Raman Micro-Spectroscopic Study of Sulfate Ion in the System Na2SO4 – H2O     

ZHU Dongliang  ZHU Ziang  PAN Junyi  DING Junying  NI Pei 《《地质学报》英文版》2015,89(3):887-893

This work aims to quantify sulfate ion concentrations in the system Na₂SO₄-H₂O using Raman micro-spectroscopy.Raman spectra of sodium sulfate solutions with known concentrations were collected at ambient temperature（293 K） and in the 500 cm^₁-4000 cm^-1 spectral region.The results indicate that the intensity of the SO₄^2- band increases with increasing concentrations of sulfate ion.A linear correlation was found between the concentration of SO₄^2-（c） and parameter I₁,which represents the ratio of the area of the SO₄^2- band to that of the O-H stretching band of water（A_s/A_w）:I₁=-0.00102+0.01538 c.Furthermore,we deconvoluted the O-H stretching band of water(2800 cm^-1-3800 cm^-1) at 3232 and 3430 cm^-1 into two sub-Gaussian bands,and then defined Raman intensity of the two sub-bands as A_Bi(3232 cm^-1) and A_B2(3430 cm^-1),defined the full width of half maximum（FWHM） of the two sub-bands as W_B1(3232 cm^-1) and W_B2(3430 cm^-1).A linear correlation between the concentration of SO₄^2-（c） and parameter I₂,which represents the ratio of Raman intensity of SO₄^2-（A_s）(in 981 cm^-1) to(A_B1+A_B2),was also established:I₂=-0.0111+0.3653 c.However,no correlations were found between concentration of SO₄^2-（c） and FWHM ratios,which includes the ratio of FWHM of SO₄^2-（W_s） to W_B1 W_B2 and W_B1+B2(the sum of W_B1 and W_B2),suggesting that FWHM is not suitable for quantitative studies of sulfate solutions with Raman spectroscopy.A comparison of Raman spectroscopic studies of mixed Na₂SO₄ and NaCI solutions with a constant SO₄^2- concentration and variable CI^- concentrations suggest that the I\ parameter is affected by CI^-,whereas the I₂ parameter was not.Therefore,even if the solution is not purely Na₂SO₄-H₂O,SO₄^2- concentrations can still be calculated from the Raman spectra if the H₂O band is deconvoluted into two sub-bands,making this method potentially applicable to analysis of natural fluid inclusions.  相似文献   

Comparison of Simulated and Reconstructed Temperature in China during the past 2000 years     

Wang Xiaoqing  Liu Jian  Wang Zhiyuan 《地球科学进展》2015,30(12):1318

Studying climate changes over the past 2 000 years has important scientific significance in exploring climate variability on decadal to centennial timescales, assessing the natural and anthropogenic contribution to the climate warming, and understanding the effects of human activities in the past and future climate changes. Due to the scarcity of observation and uncertainty of reconstruction in this period, climate model is developed as a useful tool for studying paleoclimate.The Community Earth System Model (CESM) is one of the state-of-the-art climate models, but its performance in simulating the temperature in China has not been examined.The temperature datasets of observation/reanalysis (GHCN_CAMS) and reconstructions during the past 2000 years in China were used to examine the performance of CESM. The comparison between the annual average temperatures of GHCN_CAMS reanalysis and simulation showed that the model well reproduced the spatial distributions and upward trend of the annual average temperature in China, and the comparison with reconstructions in five sub-regions of China indicated that the simulation were in good consistent with the average temperature changes of reconstructionson decadal time scales. On the centennial time scale, the average temperature fluctuations of simulation in the regions of China were in accord with reconstructions generally except for Central East and Tibet.There existed three warm periods of simulated temperature variation in China over the past 2000 years, including 0-540AD, 800-1250AD and 1901-2000AD, and two cold periods involving the 551-721AD and 1400-1850AD, which had some discrepancies with reconstructions. And the discrepancies between simulation and reconstructions might be related to uncertainties of the resolution, external forcing and parameterization of the subgrid-scale process in the model.  相似文献   

The Paleoceanography during the Time with High δ13C of Phanerozoic marine carbonates     

Huang Sijing  Li Xiaoning  Wu Wenhui  Zhang Meng  Hu Zuowei  Liu Sibing  Huang Keke  Zhong Yijiang 《地球科学进展》2015,30(11):1185-1197

Carbon isotopic composition of marine carbonates is a record for various important geological events in the process of earth development and evolution. The carbonates of Carboniferous, Permian and Triassic, as the transition from Paleozoic to Mesozoic-Cenozoic have very high ¹³C value. Taking this as the main point, and combined with the oxygen, strontium isotopic composition in carbonates, distribution of carbonate basin area through geologic time, the correlation of carbon isotopic composition of marine carbonates to sea level change, organic carbon burial flux, exchange of CO₂ content in atmosphere and ocean, and long cycle evolution of the earth ecosystems were approached. The results are shown as follows: ①The interval of ¹³C >3‰ during Phanerozoic was concentrated in Carboniferous, Permian and the beginning of Triassic, but the beginning of Triassic was characterized by higher frequency and larger fluctuations in ¹³C value during a short time, whereas the Carboniferous-Permian presented a continuously stable high ¹³C value, indicating a larger amount of organic carbon accumulation in this time interval. Relatively high ¹⁸O values during this time was also observed, showing a long time of glaciations and cold climate, which suggest a connection among rapid organic carbon burial, cold climate, as well as pCO₂ and pO₂ states of atmosphere. ②The over consumption of atmosphere CO₂ by green plants during the time with high ¹³C of seawater forced CO₂ being transferred from ocean to atmosphere for the balance, but the decrease in the seawater amount and water column pressure caused by the global cooling could weaken dissolution capacity of CO₂ in seawater and carbon storage of marine carbonates, and also reduce the carbonate sedimentary rate and decrease the carbonate basin area globally from Devonian to Carboniferous and Permian. During the middle-late Permian carbonate was widely replaced by siliceous sediments even though in shallow carbonate platform, which resulted in the decrease of marine invertebrates, suggesting the Permian chert event should be global. ③The Phanerozoic ⁸⁷Sr/⁸⁶Sr trend of seawater showed a sharp fall in Permian and drop to a minimum at the end of the Permian, indicting input of strontium from the submarine hydrothermal systems (mantle flux). Such process should accompany with a supplement of CO₂ from deep earth to atmosphere and ocean system, but the process associated with widespread volcanism and rises of earth’s surface temperature pricked up the mass extinction during the time of end Permian. ④Cold climate and increase of continental icecap volume, the amalgamation of northern Africa and Laurentia continentals were the main reasons responsible for the sea level drop, but the water consumption result from the significantly increased accumulation of organic carbon should also be one of the reasons for the sea level drop on the order of tens of meters. ⑤The mass extinction at the end Permian was an inevitable event in the process of earth system adjustment. It was difficult for marine invertebrates to survive because of the continuously rapid burial of organic carbon, and of the decrease of sea water amount and its dissolution ability to CO₂. At last, at the end of Paleozoic, the supplement of CO₂ to atmosphere and ocean by widely magma activities resulted in a high temperature of earth surface and intensified mass extinction.  相似文献   

EH-4电磁系统在寻找地下水中的应用     

张文科  吴艳军  徐玺萍  张健健 《地下水》2015,(1):97-98,177

EH-4电磁成像系统具有勘查深度大、轻便高效、反映成果直观等特点。在寻找地下水及水文地质方面得到了广泛的应用。为帮助青海省平安县严重缺水南部山区寻找地下水,选用了EH-4电磁系统进行剖面探测,通过确定该区内隐伏断层的位置及断层破碎带,进行构造找水,实践证明:以其他电磁法相比,EH-4电磁成像系统穿透力强、不受浅部高阻层的影响,适用性强、效率高。  相似文献   

鄂尔多斯盆地LFP区块长2段沉积相研究     

叶亚坤  苏海伦  薛永康  李阳阳 《地下水》2015,(4)

储层的沉积相研究通常是油气藏勘探开发过程中一项十分重要的任务,它控制着储集砂体的成因类型及宏观分布。在岩芯观察的基础上,结合综合录井资料和野外露头剖面信息,运用沉积学、沉积构造、剖面结构、古生物及测井相等划分沉积相的标志,对研究区内钻井进行单井沉积相划分,对不同钻井之间的沉积相进行综合比对,结果认为LEP区块长2段主要从三角洲前缘高建设的水下分流河道骨架砂体沉积为主。  相似文献   

华北克拉通辽东半岛新元古代早期基性岩浆活动:辉绿岩墙年代学和岩石地球化学证据     

韩吉龙  王清海 《世界地质》2015,34(4):886-902

华北克拉通辽东半岛地区广泛发育侵位于青白口系不同层位中的辉绿岩(脉)岩墙,对其锆石CL图像、U--Pb定年和岩石地球化学特征研究得出以下结论。锆石类型有三组:前两组锆石具有早期岩浆作用的锆石属性或结晶基底的变质锆石属性,反映该区辉绿岩岩浆上升过程受到了陆壳的混染;第三组锆石多呈自形--半自形短柱状,发育岩浆振荡生长环带结构或条带结构,具原生岩浆成因锆石属性,锆石SHRIMP U--Pb定年显示其加权平均年龄为832.3±8.1 Ma(n=14,MSWD=1.3),可以代表辉绿岩的结晶年龄。岩石地球化学组成,其具有低Si O_2、Al_2O_3,高TFe_2O_3、MgO、Ti O_2的特征,这与拉斑玄武岩特征相似;其稀土元素总量相对较低(ΣREE=71.88×10~-6~129.64×10~-6),且具弱的正Eu异常和铌亏损;略富集轻稀土元素(LREE)、富集大离子亲石元素(LILE:Rb、Pb、Ba)和高场强元素(HFSE:Th、U、Zr、Ti、Hf),而亏损高场强元素(HFSE:Nb、Sm、Gd、P)等;以上特征指示岩浆源区为富集型地幔,且上侵位就位过程中受陆壳不同程度的同化混染。本文对辉绿岩的研究显示华北克拉通辽东半岛地区在新元古代早期存在基性岩浆活动,结合前人对华北克拉通中元古代晚期—新元古代早期构造--岩浆事件的研究成果,进一步证明了华北克拉通东北部在新元古代早期经历了挤压汇聚后的伸展裂解演化过程,这与Rodinia超大陆聚合和裂解事件一致。  相似文献   

小兴安岭西北部霍龙门地区花岗质杂岩锆石U--Pb年龄、岩石地球化学特征及地质意义   总被引：1，自引：0，他引：1  

曲晖  李成禄  杨福深 《世界地质》2015,34(1):34-43

小兴安岭西北部的霍龙门地区位于兴蒙造山带东段,该区出露的大面积花岗质杂岩为新开岭—科洛杂岩的重要组成部分。该花岗质杂岩主要由花岗质和花岗闪长质糜棱岩等组成,其中花岗质糜棱岩的SHRIMP锆石U--Pb定年结果为310.7±6.5 Ma,表明其原岩形成于晚石炭世。该杂岩的主量元素总体显示中、高钾钙碱性准铝质--过铝质系列岩石的特点;微量元素表现出Th、Zr、Hf、Nd、Rb、K明显富集,而Ba、Sr、Nb、P、Ti明显亏损;稀土元素具有明显的轻稀土元素富集、重稀土元素相对亏损的特征,有较明显的负Eu异常,轻、重稀土元素分馏程度较强。结合区域构造演化特点及花岗质杂岩的形成环境等,综合显示该杂岩的原岩应形成于晚古生代,于三叠纪时期发生明显的变质变形作用。  相似文献   

陕西延安Q_2原状黄土抗拉强度试验研究     

孙纬宇  梁庆国  严松宏  欧尔峰  邵森林 《地质力学学报》2015,21(3):386-392

对陕西延安新宝塔山隧道Q2原状黄土进行了不同加载速率的无侧限抗压与贯入抗拉试验,研究了Q2原状黄土抗压与抗拉强度的影响因素。结果表明:加载速率对宝塔山Q2原状黄土抗压和抗拉强度影响较大,抗压强度与抗拉强度随加载速率增大而增大;高径比对抗拉强度也有较大影响,试验时当高径比控制在1.0左右时,高径比对宝塔山Q2原状黄土的抗拉强度影响相对较小,因此采用轴向压裂法测量黄土的抗拉强度时,高径比宜控制在1.0;在试验加载速率范围内,加载速率对宝塔山Q2原状黄土的压拉比影响不大,其压拉比在9.88~13.68范围内变化。  相似文献   

珠江流域碳酸盐岩与硅酸盐岩风化对大气CO_2汇的效应   总被引：6，自引：0，他引：6  

覃小群  蒋忠诚  张连凯  黄奇波  刘朋雨 《地质通报》2015,34(9):1749-1757

对珠江流域11个测站的河水1个水文年4次取样进行水化学和同位素测试分析,揭示无论是碳酸盐岩区还是硅酸盐岩区,岩石风化均使河流的离子成分以HCO3-、Ca2+、Mg2+为主,碳酸盐岩风化溶蚀速率和由碳酸盐岩风化溶蚀引起的大气CO2消耗量分别为27.60 mm/ka和540.21x103mol/(km2·a-1),是硅酸盐岩风化速率和由硅酸盐岩风化引起的大气CO2消耗量的10.8倍和6.7倍,说明碳酸盐岩风化是流域碳汇过程及效应的主体。由于有利的水热条件和高的碳酸盐岩面积比例,珠江流域平均岩石风化速率和由岩石风化作用引起的大气CO2消耗量分别为30.15mm/ka和620.36×103mol/(km2·a-1),为全球60条河流平均值的2.6倍。  相似文献   

基于ENVI的高分辨率遥感影像城市绿地信息提取研究   总被引：1，自引：0，他引：1  

陈阳  赵俊三  陈应跃 《测绘工程》2015,(4):33-36

近年来众多高分辨率遥感卫星的发射为城市绿地信息提取提供了高效的手段,如何充分利用高分辨率遥感影像对现代城市进行规划和生态环境评价具有重要意义。文中介绍一个完整的遥感工程在ENVI下的实现过程,包含高分辨率数据的处理、高分辨率信息提取流程的合理安排、FX模块面向对象信息提取等内容,可全面快速掌握城市绿地总量与分布现状,为绿地系统规划与日常管理决策提供参考,对生态城市建设具有重要意义。  相似文献