长江中下游六省大气甲烷柱浓度时空分布   总被引：2，自引：0，他引：2  

冯敏玉  张根  夏玲君  熊劦  李柏贞  孔萍  占明锦  张玉霞 《地球化学》2021,50(1):121-132

甲烷(CH4)是造成气候变暖的主要温室气体之一。为了了解长江中下游水稻种植区CH4浓度的分布情况,本次研究基于温室气体观测卫星(greenhouse gases observing satellite,GOSAT)和大气红外探测仪(atmospheric infrared sounder,AIRS)卫星反演的数据产品,对我国长江中下游六省大气CH4柱浓度的时空分布特征进行了研究。研究结果表明,由GOSAT反演的长江中下游六省大气CH4浓度呈逐年增长趋势,其年均浓度由2011年的1817×10^?9增长至2018年的1875×10^?9,高于东三省、华北平原和全国平均水平。区域平均年增长量为8.2×10^?9 a^?1。各省年际增长幅度略有差异,纬度偏低的江西、湖南和浙江三省大气CH4浓度高且增长量偏大,纬度偏高的湖北、安徽和江苏三省大气CH4浓度略低且增长量偏小。长江中下游六省大气CH4呈现较强的季节变化特征,湖北、湖南、江西和浙江峰值出现在9月,安徽、江苏峰值出现在8月。垂直方向上长江中下游六省CH4浓度随气压降低,浓度逐渐减小,呈现出明显的季节变化特征,近地面层GOSAT反演的最高值出现在夏季,最低值出现在春季;高层最高值出现在秋季,最低值出现在春季。AIRS反演的大气CH4浓度空间分布上北高南低,与GOSAT反演结果不一致,可能由于AIRS主要反映了对流层中层大气状况而GOSAT更多的反映了近地面层大气CH4的变化。其垂直方向上呈现高度越高,浓度越低,不同高度上秋季浓度均最高。  相似文献   

河南产宝石级高温高压合成钻石的谱学特征及电磁性研究     

杨池玉  陆太进  张健  宋中华  陈华  柯捷  何明跃 《岩矿测试》2021,(2):217-226

为快速鉴定高温高压(HPHT)合成钻石,前人已开展了系统的发光特征和谱学特征研究,但对比性分析较少,且对电学性质和磁学性质关注不多。本文结合常规宝石学观察、高精度谱学测试以及导电性和磁性测试,对49粒无色、黄色样品进行了深入研究和对比分析。结果表明:①铁、钴、镍等金属元素的触媒残余是HPHT合成钻石的磁性来源,测试样品均能被磁强达到12000Gs的磁棒吸引。②无色HPHT合成钻石为Ⅱa+Ⅱb型钻石,硼元素的存在导致其具有良好的导电能力,且随着硼含量的增多,导电能力逐渐增强;黄色样品为Ⅰb+ⅠaA型钻石,约三分之一的孤氮转化为A集合体,揭示合成钻石在生长完成后经过了高温退火处理。③硼元素的普遍存在,以及氮元素主要以孤氮原子和A集合体的方式存在,导致了HPHT合成钻石的特征红外光谱;HPHT合成钻石中常含有氮、镍、硅等杂质元素引起的晶格缺陷,导致了特征的光致发光光谱。④无色HPHT合成钻石具有强蓝绿色荧光和磷光,黄色HPHT合成钻石具有绿色荧光,可见明显的立方体-八面体分区现象。本研究表明:谱学特征和发光特征仍然是筛查鉴定HPHT合成钻石的重要依据。现生长技术下合成的HPHT合成钻石在导电性和磁性两方面也与天然钻石存在明显差异,可以作为快速鉴定合成钻石的辅助性依据。  相似文献   

Deformation patterns of upper Quaternary strata and their relation to active tectonics,Po Basin,Italy     

Alessandro Amorosi  Luigi Bruno  Bruno Campo  Bianca Costagli  Wan Hong  Vincenzo Picotti  Stefano Claudio Vaiani 《Sedimentology》2021,68(1):402-424

Despite increased application of subsurface datasets below the limits of seismic resolution, reconstructing near‐surface deformation of shallow key stratigraphic markers beneath modern alluvial and coastal plains through sediment core analysis has received little attention. Highly resolved stratigraphy of Upper Pleistocene to Holocene (Marine Isotope Stage 5e to Marine Isotope Stage 1) alluvial, deltaic and coastal depositional systems across the southern Po Plain, down to 150 m depth, provides an unambiguous documentation on the deformation of previously flat‐lying strata that goes back in time beyond the limits of morphological, historical and palaeoseismic records. Five prominent key horizons, accurately selected on the basis of their sedimentological characteristics and typified for their fossil content, were used as highly effective stratigraphic markers (M1 to M5) that can be tracked for tens of kilometres across the basin. A facies‐controlled approach tied to a robust chronology (102 radiocarbon dates) reveals considerable deformation of laterally extensive nearshore (M1), continental (M2 and M3) and lagoon (M4 and M5) marker beds originally deposited in a horizontal position (M1, M4 and M5). The areas where antiformal geometries are best observed are remarkably coincident with the axes of buried ramp anticlines, across which new seismic images reveal substantially warped stratal geometries of Lower Pleistocene strata. The striking spatial coincidence of fold crests with the epicentres of historic and instrumental seismicity suggests that deformation of marker beds M1 to M5 might reflect, in part at least, syntectonically generated relief and, thus, active tectonism. Precise identification and lateral tracing of chronologically constrained stratigraphic markers in the ¹⁴C time window through combined sedimentological and palaeoecological data may delineate late Quaternary subsurface stratigraphic architecture at an unprecedented level of detail, outlining cryptic stratal geometries at the sub‐seismic scale. This approach is highly reproducible in tectonically active Quaternary depositional systems and can help to assess patterns of active deformation in the subsurface of modern alluvial and coastal plains worldwide.  相似文献   

土壤中总有机碳环境标准样品研制     

王尧  田衎  封跃鹏  王伟 《岩矿测试》2021,(4):593-602

土壤环境标准样品是土壤生态环境监测质量控制的重要技术工具。目前,土壤中总有机碳环境标准样品仍为中国环境标准样品体系的空缺,特别是配套燃烧氧化-非分散红外法的土壤标准样品一直未曾问世。本文以有机碳含量较高的农用地土壤为原材料,经干燥、研磨、混匀、装瓶、灭菌等加工步骤,制备获得土壤中总有机碳环境标准样品。分层随机抽取10瓶样品进行均匀性检验,经评价统计量F小于临界值F_(0.05)(9,10),瓶间均匀性相对不确定度(u_(bb))为1.5%,样品均匀性良好。在室温避光保存条件下,对样品进行了18个月的稳定性检验,稳定性相对不确定度(u_(lts))为1.2%,样品具有良好稳定性。由中国11家实验室采用燃烧氧化-非分散红外法和重铬酸钾容量法进行协作定值,通过对检测结果的数理统计分析,样品量值评定结果为(25.2±1.4)mg/g。该标准样品为采用燃烧氧化-非分散红外法参与定值的土壤中总有机碳环境标准样品,可作为土壤中总有机碳测定标准方法配套的实物标准,满足土壤生态环境监测及相关研究需求,且与国外同类样品具有可比性。  相似文献   

热红外遥感技术在江西寻乌地区地热勘查中的应用     

任正情  方泓锦  王学平 《江苏地质》2021,45(3):277-282

热红外遥感是地热资源勘查中的常用技术,对江西寻乌地区的Landsat 8热红外影像采用单窗算法,根据MODIS影像计算大气水汽含量,并逐步获取反演参数,得到地表温度反演结果;利用MOD11_L2地表温度产品对结果进行对比分析,验证反演有效性。通过对已有地热资料和地质构造背景的研究,总结地热形成的有利构造条件,分析地表反演温度与已有地热及断裂构造之间的空间关系,建立地热异常区圈定依据,并剔除假异常,最终在研究区圈定了11个潜在地热异常区,为该区地热勘查提供依据。  相似文献   

短波红外光谱、X射线荧光光谱、黄铁矿热电性分析在胶东新城金矿田深部找矿中的应用     

邵雪维  彭永明  王功文  赵显勇  唐佳洋  黄蕾蕾  刘晓宁  赵宪东 《地学前缘》2021,28(3):236-251

胶东半岛是我国最重要的金矿集区之一,其矿床是典型受北东向断裂构造(焦家断裂带、三山岛断裂带和招平断裂带),以及次生断裂构造(如望儿山断裂和灵北断裂等)控制的矿床类型。前人在该区域做了大量研究,但主要集中在地表和浅层成矿段,对于深部成矿规律与预测的研究相对较少。新城金矿田是胶东半岛的特大型金矿之一,由新城矿床、曲家矿床和招贤矿床三部分组成。由于受到焦家断裂带控制,在招贤矿区中的科研深钻达到2 500 m以下,为我们研究深部成矿规律提供了良好的样品。本文通过该地区蚀变矿物的短波红外光谱特征(short-wave infrared spectroscopy,SWIR),并结合X 射线荧光光谱(X-ray fluorescence spectrometry,XRF)法和黄铁矿热电性法,选取该地的不同成矿阶段的蚀变岩石和典型载金矿物黄铁矿,并在三维环境中,定量化分析了主要的蚀变矿物——白云母族的短波红外光谱的特征值,揭示其找矿规律与指示意义,进一步提取矿床中蚀变矿物的找矿标志。研究结果表明:(1)在靠近焦家主断裂构造蚀变岩型矿体的位置,伊利石结晶度(≥1.2)和绢云母Al—OH吸收位置(≥2 205 nm)偏高,而在远离焦家主断裂构造蚀变岩型矿体的位置伊利石结晶度和绢云母Al—OH吸收位置偏低,分别为0.2~1.2和2 198~2 205 nm。(2)X 射线荧光光谱结果提取了该地区20种元素含量,通过对元素的主成分分析和聚类分析, Al—OH吸收峰位置偏移与Al、K、Si含量变化有一定相关性。(3)黄铁矿热电性导型在近焦家主断裂构造蚀变岩主要为P型,远离主断裂的主要为N型。在新城矿区的Ⅰ号和Ⅴ号矿体的顶部到底部整体呈现N-P→P→P-N→N→N-P→P-N和P-N→N-P的规律;在招贤矿区中绝大部分是P型。剥蚀度整体处于在25%~50%,因此在新城矿区约-800 m以下和招贤矿区约-1 500 m以下,仍有较好的深部找矿前景。整体上P型黄铁矿成矿温度主要为180~250 ℃,N型成矿温度主要区间值在380~460 ℃;利用温度场进行三维插值建模,其与三维矿体品位模型空间展布趋势一致。本文综合研究方法为深部矿产资源评价提供新的研究思路,将光谱数据、地化数据等多维度信息集成整合,同时使用三维模型可视化功能,对于矿产模型定量化构建具有重要参考价值。  相似文献   

An Operational Precipitable Water Vapor Retrieval Algorithm for Fengyun-2F/VISSR Using a Modified Three-Band Physical Split-Window Method     

Juyang HU  Shihao TANG  Hailei LIU  Min MIN 《Journal of Meteorological Research》2019,(2):276-288

The Visible and Infrared Spin-Scan Radiometer(VISSR) onboard the Fengyun-2(FY-2) satellite can provide valuable thermal infrared observations to help create a precipitable water vapor(PWV) product with high spatial and temporal resolutions. The current FY-2/VISSR PWV product in operation is produced by using a traditional two-band physical split-window(PSW) method, which produces low quality results under dry atmospheric conditions. Based on the sensitivity characteristics of FY-2 F/VISSR water vapor channel and two split-window channels to atmospheric water vapor, this study developed a new, robust operational PWV retrieval algorithm for FY-2 F to improve the operational precision of the current PWV product. The algorithm uses a modified three-band PSW method, which adds a scale for the water vapor channel in the improved three-band PSW method. Integrated PWV products from the radiosonde data in 2016 are used here to validate the precision of the PWV retrieved by the modified three-band and traditional two-band PSW methods. The mean bias, root mean square error(RMSE), and correlation coefficient of the PWV retrieved by the modified three-band PSW method are 0.28 mm, 4.53 mm, and 0.969, respectively. The accuracy is much better than the PWV retrieved by the two-band method, whose mean bias, RMSE, and correlation coefficient are 12.67 mm, 29.35 mm, and 0.23. Especially, in mid-or high-latitude regions, the RMSE of the PWV is improved from 10 to 2 mm by changing the inversion in the two-band method to the modified three-band PSW method. Furthermore, the modified three-band PSW results show a better consistency with the radiosonde PWV at any zonal belt and season than the two-band PSW results. This new algorithm could significantly improve the quality of the current FY-2 F/VISSR PWV product, especially at sites where the actual PWV are lower than 15 mm.  相似文献   

白天和夜间通用的卫星遥感沙尘判识算法构建与验证分析     

王威  胡秀清  张鹏  闵敏 《气象》2019,45(12):1666-1679

Himawari-8是日本发射的新一代静止气象卫星,与前一代的MTSAT-2相比,在时间、空间分辨率上都有了很大提升,特别是红外通道数量从4个增至10个,为红外遥感沙尘提供了新的观测数据。本研究利用Himawari-8的红外观测数据,发展了仅用红外通道的沙尘全天候判识算法,可以实现对白天和夜间的连续监测。算法在前人基础上去除了可见光通道,同时引入更多红外通道来进行云检测和沙尘判识。由于一日之中,地表温度发生变化,因此针对白天和夜间设置了两套不同的判别阈值,来保证算法的全天适用性。最后通过两次沙尘事件对沙尘判别结果的分析和检验表明,遥感判识结果与地面气象站和PM_(10)观测较为一致,说明了只用红外通道全天候判识沙尘的可行性。  相似文献   

Finite element modeling of heating phenomena of cracks excited by high-intensity ultrasonic pulses     

陈赵江  郑江  张淑仪  米小兵  郑凯 《海洋学报(英文版)》2010,29(11)

A three-dimensional thermo-mechanical coupled finite element model is built up to simulate the phenomena of dynamical contact and frictional heating of crack faces when the plate containing the crack is excited by high-intensity ultrasonic pulses. In the finite element model, the high-power ultrasonic transducer is modeled by using a piezoelectric thermal-analogy method, and the dynamical interaction between both crack faces is modeled using a contact-impact theory. In the simulations, the frictional heating taking place at the crack faces is quantitatively calculated by using finite element thermal-structural coupling analysis, especially, the influences of acoustic chaos to plate vibration and crack heating are calculated and analysed in detail. Meanwhile, the related ultrasonic infrared images are also obtained experimentally, and the theoretical simulation results are in agreement with that of the experiments. The results show that, by using the theoretical method, a good simulation of dynamic interaction and friction heating process of the crack faces under non-chaotic or chaotic sound excitation can be obtained.  相似文献   

波伏棱（Povlen）型羟基纤蛇纹石的谱学研究     

朱和宝  江绍英  邵涵如  吴卫芳 《岩石矿物学杂志》1989,8(1):43-53

波伏棱型羟基纤蛇纹石是波伏棱型纤蛇纹石矿物的新变种,本文报导它的吸收光谱、红外光谱、穆斯堡尔谱、电子顺磁共振谱和核磁共振谱。 研究表明,吸收光谱是Fe~(3 )和Fe~(2 )的晶场跃迁以及Fe~(2 )→Fe~(3 )的荷移跃迁引起的;红外光谱是OH和Si-O的伸缩振动、OH转动以及Mg-O和Si-O的弯曲振动引起的;穆斯堡尔谱是Fe~(2 )_(八面体)、Fe~(3 )_(八面体)和Fe~(3 )_(四面体)引起的;电子顺磁共振谱是Mn~(2 )_(八面体)、Fe~(3 )_(八面体)和Fe~(3 )_(四面体)引起的;核磁共振谱是管道水,镁八面体和硅氧四面体上的OH引起的;矿物加热到825℃时,结构开始破坏并出现镁橄榄石相。 此外,本文还解释了该蛇纹石颜色的本质,阐明了上述过渡金属离子和OH在该矿物中的结构环境。  相似文献