Raman spectroscopic detection of key biomarkers of cyanobacteria and lichen symbiosis in extreme Antarctic habitats: Evaluation for Mars Lander missions     

Howell G.M. Edwards  Caroline D. Moody  David D. Wynn-Williams 《Icarus》2005,174(2):560-571

With proposals that micro-miniaturised Raman spectrometers could soon be part of a suite of analytical instrumentation on the surface of Mars, it is critically important to examine the spectral information that could be forthcoming from attempts to determine key molecular biosignatures under the hostile conditions of extra-terrestrial planetary exploration. Current approaches include the analysis of genuine martian geological material in the form of the SNC class meteorites, the formulation of simulated martian regoliths and the examination of putative martian terrestrial analogues; the latter provide the basis of this paper in the form of Antarctic extremophile habitats. In particular, specimens of epilithic, chasmolithic and endolithic lichen and cyanobacterial colonies sampled along a progressively worsening transect towards a “limits of life” situation, beyond which survival of organisms becomes impossible, provide what is arguably the best terrestrial proving-ground for prototype Raman spectrometers for martian exploration. Here, we report the results of experiments on these extant Antarctic extremophile colonies using a range of Raman excitation wavelengths and experimental conditions and also include a compilation of molecular spectral biosignatures, which may be considered as a suitable database for recognition of bioorganic modification of geological strata.  相似文献   

Stratigraphical and morphological evidence for pingo genesis in the Cerberus plains     

David P. Page  John B. Murray 《Icarus》2006,183(1):46-54

‘Rootless’ debris cones (or pseudocraters) occur in platy, patterned ground throughout the Cerberus plains of Mars and are thought to represent the products of explosive magma-ice interaction [Lanagan et al., 2001. Geophys. Res. Lett. 28, 2365-2368; Fagents et al., 2002. In: Smellie, J.L., Chapman, M.G. (Eds.), Volcano-Ice Interaction on Earth and Mars. In: Geol. Soc. Spec. Publ., vol. 202, pp. 295-317]. Requiring lava and water interspersed, they are central to theories of multiple magmatic and aqueous flood events [Burr et al., 2002. Icarus 159, 53-73; Berman, D.C., Hartmann, W.K., 2002. Icarus 159, 1-17] and widespread sheet volcanism [Keszthelyi et al., 2000. J. Geophys. Res. 105, 15027-15049] in the region during the late Amazonian (a region reported to have been occupied by water bodies ranging from lakes to oceans [Scott et al., 1995. Map of Mars showing channels and possible paleolake basins. USGS Miscellaneous Investigations Series, Map I-2461 (1:30,000,000)]). The nature of the platy substrate is the subject of debate, with evidence given for lava [Keszthelyi et al., 2000. J. Geophys. Res. 105, 15027-15049; Plescia, J.B., 2003. Icarus 164, 79-95] and ice [Brakenridge, G.R., 1993. Lunar Planet. Sci. XXIV (Part 1), 175-176; Rice et al., 2002. Lunar Planet. Sci. XXXIII. Abstract #2026; Murray et al., 2005. Nature 434, 352-355]. The superposition relationships of cones and platy deposits in the channels of the Athabasca Valles precludes a magmatic origin, indicating later formation as permafrost mounds (or ‘pingos’), with implications for geologically recent flood volcanism, age constraints on young surfaces and recent climate change on Mars.  相似文献   

Surface and near-surface atmospheric temperatures for the Mars Exploration Rover landing sites     

N. Spanovich  M.D. Smith  M.J. Wolff  S.W. Squyres 《Icarus》2006,180(2):314-320

Downward-looking spectra of the martian surface from the Miniature Thermal Emission spectrometer (Mini-TES), onboard each of the two Mars Exploration Rovers, are modeled in order to retrieve surface and near-surface atmospheric temperatures. By fitting the observed radiance in the vicinity of the 15-μm CO₂ absorption feature, the surface temperature and the near-surface atmospheric temperature, approximately 1.1 m above the surface, are determined. The temperatures from the first 180 sols (martian days) of each surface mission are used to characterize the diurnal dependence of temperatures. The near-surface atmospheric temperatures are consistently 20 K cooler than the surface temperatures in the warmest part of each sol, which is 1300-1400 LTST (local true solar time) depending on the location. Seasonal cooling trends are seen in the data by displaying the temperatures as a function of sol. Long ground stares, 8.5 min in duration, show as much as 8 K fluctuation in the near-surface atmospheric temperatures during the early afternoon hours when the near-surface atmosphere is unstable.  相似文献   

Carbon dioxide photoelectron energy peaks at Mars     

R.A. Frahm  J.D. Winningham  J.R. Scherrer  A.J. Coates  D.O. Kataria  S. Barabash  H. Andersson  A. Grigoriev  T. Säles  W. Schmidt  J.U. Kozyra  E.C. Roelof  S. Livi  K.C. Hsieh  M. Grande  J.-A. Sauvaud  J.-J. Thocaven  S. Orsini  M. Maggi  P. Bochsler  J. Woch  K. Asamura 《Icarus》2006,182(2):371-382

The ELectron Spectrometer (ELS) from the Analyzer of Space Plasmas and Energetic Atoms (ASPERA-3) flown on the Mars Express spacecraft has an 8% energy resolution, combined with the capability to oversample the martian electron distribution. This makes possible the resolution and identification of electrons generated as a result of the He 304 Å ionization of CO₂ at the martian exobase on the dayside of the planet. Ionospheric photoelectrons were observed during almost every pass into the ionosphere and CO₂ photoelectron peaks were identified near the terminator. Atmospherically generated CO₂ photoelectrons are also observed at 10,000 km altitude in the martian tail near the inner magnetospheric boundary. Observations over a wide range of spacecraft orbits showed a consistent presence of photoelectrons at locations along the inner magnetospheric boundary and in the ionosphere, from an altitude of 250 to 10,000 km.  相似文献   

Mars atmospheric water vapor abundance: 1991-1999, emphasis 1998-1999     

A.L. Sprague  D.M. Hunten  R.E. Hill  M.D. Smith 《Icarus》2006,184(2):372-400

Our ground-based measurements of martian atmospheric water vapor, made throughout Ls=34° to 249°, 24 September 1998 to 23 November 1999, during Mars year 24 (MY 24), show changes in Mars' humidity on hourly, daily, and seasonal timescales. We made concomitant measurement of nearby CO₂ bands, and when possible, results were corrected for aerosol extinction using aerosol optical depths derived from our own CO₂ analysis. Where there is spatial and temporal overlap, similar results are obtained for water vapor abundances and aerosol opacities as those observed from the Thermal Emission Spectrometer on Mars Global Surveyor. In addition some further discussion of our published earlier water vapor measurements (1991-1995) is included. Six results from this data set are: (1) the measured aerosol opacity in Mars atmosphere was variable but not greater than τ=1, with almost no clear atmosphere being observed, (2) measurements made with the slit crossing many hours of local time on Mars' Earth-facing disk show a diurnal pattern with highest abundances at mid-day and low abundance in very early morning and late afternoon for some but not all measurements, (3) water vapor abundance is patchy on hourly and daily time scales but follows the usual seasonal trends seen by instrumentation on the Mars Atmospheric Water Detector on the Viking Orbiters and by the Thermal Emission Spectrometer on Mars Global Surveyor, (4) there is a slight longitudinal correlation with the ground-ice observed by the Gamma Ray Spectrometer on Mars Odyssey, (5) there is evidence of the Low Southern Latitude Summer Minimum in our water vapor measurements but our data set for southern summer is limited, and (6) MY 24 appears to be wetter than MY 22 and MY 23.  相似文献   

A new extraction technique for in situ analyses of amino and carboxylic acids on Mars by gas chromatography mass spectrometry   总被引：1，自引：0，他引：1  

A. Buch  D.P. Glavin  R. Sternberg  C. Szopa  C. Rodier  R. Navarro-Gonzlez  F. Raulin  M. Cabane  P.R. Mahaffy 《Planetary and Space Science》2006,54(15):1592-1599

In order to target key organic compounds in the Martian regolith using gas chromatography mass spectrometry (GC-MS), we have developed a new extraction procedure coupled with chemical derivatization. This new technique was tested on a Mars analog soil sample collected from the Atacama Desert in Chile. We found that amino and carboxylic acids can be extracted from the Atacama soil in a 1:1 mixture of isopropanol and water after ultrasonic treatment for 30 min. The extracted organic compounds were then derivatized in a single-step reaction using N-methyl-N-(tert-butyldimethylsilyl)-trifluoroacetamide (MTBSTFA) as the silylating agent in order to transform these compounds into volatile species that can then be detected by GC-MS. We are currently developing a miniaturized reaction cell suited for spaceflight, where both organic extraction and chemical derivatization processes can take place in a single step.  相似文献   

An integrated laser anemometer and dust accumulator for studying wind-induced dust transport on Mars     

J.P. Merrison  H.P. Gunnlaugsson  K. Kinch  T.L. Jacobsen  A.E. Jensen  P. Nørnberg  H. Wahlgreen 《Planetary and Space Science》2006,54(11):1065-1072

Windborne dust is one of the most important and dynamic factors affecting the Martian surface and its atmosphere, yet there lacks a detailed physical understanding how it is transported. We present a miniature laser-based optoelectronic instrument for use on a Mars lander. It integrates sensors capable of quantifying important parameters needed for the understanding and modeling of dust transport on Mars, these include wind speed, wind direction, suspended dust concentration, dust deposition and removal rates as well as the electrification of the Martian dust. Dust electrification has been seen from experimental simulations to be of considerable importance to the processes of adhesion and cohesion, specifically prompting the formation of low mass density dust aggregates. Testing of this prototype instrument has been performed under simulated Martian conditions in a wind tunnel facility. The results and analysis of its functionality will be presented.  相似文献   

Ozone abundance on Mars from infrared heterodyne spectra: I. Acquisition, retrieval, and anticorrelation with water vapor     

Kelly Fast  Theodor Kostiuk  Fred Espenak  John Annen  David Buhl  Michael F. A'Hearn  Timothy A. Livengood  Guido Sonnabend  Frank Schmülling 《Icarus》2006,181(2):419-431

Observations of ozone on Mars were made using the Goddard Space Flight Center's Infrared Heterodyne Spectrometer and Heterodyne Instrument for Planetary Wind and Composition at the NASA Infrared Telescope Facility. Ozone is an important observable tracer of martian photochemistry. Infrared heterodyne spectroscopy with spectral resolution ?¹⁰⁶ is the only technique that directly measures ozone in the martian atmosphere from the surface of the Earth. Ozone column abundances down to the martian surface were acquired in seven data sets taken between 1988 and 2003 at various orbital positions (LS=40°, 74°, 102°, 115°, 202°, 208°, 291°). Ozone abundances are compared with those retrieved using ultraviolet techniques, showing good agreement. Odd hydrogen (HO_X) chemistry predicts anticorrelation of ozone and water vapor abundances. Retrieved ozone abundances consistently show anticorrelation with corresponding water vapor abundances, providing strong confirmation of odd hydrogen activity. Deviation from strict anticorrelation between the observed total column densities of ozone and water vapor suggests that constituent vertical distribution is an additional, significant factor.  相似文献   

Ozone abundance on Mars from infrared heterodyne spectra: II. Validating photochemical models     

Kelly Fast  Theodor Kostiuk  Tilak Hewagama  Timothy A. Livengood  Sebastien Lebonnois 《Icarus》2006,183(2):396-402

Ozone is an important observable tracer of martian photochemistry, including odd hydrogen (HO_x) species important to the chemistry and stability of the martian atmosphere. Infrared heterodyne spectroscopy with spectral resolution ?¹⁰⁶ provides the only ground-based direct access to ozone absorption features in the martian atmosphere. Ozone abundances were measured with the Goddard Infrared Heterodyne Spectrometer and the Heterodyne Instrument for Planetary Wind and Composition at the NASA Infrared Telescope Facility on Mauna Kea, Hawai'i. Retrieved total ozone column abundances from various latitudes and orbital positions (LS=40°, 74°, 102°, 115°, 202°, 208°, 291°) are compared to those predicted by the first three-dimensional gas phase photochemical model of the martian atmosphere [Lefèvre, F., Lebonnois, S., Montmessin, F., Forget, F., 2004. J. Geophys. Res. 109, doi:10.1029/2004JE002268. E07004]. Observed and modeled ozone abundances show good agreement at all latitudes at perihelion orbital positions (LS=202°, 208°, 291°). Observed low-latitude ozone abundances are significantly higher than those predicted by the model at aphelion orbital positions (LS=40°, 74°, 115°). Heterogeneous loss of odd hydrogen onto water ice cloud particles would explain the discrepancy, as clouds are observed at low latitudes around aphelion on Mars.  相似文献   

Electric fields within the martian magnetosphere and ion extraction: ASPERA-3 observations     

E. Dubinin  R. Lundin  J. Woch  A. Fedorov  N. Krupp  M. Holmström  M. Yamauchi  J.-J. Thocaven  J. Sharber  A. Coates  K.S. Hsieh  H. Koskinen  P. Riihelä  T. Säles  J. Luhmann  R. Cerulli-Irelli  M. Maggi  D. Williams  P. Wurz  C. Dierker  M. Carter 《Icarus》2006,182(2):337-342

Observations made by the ASPERA-3 experiment onboard the Mars Express spacecraft found within the martian magnetosphere beams of planetary ions. In the energy (E/q)-time spectrograms these beams are often displayed as dispersive-like, ascending or descending (whether the spacecraft moves away or approach the planet) structures. A linear dependence between energy gained by the beam ions and the altitude from the planet suggests their acceleration in the electric field. The values of the electric field evaluated from ion energization occur close to the typical values of the interplanetary motional electric field. This suggests an effective penetration of the solar wind electric field deep into the martian magnetosphere or generation of large fields within the magnetosphere. Two different classes of events are found. At the nominal solar wind conditions, a ‘penetration’ occurs near the terminator. At the extreme solar wind conditions, the boundary of the induced magnetosphere moves to a more dense upper atmosphere that leads to a strong scavenging of planetary ions from the dayside regions.  相似文献