Changes to cadmium associations in canal sediments on drying and oxidation     

Samantha R. Cook John M. Chamock Andrew Parker 《中国地球化学学报》2006,25(B08):247-247

The mainly 19th Century canal system in the UK, largely managed by British Waterways, has been increasingly brought back into operation over the last few decades, and is now widely used for both leisure, and, increasingly, transport. Both initial and routine dredging of the canal sediment is carried out and these sediments are generally disposed of to land. Because many of the canals were connected with primary industries, their sediments can locally be significantly contaminated with heavy metals, and the behaviour of these metals under differing redox conditions, when introduced into a new environment （i.e., on land） is of importance for environmental risk-assessment purposes. Canal sediments are often rich in sulfidic mineral phases, and we have attempted to quantify the influence of these sulfidic phases on the release and retention of metals in dredged canal sediments, using a combination of traditional chemical techniques （e.g. sequential extraction） and X-ray absorption spectroscopy （XAS）. Sediment samples have been collected from urban fresh-water canals, one in the British Midlands and one in Northern France. It appears from XAS that Cd is largely associated with oxygen in air-dried sediment, and with sulphur in vacuum-dried sediment.  相似文献   

Origin and three-dimensional fluorescence spectrum of the chromophoric dissolved organic matter in Yangtze estuary, East China     

Fan YANG Qinghui HUANG Jianhua LI Xiaomin ZHU 《中国地球化学学报》2006,25(B08):262-262

Dissolved organic matter （DOM） is an important chemical component in natural water. Chromophoric dissolved organic matter （CDOM）, a fraction of optical properties, plays art important role in the biogeochemical cycle of nutrients in aquatic environment. People realized that DOM cycle is crucial in the global carbon and nitrogen flux, and also is inherently related to nutrients and trace metal elements. Therefore, CDOM was concerned by scientists in global oceanography and limnology fields. Water samples were collected from three sections （North Channel, South Channel and Zhuyuan） of the Yangtze （Changjiang River） estuary in March 2006 Three-dimensional excitation emission matrix （3-DEEM） fluorescence spectra were analyzed for those filtrates through Whatman GF/F filters. Dissolved organic carbon （DOC） was also measured by TOC analyzer. The tidal variety was also taken into account. The 3-D EEM fluorescence scans suggested the fluorescence characteristics of humic acid （Ex=332-344 nm, Em=439-451 nm） and fulvic acid （Ex=250-254 nm, Em=472-478 nm） were obvious, and the fluorescence group of protein-like and tyrosine （Ex=230 nm, Em=283 nm） was also found. They are mainly composed of CDOM in the Yangtze estuary. Further data analysis, especially the fluorescence index （f 450/500）, showed that terrestrial signal was rather strong （1.41-1.65） in the surface water, however, some terrestrial CDOM signals of bottom water showed excursions （1.28-1.39）. On the other hand, anthropogenic sign was impressed in the waters of Zhuyuan, which is one of the main drain outlets of Shanghai Metropolis. DOC concentrations ranged from 2.2 mg/L to 3.4 mg/L in Zhuyuan and South Channel, and from 2.0 mg/L to 2.4 mg/L in North Channel. The tide effect played a role in the composition of the CDOM measured by 3-D fluorescence scan technology.  相似文献   

Effect of particles on the photodegradation of PAHs in natural waters-A case study for the Yellow River     

Xinghui XIA 《中国地球化学学报》2006,25(B08):263-263

Photodegradation of chrysene, benzo （a） pyrene and benzo （g, h, i） perylene in natural water of the Yellow River was studied using simulation sunlight. The effects of particulates on the photodegradation were explored. Several results arose from this study. （1） The photodegradation of PAHs can be fitted with first-order kinetics when no particulate exists in water system, and the first-order constant increases with decreasing of initial concentration of PAHs. The photodegradation rates of the three PAHs are related to their molecule absorption spectrum. （2） The existence of loess exerts two kinds of effects on the photodegradation of PAHs, including the inner filter effects and the photosensitizing effects of humic substance in loess. These two contrary effects lead to the difference of net effects among different contents of loess. When the loess contents are 0.1 and 5.0 g/L, the existence of loess stimulates the photodegradation of chrysene, benzo （a） pyrene. When the loess content is 5.0 g/L, the existence of loess stimulates the photodegradation of benzo （g, h, i） perylene. In addition, the photodegradation of PAHs can be fitted with the second-order kinetics when there is loess in the water system. （3） The soluble humic substances in loess can accelerate the photodegradation of PAHs while the in soluble part cannot. （4） Since the soluble humic substances in the suspended solids of the river have been dissolved in water,  相似文献   

吸水剖面综合解释方法及应用     

ZHANG Jian-min ZHAO Yong-zhong XU Jing HUANG Juan The Logging Company  Jilin Petroleum Group Co.  Ltd  Songyuan  Jilin  China 《吉林大学学报(地球科学版)》2006,(Z2)

吉林油田同位素吸水剖面测井采用~(113)In同位素追踪技术,根据同位素追踪过程解释基本可以判断配水层段吸水情况。但是在注水井存在沾污、大孔道以及串槽等影响时,吸水面积确定比较困难。在同位素测井中增加井温、流量参数,通过多参数综合解释,不仅可以对沾污影响进行合理校正,确定准确的小层吸水量,而且能够正确判断各级封隔器、配水器的工作情况,在地层存在大孔道的情况下,确定地层的吸水面积。吸水剖面综合解释方法在吉林油田已普遍应用,见到明显的效果。  相似文献   

盛源盆地南部铀成矿水文地球化学条件分析     

石平 《铀矿地质》2005,21(1):38-44,51

本文阐述了盛源盆地南部铀成矿的地质、水文地质和水文地球化学条件 ,分析了区内放射性水异常的产出、分布特征和控制因素 ,认为坝口等地段水的循环深度大 ,深部氧化 还原过渡带发育 ,大面积、交互叠加的放射性水异常是寻找大型隐伏铀矿床的重要标志。  相似文献   

吐哈盆地十红滩铀矿床水文地球化学特征   总被引：6，自引：0，他引：6  

乔海明  张天太  张复新  尚高峰  宋哲 《铀矿地质》2005,21(6):345-352

本文根据水化学资料的研究,探讨了十红滩铀矿床含矿含水层高矿化度地下水的成因,分析了高矿化度水对铀溶解迁移的影响及碳酸盐的形成机理.  相似文献   

水文信息处理系统研究     

舒大兴 王健郑召平  刘易娜肖泰峰 李丽华 《水文》2005,25(3):26-29

水文信息处理系统是在Windows环境下、用Visual Basic 6．0高级语言研制开发的智能水文资料整编软件，引用数据库存储信息，调用Excel输出整编成果。该软件实现了水位、流量、泥沙等要素关系线的自动生成和人工辅助定线，并完成全部整编计算工作，结束了我国水文资料电算整编工作中依靠手工定线整编的历史，解决了计算机定线、推流和成果输出一次完成的技术难题，真正实现了水文资料整编计算机化。  相似文献   

MapGIS下空间数据库的建立及其典型问题研究   总被引：4，自引：0，他引：4  

李定平  胡光道  程路 《武汉大学学报(信息科学版)》2005,30(11):1029-1032

以云南省地质图、水文地质图空间数据库的建立为例,通过对空间数据库建设中资料准备、图形矢量化、空间数据处理及文件转换四个过程的分析,总结了在进行回溯型空间数据库建库过程中需要注意的一些典型问题,并提出了解决的办法。论述了在MapGIS下空间数据库建立过程中的一些技巧及经验。  相似文献   

云南省“九五”期间雨情水情特性分析     

伍立群 《防汛与抗旱》2002,(1):47-54

  相似文献   

费县地下水分布规律及其水质特征浅析     

邵卫华  李洪强  李庆德  房桂祥 《地下水》2002,24(2):111-112

本文阐述了县内第四系孔隙水富水区、灰岩岩溶水富水区、变质岩贫水区、碎屑岩贫水区的水文地质构造、地下水分布状况及单井出水量的大小。采用模糊数学法对水质现状及趋势进行了分析评价，总体上水于恶化趋势。认为加强地下水保护已成当务之急。  相似文献