Effects of the Chemical Compositions of Salars de Uyuni and Atacama Brines on Lithium Concentration during Evaporation   总被引：2，自引：0，他引：2  

Yasumasa Ogawa  Hiroshi Koibuchi  Koichi Suto  Chihiro Inoue 《Resource Geology》2014,64(2):91-101

During Li recovery from salar brines, Li concentration is typically increased to about 60,000 mg L^?1 by evaporation. We investigated the concentration changes of Li, Na, K, Mg, Cl, SO₄, and B during evaporation of both natural Uyuni and artificial Atacama brines. The Uyuni brine exhibited a maximum Li concentration of 6810 mg L^?1 at 31 days of evaporation, at which point the majority of the Na and K in the brine was removed. The Li concentration decreased with further evaporation due to precipitation as Li₂SO₄, such that the level at the 56 day mark was approximately 4130 mg L^?1. In contrast, the artificial Atacama brine showed no pronounced Li precipitation, even after 54 days, at which point the Li concentration was 21,800 mg L^?1. The initial concentrations of Na and K in the Atacama brine were higher than those in the Uyuni brine, and the Atacama solution still retained K after 54 days of evaporation. The order of precipitation of cation species during the evaporation of both brines was: Na, followed by K, Mg, and Li. Thus, Li precipitation in the Atacama brine might be prevented due to the more favored precipitations of Na and K, such that significant Li removal did not occur in this brine.  相似文献   

Pollen analyses from a 50 000‐yr rodent midden series in the southern Atacama Desert (25° 30′ S)     

Antonio Maldonado  Julio L. Betancourt  Claudio Latorre  Carolina Villagran 《第四纪科学杂志》2005,20(5):493-507

Precipitation in northern Chile is controlled by two great wind belts—the southern westerlies over the southern Atacama and points south (> 24° S) and the tropical easterlies over the northern and central Atacama Desert (16–24° S). At the intersection of these summer and winter rainfall regimes, respectively, is a Mars‐like landscape consisting of expansive surfaces devoid of vegetation (i.e. absolute desert) except in canyons that originate high enough to experience runoff once every few years. Pollen assemblages from 39 fossil rodent middens in one of these canyons, Quebrada del Chaco (25° 30′ S), were used to infer the history of vegetation and precipitation at three elevations (2670–2800 m; 3100–3200 m; 3450–3500 m) over the past 50 000 years. When compared to modern conditions and fossil records to the north and south, the pollen evidence indicates more winter precipitation at > 52, 40–33, 24–17 k cal. yr BP, more precipitation in both seasons at 17–14 k cal. yr BP, and more summer precipitation from 14–11 k cal. yr BP. Younger middens are scarce at Quebrada del Chaco, and the few Holocene samples indicate hyperarid conditions comparable to today. The only exception is a pollen assemblage that indicates a brief but significant interlude of increased winter precipitation in the last millennium. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Sublimation extraction coupled with gas chromatography-mass spectrometry: A new technique for future in situ analyses of purines and pyrimidines on Mars     

D.P. Glavin  H.J. Cleaves  A. Buch  M. Schubert  A. Aubrey  J.L. Bada  P.R. Mahaffy 《Planetary and Space Science》2006,54(15):1584-1591

We have developed a sublimation technique coupled with chemical derivatization and gas chromatography mass spectrometry (GC-MS) to detect nucleobases and other volatile organic compounds derived from bacteria in Mars analog materials. To demonstrate this technique, a sample of serpentine inoculated with Escherichia coli (E. coli) cells was heated to 500 °C for several seconds under Martian ambient pressure. The sublimate was collected on a cold finger, then derivatized and analyzed by GC-MS. We found that adenine, cytosine, thymine and uracil were the most abundant molecules detected in the sublimed E. coli extract by GC-MS. In addition, nucleobases were also detected in sublimed extracts of a deep-sea sediment sample, seawater, and soil collected from the Atacama Desert in Chile after heating the samples under the same conditions. Our results indicate that nucleobases can be easily isolated directly from natural samples using sublimation and then detected by GC-MS after chemical derivatization. The sublimation-based extraction technique is one approach that should be considered for use by future in situ instruments designed to detect organic compounds relevant to life in the Martian regolith.  相似文献   

The great Atacama flood of 2001 and its implications for Andean hydrology     

John Houston 《水文研究》2006,20(3):591-610

In February 2001, widespread flooding occurred throughout the Atacama Desert of northern Chile and southern Peru. It was particularly severe in the Río Loa basin, where roads and bridges were disrupted and the town of Calama inundated. The instantaneous peak flow in the Río Salado, a tributary of the Río Loa, reached 310 m³ s^?1, an order of magnitude higher than any previously recorded event. The flood is estimated to have a return period of 100–200 years and is shown to have been caused by intense, long‐duration rainfall in the western Cordillera associated with La Niña. The surface water response is typical of arid areas and highly dependent on antecedent conditions, but is quite different in perennial and ephemeral catchments. Ephemeral flood flows suffer high transmission losses, recharging phreatic aquifers. Perennial rivers have lower runoff coefficients, but baseflow levels remained high after the event for several months due to bank storage rebound and interflow. Extremely high energies of ～3000 W m^?2 were generated by the floods in the Cordillera, becoming less in the Precordillera and downstream. Erosion and sediment transport were consequently highest in the upper and middle reaches of the rivers, with mixed erosion‐deposition in the lowest reach. The new insights gained from the interpretation and quantification of this event have important implications for palaeoenvironmental analysis, hazard management, water resource evaluation and the palaeohydrological evolution of the Andes. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

The spatial and temporal variability of fog and its relation to fog oases in the Atacama Desert, Chile     

P. Cereceda  H. Larrain  P. Osses  M. Farías  I. Egaa 《Atmospheric Research》2008,87(3-4):312

Fog has been studied in the Atacama Desert of Chile for the past ten years. This paper analyzes its temporal and spatial variability, relying in part on satellite images (GOES) to analyze the frequent orographic fog and the low cloud deck (stratocumulus, Sc) that generates advective fog in the area. Fog water fluxes were measured with Standard Fog Collectors (SFC). Field trips and observers provided information on cloud top and base and the presence of fog. Vegetation in fog oases were used to confirm the results of these surveys.The Sc moves onshore into the continent with different intensities depending on season and time of day. The maximum spatial extent occurs during winter and at night. Fog is frequent in the coastal cliffs, where fog water fluxes of 7.0 L m^− 2 day^− 1 were measured using a SFC. It is less frequent 12 km inland, where the collection rates were less than 1 L m^− 2 day^− 1. The height of the fog collector above the ground affected the collection rate. The highest fog water fluxes were recorded at Alto Patache at altitudes of between 750 and 850 m a.s.l. The growth or thickness of the cloud is important in the collection of fog water. The information that GOES provides on the altitude of the top of low clouds is used to analyze this factor. Fog oases are described and analyzed in relation to how the geographical location of fog influences the growth of vegetation.  相似文献   

The climate of the coast and fog zone in the Tarapacá Region, Atacama Desert, Chile     

P. Cereceda  H. Larrain  P. Osses  M. Farías  I. Egaa 《Atmospheric Research》2008,87(3-4):301

In the Atacama Desert, the narrow littoral plain and the adjacent mountain range have a unique climate. This area is locally called the “coastal desert with abundant cloudiness”, and extends from the coastline up to an elevation of 1000 m. The climate is designated as being BWn according to Köppen's Climate Classification as adapted for Chile. In the original classification the acronym (Bn) is used for foggy environments. Toward the east a “normal desert” climate (BW) is found. This is known as one of the most extreme deserts of the world. In the BWn areas there are meteorological differences between low and high elevation zones. The climate of the coastal plains and the mountains is described in this paper in order to show that there is an area where the climate differs from those classified as BWn and BW in the Chilean Climate Classification. This area is located between 650 and 1200 m a.s.l. and contains several fog oases or lomas vegetation, rich in biodiversity and endemism.The weather is warmer near sea level, with an annual average temperature of 18 °C. At high elevation sites like Alto Patache, the temperature decreases at a rate of 0.7 °C for every 100-m increase in altitude. The average annual minimum temperature often approaches 1 °C in winter, while the mean annual temperature range is significant (8.3 °C in Los Cóndores). The mean monthly relative humidity in Alto Patache is over 80%, except during the summer months. During autumn, winter and spring high elevation fog is present in the study area at altitudes ranging from 650 m up to 1060 m, giving annual water yields of 0.8 to 7 L m^− 2 day^− 1. If vegetation is used as an indicator, the foggy zone lies between 650 m a.s.l. and 1200 m a.s.l. About 70% of the mountain range experiences the foggy climate, as opposed to the coastal plains that are characterized by a cloudy climate.  相似文献   

Late Quaternary vegetation and climate history of a perennial river canyon in the Río Salado basin (22°S) of Northern Chile     

Claudio Latorre  Julio L. Betancourt  Mary T.K. Arroyo 《Quaternary Research》2006,65(3):450-466

Plant macrofossils from 33 rodent middens sampled at three sites between 2910 and 3150 m elevation in the main canyon of the Río Salado, northern Chile, yield a unique record of vegetation and climate over the past 22,000 cal yr BP. Presence of low-elevation Prepuna taxa throughout the record suggests that mean annual temperature never cooled by more than 5°C and may have been near-modern at 16,270 cal yr BP. Displacements in the lower limits of Andean steppe and Puna taxa indicate that mean annual rainfall was twice modern at 17,520–16,270 cal yr BP. This pluvial event coincides with infilling of paleolake Tauca on the Bolivian Altiplano, increased ENSO activity inferred from a marine core near Lima, abrupt deglaciation in southern Chile, and Heinrich Event 1. Moderate to large increases in precipitation also occurred at 11,770–9550 (Central Atacama Pluvial Event), 7330–6720, 3490–2320 and at 800 cal yr BP. Desiccation occurred at 14,180, 8910–8640, and 4865 cal yr BP. Compared to other midden sites in the region, early Holocene desiccation seems to have happened progressively earlier farther south. Emerging trends from the cumulative midden record in the central Atacama agree at millennial timescales with improved paleolake chronologies for the Bolivian Altiplano, implying common forcing through changes in equatorial Pacific sea-surface temperature gradients.  相似文献   

Spatial characterization of land surface energy fluxes and uncertainty estimation at the Salar de Atacama,Northern Chile     

Stephanie K. Kampf  Scott W. Tyler 《Advances in water resources》2006

We use Advanced Spaceborne Thermal Emission and Reflection radiometer (ASTER) data to estimate spatial energy flux and evaporation distributions at the Salar de Atacama, a playa in Northern Chile. Our approach incorporates ASTER surface kinetic temperature, emissivity, and reflectance data, ground-based meteorological measurements, and empirical parameters. Energy flux distributions are estimated using either spatially constant or spatially distributed values of model parameters, with spatially distributed parameters assigned separately to each land cover category in an image classification. We test the sensitivity of energy budget calculations to state variable and parameter values by conducting Monte Carlo simulations for regions with ground energy budget measurements. Results show that assigning spatially distributed model parameters via land cover classifications yields significant improvements to ground and sensible heat flux predictions. Latent heat fluxes cannot, however, be predicted with sufficient accuracy to allow estimation of area-integrated evaporative moisture loss at this low-evaporation playa.  相似文献   

Evaporation and land surface energy budget at the Salar de Atacama, Northern Chile   总被引：3，自引：0，他引：3  

Stephanie K. Kampf  Scott W. Tyler  Cristin A. Ortiz  Jos F. Muoz  Paula L. Adkins 《Journal of Hydrology》2005,310(1-4):236-252

Playa systems are driven by evaporation processes, yet the mechanisms by which evaporation occurs through playa salt crusts are still poorly understood. In this study we examine playa evaporation as it relates to land surface energy fluxes, salt crust characteristics, groundwater and climate at the Salar de Atacama, a 3000 km² playa in northern Chile containing a uniquely broad range of salt crust types. Land surface energy budget measurements were taken at eight representative sites on this playa during winter (August 2001) and summer (January 2002) seasons. Measured values of net all-wave radiation were highest at vegetated and rough halite crust sites and lowest over smooth, highly reflective salt crusts. Over most of the Salar de Atacama, net radiation was dissipated by means of soil and sensible heat fluxes. Dry salt crusts tended to heat and cool very quickly, whereas soil heating and cooling occurred more gradually at wetter vegetated sites. Sensible heating was strongly linked to wind patterns, with highest sensible heat fluxes occurring on summer days with strong afternoon winds. Very little energy available at the land surface was used to evaporate water. Eddy covariance measurements could only constrain evaporation rates to within 0.1 mm d⁻¹, and some measured evaporation rates were less than this margin of uncertainty. Evaporation rates ranged from 0.1 to 1.1 mm d⁻¹ in smooth salt crusts around the margin of the salar and from 0.4 to 2.8 mm d⁻¹ in vegetated areas. No evaporation was detected from the rugged halite salt crust that covers the interior of the salar, though the depth to groundwater is less than 1 m in this area. These crusts therefore represent a previously unrecorded end member condition in which the salt crusts form a practically impermeable barrier to evaporation.  相似文献   

Fault zone development and strain partitioning in an extensional strike-slip duplex: A case study from the Mesozoic Atacama fault system, Northern Chile   总被引：3，自引：0，他引：3  

J. Cembrano  G. Gonzlez  G. Arancibia  I. Ahumada  V. Olivares  V. Herrera 《Tectonophysics》2005,400(1-4):105-125

Upper crustal strike-slip duplexes provide an excellent opportunity to address the fundamental question of fault zone development and strain partitioning in an evolving system. Detailed field mapping of the Mesozoic Atacama fault system in the Coastal Cordillera of Northern Chile documents the progressive development of second- and third-order faults forming a duplex at a dilational jog between two overstepping master faults: the sinistral strike-slip, NNW-striking, Jorgillo and Bolfin faults. These are constituted by a meter-wide core of foliated S-C ultracataclasite and cataclasite, flanked by a damage zone of protocataclasite, splay faults and veins. Lateral separation of markers along master faults is on the order of a few kilometers. Second-order, NW-striking, oblique-slip subsidiary fault zones do not show foliated ultracataclasite; lateral sinistral separations are in the range of  10 to 200 m with a relatively minor normal dip-slip component. In turn, third-order, east–west striking normal faults exhibit centimetric displacement. Oblique-slip (sinistral–normal) fault zones located at the southern termination of the Bolfin fault form a well-developed imbricate fan structure. They exhibit a relatively simple architecture of extensional and extensional-shear fractures bound by low displacement shear fractures. Kinematic analysis of fault slip data from mesoscopic faults within the duplex area, document that the NW-striking and the EW-striking faults accommodate transtension and extension, respectively. Examination of master and subsidiary faults of the duplex indicates a strong correlation between total displacement and internal fault structure. Faults started from arrays of en echelon extensional/extensional-shear fractures that then coalesced into throughgoing strike-slip faults. Further displacement leads to the formation of discrete bands of cataclasite and ultracataclasite that take up a significant part of the total displacement. We interpret that the duplex formed by progressive linkage of horsetail-like structures at the southern tip of the Bolfin fault that joined splay faults coming from the Jorgillo and Coloso faults. The geometry and kinematics of faults is compared with that observed in analog models to gain an insight into the kinematic processes leading to complex strike-slip fault zones in the upper crust.  相似文献