The assemblage diaspore+quartz in metamorphic rocks: a petrological, experimental and thermodynamic study   总被引：1，自引：0，他引：1  

T. THEYE  C. CHOPIN  K.-D. GREVEL  & E. OCKENGA 《Journal of Metamorphic Geology》1997,15(1):17-28

The upper pressure limit of pyrophyllite is given by the equilibria (i) pyrophyllite=diaspore+quartz and (ii) pyrophyllite=diaspore+coesite. High- P experimental investigations carried out to locate equilibrium (i) yield brackets between 497 °C/24.8  kbar and 535 °C/25.1  kbar, and between 500 °C/23  kbar and 540 °C/23  kbar. Equilibrium (ii) was bracketed at 550 °C between 26.0 and 28.3  kbar. In the experimental P–T  range, equilibria (i) and (ii) are metastable with respect to kyanite. A stable P–T  grid is calculated using thermodynamic data derived under consideration of the present experimental results. According to these data, the lower pressure limit of the assemblage diaspore+quartz according to equilibrium (i) range from about 12  kbar/300 °C to 20  kbar/430 °C (in the presence of pure water). The upper stability of diaspore+quartz is limited by the reaction diaspore+quartz=kyanite+H₂O at about 450 °C (nearly independent of pressure) and, to higher pressure, by the quartz=coesite transition. Equilibrium (ii) is metastable over the whole P–T  range.
Natural occurrences600.S of the diaspore–quartz assemblage in metamorphic rocks in Sulawesi, New Caledonia, Amorgos and the Vanoise are characterized by minerals indicative of high- P such as ferro-magnesiocarpholite, glaucophane, sodic pyroxene and lawsonite. The metamorphic P–T  conditions of these rocks are estimated to be in the range 300–400 °C, >8  kbar. These data are compatible with the derived P–T  stability field of the diaspore+quartz assemblage. We conclude that, in metamorphic rocks, diaspore+quartz is, as ferrocarpholite, an indicator for unusual low- T  /very high- P settings.  相似文献   

Accurate area determination in the cadaster: case study of Slovenia     

Sandi Berk  Miran Ferlan 《制图学和地理信息科学》2018,45(1):1-17

This paper discusses methodological problems of accurate area determination in the cadaster. The paper contrasts the ambiguous legal definition of the parcel boundary and parcel area in relation to the theoretically well-defined geodetic parcel boundary and the geodetic parcel area on the reference ellipsoid. To align with the real world, parcel area must account for terrain elevation. Various approximate methods for area determination which can be used in the cadaster are tested. A highly accurate method for parcel area computation is proposed, based on an equal-area projection. Considering the geodetic parcel area as a reference, the achievable accuracy of different methods is evaluated. For this analysis, the coordinates of the parcel boundary points are treated as error-free. Finally, the relevance of various systematic errors is discussed in relation to the statistical uncertainty of the parcel area, which could be gained by an a real-time kinematic GNSS survey. A case study is presented for the territory of Slovenia, its georeferencing rules, land demarcation pattern, and characteristics of its topography. Based on the results of this study, some general recommendations for the parcel area determination are given.  相似文献   

The generation and evolution of the Archean continental crust: The granitoid story in southeastern Brazil     

《地学前缘(英文版)》2022,13(4):101402

The Archean Eon was a time of geodynamic changes. Direct evidence of these transitions come from igneous/metaigneous rocks, which dominate cratonic segments worldwide. New data for granitoids from an Archean basement inlier related to the Southern São Francisco Craton (SSFC), are integrated with geochronological, isotopic and geochemical data on Archean granitoids from the SSFC. The rocks are divided into three main geochemical groups with different ages: (1) TTG (3.02–2.77 Ga); (2) medium- to high-K granitoids (2.85–2.72 Ga); and (3) A-type granites (2.7–2.6 Ga). The juvenile to chondritic (Hf-Nd isotopes) TTG were divided into two sub-groups, TTG 1 (low-HREE) and 2 (high-HREE), derived from partial melting of metamafic rocks similar to those from adjacent greenstone belts. The compositional diversity within the TTG is attributed to different pressures during partial melting, supported by a positive correlation of Dy/Yb and Sr/Zr, and batch melting calculations. The proposed TTG sources are geochemically similar to basaltic rocks from modern island-arcs, indicating the presence of subduction processes concomitant with TTG emplacement. From ～2.85 Ga to 2.70 Ga, the dominant rocks were K-rich granitoids. These are modeled as crustal melts of TTG, during regional metamorphism indicative of crustal thickening. Their compositional diversity is linked to: (i) differences in source composition; (ii) distinct melt fractions during partial melting; and (iii) different residual mineralogies reflecting varying P–T conditions. Post-collisional (～2.7–2.6 Ga) A-type granites reflect rifting in that they were closely followed by extension-related dyke swarms, and they are interpreted as differentiation or partial melting products of magmas derived from subduction-modified mantle. The sequence of granitoid emplacement indicates subduction-related magmatism was followed by crustal thickening, regional metamorphism and crustal melting, and post-collisional extension, similar to that seen in younger Wilson Cycles. It is compelling evidence that plate tectonics was active in this segment of Brazil from ～3 Ga.  相似文献   

基于ArcGIS的三维航测成果在露天采坑生态修复与矿山生产中的应用研究          下载免费PDF全文

张启慧  王程松  卫石印  董玉芬  冯英明 《山东国土资源》2022,38(10)

基于ArcGIS的三维航测成果在生态修复与露天矿山生产中具有广泛的应用前景。针对日照某地露天矿坑地质环境现状,在无人机三维航测的基础上,运用ArcGIS的相关功能,对矿坑生态修复设计,土石方余量计算、指导露天矿山生产中以及三维可视化展示等方面的应用进行了研究。通过多次无人机航测,获取项目实施过程中的多期DSM数据,进一步实现生态修复全过程、矿山生产全过程的监理、动态储量监测。  相似文献   

Insights into oxygen-cation bonding in fresnoite-type structures from O <Emphasis Type="Italic">K</Emphasis>- and Ti <Emphasis Type="Italic">L</Emphasis><Subscript>23</Subscript>-electron energy-loss spectra and ab initio calculations of the electronic structure     

P. A.?van AkenEmail author  T.?H?che  F.?Heyroth  R.?Keding  R.?Uecker 《Physics and Chemistry of Minerals》2004,31(8):543-552

O K- and Ti L₂₃-core-loss spectra of fresnoite Ba₂TiSi₂O₈ (BTS) and Sr₂TiSi₂O₈ (STS), which is isotypic to BTS, have been measured by electron energy-loss spectroscopy (EELS). The energy-loss near-edge structures (ELNES) of the O K edge have been identified on the basis of theoretical simulations and interpretations of the X-ray absorption near-edge structures (XANES), which have been modelled in the framework of self-consistent full multiple-scattering (FMS) theory using FEFF8. Herewith, the K-absorption spectra of oxygen (E) and the local partial electron density of states (DOS) of all atoms have been calculated. For BTS, the observed spectral features in the O K-edge spectra are interpreted in terms of mixing between the central O p and neighbouring Ba 5d and 4f, Si 3p and 3d, and Ti 3d orbitals. The observed differences in the O K-edge spectra for STS and BTS can mainly be attributed to three properties: (1) The lack of high local partial Sr unoccupied DOS with 4f symmetry near the Fermi level compared to the high Ba 4f unoccupied DOS results in differences of overlapping O 2p – cation orbitals. (2) The differences in the ionic radii of Sr and Ba result in a larger unit cell for BTS and, thus, in larger oxygen-cation bonding distances. (3) In comparison to STS, the strength of the incommensurate 2-D structural modulation is significantly weaker in BTS, i.e. distortions of coordination polyhedra occur to a much lesser extent. All these effects alter the oxygen-cation hybridization and, hence, result in a variation of the O 1s p transition and consequently of the O K-edge spectral shape. The observed peak broadening in Ti L₂₃ ELNES of STS compared to BTS is correlated with strong displacive modulations hosted in STS.  相似文献   

First-principles simulation of high-pressure polymorphs in MgAl<Subscript>2</Subscript>O<Subscript>4</Subscript>     

Shigeaki Ono  John P. Brodholt  G. David Price 《Physics and Chemistry of Minerals》2008,35(7):381-386

We have used density functional theory to investigate the stability of MgAl₂O₄ polymorphs under pressure. Our results can reasonably explain the transition sequence of MgAl₂O₄ polymorphs observed in previous experiments. The spinel phase (stable at ambient conditions) dissociates into periclase and corundum at 14 GPa. With increasing pressure, a phase change from the two oxides to a calcium-ferrite phase occurs, and finally transforms to a calcium-titanate phase at 68 GPa. The calcium-titanate phase is stable up to at least 150 GPa, and we did not observe a stability field for a hexagonal phase or periclase + Rh₂O₃(II)-type Al₂O₃. The bulk moduli of the phases calculated in this study are in good agreement with those measured in high-pressure experiments. Our results differ from those of a previous study using similar methods. We attribute this inconsistency to an incomplete optimization of a cell shape and ionic positions at high pressures in the previous calculations.  相似文献   

Theoretical study of point defects in crystalline zircon     

J.-P. Crocombette 《Physics and Chemistry of Minerals》1999,27(2):138-143

We present a numerical study of point defects in crystalline zircon (ZrSiO₄). Vacancies and interstitials of all the constituents of zircon have been considered. For each defect, the structure and the formation energies have been calculated. Calculations, using the supercell method, are based on the Density Functional Theory in the Local Density Approximation. Empirical potentials have also been considered for comparison with electronic structure results. We find a formation energy for the oxygen interstitial of 1.7 eV. This value is compatible with the experimental activation energy for oxygen diffusion in zircon, which proves an interstitial mechanism for the diffusion of oxygen in zircon. For all other defects the calculated formation energies lead to negligible thermal concentration at equilibrium. Received: 8 January 1999 / Revised, accepted: 14 May 1999  相似文献   

Mössbauer and molecular orbital study of chlorites     

A. Lougear  M. Grodzicki  C. Bertoldi  A. X. Trautwein  K. Steiner  G. Amthauer 《Physics and Chemistry of Minerals》2000,27(4):258-269

The different Fe²⁺ lattice sites in iron-rich chlorites have been characterized by Mössbauer spectroscopy and molecular orbital calculations in local density approximation. The Mössbauer measurements were recorded at 77?K within a small velocity range (±3.5?mm?s^?1) to provide high energy resolution. Additionally, measurements were recorded in a wider velocity range (±10.5?mm?s^?1) at temperatures of 140, 200, and 250?K in an applied field (7?T) parallel to the γ-beam. The zero-field spectra were analyzed with discrete Lorentzian-shaped quadrupole doublets to account for the Fe²⁺ sites M1, M2, and M3 and with a quadrupole distribution for Fe³⁺ sites. Such a procedure is justified by the results obtained from MO calculations, which reveal that different anion (OH^?) distributions in the first coordination sphere of M1, M2, and M3 positions have more influence on the Fe²⁺ quadrupole splitting than cationic disorder. The spectra recorded in applied field were analyzed in the spin-Hamiltonian approximation, yielding a negative sign for the electric field gradient (efg) of Fe²⁺ in the M1, M2, and M3 positions. The results of the MO calculations are in quantitative agreement with experiment and reveal that differences in the quadrupole splittings (ΔE _Q ), their temperature dependence and in the isomer shifts (δ) of Fe²⁺ in M1, M2, and M3 positions can theoretically by justified. Therefore, the combined Mössbauer and MO investigation shows that the three Fe²⁺ lattice sites in the chlorites investigated here can be discriminated according to their ΔE _Q -δ parameter pairs. With the calculated average iron-oxygen bond strength, the MO study provides an explanation for the observed trend that the population of the three lattice sites by Fe²⁺ increases according to the relation M1?相似文献   

结合无人船与网络RTK技术测量露天矿坑土方量     

吉绪发 《测绘通报》2019,(7):151-155

利用无人测量船与网络RTK技术联合测量某一涵盖水陆区域的填挖土方量。其中，利用无人船系统测量水下地形，利用网络RTK测量陆地地形，并将水陆两部分的地形数据融合，利用基于不规则三角网的DTM法计算了该区域的填挖土方量，同时得到水域部分的水下地形图，为后续施工建设提供了基础资料。本文提出的结合无人船和网络RTK技术测量复杂水陆地形的方案可为相关工程的测量实践提供参考依据。  相似文献   

Ab initio calculations on the O<Subscript>2</Subscript><Superscript>3−</Superscript>-Y<Superscript>3+</Superscript> center in CaF<Subscript>2</Subscript> and SrF<Subscript>2</Subscript>: its electronic structure and hyperfine constants     

Sanda M. Botis  Davy A. Adriaens  Yuanming Pan 《Physics and Chemistry of Minerals》2009,36(1):1-7

The O₂ ^3?-Y³⁺ center in fluorite-type structures (CaF₂ and SrF₂) has been investigated at the density functional theory (DFT) level using the CRYSTAL06 code. Our calculations were performed by means of the hybrid B3PW method in which the Hartree–Fock exchange is mixed with the DFT exchange functional, using Becke’s three parameter method, combined with the non-local correlation functionals by Perdew and Wang. Our calculations confirm the stability and the molecular character of the O₂ ^3?-Y³⁺ center. The unpaired electron is shown to be almost exclusively localized on and equally distributed between the two oxygen atoms that are separated by a bond distance of 2.47 Å in CaF₂ and 2.57 Å in SrF₂. The calculated ¹⁷O and ¹⁹F hyperfine constants for of the O₂ ^3?-Y³⁺ center are in good agreement with their corresponding experimental values reported by previous electron paramagnetic resonance and electron nuclear double resonance studies, while discrepancies are notable for the ⁸⁹Y hyperfine constants.  相似文献