地质样品中高精度铬同位素分析纯化技术研究进展   总被引：1，自引：1，他引：0  

史凯  朱建明  吴广亮  王静  曾理 《岩矿测试》2019,38(3):341-353

随着多接收器热电离质谱仪(MC-TIMS)和多接收器电感耦合等离子体质谱仪(MC-ICP-MS)的发展,高精度铬(Cr)同位素测试已成为可能。铬同位素在地球、环境、农业生态和宇宙化学等科学领域中已显示出良好的应用潜力。然而,样品的纯化分离、干扰和仪器质量分馏的校正,依然是制约铬同位素高精度测试的重要因素。本文在近年来铬同位素分析技术最新进展的基础上,结合本课题组已有的研究,对陨石、地质和环境等各类样品中铬同位素的分离纯化方法、MC-ICP-MS测试中干扰与质量歧视校正等进行了详细综述。本文认为,阴阳离子树脂交换联用与过硫酸钾等强氧化剂的结合,可以进行低铬高基质样品的有效纯化,是一种较为普适性的纯化方法。使用铬同位素双稀释剂校正质量歧视效应,在MC-ICP-MS的中高分辨与静态测量模式下,不仅可以有效分开多原子离子的干扰,而且也可以进行高精度铬同位素分析,其δ~(53/52)Cr的分析精度与TIMS相当,可以达到0.04‰(2SD),且最低测试浓度可低至10ng,能够实现超微量铬的同位素分析。  相似文献   

Hydrofluoric Acid‐Free Digestion of Geological Samples for the Quantification of Rare Earth Elements by Inductively Coupled Plasma‐Optical Emission Spectrometry     

Andrey Linhares Bezerra de Oliveira  Júlio Carlos Afonso  Lilian da Silva  Arnaldo Alcover Neto  Manuel Castro Carneiro  Lílian Irene Dias da Silva  Maria Inês Couto Monteiro 《Geostandards and Geoanalytical Research》2019,43(4):689-699

Rare earth elements (REEs) are very important to technological development as well as to geochemical and environmental studies. In this work, hydrofluoric acid (HF) was replaced by condensed phosphoric acid (CPA) in the digestion of geological samples, and the quantification of REEs was performed by inductively coupled plasma‐optical emission spectrometry (ICP‐OES). Six international reference materials (RMs), named DC86318, CGL 111, CGL 124, CGL 126, OKA‐2 and COQ‐1 and three Brazilian ore samples, named Araxá, Catalão and Pitinga were analysed. Only zircon and xenotime, which are potential REE‐bearing minerals, were not completely dissolved. Nevertheless, no REE associated with zircon was detected. The investigated digestion method presented many advantages: It was relatively fast (3 h), avoided fluoride precipitation, it was less hazardous because handling diluted H₃PO₄ is safer than HF, NH₄F or NH₄HF₂ aqueous solutions, it preserved the quartz fittings of the measurement equipment and the final solution contained lower levels of total dissolved solids than those produced by the fusion method.  相似文献   

从中国、美国、欧洲抗震设计规范谱的比较 探讨我国的抗震设计反应谱   总被引：2，自引：0，他引：2  

余湛  石树中  沈建文  刘峥 《震灾防御技术》2008,3(2):136-144

本文分析了中国、美国、欧洲 3 种抗震设计规范的地震动参数取值,并比较了 3 种抗震设计反应谱。结果表明,总体上说,欧洲、美国规范的加速度短周期反应谱高于中国规范。但随着周期的扩大,由于中国规范中反应谱的下降指数较小,导致了中国规范中的反应谱逐渐接近并可能超过了欧洲、美国规范。本文的结果可为我国未来抗震设计规范修订,以及地震安全性评价工作中确定设计反应谱提供参考。  相似文献   

中国北方森林群落现代花粉与植被和气候的关系   总被引：3，自引：0，他引：3  

李月丛  许清海  王学丽  曹现勇  阳小兰 《地理学报》2008,63(9):945-957

来自中国北方10 座山地16 个森林群落53 个样点的表土和Tauber 捕捉器花粉研究揭示了中国北方森林群落的花粉组合特征及其与植被和气候的关系。捕捉器花粉组合与表土花粉组合具有较好的相似性, 花粉组合中共有类型80 个, 共有类型花粉百分比占总数的90%以上, 植被中的优势种通常也是花粉组合的主要类型。松林中松花粉浓度和通量均较高, 表明花粉产量与保存能力均较高; 云、冷杉林中云、冷杉花粉通量较低, 但花粉浓度较高, 显示虽然花粉产量较低, 但花粉保存能力较好; 栎林、桦林中, 栎属和桦属花粉通量较高, 但花粉浓度较低, 说明虽然花粉产量较高, 但花粉保存能力较差。花粉与植被关系判别分析表明, 表土样品与捕捉器花粉组合均能较好地反映不同区域森林群落特征及其差异, 但表土样品能 更好地反映植被的优势成分。花粉组合与样点气候因子的DCCA 分析表明, 花粉组合与最冷月温度相关最显著(相关系数: 捕捉器0.84, 表土0.72), 其次为年降水量(相关系数: 捕捉 器0.73, 表土0.71)。  相似文献   

陕西陇县李家下滑坡稳定性分析   总被引：1，自引：0，他引：1  

李东林  吴树仁  韩金良  刘景儒 《煤田地质与勘探》2008,36(6):42

李家下滑坡是大型岩质滑坡,发育在黄土滑坡众多的黄土高原区。基于野外地质调查、工程地质勘探和室内岩土体分析测试及土工试验,利用Ansys有限元软件对3种气候条件及3种滑带土强度条件下李家下滑坡的稳定性进行了模拟分析。模拟结果表明:滑带土强度参数的改变对李家下滑坡的稳定性有极大的影响,李家下滑坡已处于不稳定状态。结合李家下滑坡最新的变形现象,认为沿主滑带再次滑动的可能性较大。   相似文献   

对虾样品中Pb、cd的微波消解与常规消解分析方法比较研究   总被引：8，自引：0，他引：8  

徐维海  江志刚  朱校斌  王新亭  马绪丽 《海洋科学》2005,29(6):38-41

采用微波消解与常规消解2种方法消解对虾样品,石墨炉原子吸收法(GFAAS)测定其Pb、Gd的含量,对样品中Pb、Cd的微波消解与常规消解分析方法做了系统的比较。结果表明。微波消解法准确度、精密度以及回收率的准确度等与常规消解法相比均有较大幅度的提高。  相似文献   

胶州湾营养盐结构的长期变化及其对生态环境的影响   总被引：48，自引：10，他引：48  

沈志良 《海洋与湖沼》2002,33(3):322-331

根据 1 962年— 1 998年 81个航次的调查和历史资料 ,讨论了胶州湾营养盐及其结构的长期变化和对生态环境的影响。近 40年来 ,胶州湾无机N和P浓度分别增加了 3.9倍和1 .4倍 ,DIN/PO4 P摩尔比从 1 5 .9± 6.3增加到 37.8± 2 2 .9,SiO3 Si浓度保持在一个很低的水平。高的DIN/PO4 P比例和很低的SiO3 Si/PO4 P比例 ( 7.6± 8.9)及SiO3 Si/DIN比例 ( 0 .1 9±0 .1 5 )表明 ,胶州湾营养盐结构已经从比较平衡到不平衡。根据化学计量营养盐限制的标准 ,DIN和PO4 P作为胶州湾浮游植物限制因子的可能性已经减少或消失 ,SiO3 Si限制已经增加。营养盐结构的变化已经导致大型硅藻的减少和浮游植物优势种组成的变化 ,大型硅藻可能趋向于小型化。胶州湾生态系统的这些变化是人类活动影响的直接结果。  相似文献   

冰后期最大海侵以来长江口潮波特性的变化   总被引：1，自引：0，他引：1  

朱玉荣 《海洋科学》2000,24(5):34-36

冰后期最大海侵时,现今长江三角洲地区为一巨大河口湾,研究古长江河口湾及其周围海域的潮波特性,并与现今长江口的进行对比,有助于深入了解长江三角洲形成发育的动力过程。根据冰后期最大海侵时古长江河口湾及其周围海域３５个计算站一个半日潮周期的潮位、潮流过程曲线得知,冰后期最大海侵时古长江河口 及其周围海域的潮波为驻波以及驻波－前进波混合型。此后,丰古长江河口被充填、长江口东进南移,长江口的潮波也逐渐转 变  相似文献   

First record of Prorocentrum lima (Dinophyceae) inside harbor areas and along the Abruzzo region coast, W Adriatic     

Cristina Ingarao  Giovanna Lanciani  Carmen Verri  Tommaso Pagliani 《Marine pollution bulletin》2009,58(4):596-600

Prorocentrum lima (Ehrenberg) Dodge has been found for the first time during the summer of 2007 inside Ortona harbor and along the coast of the Abruzzo region, a slightly eutrophic area influenced by runoff from a nearby river. The investigations were conducted in two harbors and at six coastal sampling stations. Samplings were conducted using a phytoplankton net and with a pump. Average P. lima cellular concentrations were 3.2 × 10⁴ cells L⁻¹. Other well-known toxic and potentially toxic phytoplankton species have been considered. The number of toxic cells from net samples were higher than the numbers of toxic cell samples collected without the net. Occurrences of P. lima with abiotic factors revealed that temperature was positively correlated with P. lima abundance (p = 0.01), while salinity was highly negatively correlated with P. lima presence (p = 0.001). The total phytoplankton community was studied.  相似文献   

PCBs in fish from the southern Baltic Sea: levels, bioaccumulation features, and temporal trends during the period from 1997 to 2006   总被引：1，自引：0，他引：1  

Szlinder-Richert J  Barska I  Mazerski J  Usydus Z 《Marine pollution bulletin》2009,58(1):85-92

Levels of seven marker polychlorinated biphenyls (PCBs) have been determined in five species of Baltic fish collected during 1997-2006. Downward time trends in the concentrations of heavier congeners of PCBs in different Baltic fish, with the exception of cod, have been observed between 1997 and 2001. In case of sprat and herring samples, the statistical significance of the time trends of the PCBs: 101, 118, 153, 138 and 180 concentrations has been proved. Species-specific bioaccumulation of PCBs has been indicated, and the lowest and highest levels of PCBs (expressed on the basis of lipid weight) have been observed in sprat and salmon samples, respectively. PCB profiles have been found to be similar in all the fish species tested. Sampling location has not been a crucial factor for the observed levels of various PCBs. In some fish species, PCB concentrations are negatively correlated with the fat content but have no relation with the fish length.  相似文献