催化光度法测定痕量锇   总被引：3，自引：0，他引：3  

唐宁莉  唐建洪 《岩矿测试》1996,15(4):283-285

在０５ｍｏｌ／Ｌ的Ｈ２ＳＯ４介质中，Ａｓ（Ⅲ）存在下，Ｏｓ（Ⅷ）催化ＫＣｌＯ３氧化邻苯二酚紫褪色反应。反应受温度、反应时间影响，冷却及加入抗坏血酸可终止反应。据此，建立了一个测定痕量Ｏｓ（Ⅷ）的新方法。方法的灵敏度为２５７×１０－１０ｇ／ＬＯｓ（Ⅷ），测定范围为０～００９１μｇ／Ｌ，用地质管理样中锇的测定验证，结果与原结果相符  相似文献   

催化褪色光度法测定痕量锰的研究及应用   总被引：2，自引：0，他引：2  

康文  周发连 《华东地质学院学报》1997,20(2):141-146

本研究了在ＰＨ＝４．０醋酸－醋酸钠缓冲溶液中，锰催化ＫＩＯ４氧化５－Ｂｒ－ＰＡＤＡＰ的褪色反应及其动力学条件，建立了一个痕量锰的高灵敏度新方法，方法灵敏度为１．３２×１０＾－１０ｇ／ｍｌ，测定范围Ｍｎ＾２＋浓度为０￣１．５μｇ／ｍｌ，用于测定人发，自来水，茶叶中痕量锰，结果满意。  相似文献   

A Modeling Study of the Effects of Anomalous Snow Cover over the Tibetan Plateau upon the South Asian Summer Monsoon   总被引：1，自引：0，他引：1  

刘华强  孙照渤王举 闵锦忠 《大气科学进展》2004,21(6):964-975

The effect of anomalous snow cover over the Tibetan Plateau upon the South Asian summer monsoon is investigated by numerical simulations using the NCAR regional climate model (RegCM2) into which gravity wave drag has been introduced. The simulations adopt relatively realistic snow mass forcings based on Scanning Multi-channel Microwave Radiometer (SNINIR) pentad snow depth data. The physical mechanism and spatial structure of the sensitivity of the South Asian early summer monsoon to snow cover anomaly over the Tibetan Plateau are revealed. The main results are summarized as follows. The heavier than normal snow cover over the Plateau can obviously reduce the shortwave radiation absorbed by surface through the albedo effect, which is compensated by weaker upward sensible heat flux associated with colder surface temperature, whereas the effects of snow melting and evaporation are relatively smaller.The anomalies of surface heat fluxes can last until June and become unobvious in July. The decrease of the Plateau surface temperature caused by heavier snow cover reaches its maximum value from late April to early May. The atmospheric cooling in the mid-upper troposphere over the Plateau and its surrounding areas is most obvious in May and can keep a fairly strong intensity in June. In contrast, there is warming to the south of the Plateau in the mid-lower troposphere from April to June with a maximum value in May.The heavier snow cover over the Plateau can reduce the intensity of the South Asian summer monsoon and rainfall to some extent, but this influence is only obvious in early summer and almost disappears in later stages.  相似文献   

用工程化方法进行GPS大地测量质量管理     

郑广伟王俊勤  王宗伟贾国宪 《测绘科学与工程》2004,24(2):45-46,61

传统的GPS大地测量质量管理，一般采取作业完成后检查修正的方法。本文提出用工程化管理的方法，定义各个阶段的工作任务，给出作业过程质量管理的参考框架，以提高作业过程的可靠度，确保最后成果的质量。  相似文献   

利用屏幕截取技术制作人降作业炮点环境示意图     

黄晓辉 《气象研究与应用》2004,25(4):41-43

介绍利用屏幕截取技术制作人降作业炮点四周环境坐标示意图的方法。  相似文献   

曲靖市冰雹云雷达回波特征及防雹     

王涛  李静  詹继锋 《云南地理环境研究》2004,(Z1)

本文通过对曲靖市711B数字化雷达冰雹云回波特征进行分析,总结2002年～2003年曲靖市防雹工作3年取得的经验,以期提高县级防雹指挥人员雷达回波分析能力和作业指挥能力,在防雹作业中科学的安排防雹炮弹的使用量。  相似文献   

地形可视化的进展与评述   总被引：4，自引：0，他引：4  

詹发新 《四川测绘》2004,27(2):58-61

地形可视化由于具有越来越广泛的用途，因此越来越多地引起了大家的关注。本文在简要论述科学可视化、地形可视化定义及其研究内容的基础上，着重讨论了当前地形可视化的表达手段、可视化建模与技术、可视化生成工具、实时地形生成等方面的研究现状及存在的问题，最后对可视化的应用前景和发展趋势进行了展望。  相似文献   

人工影响天气作业炮弹不发火的原因及处理     

李定才 《河南气象》2005,(4):8-8

若遇人工影响天气高炮射击不发火时,首先关闭保险,打高炮身,人员撤离炮位.一般情况下,至少停3分钟,以防膛内炮弹迟发火而出意外.待观察确无险情后,再退出压弹机内的炮弹.然后,进一步确定炮膛内究竟是不发火的炮弹,还是没有退出的药筒.具体方法为：将洗把杆连接好,使其紧贴并平行于身管.再从身管后端面向前量出一发炮弹的长度,并做一标记.  相似文献   

Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China     

马安来张水昌  张大江金之钧马晓娟  陈清棠 《中国地球化学学报》2005,24(1):28-36

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.  相似文献   

Biomineralization of Uranium: A Simulated Experiment and Its Significance   总被引：5，自引：0，他引：5  

L. L. BARTON  H. WIATROWSKI 《《地质学报》英文版》2005,79(1):134-138

A simulated experimental reduction of U^v1 and the synthesis of uraninite by a sulfate-reducing bacteria,Desulfovibrio desulfuricans DSM 642, are first reported. The simulated physicochemical experimental conditions were:35℃, pH=7.0-7.4, corresponding to the environments of formation of the sandstone-hosted interlayer oxidation-zone type uranium deposits in Xinjiang, NW China. Uraninite was formed on the surface of the host bacteria after a one-week‘s incubation. Therefore, sulfate-reducing bacteria, which existed extensively in Jurassic sandstone-producing environments,might have participated in the biomineralization of this uranium deposit. There is an important difference in the orderdisorder of the crystalline structure between the uraninite produced by Desulfovibrio desulfuricans and naturally occurring uraninite. Long time and slow precipitation and growth of uraninite in the geological environment might have resulted in larger uraninite crystals, with uraninite nanocrystals arranged in order, whereas the experimentally produced uraninite is composed of unordered uraninite nanocrystals which, in contrast, result from the short time span of formation and rapid precipitation and growth of uraninite. The discovery has important implications for understanding genetic significance in mineralogy, and also indicates that in-situ bioremediation of U-contaminated environments and use of biotechnology in the treatment of radioactive liquid waste is being contemplated.  相似文献