Determination of Lithium, Beryllium and Boron at Trace Levels by Laser Ablation-Inductively Coupled Plasma-Sector Field Mass Spectrometry   总被引：1，自引：2，他引：1  

Massimo Tiepolo  Alberto Zanetti  Riccardo Vannucci 《Geostandards and Geoanalytical Research》2005,29(2):211-224

The analytical capabilities of laser ablation (LA)-ICP-MS in determining Li, Be and B at trace levels in geological samples have been tested on a series of glass reference materials and natural samples. The LA-ICP-MS instrument used consisted of a sector-field ICP-MS coupled with a laser ablation microprobe operating at either 266 or 213 nm wavelength. Reference glasses from NIST (SRM 612, 614 and 616) and MPI-DING (KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, T1-G and ATHO-G) were selected to develop the analytical method and to assess the best instrumental configuration. A series of calcic amphiboles with different Li, Be and B concentrations were also analysed using both LA-ICP-MS and SIMS to test the applicability of the method to natural minerals. Results indicated that with a spot size of 40 μm the agreement between measured and reference values of Li, Be and B is generally better than 10% for NIST SRM 612 and 20% for NIST SRM 614. Average reproducibility at the 2s level was 10% for Li, 20% for Be and 15% for B. Limits of detection were approximately 100 ng g^-1 for Be and B and 200 ng g^-1 for Li. These results were confirmed by analyses carried out on natural amphiboles and compared well in terms of precision and accuracy with those commonly achieved by SIMS.  相似文献   

Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths   总被引：5，自引：1，他引：5  

Marcel Guillong  Kathrin Hametner  Eric Reusser  Stephen A. Wilson  Detlef Günther 《Geostandards and Geoanalytical Research》2005,29(3):315-331

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.  相似文献   

Microcrack networks in granite affected by a fault zone: Visualization by confocal laser scanning microscopy     

Celia T. Onishi  Ichiko Shimizu   《Journal of Structural Geology》2005,27(12):170

Microcracks in the Cretaceous Ryoke-type granite in Japan were investigated by using deep drilling core samples collected in the Mizunami Underground Research Project of the Japan Nuclear Cycle Development Institute (JNC). The granite body suffered brittle deformation associated with Tertiary thrust movement. Based on core-scale and microscopic deformation features, the drill core from a depth of 300 to 700 m is divided into four domains, i.e. (A) undeformed granite, (B) granite intruded by cataclastic seams, (C) fractured granite in the fault damage zone, and (D) foliated cataclasite at the fault center. To characterize microcrack geometries in each domain, we employed the impregnation method using a low-viscous acrylic resin doped with fluorescent agents and captured the microcrack images by confocal laser scanning microscopy (CLSM). The CLSM image in the fault damage zone revealed anisotropic development of microcrack networks related to the fault movement. Both CLSM observation and porosity measurements reveal a drastic increase of micro-pores in the foliated cataclasite, possibly caused by fragmentation, and granulation and crack sealing in the fault zone.  相似文献   

Intra-interstadial environmental changes in Last Glacial loess revealed by molluscan assemblages from the Upper Palaeolithic site of Amiens-Renancourt 1 (Somme,France)     

Olivier Moine  Pierre Antoine  Sylvie Coutard  Gilles Guérin  Christine Hatté  Clément Paris  Ségolène Saulnier-Copard 《第四纪科学杂志》2021,36(8):1322-1340

The Amiens-Renancourt 1 site recently yielded one of the most important Upper Palaeolithic human occupations of northern France by the number of flint artefacts and especially by the presence of Venus figurines. All the material comes from a single archaeological layer located in a tundra gley bracketed by loess units. A multi-proxy study combining a detailed stratigraphy, luminescence and radiocarbon datings and high-resolution (5 cm per sample) grain size and molluscan analyses was therefore carried out to reconstruct and date the associated environmental changes and to determine the exact context of the human occupation. The chronological frame thus established supports the correlations of the archaeology-bearing tundra gley and of an underlying arctic brown soil with Greenland interstadials GI-4 and GI-3. Composition changes in the molluscan population enabled the identification of transitional and optimum phases and sub-phases within these two pedogenetic horizons. A conceptual correlation model linking molluscan phases with millennial-scale variations of Greenland ice-core and Sieben Hengste speleothem climate records is proposed. The Human occupation appears contemporaneous to the end of the stadial–interstadial transition of GI-3. Synchronous in Amiens-Renancourt 1 and Nussloch, subsequent micro-gleys may also result from a regional/global forcing. Such a level of detail is unprecedented in a loess sequence.  相似文献   

利用3S技术及三维激光扫描仪进行耕地损毁勘测     

林学艺 《测绘与空间地理信息》2016,(2):88-90

利用RS技术发现耕地损毁,网络RTK测量耕地损毁范围及面积,GIS提取耕地被损毁前的分类面积和等别,以及利用网络RTK配合Maptek I-Site8810三维激光扫描仪重构损毁耕地三维模型。  相似文献   

地面三维激光扫描仪测量误差检定     

代志宇  肖昭然  王力  杨文峰 《测绘与空间地理信息》2016,(7):79-81

在利用三维激光扫描仪进行测量工作前,我们首先应了解其实际测量精度是否符合标称精度,而可靠的评价方式对得到精确的数据结果至关重要。本文利用北京卓立汉光TSA50-C型电动位移台作为评价标准,通过其精确的位移功能,准确地评价了RIGEL VZ-400三维激光扫描仪在测量单点位移时的误差,从而得到了其最佳工作距离。  相似文献   

三维激光扫描技术在曲面模型重建中的应用     

杨忞婧  刘丽  张金兰  王阳 《测绘与空间地理信息》2016,(8)

利用地面三维激光扫描仪对目标物体表面进行多方位、多角度的扫描,可以获取其表面大量且密集的高精度点的三维坐标信息以及反射率信息,将这些信息存储到电脑中,使用专业软件进行处理,再使用建模软件生成建筑物的三维模型。本文所研究的是使用地面三维激光扫描仪,通过高速激光测量方式,快速、全面、精确地获取建筑物表面的三维信息,经过一系列的点云数据处理及模型处理,最终完成曲面模型三维重建的过程。  相似文献   

浅析运营期间电力隧道自动化监测技术     

罗静  卢凌燕  任卫波  许业霞 《测绘与空间地理信息》2016,(8):204-206

针对城市电力隧道结构、走向多变、电缆设施多、电磁干扰大等因素,常规的监测方法难以顺利完成的现状,对目前先进的3种隧道结构自动化监测系统进行深入的研究比较,光纤传感自动技术解决了电力隧道结构监测点布设困难,数据受电磁干扰大的问题,能实时有效、可靠、高精度地监控电力隧道,及时掌握隧道的应力、应变及振动等主要结构参数,确保隧道结构安全。研究对类似的城市电力隧道自动化监测具有一定的参考意义。  相似文献   

基于3D激光扫描的变形监测技术研究     

王士玉  耿奕超 《测绘与空间地理信息》2016,(6):180-181

传统基于GPS和全站仪的地表变形监测手段由于监测点少,难以对滑坡体进行整体监测,本文提出基于点云所成模型间比较的变形信息提取方法,结合试验验证了算法的效果。结果表明,地面三维激光扫描技术应用于变形监测领域是完全可行的,虽然其在测量精度上略低于GPS、全站仪等传统监测手段,但对大范围区域快速、连续、全方位监测的优势是其他监测手段所不具备的。  相似文献   

Retrieval of effective leaf area index (LAIe) and leaf area density (LAD) profile at individual tree level using high density multi-return airborne LiDAR     

《International Journal of Applied Earth Observation and Geoinformation》2016

As an important canopy structure indicator, leaf area index (LAI) proved to be of considerable implications for forest ecosystem and ecological studies, and efficient techniques for accurate LAI acquisitions have long been highlighted. Airborne light detection and ranging (LiDAR), often termed as airborne laser scanning (ALS), once was extensively investigated for this task but showed limited performance due to its low sampling density. Now, ALS systems exhibit more competing capacities such as high density and multi-return sampling, and hence, people began to ask the questions like—“can ALS now work better on the task of LAI prediction?” As a re-examination, this study investigated the feasibility of LAI retrievals at the individual tree level based on high density and multi-return ALS, by directly considering the vertical distributions of laser points lying within each tree crown instead of by proposing feature variables such as quantiles involving laser point distribution modes at the plot level. The examination was operated in the case of four tree species (i.e. Picea abies, Pinus sylvestris, Populus tremula and Quercus robur) in a mixed forest, with their LAI-related reference data collected by using static terrestrial laser scanning (TLS). In light of the differences between ALS- and TLS-based LAI characterizations, the methods of voxelization of 3D scattered laser points, effective LAI (LAIe) that does not distinguish branches from canopies and unified cumulative LAI (ucLAI) that is often used to characterize the vertical profiles of crown leaf area densities (LADs) was used; then, the relationships between the ALS- and TLS-derived LAIes were determined, and so did ucLAIs. Tests indicated that the tree-level LAIes for the four tree species can be estimated based on the used airborne LiDAR (R² = 0.07, 0.26, 0.43 and 0.21, respectively) and their ucLAIs can also be derived. Overall, this study has validated the usage of the contemporary high density multi-return airborne LiDARs for LAIe and LAD profile retrievals at the individual tree level, and the contribution are of high potential for advancing forest ecosystem modeling and ecological understanding.  相似文献