Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China     

马安来张水昌  张大江金之钧马晓娟  陈清棠 《中国地球化学学报》2005,24(1):28-36

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.  相似文献   

小动力旋挖钻机用嵌岩短螺旋钻头结构形式的改进          下载免费PDF全文

刘南昌  胡继良  黄玉文  翁炜  张宏智 《探矿工程》2005,32(2):43-43,46

采用小动力无加压旋挖钻机在粒径较大的卵砾石地层和泥页岩地层中进行1500 mm以上大口径钻孔灌注桩施工，由于钻机动力小且不能加压，用常规嵌岩短螺旋钻头钻进出现进尺慢或不进尺现象。通过对河南西峡县宛西制药责任有限公司新厂房桩孔施工过程中出现此种现象的分析和处理，提出了嵌岩短螺旋钻头针对性的改进措施，并取得了良好效果。  相似文献   

湿式旋挖工法中埋钻事故的处理          下载免费PDF全文

谭现锋  朱学顺 《探矿工程》2005,32(10):26-27

介绍了在静态泥浆护壁的湿式旋挖工法中出现的埋钻事故的处理工艺以及在使用湿式旋挖工法中出现的一些实际问题的处理办法。  相似文献   

旋挖钻机掉钻的原因分析及预防处理          下载免费PDF全文

李海发 《探矿工程》2005,32(5):29-30

总结分析了旋挖钻机在施工中掉钻的各种原因，详述了其预防措施和处理方法。  相似文献   

Water soluble components of PM10 Chongqing, China   总被引：1，自引：0，他引：1  

Luo Qingquan  Xian Xuefu  Chen Gangcai  Yang Qinglin 《中国地球化学学报》2005,24(2):155-157

The concentrations of water soluble ions (Na⁺, NH₄ ⁺, K⁺, Mg²⁺, Ca²⁺, NO₃ ^-, Cl^-, and SO ₄ ^2- ) in PM₁₀ samples collected on cellulose filters by a medium-volume cascade impactor were determined, which were obtained from three kinds of areas in Chongqing: industrial area (Jiulongpo district), commercial and residential area (Jiangbei district) and background area (Jinyun Mountain in the Beibei district). The results showed that except for the background site, the annual average values of PM₁₀ are 23% – 61% higher than the national air quality standard (GradeII) (0.1 mg/m³), even that the value of the control site is still 20% higher than American standard (0.05 mg/m³). This implied that serious pollution of fine particles occurred in Chongqing. Nine kinds of soluble ions in water of PM₁₀ were analyzed by ion chromatography (IC) and the annual average concentrations follow the order of [SO ₄ ^2- ] > [NO³ _-] > [Cl^-] > [F^-], and [Ca²⁺] > [NH₄ ⁺] > [K⁺] > [Na⁺] > [Mg²⁺]. Their values were different in these areas: the industrial area > the commercial and living area > the control area. As for NH_{4 +}, K⁺, Ca²⁺, NO₃ ^- and SO ₄ ^2- , their seasonal average concentrations show a similar variation trend: the values in spring and fall were higher than those in summer and winter. The seasonal average concentrations of [Cl^-], [F^-], [Na⁺] and [Mg²⁺] are much lower than those of other ions. However, the concentrations of [Na⁺] changed more greatly in different seasons than those of the other three ions. Correlation coefficients showed that the three areas have been polluted by coal smoke and dust to different extents, while some local resources of pollution should be taken into consideration as well.  相似文献   

浓硫酸钠水溶液中的离子对          下载免费PDF全文

刘元会  房春晖 《盐湖研究》2005,13(4):42-46

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。  相似文献   

肾实证现代文献研究概况          下载免费PDF全文

吴玲  程孟祺  杨梦婷 《应用海洋学学报》2019,35(5):174-176

  相似文献   

基于冲任督三脉探析前列腺癌病机规律          下载免费PDF全文

保卫东  姚德蛟  蔡懿 《应用海洋学学报》2018,34(11):113-114

冲任督三脉属于人体“奇经八脉”系统，冲任督一源三歧共同源自男子胞而前列腺癌病位在男子胞，故前列腺癌发病及病证与冲任督三脉关系密切。老年男子“冲脉衰少”的生理基础状态，加之后天调摄不当，水不涵木，土壅木郁，木郁土虚，先后天不资，是前列腺癌发病的关键。病理产物堆积于男子胞，使前列腺癌表现出独特的任、督病证，“任督涩滞，经脉虚损”是其主要病证特点。上述关于前列腺癌病机中对冲脉的干预和任督病证的预知符合“治未病”的理念，为中医学认识、防治前列腺癌提供了新思路。  相似文献   

基于支持向量机的GNSS时间序列预测          下载免费PDF全文

邓永春  徐跃  徐丹丹  贾雪  田先才 《全球定位系统》2019,44(2):70-75

在深度学习的理论框架下,针对预测全球卫星导航系统(GNSS)时间序列,传统的经验风险最小化预测模型误差大精度低,泛化性能差且对历史数据的经验依赖大的问题.提出一种采用结构风险最小化原则的基于支持向量机(SVM)的时间序列预测模型．通过和多层的BP神经网络预测模型预测效果比较,结果证明SVM预测模型拥有更好的时间序列预测效果．   相似文献   

从虚邪痰瘀浅谈类风湿性关节炎          下载免费PDF全文

解泽文  付新利 《应用海洋学学报》2019,35(7):117-118

中医学认为，类风湿性关节炎的病机为正气不足，肝脾肾亏虚。其病因为受风、寒、湿、热等邪侵袭，内外合邪，气血不畅，痰浊瘀血闭阻经络、筋脉、骨节所致。痰瘀是病理因素，虚邪是痰瘀形成的病理基础。从虚、邪、痰、瘀4个方面治疗类风湿关节炎可获较好疗效。  相似文献