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Stable oxygen isotope analysis and measurement of several dissolved cations and anions of bulk meltwater samples have provided information about the hydrochemical environment of the glacial hydrological system at Imersuaq Glacier, an outlet tongue from the Greenland ice‐sheet, West Greenland. The samples were collected at frequent intervals during the period 20–28 July 2000 in a small (<20 L s?1) englacial meltwater outlet at the glacier margin. The results document the following findings: (i) a marked diurnal variation of δ18O is related to the composition of oxygen isotope provenances, mainly near‐marginal local superimposed ice and basal up‐sheared ice further up‐glacier; (ii) a relationship is seen between all base cations (Na+, K+, Ca2+, Mg2+), SO42? and δ18O, indicating that solute acquisition is provided by solid–solution contact with the up‐sheared ice—as the relationship with Cl? is weak the influence of seasalt‐derived solutes is small in the area; (iii) when the melt rate is high, two diurnal maxima of δ18O values and solute concentrations are measured, and it is suggested that a snow meltwater component is responsible for the second maximum of δ18O—a short residence time leads to a delayed decrease in ion concentrations. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
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Development of a 3D GIS and its application to karst areas   总被引:1,自引:0,他引:1  
There is a growing interest in modeling and analyzing karst phenomena in three dimensions. This paper integrates geology, groundwater hydrology, geographic information system (GIS), database management system (DBMS), visualization and data mining to study karst features in Huaibei, China. The 3D geo-objects retrieved from the karst area are analyzed and mapped into different abstract levels. The spatial relationships among the objects are constructed by a dual-linker. The shapes of the 3D objects and the topological models with attributes are stored and maintained in the DBMS. Spatial analysis was then used to integrate the data in the DBMS and the 3D model to form a virtual reality (VR) to provide analytical functions such as distribution analysis, correlation query, and probability assessment. The research successfully implements 3D modeling and analyses in the karst area, and meanwhile provides an efficient tool for government policy-makers to set out restrictions on water resource development in the area.  相似文献   
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This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.
Luigi Marini (Corresponding author)Email:
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Flood mapping requires the combination and integration of geomorphological and hydrological-hydraulic methods; however, despite this, there is very little scientific literature that compares and validates both methods. Two types of analysis are addressed in the present article. On the one hand, maps of flood plains have been elaborated using geomorphological evidence and historical flood data in the mountainous area of northwestern Spain, covering an area of more then 232 km2 of floodplains. On the other hand, a hydrometeorological model has been developed (Clark semidistributed unit hydrograph) in the Sarria River basin (155 km2, NW Spain). This basin is not gauged, hence the model was subjected to a goodness-of-fit test of its parameter (curve number) by means of Monte Carlo simulation. The peak flows obtained by means of the hydrological model were used for hydraulic modeling (one-phase, one-dimensional and steady flow) in a 4 km2 urban stretch of the river bed. The delineation of surface areas affected by floods since 1918, as well as those analyzed subsequent to the geomorphological study, reveals a high degree of reliability in the delineation of the flooded areas with frequent recurrence intervals (<50 years). If we compare these flooded surface areas with the estimate obtained by the hydrological-hydraulic method we can see that the latter method overestimates the extent of the surface water by 144% for very frequent recurrence intervals (>10 years) and underestimates it as the recurrence interval increases, by up to 80% less floodplain for exceptional events (>500 years). Finally, a management map is put forth combining the most reliable results available by integrating both methods. Originally presented at the Sixth International Conference on Geomorphology.  相似文献   
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The EPR spectra of Maxixe-type beryl contain a large number of overlapping signals. The angular dependence of the 1:3:3:1 signal typical for the CH3 radical shows that this radical is located at the center of the channel cavity with its symmetry axis parallel to the crystal c-axis and is rotating around this axis. Its EPR spectrum is axially symmetric with g // = 2.00263, g  = 2.00249 and A// = 2.288 mT, A = 2.256 mT. These anisotropies have the opposite signs of those found for surface-adsorbed methyl radicals. Hydrogen atoms are located at position 2a at the center of the beryl cavity and the EPR parameters of the narrow doublet signal are A 0 = 1,407 MHz and g = 2.00230. Another doublet signal, which is broader and has axial symmetry with g // = 2.00265, g  = 2.00625 and A// = 0.895 mT, A = 0.885 mT, could come from a HCO3 radical. One narrow and easily saturated signal with g // = 2.00227 and g  = 2.00386 is interpreted to arise from a carbon monoxide radical in the beryl channel, oriented with its axis parallel to the crystal c-axis. Additional weak doublet lines, which have similar g values as the carbon monoxide radical, are created by nearby hydrogens. A powder spectrum with g // = 2.0017 and g  = 2.0004 appears upon UV irradiation of the single crystal and is easily saturated. This spectrum is interpreted to arise from a carbon dioxide radical, which rotates around its symmetry axis.  相似文献   
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Summary Structural non-stationarity of surface roughness affects accurate morphological characterization as well as mechanical behaviour of rock joints at the laboratory scale using samples with a size below the stationarity threshold. In this paper, the effect of structural non-stationarity of surface roughness is investigated by studying the scale dependence of surface roughness and mechanical behaviour of rock joints. The results show that the structural non-stationarity mainly affects the accurate characterization of the surface roughness of the fracture samples. It also controls the amount and location of the contact areas during shear tests, which in turn affects the mechanical properties and asperity degradation of the samples. It is concluded that for accurate determination of the morphological and mechanical properties of rock joints at laboratory and field scales, samples with size equal to or larger than the stationarity threshold are required. Author’s address: Nader Fardin, Rock Mechanics Group, Department of Mining Engineering, Faculty of Engineering, University of Tehran, P.O. Box: 11365/4563, Tehran, Iran  相似文献   
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