Mineral inclusions recovered from 100 diamonds from the A154 South kimberlite (Diavik Diamond Mines, Central Slave Craton, Canada) indicate largely peridotitic diamond sources (83%), with a minor (12%) eclogitic component. Inclusions of ferropericlase (4%) and diamond in diamond (1%) represent “undetermined” parageneses.
Compared to inclusions in diamonds from the Kaapvaal Craton, overall higher CaO contents (2.6 to 6.0 wt.%) of harzburgitic garnets and lower Mg-numbers (90.6 to 93.6) of olivines indicate diamond formation in a chemically less depleted environment. Peridotitic diamonds at A154 South formed in an exceptionally Zn-rich environment, with olivine inclusions containing more than twice the value (of 52 ppm) established for normal mantle olivine. Harzburgitic garnet inclusions generally have sinusoidal rare earth element (REEN) patterns, enriched in LREE and depleted in HREE. A single analyzed lherzolitic garnet is re-enriched in middle to heavy REE resulting in a “normal” REEN pattern. Two of the harzburgitic garnets have “transitional” REEN patterns, broadly similar to that of the lherzolitic garnet. Eclogitic garnet inclusions have normal REEN patterns similar to eclogitic garnets worldwide but at lower REE concentrations.
Carbon isotopic values (δ13C) range from − 10.5‰ to + 0.7‰, with 94% of diamonds falling between − 6.3‰ and − 4.0‰. Nitrogen concentrations range from below detection (< 10 ppm) to 3800 ppm and aggregation states cover the entire spectrum from poorly aggregated (Type IaA) to fully aggregated (Type IaB). Diamonds without evidence of previous plastic deformation (which may have accelerated nitrogen aggregation) typically have < 25% of their nitrogen in the fully aggregated B-centres. Assuming diamond formation beneath the Central Slave to have occurred in the Archean [Westerlund, K.J., Shirey, S.B., Richardson, S.H., Gurney, J.J., Harris, J.W., 2003b. Re–Os systematics of diamond inclusion sulfides from the Panda kimberlite, Slave craton. VIIIth International Kimberlite Conference, Victoria, Canada, Extended Abstracts, 5p.], such low aggregation states indicate mantle residence at fairly low temperatures (< 1100 °C). Geothermometry based on non-touching inclusion pairs, however, indicates diamond formation at temperatures around 1200 °C. To reconcile inclusion and nitrogen based temperature estimates, cooling by about 100–200 °C shortly after diamond formation is required. 相似文献
Large earthquakes along the Kuril subduction zone in northern Japan are known to have caused damaging tsunami, although there is a little information on historical earthquakes and tsunami in this area because no documents exist before the 19th century that might refer to tsunami events. To determine the likely timing and size of future events we need information on their recurrence intervals and to do this for the prehistoric past we have investigated sediments located in the Kiritappu marsh in eastern Hokaido that we interpret as laid down by tsunami. Using reliable multiple lines of evidence from sedimentological, geomorphological, micropaleontological, and chronological results, we identify 13 tsunami sands. Two of these lie within a peat bed above a historical tephra, Ta-a (AD 1739); the upper one probably corresponds to the AD 1843 Tempo Tokachi-oki earthquake (M 8.2) tsunami, and the lower to either the AD 1952 Tokachi-oki earthquake (M 8.2) tsunami or the AD 1960 Chilean earthquake (M 9.5) tsunami. Underlying are 11 prehistoric tsunami sand beds (nine large sand beds and two smaller sand beds) deposited during the past 4000 years. Because of the wide spatial distribution of the large sand beds, and inundation distances inland of between 1200 to 3000 m, we suggest that they record unusually large tsunamis along the Kuril subduction zone. According to our analyses, these tsunami sands were derived from the coastal area and, although they do not show clear graded bedding, they commonly have gradational upper boundaries and erosional bases and include internal sedimentary structures such as plane beds, dunes, and current ripples, reflecting bedload transportation. Based on our results we calculate the recurrence interval of unusually large earthquakes (probably M 8.6) along the Kuril subduction zone as about 365–553 years and estimate the youngest large event to have occurred in the 17th century. 相似文献
Holocene environmental changes in the northern Fertile Crescent remain poorly understood because of the scarcity of local proxy records in the region. In this study we investigated pedogenic (soil-formed) carbonate coatings on stones at the Pre-Pottery Neolithic site Göbekli Tepe as an indicator of local early-mid Holocene environmental changes. The 14C ages and stable isotopic composition of carbon and oxygen in thin (0.2–0.3 mm thick) pedogenic carbonate lamina indicate two main periods of coating formation: the early-Holocene (ca. 10000–6000 cal yr BP) and the mid-Holocene (ca. 6000–4000 cal yr BP). During the first period, there was an inverse relationship between δ13C and δ18O curves: a decrease in δ13C values coincide with an increase in δ18O values. For this period a trend towards higher temperatures is suggested. In the mid-Holocene, the mean rate of coating growth was 2–3 times higher than in the early Holocene. Both δ13C and δ18O reached their maximum values during this time and the direction of changes of the δ13C and δ18O curves became similar. The combination of data suggests that this period was the most humid in the Holocene and on average warmer than the early Holocene. At ca. 4000 cal yr BP secondary accumulation of carbonate ceased, presumably reflecting a shift to a more arid climate. 相似文献
