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91.
反射光谱技术:研究南极企鹅古生态演化的一种新方法 总被引:2,自引:0,他引:2
为探求快速、廉价、无损和同步的光谱技术在南极生态环境研究中的可能性,本文利用南极阿德雷岛的四根企鹅粪土沉积柱样品的反射光谱,通过逐步多元线性回归和主成分回归两种数学运算方法,建立了反射光谱数据与企鹅粪九种标型元素浓度之间的关系,并探讨了南极企鹅粪土沉积物光谱数据的古生态意义。结果表明:南极粪土沉积样品反射率光谱与企鹅粪九种标型元素(P、Ca、Cu、F、Ba、S、Zn、Sr、Se)含量之间存在良好的相关性,预测值与实测值之间的相关系数R都达到了0.9以上,在深度剖面上预测浓度与实测浓度具有非常一致的变化趋势;南极粪土沉积物光谱数据包含有明确的古生态变化信息,可利用主成分分析快速恢复历史时期企鹅数量演化过程。本研究结果为在偏远的南极地区开展古生态环境研究提供了一种新的快捷方法和技术途径。 相似文献
92.
On May 28, 1998, a moderate size earthquake of mb 5.5 occurred offshore the northwestern part of Egypt (latitude 31.45°N and
longitude 27.64°E). It was widely felt in the northern part of Egypt. Being the largest well-recorded event in the area for
which seismic data from the global digital network are available, it provides an excellent opportunity to study the tectonic
process and present day stress field occurring along the offshore Egyptian coast. The source parameters of this event are
determined using three different techniques: modeling of surface wave spectral amplitudes, regional waveform inversion, and
teleseismic body waveform inversion. The results show a high-angle reverse fault mechanism generally trending NNW–SSE. The
P-axis trends ENE–WSW consistently with the prevailed compression stress along the southeastern Hellenic arc and southwestern
part of the Cyprean arc. This unexpected mechanism is most probably related to a positive inversion of the NW trending offshore
normal faults and confirms an extension of the back thrusting effects towards the African margin. The estimated focal depth
ranges from 22 to 25 km, indicating a lower crustal origin earthquake owing to deep-seated tectonics. The source time function
indicates a single source with rise time and total rupture duration of 2 and 5 s, respectively. The seismic moment (M
o) and the moment magnitude (M
w) determined by the three techniques are 1.03 × 1017 Nm, 5.28; 1.24 × 1017 Nm, 5.33; and 1.68 × 1017 Nm, 5.42; respectively. The calculated fault radius, stress drop, and the average dislocation assuming a circular fault model
are 7.2 km, 0.63 Mpa, and 0.11 m, respectively. 相似文献
93.
A statistical analysis of the peak acceleration demands for nonstructural components (NSCs) supported on a variety of stiff and flexible inelastic regular moment‐resisting frame structures with periods from 0.3 to 3.0 s exposed to 40 far‐field ground motions is presented. Peak component acceleration (PCA) demands were quantified based on the floor response spectrum (FRS) method without considering dynamic interaction effects. This study evaluated the main factors that influence the amplification or decrease of FRS values caused by inelasticity in the primary structure in three distinct spectral regions namely long‐period, fundamental‐period, and short‐period region. The amplification or decrease of peak elastic acceleration demands depends on the location of the NSC in the supporting structure, periods of the component and building, damping ratio of the component, and level of inelasticity of the supporting structure. While FRS values at the initial modal periods of the supporting structure are reduced due to inelastic action in the primary structure, the region between the modal periods experiences an increase in PCA demands. A parameter denoted as acceleration response modification factor (Racc) was proposed to quantify this reduction/increase in PCA demands. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
94.
95.
Steve Dury Brian Turner Bill Foley Ian Wallis 《International Journal of Applied Earth Observation and Geoinformation》2001,3(4):328
In this study we assess the feasibility of remotely measuring canopy biochemistry, and thus the potential for conducting large-scale mapping of habitat quality. A number of studies have found nutrient composition of eucalypt foliage to be a major determinant of the distribution of folivorous marsupials. More recently it has been demonstrated that a specific group of secondary plant chemicals, the diformylphloroglucinols (DFPs), are the most important feeding deterrents, and are thus vital determinants of habitat quality. We report on the use of laboratory spectroscopy to attempt to identify one such DFP, sideroxylonal-A, in the foliage of Eucalyptus melliodora, one of the few eucalypt species browsed by folivorous marsupials. Reflectance spectra were obtained for freeze-dried, ground leaves using near infrared spectroscopy (NIRS) and for both oven-dried and fresh whole leaves using a laboratory-based (FieldSpec) spectroradiometer. Modified partial least squares (MPLS) regression was used to develop calibration equations for sideroxylonal-A concentration based on the reflectance spectra transformed as both the first and second difference of absorbance (Log 1/R). The predictive ability of the calibration equations was assessed using the standard error of calibration statistic (SECV). Coefficients of determination (r2) were highest for the ground leaf spectra (0.98), followed by the fresh leaf and dry leaf spectra (0.94 and 0.87, respectively). When applied to independent validation sub-sets, sideroxylonal-A was most accurately predicted from the ground leaf spectra (r2 = 0.94), followed by the dry leaf and fresh leaf spectra (0.72 and 0.53, respectively). Two spectral regions, centred on 674 nm and 1394 nm, were found to be highly correlated with sideroxylonal-A concentration for each of the three spectral data sets studied. Results from this study suggest that calibration equations derived from modified partial least squares regression may be used to predict sideroxylonal-A concentration, and hence leaf palatability, of Eucalyptus melliodora trees, thereby indicating that the remote estimation of habitat quality of eucalypt forests for marsupial folivores is feasible. 相似文献
96.
WEI Heli LIU Qinghong XU Qingshan ZHAO Fengsheng SONG Zhengfang 《Acta Meteorologica Sinica》2001,15(2):249-256
Infrared solar spectra on clear days were measured automatically by an infrared solar spectrometer(ISS) with 0.4 cm-1 resolution developed by us.A line-by line(LBL) computation method was used to calculate theoretical atmospheric absorption.In the wavelength range of 3.410-3.438 μm.the absorption is mainly due to atmospheric methane and water vapor.Columnatmospheric methane was retrieved from the recorded infrared solar spectra.The seasonal variation of column atmospheric methane in Hefei has been obtained from the measuremental data of nearly 18 months since the April of 1997.and found that it is similar to that of background data.The instruments.principles of measurement and some of results were introduced,and the results are also discussed briefly in the paper. 相似文献
97.
In recent years, more and more studies are focused on the performance in seismic design instead of the strength of structures. People have realized that the structure deformation (displacement) can describe the damage more properly and directly than the strength (force). The displacement design spectra need to be constructed within more wide range of the period and the damping for the displacement-based seismic design. 相似文献
98.
99.
J. A. Tossell 《Aquatic Geochemistry》2001,7(4):239-254
Changes in the UV spectra of As(OH)3 solutions with variations in pH and temperature have recently been used to determine the temperature dependence of the pKa of the acid. In previous studies I used quantum mechanical techniques to study changes in structure and vibrational spectra as a function of pH for arsenites and thioarsenites. I previously calculated UV spectra for ``molecular' minerals, like realgar As4S4. Here I use a number of different quantum mechanical methods, both Hartree-Fock and density functional theory based, to calculate the UV spectra for both a related simple well-characterized gas-phase molecule PF3 and for As(OH)3 and As(SH)3 and their conjugate anions and some neutral and anionic oligomers in aqueous solution. For the monomeric species small numbers of water molecules have been explicitly included, in a supermolecule or microsolvation approach. I find that UV absorption energies accurate to a few tenths of an eV can be obtained both for gas- phase PF3 and for neutral arsenious acid in aqueous solution, for which the UV absorption maximum is calculated to occur around 6.5 eV, consistent with experiment. Accurate calculation of the UV energies for arsenite anions in aqueous solution is much more difficult, since basis set size and solvation effects are considerably larger than for the neutral molecules, but fairly reliable results can still be obtained. Deprotonation is found to reduce the lowest calculated UV transition energy by about half an eV. Oligomerization also reduces the lowest calculated UV energy by at least half an eV. Replacement of one or all the –OH groups by –SH groups reduces the lowest calculated UV energies by about 2 eV. UV excitation energies have been calculated for oligomeric species as large as As3E3(EH)3 and As4E6, where E = O, S, and may be useful for identifying such species in solution. 相似文献
100.
北京地区一次特大强风过程边界层结构的研究 总被引:21,自引:2,他引:21
利用北京325 m气象塔资料对1993年4月9日北京地区出现的一次特大强风过程的边界层结构(风、温、风切变及阵风特征)进行了分析。随着该次大风的过境,边界层内风场出现数个风速高值中心,高度位于200~300 m,时间间隔1~3 h。伴随上层风速垂直切变和阵风特性。湍流能谱的计算结果表明了大尺度涡旋对边界层湍流微结构的影响。 相似文献