Structural Evolvement of Heating Treatment of Mg/AI-LDH and Preparation of Mineral Mesoporous Materials     

CHEN Tianhu XU Huifang WANG Yifeng QING Chengsong FAN Mingde CHEN Gang 《《地质学报》英文版》2006,80(2):170-174

Although hydrotalcite, or layered double hydroxides （LDHs）, is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of （Mg, Al）-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like （Mg, Al）-oxide is transformed into a composite with periclase （MgO） and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.  相似文献   

Modeling the cyclic swelling pressure of mudrock using artificial neural networks     

M. Moosavi  M.J. Yazdanpanah  R. Doostmohammadi 《Engineering Geology》2006,87(3-4):178-194

The stochastic nature of the cyclic swelling behavior of mudrock and its dependence on a large number of interdependent parameters was modeled using Time Delay Neural Networks (TDNNs). This method has facilitated predicting cyclic swelling pressure with an acceptable level of accuracy where developing a general mathematical model is almost impossible. A number of total pressure cells between shotcrete and concrete walls of the powerhouse cavern at Masjed–Soleiman Hydroelectric Powerhouse Project, South of Iran, where mudrock outcrops, confirmed a cyclic swelling pressure on the lining since 1999. In several locations, small cracks are generated which has raised doubts about long term stability of the powerhouse structure. This necessitated a study for predicting future swelling pressure. Considering the complexity of the interdependent parameters in this problem, TDNNs proved to be a powerful tool. The results of this modeling are presented in this paper.  相似文献   

Analysis of a rigid footing lying on three-layered soil using the finite difference method     

Priti Maheshwari  M. R. Madhav 《Geotechnical and Geological Engineering》2006,24(4):851-869

A numerical procedure is described for the analysis of the vertical deformation and the stress distribution of the strip footings on layered soil media. Three layers of soil with different stiffness are considered with the middle soil layer the thinnest and most stiff layer. The soil media is discretized and using the theory of elasticity, the governing differential equations are obtained in terms of vertical and horizontal displacements. These equations along with appropriate boundary and continuity conditions are solved by using the finite difference method. The vertical and horizontal displacements, strains and stresses are found at various nodes in the soil media. Parametric studies are carried out to study the effect of the placement depth of the middle soil layer, the relative ratios of the moduli of deformation of the soil layers on the vertical displacement of the footing and the vertical stress distribution. These studies reveal that the middle thin but very stiff layer acts like a plate and redistributes the stresses on the lower soft soil layer uniformly. The displacement on the top and bottom of the middle soil layer is almost the same showing that the compression of the middle layer is negligible as it is very stiff.  相似文献   

Time domain Gauss–Newton seismic waveform inversion in elastic media     

Dong-Hoon Sheen  Kagan Tuncay  Chang-Eob Baag  Peter J. Ortoleva 《Geophysical Journal International》2006,167(3):1373-1384

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Dual simulations of fluid flow and seismic wave propagation in a fractured network: effects of pore pressure on seismic signature   总被引：1，自引：0，他引：1  

S. Vlastos  E. Liu  I. G. Main  M. Schoenberg  C. Narteau  X. Y. Li  B. Maillot 《Geophysical Journal International》2006,166(2):825-838

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Traction image method for irregular free surface boundaries in finite difference seismic wave simulation   总被引：16，自引：1，他引：16  

Wei Zhang  Xiaofei Chen 《Geophysical Journal International》2006,167(1):337-353

In this study, we propose a new numerical method, named as Traction Image method, to accurately and efficiently implement the traction-free boundary conditions in finite difference simulation in the presence of surface topography. In this algorithm, the computational domain is discretized by boundary-conforming grids, in which the irregular surface is transformed into a 'flat' surface in computational space. Thus, the artefact of staircase approximation to arbitrarily irregular surface can be avoided. Such boundary-conforming gridding is equivalent to a curvilinear coordinate system, in which the first-order partial differential velocity-stress equations are numerically updated by an optimized high-order non-staggered finite difference scheme, that is, DRP/opt MacCormack scheme. To satisfy the free surface boundary conditions, we extend the Stress Image method for planar surface to Traction Image method for arbitrarily irregular surface by antisymmetrically setting the values of normal traction on the grid points above the free surface. This Traction Image method can be efficiently implemented. To validate this new method, we perform numerical tests to several complex models by comparing our results with those computed by other independent accurate methods. Although some of the testing examples have extremely sloped topography, all tested results show an excellent agreement between our results and those from the reference solutions, confirming the validity of our method for modelling seismic waves in the heterogeneous media with arbitrary shape topography. Numerical tests also demonstrate the efficiency of this method. We find about 10 grid points per shortest wavelength is enough to maintain the global accuracy of the simulation. Although the current study is for 2-D P-SV problem, it can be easily extended to 3-D problem.  相似文献   

A traveltime reciprocity discrepancy in the Podvin & Lecomte time3d finite difference algorithm     

Ari Tryggvason  Björn Bergman 《Geophysical Journal International》2006,165(2):432-435

We have found that the extensively used finite difference scheme time3d produces time fields which are 'asymmetric' in the sense that traveltimes computed to the right of the source are faster than traveltimes computed to the left. All finite difference schemes will, as they are approximations to the wave equation, to some extent fail to obey reciprocity perfectly. We show, however, that the errors in time3d may be significant—and unnecessarily large. An asymmetry in the point source initialization has been identified, and after correction time3d produces time fields with an improved reciprocity.  相似文献   

基于有限差分法的抗滑桩计算机辅助设计   总被引：3，自引：0，他引：3  

杨佑发  黄小鹏 《中国地质灾害与防治学报》2006,17(2):95-98

基于地基系数“m-m”法、“m-k”法、“k-k”法的原理,考虑桩顶和桩底边界条件以及桩在滑动面处位移、转角、弯矩和剪力的连续条件,可解得桩身各节点的位移和内力,提出了进行抗滑桩全桩内力计算的有限差分法。根据差分方程并用VB6.0编制了实用的计算程序,既可避免繁琐的查表计算,提高计算速度,又可提高计算精度,直观生动,真正实现了人机交互,在界面的引导下,设计人员可完成全部计算,并绘出内力图形和抗滑桩截面配筋图,使设计更方便快捷,该软件可以极大地提高生产效率,降低工程造价,从而实现抗滑桩的优化设计。最后采用上述方法对某滑坡的悬臂抗滑桩进行了设计与计算。  相似文献   

惯性／双星组合导航系统的滤波与仿真   总被引：2，自引：0，他引：2  

蔺玉亭李洪涛  孙付平吴太旗 《测绘学院学报》2005,22(1):21-23

介绍了惯性导航系统和双星导航系统各自的运行方式和优缺点；详细推导了组合导航系统的误差方程和量测方程；介绍了Kalman滤波的整个过程并最后进行了仿真计算。仿真结果显示，惯性导航系统和双星导航系统的组合弥补了各自的不足，具有较好的精度和可靠性。  相似文献   

碳酸盐岩溶洞型储层反演方法     

王晓梅  唐文榜  李学著  杨勇 《物探与化探》2005,29(1):44-46

常规声波反演的方法原理和反演技术以层状介质为基础,其研究目标多是层状储层。碳酸盐岩溶洞型储层具有非规则形态、非均匀散布的特征,常规声波反演技术有其不适应之处。笔者研究的测井约束多重反演技术,解决了非层状、非均匀储层的地震反演问题,得出反映碳酸盐岩溶洞储层信息的波阻抗数据体,提取了突出溶洞型储集体低速特征的差异波阻抗,为寻找碳酸盐岩溶洞型油气藏提供了可靠的依据。  相似文献