黄铁矿中晶格金的萃取实验及有关问题的初步研究     

陈伟  张振儒 《吉林大学学报(地球科学版)》1991,(4)

尽管某些研究者认为黄铁矿中确实存在有晶格金,但以前的研究都没有取得直接而充分的证据。为此,作者做了晶格金的萃取实验,使黄铁矿中的晶格金(离子金)形成[AuCl_4]-络合物,然后利用紫外—可见光谱证实了[AuCl_4]-的存在,从而取得了晶格金存在较为直接而充分的证据。作者认为,象黄铁矿中Fe~(2+)与Au~(+)的取代关系的理论解释不应局限于类质同象的传统理论上,而应用现代的配位场理论解释之。计算表明,只要温度足够高,Au~(+)是可以取代Fe~(2+)形成晶格金的。本文还通过穆斯鲍尔谱的研究,探讨了晶格金的形成机理。  相似文献   

Theoretical research on intensity envelope function of strong ground motion     

金星  瘳振鹏 《地震学报(英文版)》1994,7(4):637-644

（金星，瘳振鹏）Ｔｈｅｏｒｅｔｉｃａｌｒｅｓｅａｒｃｈｏｎｉｎｔｅｎｓｉｔｙｅｎｖｅｌｏｐｅｆｕｎｃｔｉｏｎｏｆｓｔｒｏｎｇｇｒｏｕｎｄｍｏｔｉｏｎ￥ＸｉｎｇＪＩＮａｎｄＺｈｅｎ－ＰｅｎｇＬＩＡＯ（ＩｎｓｔｉｔｕｔｅｏｆＥｎｇｉｎｅｅｒｉｎｇＭｅｃｈ...  相似文献   

CHARACTERISTICS OF TURBULENCE SPECTRA IN DIFFERENT WEATHER PROCESSES UNDER UNSTABLE CONDITIONS^*          下载免费PDF全文

Zhu Wenqin  Zhu Cuijuan  Li Xingsheng 《Acta Meteorologica Sinica》1994,8(3):296-304

In this paper,the data chosen from measurements by supersonic anemometers in Tongxian County of Beijing in 1990 are used to study characteristics of turbulence spectra in precipitation weather.Some turbulence parameters such as turbulence intensity,heat and momentum fluxes,friction velocity,M-O length and stability parameter are calculated and their dependence on turbulence spectra in different stability conditions are analyzed.Some encouraging results are obtained and compared with others' results.  相似文献   

Petroleum isoprenoid hydrocarbons derived from catagenetic degradation of archaebacterial lipids     

J. Albaigés  J. Borbón  W. Walker 《Organic Geochemistry》1985,8(4):293-297

The three GC coeluting C₄₀ bis-phytanes with head-to-tail, tail-to-tail and head-to-head linkages considered to be archaebacterial markers, have been recognized in petroleum by enhanced mass-fragmentography. Supporting evidence has been obtained by the simultaneous occurrence of two C₂₁–C₂₄ series of isoprenoid and quasi-isoprenoid hydrocarbons that are supposedly formed during the catagenetic degradation of the isomeric C₄₀ isoprenoids. The C₂₁–C₂₄ quasi-isoprenoid hydrocarbons have been identified conclusively for the first time by comparison with authentic standards.  相似文献   

Contact-metamorphic effect on parameters for kerogen maturation     

Yoshihiro Uji 《Organic Geochemistry》1986,9(6)

This study examines the effect of contact metamorphism by an igneous dyke on parameters for kerogen maturation, such as elemental composition (H/C, O/C, N/C), ¹H-NMR T₁, vitrinite reflectance and infrared spectra. Although elemental composition and ¹H-NMR T₁ of the kerogen changed only within 1.5 and 5.0 m from the dyke respectively, vitrinite reflectance of the kerogen was thermally affected beyond 10.0 m from the intrusion. It is concluded that vitrinite reflectance is the most sensitive of the parameters evaluated to assess thermal stress of kerogens.  相似文献   

内蒙赤峰莲花山金矿田石英脉的红外光谱成矿信息及定量预测     

郭树平  张培萍  孙本龙  王自杰 《吉林大学学报(地球科学版)》1995,(4)

测试了１３０余件含金石英脉及不含金石英脉的红外光谱试样，查明了该区含金石英脉的红外光谱特征，同时配合其它预测含金石英脉的测量方法，提出了该区含金石英脉的预测靶区，经过初步验证，预测基本上是准确的。  相似文献   

水文时间系列周期分析方法探讨   总被引：15，自引：2，他引：15  

易淑珍  王钊 《水文》2005,25(4):26-29

以分析广东省降水周期变化规律为例，探讨了最大熵谱方法在提取水文时间系列的主次周期上以及小波变换方法在分析水文时间系列的多时间尺度演变规律上的应用。由计算结果分析得到广东省降水过程主要存在的周期特性和旱涝变化趋势，为广东省降水趋势预测提供了重要信息。  相似文献   

黄土剖面中赤铁矿和针铁矿的定量分析与气候干湿变化研究   总被引：2，自引：6，他引：2  

季峻峰  陈骏  W.Balsam  刘连文  陈旸  赵良  周玮 《第四纪研究》2007,27(2):221-229

为了了解黄土剖面中赤铁矿和针铁矿的分布特征,文章采用对铁氧化物矿物灵敏的漫反射光谱法(DRS),开展了赤铁矿和针铁矿的鉴定和测定研究,提出了定量分析赤铁矿和针铁矿含量的DRS新方法.选择天然典型黄土和古土壤样品,首先采用柠檬酸盐-重碳酸盐-连二亚硫酸盐(CBD)方法去除其中成壤成因的铁氧化物矿物,以其为基体配制含不同赤铁矿和针铁矿的系列标样,然后进行DRS测试和多元逐步回归分析,分别建立测定赤铁矿和针铁矿含量的校准方程并加以检验.利用DRS方法,分析了多个黄土剖面的赤铁矿和针铁矿含量,发现黄土-古土壤剖面的赤铁矿/针铁矿比值可作为东亚季风干/湿变化的敏感指标.该比值较高时反映了干燥土壤环境,而较低时指示了潮湿土壤环境.对灵台和洛川剖面中赤铁矿/针铁矿比值的分析,初步揭示了2.6Ma年以来黄土高原东亚季风阶段性变强的特征.  相似文献   

Physical and chemical environments of abnormal vitrinite reflectance evolution in the sedimentary basins     

Qiu Nansheng  Wang Weixiao  Xie Mingju 《Frontiers of Earth Science》2007,1(3):341-350

Based on the tested data of pressure and vitrinite reflectance of some wells in sedimentary basins, abnormal high pressure is regarded as not the only factor to retard the increase of vitrinite reflectance (R _o). Apart from the types of the organic matter, the physical environment (temperature and pressure) and chemical environment (fluid composition and inorganic elements) will result in the abnormal vitrinite reflectance values in the sedimentary basins. This paper tested trace elements and vitrinite reflectance data from the the abnormal high pressure and normal pressure strata profiles, respectively, and found that the acidic and lower salinity starta are favorable for the increase of R _o. By discussing the corresponding relationship between the contents of some trace elements in the mudstone and the vitrinite reflectance values, the typical trace elements were found to suppress and/or catalyze the vitrinite reflectance of organic matter, while the elements of Ca, Mn, Sr, B, Ba and P may result in the retardation of R _o. However, elements of Fe, Co, Zn, Ni and Rb may catalyze the organic matter maturation. This study is conductive to the organic maturation correction, oil and gas assessment and thermal history reconstruction by the paleothermometry. Translated from Acta Geologica Sinica, 2006, 80(11): 1760–1769 [译自: 地质学报]  相似文献   

利用漫反射光谱鉴定红粘土中针铁矿和赤铁矿   总被引：5，自引：0，他引：5  

周玮  季峻峰  Balsam William  陈骏 《高校地质学报》2007,13(4):730-736

针铁矿(Gt)和赤铁矿(Hm)是广泛存在于土壤和沉积物中的重要铁矿物。这两种矿物在土壤和沉积物中含量很低,常规的测试手段很难有效地测定其含量。利用反射光谱联合加热处理的方法,可对土壤及沉积物样品中针铁矿和赤铁矿进行定性或半定量测定。实验结果显示,样品加热到300℃后,针铁矿的反射光谱的一阶导数特征峰发生了变化,赤铁矿的一阶导数特征峰却没有明显的变化。因此加热前后样品反射光谱一阶导数的变化取决于针铁矿和赤铁矿的含量。利用这种方法估计黄土高原第三纪红粘土样品中的赤铁矿含量约为0.3%～0.4%,针铁矿含量约为0.5%～1%。  相似文献