High‐Precision Measurement of 187Os/188Os Isotope Ratios of Nanogram to Picogram Amounts of Os in Geological Samples by N‐TIMS using Faraday Cups Equipped with 1013 Ω Amplifiers     

Guiqin Wang  Hauke Vollstaedt  Jifeng Xu  Wengui Liu 《Geostandards and Geoanalytical Research》2019,43(3):419-433

N(¹⁸⁷Os)/N(¹⁸⁸Os) ratios of six geological reference materials were measured using static Faraday cups (FCs) with 10¹³ Ω amplifiers by N‐TIMS. Our results show that the repeatability precision was 2–3‰ (2 RSD, n = 3), when taking ~ 1 g of BHVO‐2 with 76 pg g^?1 of Os mass fraction and ~ 2 g of BCR‐2 with 21 pg g^?1 of Os mass fraction for each sample, whether measured by FCs or by secondary electron multiplier. The repeatability precision measured by FCs was 1–0.2‰ (2 RSD, n = 3) when taking ~ 1 g of BIR‐2 with 350 pg g^?1 of Os mass fraction, ~ 1 g of WGB‐1 with 493 pg g^?1 of Os mass fraction or ~ 0.5 g of WPR‐1 with 13.3 ng g^?1 of Os mass fraction for each sample, which is much better than those measured by secondary electron multiplier. Instead, when taking ~ 2 g of AGV‐2 with 4 pg g^?1 Os mass fraction, the repeatability precision measured by secondary electron multiplier is 3–4‰ (RSD, n = 3), which is better than those measured by FCs. Of the six reference materials analysed, WPR‐1 and BIR‐1a are the most homogeneous with regard to Os isotopic composition (2 RSD of 0.08% and 0.23%, respectively) when test portion masses are 0.5–1 g.  相似文献   

利用碳酸盐岩的Fe/Mn比值恢复海洋的氧化还原状态     

蔡青青  闫宝强  王永志 《地质与资源》2019,28(2):160-164

碳酸盐岩的Fe/Mn元素比值,作为一项新的地球化学指标,可以用于恢复海洋的氧化还原状态.在氧化条件下,Fe³⁺和Mn⁴⁺均不可溶,因此氧化海水中的溶解Fe和Mn的含量均很低.Fe³⁺和Mn⁴⁺在还原条件下可以被细菌还原为可溶的Fe²⁺和Mn²⁺,而氧化还原电位的计算表明,Mn⁴⁺的还原要早于Fe³⁺的还原,因此细菌的Mn还原过程发生在沉积物的更浅层.可溶的Fe²⁺和Mn²⁺向上扩散到海水中,替代碳酸盐岩晶格里的Ca²⁺,因此碳酸盐岩晶格中的Fe²⁺和Mn²⁺的含量受控于来自沉积物孔隙水的扩散,而后者又与水岩界面的氧化还原状态相关.因此可以预测,随着海水变得逐渐缺氧,碳酸盐岩中的Fe/Mn比值会逐渐增高.为了验证这一假说,我们分析了中元古代高于庄组白云岩的Fe/Mn比值.研究发现,几乎所有的样品的Fe/Mn比值介于20～30之间,显著高于泥盆纪末期深水碳酸盐岩和浅水台地碳酸盐岩的Fe/Mn比值.高于庄组碳酸盐岩高的Fe/Mn比值一方面可能指示了中元古代低的大气氧气浓度和海洋的广泛缺氧,也可能反映了白云岩形成于缺氧的沉积物空隙水里.  相似文献   

四川盆地普光气田上二叠统长兴组表生岩溶特征及意义^*          下载免费PDF全文

杨飞  张洪安  王学军  彭君  莫建武  卓色强  曾正清  周凯  王运所  韦明洋  李宗峰  鲁锴 《古地理学报》2019,21(6):901-912

四川盆地二叠系和三叠系的接触关系以及长兴组岩溶成因的认识,地质界一直存在较大分歧。通过野外露头、钻井、岩心、成像测井、C-O同位素等资料研究发现,普光气田长兴组发育大规模溶沟、溶洞、囊状溶洞、岩溶角砾岩;P/T界线附近长兴组溶蚀灰岩碳同位素发生严重负偏移;长兴组顶见不整合面,成像测井岩溶相带划分明显;长兴组顶部存在地层缺失。综合分析认为,普光气田长兴组发生过表生岩溶作用,长兴阶晚期重大海退事件是引起表生岩溶的主要因素。长兴组长期接受表生岩溶作用的改造,除形成台地边缘礁滩相储集层外,在礁滩欠发育的台地内部和台地前缘上斜坡等区带,是寻找不整合岩溶储集层的有利地区。  相似文献   

科马提岩与苦橄岩的区别及对若干晚古生代“科马提岩”的质疑     

李振焕  刘学龙  朱月琴  张旗  罗应  张昌振  陈建航  王帅帅  杨富成 《地质通报》2019,38(12):1971-1980

以往学术界更多的关注科马提岩和苦橄岩的相似性,忽略其差异。通过全数据模式,采集数据库内全球的太古宙科马提岩、后太古宙低/高钛苦橄岩数据,对比三者之间的差异发现,科马提岩更富MgO、Cr、Ni、Cs、Pb、Co和Zn,其次为低钛苦橄岩(除Co和Zn),其余主量、微量元素的含量由高至低依次为高钛苦橄岩、低钛苦橄岩、科马提岩。依据元素间的差异(如Cr/Ga、MgO/Ga、MnO/Zr、Cr/Zr等),采用密度分布函数(Density Distribution)在Matlab软件中绘制出可有效区分3类岩石的等密度判别图,并用该图对若干晚古生代"科马提岩"的岩性重新厘定。结合岩相学和地球化学特征研究表明,晚古生代"科马提岩"中,印度东部为高钛苦橄岩,越南为化学成分与科马提岩类似的低钛苦橄岩,印度拉达克地区为低钛苦橄岩。  相似文献   

覆盆子-红花药对与男性不育症的治疗相关机制探讨          下载免费PDF全文

曾小艳  童丽 《应用海洋学学报》2021,37(1):147

目的：基于网络药理学探讨覆盆子-红花药对治疗男性不育症的物质基础及作用机制。方法：用TCMSP数据库检索覆盆子、红花,收集其化学成分以及靶点信息;用GeneCards和OMIM数据库筛选男性不育症的疾病靶点;应用韦恩图筛选药物与疾病的共同靶点;应用R软件进行GO富集分析及KEGG分析;应用 Cytoscape 3.7.2 软件构建药物-活性成分-疾病-靶点互作网络。结果：从覆盆子、红花得到了22个活性成分及202个药物靶点。在药物-活性成分-疾病-靶点互作网络中,degree值较高的为槲皮素及木犀草素,表明覆盆子-红花药对治疗男性不育症的主要活性成分可能为槲皮素、木犀草素等。覆盆子-红花药对治疗男性不育症的可能靶点有131个,其中核心靶点为ALB、AKT1、IL-6、VEGFA、JUN等,这些靶点主要与氧化及抗氧化生物等生物学过程相关。覆盆子-红花药对的靶点主要通过P13K/Akt信号通道治疗男性不育症。结论：覆盆子-红花药对通过多靶点、多途径治疗男性不育症。本研究为开展覆盆子-红花药对治疗男性不育症的实验提供了理论基础,为男性不育症的治疗提供了更多的思路。  相似文献   

Evaluation of riverbed magnetic susceptibility for mapping biogeochemical hot spots in groundwater-impacted rivers     

Chen Wang  Martin A. Briggs  Frederick D. Day-Lewis  Lee D. Slater 《水文研究》2021,35(5):e14184

Redox hot spots occurring as metal-rich anoxic groundwater discharges through oxic wetland and river sediments commonly result in the formation of iron (Fe) oxide precipitates. These redox-sensitive precipitates influence the release of nutrients and metals to surface water and can act as ‘contaminant sponges’ by absorbing toxic compounds. We explore the feasibility of a non-invasive, high-resolution magnetic susceptibility (MS) technique to efficiently map the spatial variations of magnetic Fe oxide precipitates in the shallow bed of three rivers impacted by anoxic groundwater discharge. Laboratory analyses on Mashpee River (MA, USA) sediments demonstrate the sensitivity of MS to sediment Fe concentrations. Field surveys in the Mashpee and Quashnet rivers (MA, USA) reveal several discrete high MS zones, which are associated with likely anoxic groundwater discharge as evaluated by riverbed temperature, vertical head gradient, and groundwater chemistry measurements. In the East River (CO, USA), widespread cobbles/rocks exhibit high background MS from geological ferrimagnetic minerals, thereby obscuring the relatively small enhancement of MS from groundwater induced Fe oxide precipitates. Our study suggests that, in settings with low geological sources of magnetic minerals such as lowland rivers and wetlands, MS may serve as a complementary tool to temperature methods for efficiently mapping Fe oxide accumulation zones due to anoxic groundwater discharges that may function as biogeochemical hot spots and water quality control points in gaining systems.  相似文献   

Modelling the internal stress field in argillaceous rocks under humidification/desiccation     

L.L. Wang  A. Pouya  M. Bornert  B. Halphen 《国际地质力学数值与分析法杂志》2014,38(16):1664-1682

This paper deals with analytical and numerical modelling of the internal stress generated in argillaceous rocks during humidification/desiccation processes, which is an essential issue for damage study. This local stress field arises from two mechanisms: (i) complex interactions between free swelling/shrinking clay matrix and non‐strained inclusions of carbonate and quartz and (ii) a self‐restraint effect induced by the moisture gradient during the transient moisture exchange process. The inclusion–matrix interaction is investigated in different cases. Firstly, the analytical solution of the stress around a cylindrical inclusion embedded in an infinite swelling matrix is derived: The inclusion would suffer tension (compression) under humidification (desiccation), and the resulting cracking patterns are discussed. Then, the problem of two inclusions with different distances in an infinite swelling matrix is considered, and it is shown that the local stress around an inclusion will be perturbed and amplified by neighbouring inclusions. Finally, an inclusion outcropping at the free surface of a swelling matrix is modelled as to investigate the effect of free surface: The inclusion–matrix interface undergoes shear stresses of which the maximum is found at the free surface. In addition to the inclusion–matrix interaction, the self‐restraint effect is investigated: The induced stress is maximal at the beginning of humidification/desiccation processes and vanishes gradually with time. The quantity of the self‐restraint stress is strongly controlled by the hydric loading rate. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Influence of dissolution/reprecipitation reactions on metamorphic greenschist to amphibolite facies mica 40Ar/39Ar ages in the Longmen Shan (eastern Tibet)          下载免费PDF全文

Laura Airaghi  Clare J. Warren  Julia de Sigoyer  Pierre Lanari  Valérie Magnin 《Journal of Metamorphic Geology》2018,36(7):933-958

Linking ages to metamorphic stages in rocks that have experienced low‐ to medium‐grade metamorphism can be particularly tricky due to the rarity of index minerals and the preservation of mineral or compositional relicts. The timing of metamorphism and the Mesozoic exhumation of the metasedimentary units and crystalline basement that form the internal part of the Longmen Shan (eastern Tibet, Sichuan, China), are, for these reasons, still largely unconstrained, but crucial for understanding the regional tectonic evolution of eastern Tibet. In situ core‐rim ⁴⁰Ar/³⁹Ar biotite and U–Th/Pb allanite data show that amphibolite facies conditions (~10–11 kbar, 530°C to 6–7 kbar, 580°C) were reached at 210–180 Ma and that biotite records crystallization, rather than cooling, ages. These conditions are mainly recorded in the metasedimentary cover. The ⁴⁰Ar/³⁹Ar ages obtained from matrix muscovite that partially re‐equilibrated during the post peak‐P metamorphic history comprise a mixture of ages between that of early prograde muscovite relicts and the timing of late muscovite recrystallization at c. 140–120 Ma. This event marks a previously poorly documented greenschist facies metamorphic overprint. This latest stage is also recorded in the crystalline basement, and defines the timing of the greenschist overprint (7 ± 1 kbar, 370 ± 35°C). Numerical models of Ar diffusion show that the difference between ⁴⁰Ar/³⁹Ar biotite and muscovite ages cannot be explained by a slow and protracted cooling in an open system. The model and petrological results rather suggest that biotite and muscovite experienced different Ar retention and resetting histories. The Ar record in mica of the studied low‐ to medium‐grade rocks seems to be mainly controlled by dissolution–reprecipitation processes rather than by diffusive loss, and by different microstructural positions in the sample. Together, our data show that the metasedimentary cover was thickened and cooled independently from the basement prior to c. 140 Ma (with a relatively fast cooling at 4.5 ± 0.5°C/Ma between 185 and 140 Ma). Since the Lower Cretaceous, the metasedimentary cover and the crystalline basement experienced a coherent history during which both were partially exhumed. The Mesozoic history of the Eastern border of the Tibetan plateau is therefore complex and polyphase, and the basement was actively involved at least since the Early Cretaceous, changing our perspective on the contribution of the Cenozoic geology.  相似文献   

Large‐scale connectivity of fluvio‐deltaic stratigraphy: Inferences from simulated accommodation‐to‐supply cycles and automated extraction of chronosomes     

Pantelis Karamitopoulos  Gert J. Weltje  Rory A. F. Dalman 《Basin Research》2021,33(1):382-402

Multiscale simulation of fluvio‐deltaic stratigraphy was used to quantify the elements of the geometry and architectural arrangement of sub‐seismic‐scale fluvial‐to‐shelf sedimentary segments. We conducted numerical experiments of fluvio‐deltaic system evolution by simulating the accommodation‐to‐sediment‐supply (A/S) cycles of varying wavelength and amplitude with the objective to produce synthetic 3‐D stratigraphic records. Post‐processing routines were developed in order to investigate delta lobe architecture in relation to channel‐network evolution throughout A/S cycles, estimate net sediment accumulation rates in 3‐D space, and extract chronostratigraphically constrained lithosomes (or chronosomes) to quantify large‐scale connectivity, that is, the spatial distribution of high net‐to‐gross lithologies. Chronosomes formed under the conditions of channel‐belt aggradation are separated by laterally continuous abandonment surfaces associated with major avulsions and delta‐lobe switches. Chronosomes corresponding to periods in which sea level drops below the inherited shelf break, that is, the youngest portions of the late falling stage systems tract (FSST), form in the virtual absence of major avulsions, owing to the incision in their upstream parts, and thus display purely degradational architecture. Detailed investigation of chronosomes within the late FSST showed that their spatial continuity may be disrupted by higher‐frequency A/S cycles to produce “stranded” sand‐rich bodies encased in shales. Chronosomes formed during early and late falling stage (FSST) demonstrate the highest large‐scale connectivity in their proximal and distal areas, respectively. Lower‐amplitude base level changes, representative of greenhouse periods during which the shelf break is not exposed, increase the magnitude of delta‐lobe switching and favour the development of system‐wide abandonment surfaces, whose expression in real‐world stratigraphy is likely to reflect the intertwined effects of high‐frequency allogenic forcing and differential subsidence.  相似文献   

1961—2017年北疆初终霜日及霜期时空变化特征     

张鑫  楼俊伟  王勇  王智楷 《干旱区地理》2021,44(2):308-315

利用1961—2017年北疆37个地面气象站逐日最低气温观测资料,结合常规气象统计方法,分析北疆地区初、终霜日和霜期的时空演变特征。结果表明:(1)北疆平均初霜日以2.2 d·(10a)^-1速率推迟;平均终霜日以1.7 d·(10a)^-1速率提前;平均霜期以3.9 d·(10a)^-1速率缩短;初、终霜日和霜期的主周期均为2 a左右。(2)北疆霜期缩短趋势较大(小)的地区,能较好的对应其初霜日推迟、终霜日提前较强(弱),伊犁州、塔城地区北部及东天山东北部霜期的缩短趋势最为显著,博州至天山北坡一线居中,阿勒泰地区霜期的缩短趋势最弱。(3)北疆大部分地区初霜日的变化趋势与海拔高度有很好的相关性,其初霜日的推迟速度随海拔高度的增加而减小,垂直递减率为-0.077 d·(a·km)^-1;秋季气候变暖是初霜日推迟的主要原因,春、秋季气候变暖同时影响霜期缩短,且秋季的影响更大。  相似文献