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111.
Diagenesis of vascular plant organic matter components during burial in lake sediments 总被引:12,自引:0,他引:12
Diagenetic changes are difficult to distinguish from variations in sources of organic matter to sediments. Organic geochemical comparisons of samples of wood, bark, and needles from a white spruce (Picea glauca) living today and one buried for 10,000 years in lake sediments have been used to identify the effects of diagenesis on vascular plant matter. Important biogeochemical changes are evident in the aged spruce components, even though the cellular structures of the samples are well preserved. Concentrations of total fatty acids dramatically diminish; unsaturated and shorter chainlength components are preferentially lost from the molecular distributions. Concentrations of total alcohols are similar in the modern and 10,000-year-old wood and bark but markedly lowered in the aged needles. Hydrocarbon concentrations and distributions show little diagenetic change in the 10,000-year-old plant materials. Cellulose components in the wood decrease relative to lignin components, although both types of materials remain in high concentration in comparison to other organic components. Aromatization of abietic acid proceeds more rapidly in buried spruce wood than in bark; retene is the dominant polyaromatic hydrocarbon in the aged wood. In contrast to the variety of changes evident in molecular compositions, neither 13C values nor C/N ratios differ significantly in the bulk organic matter of modern and aged spruce components. 相似文献
112.
A. Hofzumahaus T. Brauers U. Platt J. Callies 《Journal of Atmospheric Chemistry》1992,15(3-4):283-298
The latitudinal variation of the photolysis frequency of ozone to O(1D) atoms, J(O1D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O1D) noon values exhibited a maximum of 3.6×10-5 s-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O1D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O1D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O1D) measurements and simultaneously recorded O3 and H2O mixing ratios. While the latitudinal distribution of J(O1D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH. 相似文献
113.
预测陕西关中地区需水量的改进GM(1,1)模型 总被引:6,自引:0,他引:6
需水量评价与预测是水资源规划与管理一项重要的研究内容。本文采用定额法计算需水量。通过对陕西关中地区需水量要素组成的分析,认为需水量要素属平稳时间序列,且一阶累加生成数据系列满足指数规律,符合灰色预测条件。为了提高GM(1,1)模型的精度,采用一种改变背景值的新方法,即:中心逼近方法。通过精度检验,中心逼近式GM(1,1)模型平均误差百分比、误差平方和分别比传统的GM(1,1)模型提高了0.147和1.579。用中心逼近式GM(1,1)模型预测需水量各要素近期和中长期值,经检验,其中非农业人口、农业人口、耕地面积、工业总产值预测模型满足一级模型,等级为良好。牲畜头数预测模型为不合格模型,分析其原因,主要是因为时间序列数据不完全符合指数规律。通过定额法计算,预计75%保证率时2005年和2010年关中地区工农业需水量分别占总需水量的92.21%和89.75%,生活需水量分别占7%和9.04%。 相似文献
114.
Franco Tassi Orlando Vaselli Elena Lognoli Fabrizio Cuccoli Barbara Nisi Elena Ramaldi Sandro Moretti Luca Lombardi Bruno Capaccioni 《中国地球化学学报》2006,25(B08):70-71
Mt. Amiata (Southern Tuscany, Central Italy) is an extinct Quaternary volcano located in an area still marked by high heat-flow that is caused by deep seated (6-10 km) hot masses related to Pliocene magmatic activity. The anomalous geothermal gradient gives rise, within the Mesozoic limestone formation (Tuscan series), to geothermal systems that fed the Ca-SO4 thermal springs characterizing this area. Besides of thermal fluids, several cold, dry CO2-rich gas emissions seep out on the NE flank of the volcano. These gas vents mostly consist of large sub-circular craters at variable depth and diameter (5-15 m and 10-50 m, respectively), and represent a serious hazard for the local population, as testified by the several asphyxia casualties that have been repeatedly occurred within these morphological depressions. In this work, the chemical and isotopic compositions of the Mt. Amiata "CO2-rich gas vents" and the estimation of both the CO2 flux from the soil and the CO2 distribution in air of their surroundings, has been carried out in order to: (1) assess the origin of gases, (2) recognize the mechanism of formation for these gas emissions and their relationship with local tectonics, and (3) to evaluate the CO2 hazard in the high flux emanations. The chemical composition of the gases is largely dominated by CO2 (up to 98 % by vol) and shows relatively high concentrations of N2, CH4 and H2S (up to 1.1%, 0.9% and 3.9 % by vol, respectively). These features, coupled with the carbon and nitrogen isotopic signatures, suggest that the origin of the main gas compounds may be related to the contribution of deep (i.e., thermometamorphic processes on carbonate formations for CO2) and shallow (i.e. thermal decomposition of organic material for CH4, N2 and H2S) sources. 相似文献
115.
The Guará and Botucatu formations comprise an 80 to 120 m thick continental succession that crops out on the western portion of the Rio Grande do Sul State (Southernmost Brazil). The Guará Formation (Upper Jurassic) displays a well-defined facies shift along its outcrop belt. On its northern portion it is characterised by coarse-grained to conglomeratic sandstones with trough and planar cross-bedding, as well as low-angle lamination, which are interpreted to represent braided river deposits. Southwards these fluvial facies thin out and interfinger with fine- to medium-grained sandstones with large-scale cross-stratification and horizontal lamination, interpreted as eolian dune and eolian sand sheets deposits, respectively. The Botucatu Formation is characterised by large-scale cross-strata formed by successive climbing of eolian dunes, without interdune and/or fluvial accumulation (dry eolian system). The contact between the Guará and the Botucatu formations is delineated by a basin-wide deflation surface (supersurface). The abrupt change in the depositional conditions that took place across this supersurface suggests a major climate change, from semi-arid (Upper Jurassic) to hyper-arid (Lower Cretaceous) conditions. A rearrangement of the Paraná Basin depocenters is contemporaneous to this climate change, which seems to have changed from a more restrict accumulation area in the Guará Formation to a wider sedimentary context in the Botucatu Formation. 相似文献
116.
A. B. Kuznetsov M. A. Semikhatov A. V. Maslov I. M. Gorokhov E. M. Prasolov M. T. Krupenin I. V. Kislova 《Stratigraphy and Geological Correlation》2006,14(6):602-628
New data on Sr-and C-isotopic systematics of carbonate rocks from the Upper Riphean stratotype (Karatau Group of the southern Urals) are obtained for several southwestern sections of the Bashkirian meganticlinorium, which have not been studied before. The results obtained supplement the Sr-and C-isotopic information for the group upper horizons thus detailing chemostratigraphic characterization of the entire succession. Limestone and dolostone samples used to analyze the Sr isotope composition satisfy strict geochemical criteria of the isotopic system retentivity and have been subjected to preliminary treatment in ammonium acetate to remove secondary carbonate phases. Data on 255 samples of carbonate rocks (171 studied for the first time) show that δ13C value varies in the Karatau Group succession from ?2.8 to +5.9 ‰ V-PDB with several in-phase excursions from the general trend in all the sections studied in the area 90 × 130 km. The δ13C variation trend demarcates several levels in the carbonate succession of the Karatau Group suitable for objectives of regional stratigraphy and for C-isotope chemostratigraphic subdivision of the Upper Riphean. The results of Sr isotopic analysis of 121 samples (51 unstudied before) from the Karatau Group imply that rocks in its lower part (the Katav Formation and basal horizon of the Inzer Formation) experienced considerable secondary alterations, while limestones and dolostones of the overlying interval of the group are frequently unaltered. In the “best” samples satisfying geochemical criteria of the isotopic system retentivity, the 87Sr/86Sr initial ratio increases from 0.70521–0.70532 in the lower Inzer deposits to 0.70611 in the upper Min’yar carbonates, decreasing to <0.70600 near the top of the latter. Above the regional hiatus separating the Min’yar and Uk formation, this ratio grows from 0.70533 to 0.70605–0.70609 in the limestone succession of the last formation. 相似文献
117.
The páramo is a neotropical alpine ecosystem that covers more than 75,000 km2 of the northern Andes of Colombia, Ecuador, Venezuela, and Peru. It provides important environmental services: more than 10 million people in the Andean highlands benefit from the water supply and regulation function, which is attributed to the volcanic soils that underlie the ecosystem. The soils are also major carbon sinks of global significance. Severe land use changes and soil degradation threaten both the hydrology and carbon sink function. Nevertheless, soil genesis and properties in the páramo is rather poorly understood, nor are their ecological functions well documented. The impact of the geomorphology of the páramo on soil genesis was studied in the rio Paute basin, south Ecuador. Two toposequences were described and analysed. In each toposequence, four pedons were selected representing summit, backslope, undrained plain situation, and valley bottom positions in the landscape. The soils are classified as Hydric Andosols in the World Reference Base for Soil Resources and Epiaquands or Hydrudands in Soil Taxonomy. They are very acidic and have a high organic matter content, high P deficiency, and Al toxicity. Their water content ranges from 2.64 g g− 1 at saturation, down to 1.24 g g− 1 at wilting point, resulting in a large water storage capacity. Two major soil forming processes are identified: (1) volcanic ash deposition and (2) accumulation of organic carbon. Volcanic ash deposits may vary in depth as a result of regional geomorphological factors such as parent material, orientation, slope, and altitude. Organic carbon accumulation is an interaction of both waterlogging, which depends on the position in the landscape, and the formation of organometallic complexes with Al and Fe released during volcanic ash breakdown. Despite the high variability in parent material and topography, the soil is characterised by a notable homogeneity in physico-chemical properties. Statistical analysis reveals that only topographic location has a slight but significant influence on soil pH as well as the organic matter content, saturated conductivity and water retention at high pressure. Finally, the exceptional properties of these soils provide useful insights to improve classification of the Andosols reference group of the FAO World reference Base for Soil Resources. 相似文献
118.
Nanna Noe-Nygaard Mikkel U. Hede 《Geografiska Annaler: Series A, Physical Geography》2006,88(2):87-95
Stable carbon and nitrogen isotope ratios from bones of contemporaneous Late Atlantic aurochs and early cattle in eastern Denmark are significantly different and provide information on the origin and feeding strategies of the earliest domestic cattle. The data show that the early cattle were feeding on grass right from the beginning 4000 cal. yr BC. In contrast, the youngest aurochs population primarily browsed and grazed from the dense forest floor resulting in rather negative δ13C values measured on bone collagen. The oldest aurochs have similar isotope values to the earlier cattle, whereas the youngest aurochs have similar values to Late Atlantic red deer from the same locality. As eastern Denmark was largely covered by forest, speculations on the origin of the grazing areas are many. The grass may have grown in openings in the forest, at the forest fringe, or more likely on the newly reclaimed coastal land areas exposed by the decreasing rate of eustatic sea‐level rise contemporaneously with isostatic uplift, during the Littorina transgressions. The stable isotope values do not indicate that leaf foddering of the early cattle was of importance. 相似文献
119.
Nadia Curetti Davide Levy Alessandro Pavese Gabriella Ivaldi 《Physics and Chemistry of Minerals》2006,32(10):670-678
The elastic properties of coexisting natural 3T and 2M
1 phengite samples (Cima Pal, Sesia Zone; Val Savenca; Western Alps, Italy) with similar chemical compositions have been studied by room temperature–high pressure powder diffraction, using synchrotron radiation on the ID9A beam-line at ESRF (Grenoble, France). The P–V curves have been modelled by the Birch–Murnaghan model; a third-order expansion fitted to the experimental data yields for 3T and 2M
1 K
0=60.4(±0.7) GPa, K′=5.79(±0.11) at V
0=703.8851 Å3, and K
0=57.3(±1.0) GPa, K′=6.97(±0.24) at V
0=938.8815 Å3, respectively. The relative stability of 3T vs. 2M
1 has been explored as a function of pressure and temperature in terms of configuration and deformation contributions to the Gibbs energy, using the elastic properties determined here and other thermodynamic parameters from earlier investigations. The results presented agree with the hypothesis of stability of the 3T polytype in the high pressure regime. 相似文献
120.
Monitoring of Over Cutting Area and Lubrication Distribution in a Large Slurry Pipe Jacking Operation 总被引:1,自引:0,他引:1
Saeid Khazaei Hideki Shimada Takashi Kawai Junichi Yotsumoto Kikuo Matsui 《Geotechnical and Geological Engineering》2006,24(3):735-755
Slurry pipe jacking was firmly established as a special method for the non-disruptive construction of the underground pipelines
of sewage systems. Pipe jacking, in its traditional form, has occasionally been used for short railways, roads, rivers, and
other projects. Basically the system involves the pushing or thrusting of concrete pipes into the ground by a number of jacks.
In slurry pipe jacking, during the pushing process, mud slurry and lubricant are injected into the face and the over cutting
area that is between the concrete pipes and the surrounding soil. Next, the slurry fills voids and the soil stabilizes due
to the created slurry cake around the pipes. Fillings also reduce the jacking force or thrust during operation. When the drivage
and pushing processes are finished, a mortar injection into the over cutting area is carried out in order to maintain permanent
stability of the surrounding soil and the over cutting area. Successful lubrication around the pipes is extremely important
in a large diameter slurry pipe jacking operation.
Control of lubrication and gaps between pipes and soil can prevent hazards such as surface settlement and increases in thrust.
Also, to find voids around the pipes after the jacking process, in order to inject mortar for permanent stabilizing, an investigation
around the pipes is necessary. To meet these aims, this paper is concerned with the utilization of known methods such as the
GPR (Ground Penetrating Radar) system and borehole camera to maintain control of the over cutting area and lubricant distribution
around the pipes during a site investigation. From this point of view, experiments were carried out during a tunnel construction
using one of the largest cases of slurry pipe jacking in Fujisawa city, Japan. The advantages and disadvantages of each system
were clarified during the tests. 相似文献