factors controlling enrichment and leaching process of fluorine in soil can be found with interaction consideration.  相似文献