An Atomic Force Microscopy study of the growth of calcite in the presence of sodium sulfate   总被引：1，自引：0，他引：1  

Aikaterini I. Vavouraki  Christine V. Putnis  Andrew Putnis  Petros G. Koutsoukos   《Chemical Geology》2008,253(3-4):243-251

In situ atomic force microscopy (AFM) has been used to compare the growth of pure calcite and the growth of calcite in the presence of sulfate ions from aqueous solutions at a constant value of supersaturation (S.I. = 0.89) with respect to calcite. The effect of sulfate ions on calcite growth rates is determined and a potential incorporation of sulfate ions is identified in the calcite during growth. Solutions supersaturated with respect to calcite with solution concentration ratio of one and a constant pH of 10.2, were prepared and sulfate was added as Na₂SO₄ aqueous solution. The solution composition was readjusted in order to keep the supersaturation and pH constant. PHREEQC was used to determine relevant solution concentrations. In situ AFM experiments of calcite growth were performed using a fluid cell and flowing solutions passed over a freshly cleaved calcite surface. Growth rates were determined from the closure of the rhombohedral etch pits induced by initial dissolution with pure water. The spreading rate of 2-dimensional nuclei was also measured. At low concentrations of sulfate (≤ 0.5 mM), no effect on the growth rate of the calcite was observed. At higher concentrations (2 to 3 mM) of sulfate, the growth rate increased, possibly because a higher concentration of calcium and carbonate was necessary to maintain the supersaturation constant. At much higher concentrations of additional sulfate (up to 60 mM) the growth rate of the calcite was substantially decreased, despite the fact that a further increase of calcium and carbonate was required. The morphology of 2-dimensional growth nuclei became increasingly elongated with increasing sulfate content. Measurements of step height showed that newly grown steps were approximately 1 Å higher when grown in high sulfate concentrations, compared to steps grown in sulfate-free solutions. At sulfate concentrations above 5 mM the growth mechanism changes from layer growth to surface roughening. These observations suggest that the new growth has incorporated sulfate into the calcite surface.  相似文献   

History of crustal growth and recycling at the Pacific convergent margin of South America at latitudes 29°–36° S revealed by a U–Pb and Lu–Hf isotope study of detrital zircon from late Paleozoic accretionary systems     

A.P. Willner  A. Gerdes  H.-J. Massonne 《Chemical Geology》2008,253(3-4):114-129

Detrital zircon provides a powerful archive of continental growth and recycling processes. We have tested this by a combined laser ablation ICP-MS U–Pb and Lu–Hf analysis of homogeneous growth domains in detrital zircon from late Paleozoic coastal accretionary systems in central Chile and the collisional Guarguaráz Complex in W Argentina. Because detritus from a large part of W Gondwana is present here, the data delineate the crustal evolution of southern South America at its Paleopacific margin, consistent with known data in the source regions.Zircon in the Guarguaráz Complex mainly displays an U–Pb age cluster at 0.93–1.46 Ga, similar to zircon in sediments of the adjacent allochthonous Cuyania Terrane. By contrast, zircon from the coastal accretionary systems shows a mixed provenance: Age clusters at 363–722 Ma are typical for zircon grown during the Braziliano, Pampean, Famatinian and post-Famatinian orogenic episodes east of Cuyania. An age spectrum at 1.00–1.39 Ga is interpreted as a mixture of zircon from Cuyania and several sources further east. Minor age clusters between 1.46 and 3.20 Ga suggest recycling of material from cratons within W Gondwana.The youngest age cluster (294–346 Ma) in the coastal accretionary prisms reflects a so far unknown local magmatic event, also represented by rhyolite and leucogranite pebbles. It sets time marks for the accretion history: Maximum depositional ages of most accreted metasediments are Middle to Upper Carboniferous. A change of the accretion mode occurred before 308 Ma, when also a concomitant retrowedge basin formed.Initial Hf-isotope compositions reveal at least three juvenile crust-forming periods in southern South America characterised by three major periods of juvenile magma production at 2.7–3.4 Ga, 1.9–2.3 Ga and 0.8–1.5 Ga. The ¹⁷⁶Hf/¹⁷⁷Hf of Mesoproterozoic zircon from the coastal accretionary systems is consistent with extensive crustal recycling and addition of some juvenile, mantle-derived magma, while that of zircon from the Guarguaráz Complex has a largely juvenile crustal signature. Zircon with Pampean, Famatinian and Braziliano ages (< 660 Ma) originated from recycled crust of variable age, which is, however, mainly Mesoproterozoic. By contrast, the Carboniferous magmatic event shows less variable and more radiogenic ¹⁷⁶Hf/¹⁷⁷Hf, pointing to a mean early Neoproterozoic crustal residence. This zircon is unlikely to have crystallized from melts of metasediments of the accretionary systems, but probably derived from a more juvenile crust in their backstop system.  相似文献   

Quick-look assessments to identify optimal CO2 EOR storage sites   总被引：1，自引：0，他引：1  

Vanessa Núñez-López  Mark H. Holtz  Derek J. Wood  William A. Ambrose  Susan D. Hovorka 《Environmental Geology》2008,54(8):1695-1706

A newly developed, multistage quick-look methodology allows for the efficient screening of an unmanageably large number of reservoirs to generate a workable set of sites that closely match the requirements for optimal CO₂ enhanced oil recovery (EOR) storage. The objective of the study is to quickly identify miscible CO₂ EOR candidates in areas that contain thousands of reservoirs and to estimate additional oil recovery and sequestration capacities of selected top options through dimensionless modeling and reservoir characterization. Quick-look assessments indicate that the CO₂ EOR resource potential along the US Gulf Coast is 4.7 billion barrels, and CO₂ sequestration capacity is 2.6 billion metric tons. In the first stage, oil reservoirs are screened and ranked in terms of technical and practical feasibility for miscible CO₂ EOR. The second stage provides quick estimates of CO₂ EOR potential and sequestration capacities. In the third stage, a dimensionless group model is applied to a selected set of sites to improve the estimates of oil recovery and storage potential using appropriate inputs for rock and fluid properties, disregarding reservoir architecture and sweep design. The fourth stage validates and refines the results by simulating flow in a model that describes the internal architecture and fluid distribution in the reservoir. The stated approach both saves time and allows more resources to be applied to the best candidate sites.  相似文献   

青藏高原北缘阿尔金走滑边界的侧向扩展——甘肃北山晚新生代走滑构造与地壳稳定性分析     

郭召杰  ;张志诚  ;张臣  ;刘畅  ;张宇  ;王驹  ;陈伟明 《中国区域地质》2008,(10):1678-1686

对北山地区遥感影像和野外地质特征的分析表明,自阿尔金断裂带向NW方向依次出露三危山-双塔断裂、大泉断裂和红柳河断裂。这些断裂近于平行,且同为左行走滑断裂,具有相似的展布特征,空间走向均为NE40-50°,断裂系末端均发育“树枝状”分支断层．在断层夹块之间形成“多米诺”构造,构成了北山地区主要的构造样式。断层谷地沉积物分析和断层泥ESR年代学测试结果表明,三危山-双塔断裂形成于上新世（N2k）,大泉断裂形成于早更新世（1．2-1．5Ma）．而北山地区分支断层和次级断层的活动在400ka之后。对北山地区断裂构造几何学和年代学的研究表明．阿尔金断裂系晚新生代以来向NW方向的侧向扩展．是阿尔金走滑边界重要的生长方式。北山地区特殊的走滑构造组合样式．使该地区的构造变形难于在某条断层上聚集能量,而分散在若干条次级断层上的位移量又微乎其微,该地区成为“最稳定的活动区”。  相似文献   

岩石破坏前后曲线分类及脆-延转换围压研究——蚀变岩常规三轴压缩试验Ⅰ   总被引：2，自引：0，他引：2  

杨根兰  黄润秋  蔡国军  付小敏  林锋  徐德敏 《岩土力学》2008,29(10):2759-2763

蚀变岩是工程中少见的软弱岩类,在西南某重大水电工程中,蚀变岩处于工程的重要部位,为保证工程的长期稳定性,对蚀变岩力学特性进行了深入全面的试验研究.通过对孔隙度不同的饱水蚀变岩进行系统的常规三轴压缩试验和总结分析,提出了蚀变岩三轴压缩下破坏前应力.应变曲线可分为3大类,破坏后应力-应变曲线亦可分为3大类的形态模式.并得出结论:蚀变岩的破坏类型受围压与孔隙度的共同影响,在给定的12 MPa围压下蚀变岩以脆性破坏为主,只有孔隙度大于16%且围压大于4 MPa时才有可能进入脆-延转换状态,且脆-延转换围压随孔隙度增加而降低,临界状态应力比随孔隙度增大而增加.  相似文献   

温度对不同大小墨西哥湾扇贝生长的影响   总被引：2，自引：0，他引：2  

刘志刚  王辉  栗志民  郑云龙 《热带海洋学报》2007,26(5):47-52

在8—32℃实验室控温范围内以2℃为梯度,以壳高及体重增长作为观察指标,研究3个规格墨西哥湾扇贝Argopecten irradians concentricus的适宜、较适宜及最适宜生长温度。研究结果表明,小苗(壳高6.2mm,体重48.3mg)、中苗(壳高18.1mm,体重1191.1mg)、大苗(壳高30.7mm,体重5809.9mg)在8—32℃水温下均能生长,但在水温8及32℃,3种规格增长率均较低;适宜生长温度分别为小苗11.2—31.1℃、中苗9.8—31.8℃、大苗9.8—32.4℃;较适宜生长温度分别为小苗18.1—29.4℃、中苗18.5—29.4℃、大苗16.9—30.4℃;3种苗随规格增大,适温范围扩大(p<0.01);最适生长温度3种苗均为24—28.0℃,其范围向高温端漂移;在水温为8℃时,3种苗存活率均达到97.0%以上,水温在32℃时则小苗为47.0%、中苗为67.5%、大苗为76.0%,表现出3种苗对低温有更强的忍耐力,大苗对高温有更强的适应性。  相似文献   

鱼生长激素在水产养殖中的应用   总被引：5，自引：0，他引：5  

潘登  双宝  陈荣忠  杨丰 《台湾海峡》2001,20(Z1):85-90

鱼生长激素是鱼类脑垂体中分泌的促进生长的单一亚基的蛋白激素.它参与鱼的生长代谢，能够加速蛋白质合成和脂类降解等生理功能.鱼生长激素能够大大地加快鱼类的生长，在鱼类的水产养殖领域有重大的应用价值，日益引起了人们的关注.现阶段鱼生长激素的应用研究主要集中在转生长激素基因鱼的育种和鱼生长激素的基因工程表达两个方面，且都取得了很大的进展.  相似文献   

珠江口东岸池养鲻鱼的年龄与生长     

李加儿  区又君  王仕宏  丁彦文  郑建民 《热带海洋学报》1996,(4)

研究池养条件下鲻鱼ＭｕｇｉｌｃｅｐｈａｌｕｓＬｉｎｎａｅｕｓ的年龄和生长特性，结果表明，鳞片新年轮主要在１０—１月出现；鳞长与体长关系式为：Ｒ—０．００９０７Ｌ（０．７７６４）；Ｉ—Ｖ龄鱼体长和体重相对生长率和生长指标随着年龄增长而逐渐下降；体长与体重关系式为：Ｗ＝１．２７１６×１０（－５）Ｌ（３．０６９５），体长与全长关系式为：ＬＴ＝１０．３７１１＋１．１８０６ＬＢ，当年鱼体长和体重生长与月龄的关系分别为：ＬＢ＝８．６６６９＋２５．５７６９ｔ，Ｗ＝０．１１７０ｔ（３．５５３０），ｖｏｎＢｅｒｔａｌｌａｎｆｆｙ生长参数Ｌ∞＝６１３．２５ｍｍ，Ｋ＝０．３４１２，ｔ０＝－０．８２５，体重生长拐点值为２．４６ａ。  相似文献   

斜带髭鲷幼鱼生长和生态转换效率的研究     

刘丽华  杨圣云  冯洁娉  陈明茹 《台湾海峡》2005,24(1):109-114

在实验室内, 22. 5±0. 5℃条件下以去头去骨去鳞片去皮的金色小沙丁鱼的纯肉糜为饵料饲养斜带髭鲷幼鱼,测定体重范围在 4. 6~6. 5g的斜带髭鲷的体重、体长的生长曲线及其生态转换效率和特定生长率.实验结果表明,斜带髭鲷的体重、体长在实验期间直线增长,体重、体长的生长曲线分别为Wt(w.w.湿重,下同 ) =0. 391 7t 5. 766 2(R=0. 999 6)和Lt=0. 105t 6. 265(R=0. 989 9).用胃含物法测定斜带髭鲷的胃排空率、日摄食量、日生长量、生态转换效率和特定生长率.实验得到斜带髭鲷消化道的瞬时排空率Rt= 1. 23 4×10-3 (m/m) /h,日摄食量Cd= 1. 342 9g(w.w. ),生态转换效率Eg=29. 50% ±2. 77% [m/m(w.w. ) ],特定生长率SGR=4. 71%±0. 69% [m/m(w.w. ) ].  相似文献   

Growth and gonad production of the sea urchin Hemicentrotus pulcherrimus in the fucoid bed and algal turf in northern Japan     

Yukio Agatsuma  Nobuyasu Nakabayashi  Nobuaki Miura  & Kazuya Taniguchi 《Marine Ecology》2005,26(2):100-109

To clarify the differences in the growth and gonad size of the sea urchin Hemicentrotus pulcherrimus among algal sere, the study was conducted in June and July, and September 1998 at three fucoid beds in Oga and at three algal turfs in Hachimori, Akita Prefecture in northern Japan. The most rapid growth was observed in a large perennial fucoid bed at the climax stage. Growth in a small perennial Chondrus ocellatus‐dominated bed in algal turfs in the seral stage was then high. The slowest growth was observed in the small perennial Dictyopteris divaricata‐ and Laurencia spp.‐dominated beds which are known to possess chemicals which act as feeding deterrents against the sea urchins. The gonad index (gonad wet weight × 100/body wet weight) at a fucoid bed was high where standing crops exceeded 3 kg·m^?2. The gonad index in the Laurencia bed was lower than those at fucoid beds. These results suggest that growth and gonad production are affected by algal sere and differ among species of small perennial algae in the seral stage with or without chemical defense.  相似文献