中国大陆科学钻探主孔榴辉岩中石榴石和绿辉石原位激光探针分析及其成岩成矿指示意义   总被引：1，自引：0，他引：1  

邱检生王汝成  蒋少涌张晓琳  胡建倪培 《岩石学报》2007,23(12):3221-3230

本文以中国大陆科学钻探主孔0～2000m岩芯中的榴辉岩为对象,运用EMPA和LA-ICP-MS技术,系统测定了榴辉岩中石榴石和绿辉石的主量与微量元素组成,并据此讨论了它们的成岩成矿意义.研究结果表明,CCSD主孔榴辉岩中石榴石富重稀土和Sc、Y、Co,而绿辉石则富中稀土和Pb、Sr、V,石榴石和绿辉石的高场强元素(特别是Nb、Ta)含量均很低.石榴石存在不同程度的Ce负异常,指示榴辉岩的形成过程中卷入有地表氧化条件下形成的风化沉积物.石榴石具有低的Zr/Y比值,绿辉石普遍具有高的Sr含量,这些特征说明榴辉岩(特别是高钛榴辉岩)的原岩可能为遭受过壳源物质混染与交代的富集地幔部分熔融的产物.高钛与低钛榴辉岩中石榴石和绿辉石在主量及微量元素组成上存在一定差别,总体而言,高钛榴辉岩中石榴石具高的MgO含量和较高的MgO/TFeO比值,以及较高的稀土和Sc含量,而绿辉石则相对富TFeO、MnO,并具有较高的Sr、Zr、Hf含量.高钛榴辉岩中石榴石和绿辉石常出现不同程度的Eu正异常,Cr含量均显著低于低钛榴辉岩.综合分析表明,高钛榴辉岩的原岩最可能为富斜长石的辉长质侵入岩,原岩组成的差异应是导致二类榴辉岩中石榴石和绿辉石矿物化学组成存在差异的主要原因.  相似文献   

萃取分离—石墨炉原子吸收光谱法测定铅锌矿中的铟     

赵星  张代云  刘锐 《云南地质》2014,33(3):417-420

样品经硝酸、氢氟酸分解除硅,加热硫酸冒烟除尽硝酸、氢氟酸,利用铟与氢溴酸能生成稳定的络合物并被乙酸丁酯萃取的性质,将铟与其它干扰离子分离并富集.使用MOLAARM6（Thermo Electron Corporation）石墨炉原子吸收分光光度计,以钒为机体改进剂,测定铅锌矿中的铟.方法检出限为LD=0.012ug/ml.实验结果令人满意.  相似文献   

Metasomatic effects related to channelled fluid streaming through deep crust: fenites and associated carbonatites (In Ouzzal Proterozoic granulites, Hoggar, Algeria)     

S. FOURCADE  J.-R. KIENAST  K. OUZEGANE 《Journal of Metamorphic Geology》1996,14(6):763-781

The In Ouzzal granulitic unit (IOGU) consists predominantly of felsic orthogneisses most of which correspond to granitoids emplaced during the Archaean, plus metasediments, including olivine-spinel marbles, of late Archaean age. All units were metamorphosed at granulite facies during the Eburnean (2 Ga). The stable isotope signature of the marbles (δ¹³C=–0.8 to –4.2‰/PDB; δ¹⁸O = 7.9 to 18.9‰/SMOW) does not record a massive streaming of C-bearing fluids during metamorphism. Most of the isotopic variation in the marbles is explained in terms of pregranulitic features. Metasomatic transformation of granulites into layered potassic syenitic rocks and emplacement of carbonate veins and breccias occurred during retrogressive granulite facies conditions. The chemistry of these rocks is comparable with that of fenites and carbonatites with high contents of (L)REEs, Th, U, F, C, Ba and Sr but, with respect to these elements, a relative depletion in Nb, Ta, Hf, Zr and Ti. The isotopic compositions of Nd (?Nd_(T)=–6.3 to –9.9), of Sr (⁸⁷Sr/⁸⁶Sr_(T)= 0.7093–0.7104), and the O isotopic composition of metasomatic clinopyroxene (δ¹⁸O = 6.9 to 8‰), all indicate that the fluid had a strong crustal imprint. On the basis of the C isotope ratios (δ¹³C =–3.5 to –9.7‰), the fluid responsible for the crystallization of carbonates and metasomatic alteration is thought to be derived from the mantle, presumably through degassing of mantle-derived magmas at depth. Intense interaction with the crust during the upward flow of the fluid may explain its chemical and isotopic signatures. The zones of metasomatic alteration in the In Ouzzal granulites may be the deep-seated equivalents of the zones of channelled circulation of carbonated fluids described at shallower levels in the crust.  相似文献   

中国地质学会公布第三届科普奖评选结果     

孙莉莉  高梦瑶 《地质论评》2022,68(5):1603-1771

为推动中国地质学会地学科普研学工作的开展,根据 《中国地质学会精品地学研学路线、课程评选办法(试行)》, 学会组织开展了第二批精品地学研学路线、第一批精品地学 研学课程的申报、推荐和评审工作。  相似文献   

Gedrite–garnet–sillimanite-bearing granulites from Amessmessa area, south In Ouzzal, Hoggar, Algeria     

K. OUZEGANE  S. DJEMAI  M. GUIRAUD 《Journal of Metamorphic Geology》1996,14(6):739-753

Some granulites from the Amessmessa area (south In Ouzzal unit, Hoggar) contain the peak assemblage gedrite+garnet+sillimanite+quartz that was used to estimate the P–T conditions of metamorphism. The rocks developed symplectites and corona textures by the breakdown of the primary paragenesis to orthopyroxene, cordierite and spinel. The successive parageneses formed in separate microdomains according to a clockwise P–T path. Geothermometry, geobarometry and phase diagram calculations indicate that the textures formed by decompression and cooling from 7–9 kbar and 850–900°C to 3.5–4.5 kbar and 700–800°C. This P–T evolution is consistent with low to medium a_H2O, between 0.4 and 0.7, and is similar to the metamorphic conditions deduced in Al–Mg granulites from the north of In Ouzzal.  相似文献   

In situ measurements of contributions to the global electrical circuit by a thunderstorm in southeastern Brazil     

Jeremy N. Thomas  Robert H. Holzworth  Michael P. McCarthy 《Atmospheric Research》2009,91(2-4):153-160

The global electrical circuit, which maintains a potential of about 280 kV between the earth and the ionosphere, is thought to be driven mainly by thunderstorms and lightning. However, very few in situ measurements of electrical current above thunderstorms have been successfully obtained. In this paper, we present dc to very low frequency electric fields and atmospheric conductivity measured in the stratosphere (30–35 km altitude) above an active thunderstorm in southeastern Brazil. From these measurements, we estimate the mean quasi-static conduction current during the storm period to be 2.5 ± 1.25 A. Additionally, we examine the transient conduction currents following a large positive cloud-to-ground (+ CG) lightning flash and typical − CG flashes. We find that the majority of the total current is attributed to the quasi-static thundercloud charge, rather than lightning, which supports the classical Wilson model for the global electrical circuit.  相似文献   

The Moon 35 years after Apollo: What's left to learn?   总被引：1，自引：0，他引：1  

Clive R. Neal 《Chemie der Erde / Geochemistry》2009,69(1):3-48

With the cancellation of the Apollo program after Apollo 17 returned from the Moon in 1972, the focus of NASA switched to other areas of the Solar System. Study of the Moon did continue through analysis of the returned samples and remotely sensed data sets (both orbital and surface), as well as through Earth-based telescopic studies. In the 1990s, new orbital data were obtained from several missions (fly-by and orbital), the first being Galileo that allowed the lunar farside to be mapped, followed by global mapping by the Clementine and Lunar Prospector missions.Interest in the Moon started to increase at the beginning of the 21st century as other nations focused their space exploration programs on the Moon. The speech by President Bush in January 2004 put the Moon back into the critical exploration path for NASA, paving the way for humans to return to the lunar surface by 2020. This return will be critical for developing technologies and protocols for the eventual human exploration of other parts of the solar system. At the time of writing (June 2008), the SELENE/Kaguya mission (Japan and Chang’e-1 (China) are orbiting the Moon, with Chandrayaan-1 (India) and Lunar Reconnaissance Orbiter (USA) being scheduled to launch later in 2008.The past (and present) exploration of the Moon begs the question “what's left to be done?” With the renewed focus on the Moon, now that it is on the pathway for the exploration of Mars (and beyond) a similar question has been raised - what should the astronauts do on the Moon? The publication of the New Views of the Moon book [Jolliff et al., 2006. New Views of the Moon, Reviews in Mineralogy, vol. 60. American Mineralogical Society, 721pp] highlighted a number of important scientific questions that remain unanswered as well as posing many more on the basis of the currently available data. These questions resonated in three Lunar Exploration Analysis Group (LEAG) reports pertinent to this discussion, which were also published (on line) during 2006 (http://www.lpi.usra.edu/leag), and in the National Research Council of the National Academies [2007. The Scientific Context for Exploration of the Moon. National Academies Press, Washington, DC, 112pp] report entitled “The Scientific Context for Exploration of the Moon”. This paper synthesizes these recent studies, along with those from the 1980s and 1990s, to emphasize the lunar science questions that remain unanswered. In addition, it summarizes the missions already flown to the Moon along with those that are planned in order to give the reader an idea of exactly what lunar science has been and will be conducted in the hope that it will inspire proposals for missions to address the outstanding science questions.  相似文献   

土钉支护现场测试及三维数值模拟分析   总被引：12，自引：3，他引：9  

李志刚秦四清  张冰峰 《工程地质学报》2004,12(1):69-73

在进行土钉轴力和边坡位移测试的基础上 ,进行了土钉支护的三维数值模拟研究 ,对边坡位移、土钉轴力、塑性区分布等分别作了较为深入的探讨 ,认识到土钉与土体相互作用形成了一个完整的支护体系 ;基坑失稳破坏并非传统意义上的土体和土钉的破坏 ,而是土钉支护体系的整体性破坏 ;土钉支护体系的形成正是通过土钉的分担作用、应力传递与扩散作用来实现的 ,这是土钉支护作用的实质.  相似文献   

Identification of the Hualien soil-structure interaction system     

C. -B. Yun  J. -S. Choi  J. -M. Kim 《Soil Dynamics and Earthquake Engineering》1999,18(6):689

This article demonstrates how system identification techniques can be successfully applied to a soil-structure interaction system in conjunction with the results of the forced vibration tests on the Hualien large-scale seismic test structure which was recently built in Taiwan for an international joint research. The parameters identified are the shear moduli of several near-field soil regions as well as Young's moduli of the shell sections of the structure. The soil-structure interaction system is represented by the finite element method combined with infinite element formulation for the unbounded layered soil medium. Preliminary investigations are carried out on the results of the static stress analysis for the soil medium and the results of the in-situ tests to divide the soil-structure system into several regions with homogeneous properties and to determine the lower and upper bounds of the parameters for the purpose of identification. Then two sets of parameters are identified for two principal directions based on the forced vibration test data by minimizing the estimation error using the constrained steepest descent method. The simulated responses for the forced vibration tests using the identified parameters show excellent agreement with the test data. The present estimated parameters are also found to be well compared with the average value of those by other researchers in the joint project.  相似文献   

High temperature dehydroxylation of muscovite-2M1: a kinetic study by in situ XRPD     

E. Mazzucato  G. Artioli  A. Gualtieri 《Physics and Chemistry of Minerals》1999,26(5):375-381

Muscovite-2M₁ shows a major phase transition at about 800°C, which is generally attributed in the literature to the structural dehydroxylation process, although a number of structural models have been proposed for the dehydroxylated phase, and different transformation mechanisms have also been put forward. The observed first order transformation involves an increase in the cell volume, and it is not clear to date how the cell expansion is related to the loss of hydroxyl groups. The phase change has been re-investigated here by in situ high temperature powder diffraction, both in non-isothermal and isothermal modes, to combine for the first time the structural and the kinetic interpretation of the transformation. The results unequivocally confirm that the reaction taking place in the temperature range 700–1000°C is truly a dehydroxylation process, involving the nucleation and growth of the high temperature dehydroxylated phase, having Al in 5-fold coordination. Structural simulations of the basal peaks of the powder diffraction patterns indicate that the model originally proposed by Udagawa et al. (1974) for the dehydroxylated phase correctly describes the high temperature phase. The kinetic analysis of the isothermal data using an Avrami-type model yields values for the reaction order compatible with a reaction mechanism limited by a monodimensional diffusion step. Apparent activation energy of the process in vacuum is about 251 kJ/mol. Experiments carried out at temperatures much higher than the onset temperature of the reaction show that the dehydroxylation reaction overlaps with the reaction of formation of mullite, the final product in the reaction pathway. Received: 24 April 1998 / Revised, accepted: 12 October 1998  相似文献