锂离子选择电极的研究 Ⅲ.：开链聚醚三（二环己酰胺）锂电极的制备和应用          下载免费PDF全文

钱国英  焦天权 《盐湖研究》1993,1(3):46-51

以合成的开链聚醚三(二环己酰胺)等中性载体制成了PVC膜Li~+电极,研究了载体结构、膜成分与电极性能的关系,在聚醚三酰胺的胺基中,以环己基取代直链的烷基,显著地改善了Li~+—载体的性能,以邻苯二甲酸二癸酯或其和二苄醚混合增塑的1,1,1—三[1′—(2′—氧杂—3′—二环己胺基羰基)丙基]丙烷Li~+—电极的线性响应范围为2×10~(-5)～10~(-1)mol/L LiCl,K_(Li+Na)~(pot)～8×10~(-3),以Mg(Ac)_2为离子强度调节缓冲剂,用标准比较法或样品加入法测定了LiCl—HCl—H_2O或LiCl—MgCl_2—HCl—H_2O体系中的Li~+,LiCl含量≥2％的样品,测定误差≤5％。  相似文献   

闽粤台沿海北西西向最新构造带与大震构造背景   总被引：3，自引：0，他引：3       下载免费PDF全文

毕福志  袁又申 《地震地质》1990,12(2):183-192,T001

闽粤台沿海自台湾运动以来逐渐形成了多条北西西向隆起—拗陷的最新活动构造带,与已知的北东—北北东向隆起、拗陷带构成了区域性镶嵌构造格局。 研究区内除板块相互碰撞、俯冲及上地幔物质上涌形成大震构造背景外,莫霍面隆起或隆起断距大、低速层厚、地壳变薄、近两、三千年地表抬升差异活动显著以及台东近海有北西西向构造活动等,也都是发生大震的重要构造背景  相似文献   

黑河地区高分辨陆地分类的综合分析     

李素华  颜宏 《高原气象》1990,9(2):220-227

本文综合了国内外诸种有关资料,借鉴了国际上较通用的下垫面特征分类标准,也结合黑河地区下垫面的实际情况,对HEIFE试验区及其邻近地区的下垫面特征(包括地表特征、土壤特征及地形高度)进行归纳分类,形成了两种高分辨率(分别约为6km×6km及3km×3km)的下垫面特征的格点化资料,可供该地区地气相互作用研究用。  相似文献   

A digital model to evaluate the water balance in a typical hardrock environment     

B. H. Briz-Kishore 《Journal of Earth System Science》1984,93(4):413-422

A digital model was designed and developed to study the water balance situation in a typical hardrock environment near Hyderabad, Andhra Pradesh. The model was calibrated over a period of six years with observed field hydrographs. An optimum error factor of 0.001 m was chosen and the computer took 47 iterations for outputting the results with the desired accuracy. Prognostic studies were carried out with progressively increasing draft conditions and water levels were observed to be declining even when the draft was less than the recharge. The analysis of the experiments further amended the belief of the earlier workers.  相似文献   

单站点无地面控制摄影机自检校     

袁修孝  朱宜萱 《武汉大学学报(信息科学版)》1987,(4)

“单站点无地面控制摄影机自检校”是一种利用纯摄影测量信息检校摄影机的方法。本文由共线条件方程出发导出了顾及到摄影机旋转中心与其摄影中心不一致时正直摄影象片与倾斜摄影象片同名象点坐标的几何关系式及线性化的误差方程式。编制了适用于VAX-11/750计算机使用的FORTRAN程序,并给出了用模拟数据和实际数据的计算结果。  相似文献   

Gas chromatographic determination of peroxyacetyl nitrate: Two convenient calibration techniques     

Horst Meyrahn  Günter Helas  Peter Warneck 《Journal of Atmospheric Chemistry》1987,5(4):405-415

Two procedures for the calibration of an electron capture detector (ECD) for peroxyacetyl nitrate (PAN) are discussed. One is based on the first-order decay rate of the the PAN mixing ratio in conditioned glass storage vessels. The other method makes use of the photochemical generation of PAN in mixtures of acetone and NO₂ in air. For this purpose a Penray Hg lamp was inserted into a glass vessel filled with 1 atmosphere of air containing 10 ppm NO₂ and 1% acetone. After 3 min of irradiation, the average PAN mixing ratio formed was 8.87±0.25 ppmv as determined in six separate runs.  相似文献   

A numerically calibrated reference level (MP28) for the terrestrial mammal-based biozonation of the European Upper Oligocene     

Dieter F. Mertz  Paul R. Renne  Michael Wuttke  Clemens Mödden 《International Journal of Earth Sciences》2007,96(2):353-361

The fauna of the Enspel (Westerwald) and the neighbouring Kärlich (Neuwied basin) fossil deposits correspond to the Upper Oligocene Mammal Paleogene (MP) reference level 28 and 28–30, respectively. Basaltic flows and a trachyte tuff terminating and predating the fossil deposit sedimentation allow to numerically calibrate the MP reference levels by radioisotope dating. Laser fusion ⁴⁰Ar/³⁹Ar step heating on volcanic feldspars yield a time interval of 24.9–24.5 Ma for reference level MP28 at Enspel and a maximum age of 25.5 Ma for the time interval MP28–MP30 at Kärlich. Interpolation between the time intervals determined for the Enspel reference level MP28 and the age of the global Oligocene/Miocene boundary of 24.0 ± 0.1 Ma taken from literature results in time intervals of 24.5–24.2 Ma and 24.2–23.9 Ma for the younger reference levels MP29 and MP30, respectively. These intervals of ≤ 0.4 m.y. for MP reference levels of the latest Oligocene are short relative to older Oligocene MP reference levels 21–27 between 34 and 25 Ma. Since subdivision into MP reference levels essentially is based on assemblages of mammal taxa and on evolutionary changes in tooth morphology of mammals short MP time intervals during the latest Oligocene indicate a rapid evolutionary change relative to the early Oligocene.  相似文献   

Defining shore platform boundaries using airborne laser scan data: a preliminary investigation   总被引：1，自引：0，他引：1  

D. R. Palamara  M. E. Dickson  D. M. Kennedy 《地球表面变化过程与地形》2007,32(6):945-953

As an initial evaluation of the potential of digital elevation models (DEMs) and geographic information systems (GISs) for geomorphic characterization of rocky shorelines, airborne laser scan (ALS) data have been used to characterize shore platforms around Shag Point, southeastern New Zealand. The platforms have been characterized using field‐based techniques in previously published research, and therefore offer an ideal site for evaluation purposes. The main challenge involved the delineation of the shore platform area in terms of landward and seaward extents. The cliff top and landward edge of the shore platform was readily mapped, whereas the seaward edge of platforms was mapped with lesser precision due to difficulties associated with tidal inundation and the interference of wave action and surface water. In the central region of the study area (～0·1 km²) higher platform elevations and dense point cloud data enabled the generation of a high‐resolution (1 m) DEM. In analysing the DEM, ALS offered an advantage over the previous field survey in respect of the ability to assess continuous topography in plan‐view. The extent and form of two distinctive erosional surfaces is clearly apparent and was revealed through classifications based on slope and elevation. The spatial continuity of the upper surface implies that, in addition to the role of rock structure described in previous work, sea level and wave exposure may have been important factors in the generation and preservation of platform morphology at Shag Point. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

光电测距仪测距标准差校准结果的不确定度评定     

陈士连  朱红燕  陈益茂  高明 《测绘学报》2002,31(Z1):118-122

介绍光电测距仪的测距标准差计量校准方法并对校准结果的不确定度进行了评定,给出了测距仪的测距标准差校准结果的表示形式和20台测距仪的测距标准差校准结果及测量不确定度.  相似文献   

全站仪近距离测距精度检验方法的探讨   总被引：3，自引：0，他引：3  

李宗春  李广云  范生宏  张森 《测绘信息与工程》2002,27(4):37-39

提出了室内基线法，给出了相应的数据处理方法，并用实测数据进行了计算，结果显示全站仪在室内、短边条件下的测距精度较标称精度有很大的提高。该法所得结果与现存两种方法的结果基本相当，从而证明了该法能够客观地反映出工业测量用全站仪的近距离测距精度。  相似文献