矿物流体包裹体中的羧酸     

曾贻善  刘家齐 《矿物岩石地球化学通报》1997,(1)

矿物流体包裹体中的羧酸曾贻善刘家齐（北京大学地质系，北京１００８７１）（地矿部宜昌地质矿产研究所，宜昌４４３００３）关键词矿物包裹体浸取液羧酸离子色谱分析分子中含有羧基官能团（—ＣＯＯＨ）的物质称为羧酸。Ｆｅｉｎ［１］和Ｓｈｏｃｋ［２］曾概述羧酸在自...  相似文献   

南极长城站地区粘土矿物的空间分布规律与成因探讨          下载免费PDF全文

李锋  李天杰 《极地研究》1997,9(4):56-60

对南极长城站地区粘土矿物的空间分布与某些元素的地球化学行为之间的相关关系给予了较为详细的研究，并从地球化学方面探讨了粘土矿物的成因。研究表明，Ｃａ和Ｍｇ元素是高岭石生成的主要控制因子，高岭石的空间分布是两者共同作用的结果。Ｓｉ、Ｃａ、Ｍｇ和Ｆｅ元素的地球化学行为与蒙脱石在空间上的含量变化有明显的相关关系。Ｓｉ元素对蒙脱石的生成起到了较大的作用。  相似文献   

四川盆地西部富钾卤水水文地球化学特征及其成因意义探讨   总被引：6，自引：0，他引：6  

林耀庭  颜仰基 《盐湖研究》1996,4(1):1-12

四川盆地西部宫钾卤水以深层卤水形式赋存于地下４０００余ｍ的中三叠统雷口坡组四段（Ｔ２ｌ４）盐系的碳酸盐岩储层中。富钾卤水与海水不同浓缩阶段相比，其中含Ｋ＋含量异常高，构成液态钾矿资源；Ｂｒ－、Ｉ－、Ｂ（３＋）、Ｌｉ＋等稀有组分也远超过综合利用工业品位，为优质化工原料水。富钾卤水为沉积变质和钾盐溶滤的复合成因，具有固夜态找钾的指示意义。本文为四川盆地固液态找钾提供了有价值的线索。  相似文献   

Stabilization of swelling clays by Mg(OH)₂. Changes in clay properties after addition of Mg-hydroxide     

G. S. Xeidakis 《Engineering Geology》1996,44(1-4):107-120

Stabilization of the swelling clay structure is attempted by intercalation of Mg(OH)₂ and the development of a brucite interlayer between the clay layers. The properties of the product obtained by applying the technique, formulated as described in a previous work, are considered here. The materials used were Wyoming bentonite (USA), Fuller's Earth (UK), kaolinite, illite, lignite, and silica gels. The Mg(OH)₂-clay products were examined by the methylene blue dye test, X-ray diffraction analysis (XRD), differential thermal analysis (DTA), and derivative thermogravimetry analysis (DTGA). From the results obtained it is concluded that: the Mg-hydroxide is adsorbed by swelling clays both on their external and internal surface, whereas it is adsorbed on the external surface by non-swelling clays. The internally adsorbed phase of Mg-hydroxide forms an ill-defined interlayer of brucite, retarding swelling, whereas the external phase covers the particles modifying drastically their surface properties, like the adsorption of the MB dye. The material produced after precipitation of Mg-hydroxide on swelling clays (smectites) did not re-expand on wetting or after glycolation. The adsorption of MB dye was also reduced by some 80–90%, due to coating effect, preventing the measurements of the external surface area of the clay by polar molecules. The principal forces involved in the process are believed to be physical adsorption on the external surface, along with chemisorption and some chemical bonding, mostly in the internal surface. Cementation due to crystallization and, in the long term, some pozzolanic reactions take also place. Internal adsorption of the Mg-hydroxide is postulated to be in the form of positively charged mono- and/or small polymers and it is, chiefly, diffusion controlled. Since Mg-hydroxide is internally adsorbed by swelling clays, whereas Ca-hydroxide(lime) is not, and the (Mg, Ca)-clay aggregates are more stable than the Ca-clay or the Mg-one, the combination of the two hydroxides could give better results in soil stabilization than each hydroxide alone.  相似文献   

安徽省大别山南部宿松杂岩变质作用研究   总被引：7，自引：13，他引：7  

魏春景  单振刚 《岩石学报》1997,13(3):356-368

宿松杂岩的变质作用可分为３个阶段：早期、主期和晚期阶段。主期阶段的矿物组合在云母片岩中为石榴石＋多硅白云母＋石英＋磁铁矿±钠云母±绿帘石／黝帘石；在白云母钠长（二长）片岩和片麻岩中为石榴石＋多硅白云母＋钠长石＋石英＋绿帘石／黝帘石±冻蓝闪石；在石榴石钠长角闪岩中为石榴石＋冻蓝闪石＋钠长石＋黝帘石＋石英±钠云母±金红石／磁铁矿。根据多种地质温压计和变质反应可以推测主期变质条件为：Ｔ＝５２０℃～５８０℃，Ｐ＝１．２～１．４ＧＰａ，地热梯度为１２℃／ｋｍ，相当于高压过渡型。晚期阶段变质条件为：Ｔ＝４６０℃～４８０℃，Ｐ＝０．６～０．７ＧＰａ，为中压绿帘角闪岩相。宿松杂岩的变质条件介于其南部的蓝闪绿片岩相和北部的榴辉岩相之间，三者是扬子板块向华北板块之下俯冲到不同深度的产物。  相似文献   

Application of an optimum design technique for determining the coefficient of consolidation by using piezocone test data   总被引：4，自引：0，他引：4  

Y.S. Kim  S.R. Lee  Y.T. Kim 《Computers and Geotechnics》1997,21(4):885-293

For normally consolidated clay, several researchers have developed a number of theoretical time factors to determine the coefficient of consolidation from piezocone test results. However, depending on assumptions and analytical techniques, it could vary considerably, even for a specific degree of consolidation. In this paper a method is proposed to determine a consistent coefficient of consolidation by applying the concept of an optimum design technique over all ranges of the degree of consolidation. Initial excess pore pressure distribution is assumed to be capable of being obtained by the successive spherical cavity expansion theory. The dissipation of pore pressure is simulated by means of a two-dimensional linear-uncoupled axi-symmetric consolidation analysis. The minimization of differences between measured and predicted excess pore pressure was carried out by the BFGS unconstrained optimum design algorithm with a one-dimensional golden section search technique. By analyzing numerical examples and in-situ test results, it was found that the adopted optimum design technique gives consistent and convergent results.  相似文献   

Suction-controlled experiments on Boom clay     

F. Bernier  G. Volckaert  E. Alonso  M. Villar 《Engineering Geology》1997,47(4):135-338

The understanding of the thermo-hydro-mechanical behaviour of a clay barrier is needed for the prediction of its final in situ properties after the hydration and thermal transient in a radioactive waste repository.

As part of the CEC 1990–1994 R&D programme on radioactive waste management and storage, the CEA (Fr), CIEMAT (Sp), ENRESA (Sp), SCK · CEN (B), UPC (Sp) and UWCC (UK) have carried out a joint project on unsaturated clay behaviour (Volckaert et al., 1996). The aim of the study is to analyse and model the behaviour of a clay-based engineered barrier during its hydration phase under real repository conditions. The hydro-mechanical and thermo-hydraulic models developed in this project have been coupled to describe stress/strain behaviour, moisture migration and heat transfer. A thermo-hydraulic model has also been coupled to a geochemical code to describe the migration and formation of chemical species.

In this project, suction-controlled experiments have been performed on Boom clay (B), FoCa clay (Fr) and Almeria bentonite (Sp). The aim of these experiments is to test the validity of the interpretive model developed by Alonso and Gens (Alonso et al., 1990), and to build a database of unsaturated clay thermo-hydro-mechanical parameters. Such a database can then be used for validation exercises in which in situ experiments are simulated.

The Boom clay is a moderately swelling clay of Rupellian age. It is studied at the SCK · CEN in Belgium as a potential host rock for a radioactive waste repository. In this paper, suction-controlled experiments carried out on Boom clay by SCK · CEN are described. SCK · CEN has performed experiments to measure the relation between suction, water content and temperature and the relation between suction, stress and deformation. The applied suction-control techniques and experimental setups are detailed. The results of these experiments are discussed in the perspective of the model of Alonso and Gens. The influence of temperature on water uptake was rather small. The measured swelling-collapse behaviour can be explained by the Alonso and Gens model.  相似文献   

江西永平铜矿金属矿物化学成份及矿物包体特征   总被引：4，自引：0，他引：4  

张学书 《江西地质》1997,11(2):40-48

永平铜矿黄铁矿、黄铜矿的化学成份特征以及矿物测温和石英包体成份分析特征表明成矿经历了一个较低温度阶段，但所反映的后期成矿作用的改造特征也非常明显，特征是闪锌矿，其化学成份具明显的后期改造成矿特征，是岩浆热作用的产物。黄铁矿的同生成矿较为明显，闪锌矿的后期改造成矿特征更为明显，而黄铜矿具有明显的沉积改造特征。  相似文献   

Accretion and exhumation at a Variscan active margin, recorded in the Saxothuringian flysch     

J. Schäfer  H. Neuroth  H. Ahrendt  W. Dörr  W. Franke 《International Journal of Earth Sciences》1997,86(3):599-611

The Saxothuringian flysch basin, on the north flank of the Central European Variscides, was fed and eventually overthrust by the northwestern, active margin of the Tepla-Barrandian terrane. Clast spectra, mineral composition and isotopic ages of detrital mica and zircon have been analyzed in order to constrain accretion and exhumation of rocks in the orogenic wedge. The earliest clastic sediments preserved are of early Famennian age (ca. 370?Ma). They are exposed immediately to the NW of the suture, and belong to the par-autochthon of the foreland. Besides ultramafic (?ophiolite) material, these rocks contain clasts derived from Early Paleozoic continental slope sediments, originally deposited at the NW margin of the Saxothuringian basin. These findings, together with the paleogeographic position of the Famennian clastics debris on the northwestern passive margin, indicate that the Saxothuringian narrow ocean had been closed by that time. Microprobe analyses of detrital hornblendes suggest derivation from the “Randamphibolit” unit, now present in the middle part of the Saxothuringian allochthon (Münchberg nappes). Detrital zircons of metamorphic rocks formed a little earlier (ca. 380?Ma) indicate rapid recycling at the tectonic front. The middle part of the flysch sequence (ca. early to middle Viséan), both in the par-autochthon and in the allochthon, contains abundant clasts of Paleozoic rocks derived from the northwestern slope and rise, together with debris of Cadomian basement, 500-Ma granitoids and 380?Ma (early Variscan) crystalline rocks. All of these source rocks were still available in the youngest part of the flysch (c. middle to late Viséan), but some clasts record, in addition, accretion of the northwestern shelf. Our findings permit deduction of minimum rates of tectonic shortening well in excess of 10–30?mm per year, and rates of exhumation of ca. 3?mm/a, and possibly more.  相似文献   

Magnetostratigraphy and palaeoclimate of Red Clay sequences from Chinese Loess Plateau   总被引：5，自引：0，他引：5  

Donghuai Sun  Dongsheng Liu  Mingyang Chen  Zhisheng An  Shaw John 《中国科学D辑(英文版)》1997,40(4):337-343

Two Red Clay profiles near Xi’an and Xifeng were investigated in an attempt to determine magnetostratigraphic and palaeoclimatic records. The results show that aeolian dust accumulation and the related East Asia palaeomonsoon system had begun by 6.5 Ma, and it is deduced that the Tibetan Plateau had reached a significant elevation at that time. The late Tertiary palaeoclimatic history of the Red Clay as reflected by magnetic susceptibility is reconstructed during the period of 6.5–2.5 Ma. Stepwise increase in susceptibility of aeolian dust accumulation appears to have a close correlation to the uplift processes of the Tibetan Plateau. The remarkable increase of aeolian dust accumulation at 3.2 Ma appears to be due to the influence of global ice volume on the East Asia monsoon. Palaeomonsoon variation during the late Tertiary as recorded in the Red Clay sequences from the Chinese Loess Plateau can be regarded as the product of a number of interacting factors, such as uplift of the Tibetan Plateau, solar radiation, global ice volume, etc. Project supported by the National Natural Science Foundation of China and the Foundation of Xi’an Laboratory of Loess and Quaternary Geology, Chinese Academy of Sciences.  相似文献